DE1916886C3 - Verfahren zur Herstellung von Rohrzuckerestern von Fettsäuren durch Umesterung - Google Patents
Verfahren zur Herstellung von Rohrzuckerestern von Fettsäuren durch UmesterungInfo
- Publication number
- DE1916886C3 DE1916886C3 DE1916886A DE1916886A DE1916886C3 DE 1916886 C3 DE1916886 C3 DE 1916886C3 DE 1916886 A DE1916886 A DE 1916886A DE 1916886 A DE1916886 A DE 1916886A DE 1916886 C3 DE1916886 C3 DE 1916886C3
- Authority
- DE
- Germany
- Prior art keywords
- cane sugar
- water
- emulsion
- reaction
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical class O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 title claims description 53
- 235000014113 dietary fatty acids Nutrition 0.000 title claims description 20
- 229930195729 fatty acid Natural products 0.000 title claims description 20
- 239000000194 fatty acid Substances 0.000 title claims description 20
- 238000000034 method Methods 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 230000008569 process Effects 0.000 title claims description 12
- 150000004665 fatty acids Chemical class 0.000 title claims description 7
- 238000005809 transesterification reaction Methods 0.000 title claims description 4
- 239000000839 emulsion Substances 0.000 claims description 51
- 229930006000 Sucrose Natural products 0.000 claims description 47
- 229960004793 sucrose Drugs 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000003995 emulsifying agent Substances 0.000 claims description 28
- -1 fatty acid ester Chemical class 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 28
- 239000000376 reactant Substances 0.000 description 23
- 239000007795 chemical reaction product Substances 0.000 description 18
- 150000002148 esters Chemical class 0.000 description 15
- 239000012071 phase Substances 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000002904 solvent Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 6
- 239000004530 micro-emulsion Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- 239000000693 micelle Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001348 alkyl chlorides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- SQEDZTDNVYVPQL-UHFFFAOYSA-N dodecylbenzene;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1 SQEDZTDNVYVPQL-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000008384 inner phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002943 palmitic acids Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 238000004809 thin layer chromatography Methods 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
- C07H13/06—Fatty acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
- C07C59/10—Polyhydroxy carboxylic acids
- C07C59/105—Polyhydroxy carboxylic acids having five or more carbon atoms, e.g. aldonic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/34—Higher-molecular-weight carboxylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79479369A | 1969-01-28 | 1969-01-28 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1916886A1 DE1916886A1 (de) | 1970-07-30 |
| DE1916886B2 DE1916886B2 (de) | 1978-07-06 |
| DE1916886C3 true DE1916886C3 (de) | 1984-02-16 |
Family
ID=25163701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1916886A Expired DE1916886C3 (de) | 1969-01-28 | 1969-04-02 | Verfahren zur Herstellung von Rohrzuckerestern von Fettsäuren durch Umesterung |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3644333A (enExample) |
| JP (1) | JPS5031121B1 (enExample) |
| BE (1) | BE742318A (enExample) |
| DE (1) | DE1916886C3 (enExample) |
| ES (1) | ES375962A1 (enExample) |
| FR (1) | FR2029508A6 (enExample) |
| GB (1) | GB1286838A (enExample) |
| NL (1) | NL165468C (enExample) |
| SE (1) | SE353526B (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50142507A (enExample) * | 1974-05-02 | 1975-11-17 | ||
| JPS5917120B2 (ja) * | 1974-10-02 | 1984-04-19 | ユニチカ株式会社 | シヨ糖エステルの製造方法 |
| FR2463152A1 (fr) * | 1979-08-16 | 1981-02-20 | Rhone Poulenc Ind | Procede de preparation de sucroglycerides |
| US4571306A (en) * | 1984-04-26 | 1986-02-18 | A. E. Staley Manufacturing Company | Separation of lipophilic components from solutions by adsorption |
| NL8601904A (nl) * | 1986-07-23 | 1988-02-16 | Unilever Nv | Werkwijze voor de bereiding van polyol-vetzuurpolyesters. |
| US4950743A (en) * | 1987-07-29 | 1990-08-21 | Henkel Kommanditgesellschaft Auf Aktien | Process for preparation of alkylglycosides |
| DE3889084T2 (de) * | 1987-12-11 | 1994-08-11 | Unilever Nv | Verfahren zur Herstellung von Polyol-Fettsäureester. |
| US4927920A (en) * | 1988-11-15 | 1990-05-22 | Nebraska Department Of Economic Development, State Of Nebraska, U.S.A. | Sugar ester synthesis |
| US4983731A (en) * | 1989-03-17 | 1991-01-08 | Nebraska Department Of Economic Development | Separation and purification of sugar esters |
| JP3242649B2 (ja) * | 1990-09-11 | 2001-12-25 | ザ、プロクター、エンド、ギャンブル、カンパニー | ポリオールポリエステルの合成 |
| BR9205872A (pt) * | 1991-04-12 | 1994-09-27 | Procter & Gamble | Processo para aperfeiçoar a estabilidade oxidativade poliésteres de acido graxo poliol. |
| US5585506A (en) * | 1994-07-22 | 1996-12-17 | Lonza Inc. | One phase production of polyglycerol esters |
| US5756716A (en) * | 1995-06-07 | 1998-05-26 | Kimball Chase Tech. Ltd. | Sugar-ester manufacturing process |
| US6121440A (en) * | 1998-01-29 | 2000-09-19 | The Procter & Gamble Company | Process for synthesis of polyol fatty acid polyesters |
| US20040063928A1 (en) * | 2001-01-18 | 2004-04-01 | Jo In-Ho | Preparation of aliphatic acid ester of carbohydrate |
| US10210216B2 (en) * | 2009-12-18 | 2019-02-19 | Sybase, Inc. | Dynamic attributes for mobile business objects |
| CN103037708B (zh) * | 2010-03-23 | 2015-05-20 | 维尔恩公司 | 含有蔗糖脂肪酸酯的纳米乳液 |
| WO2011162802A1 (en) | 2010-06-21 | 2011-12-29 | Virun, Inc. | Compositions containing non-polar compounds |
| CN102863480A (zh) * | 2012-09-24 | 2013-01-09 | 广西工学院 | 水力空化合成蔗糖酯的方法 |
| US9351517B2 (en) | 2013-03-15 | 2016-05-31 | Virun, Inc. | Formulations of water-soluble derivatives of vitamin E and compositions containing same |
| AU2014235283B2 (en) | 2013-03-15 | 2017-06-01 | Virun, Inc. | Formulations of water-soluble derivatives of vitamin E and compositions containing same |
| JP5753600B1 (ja) | 2014-02-14 | 2015-07-22 | マイクロ波化学株式会社 | 有機化合物の製造方法、及びエステルの製造方法 |
| WO2016044805A1 (en) | 2014-09-18 | 2016-03-24 | Virun, Inc. | Soft gel compositions and pre-gel concentrates |
| US10016363B2 (en) | 2014-09-18 | 2018-07-10 | Virun, Inc. | Pre-spray emulsions and powders containing non-polar compounds |
| US9861611B2 (en) | 2014-09-18 | 2018-01-09 | Virun, Inc. | Formulations of water-soluble derivatives of vitamin E and soft gel compositions, concentrates and powders containing same |
| WO2018174938A1 (en) | 2017-03-23 | 2018-09-27 | Virun, Inc. | Stable dry powders and emulsions containing probiotics and mucoadhesive protein |
| CN117241878A (zh) | 2021-03-05 | 2023-12-15 | 伊努梅里斯公司 | 用于生成微滴和执行数字分析的系统和方法 |
| EP4351788A4 (en) | 2021-06-04 | 2025-04-09 | Enumerix, Inc. | COMPOSITIONS, METHODS AND SYSTEMS FOR SINGLE-CELL ENCODING AND SEQUENCING |
| US12252745B2 (en) | 2021-09-02 | 2025-03-18 | Enumerix, Inc. | Detection and digital quantitation of multiple targets |
| EP4453246A1 (en) | 2021-12-20 | 2024-10-30 | Enumerix, Inc. | Detection and digital quantitation of multiple targets |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2948717A (en) * | 1959-01-14 | 1960-08-09 | Drew & Co Inc E F | Sugar ester preparation and purification |
| FR1433567A (fr) * | 1964-02-19 | 1966-04-01 | Henkel & Cie Gmbh | Procédé d'addition de bisulfite à des composés contenant des doubles liaisons |
-
1969
- 1969-01-28 US US794793*A patent/US3644333A/en not_active Expired - Lifetime
- 1969-02-14 JP JP44011411A patent/JPS5031121B1/ja active Pending
- 1969-04-02 DE DE1916886A patent/DE1916886C3/de not_active Expired
- 1969-04-03 SE SE04854/69A patent/SE353526B/xx unknown
- 1969-04-24 NL NL6906336.A patent/NL165468C/xx not_active IP Right Cessation
- 1969-05-12 FR FR6915314A patent/FR2029508A6/fr not_active Expired
- 1969-10-29 GB GB53011/69A patent/GB1286838A/en not_active Expired
- 1969-11-27 BE BE742318D patent/BE742318A/xx unknown
-
1970
- 1970-01-28 ES ES375962A patent/ES375962A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1916886A1 (de) | 1970-07-30 |
| NL165468B (nl) | 1980-11-17 |
| FR2029508A6 (enExample) | 1970-10-23 |
| BE742318A (enExample) | 1970-05-04 |
| ES375962A1 (es) | 1972-04-16 |
| US3644333A (en) | 1972-02-22 |
| NL165468C (nl) | 1981-04-15 |
| GB1286838A (en) | 1972-08-23 |
| SE353526B (enExample) | 1973-02-05 |
| JPS5031121B1 (enExample) | 1975-10-07 |
| NL6906336A (enExample) | 1970-07-30 |
| DE1916886B2 (de) | 1978-07-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OI | Miscellaneous see part 1 | ||
| 8227 | New person/name/address of the applicant |
Free format text: STATE OF NEBRASKA VERTRETEN DURCH NEBRASKA STATE DEPARTMENT OF ECONOMIC DEVELOPMENT, LINCOLN, NEBR., US |
|
| 8228 | New agent |
Free format text: SCHOENWALD, K., DR.-ING. FUES, J., DIPL.-CHEM. DR.RER.NAT. VON KREISLER, A., DIPL.-CHEM. KELLER, J., DIPL.-CHEM. SELTING, G., DIPL.-ING. WERNER, H., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 5000 KOELN |
|
| 8281 | Inventor (new situation) |
Free format text: OSIPOW, LLOYD IRVING, NEW YORK, N.Y., US ROSENBLATT, WILLIAM, SPRING VALLEY, N.Y., US |
|
| 8225 | Change of the main classification |
Ipc: C07H 13/06 |
|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |