DE1814072C3 - Überzugsmittel zum Beschichten von Oberflächen durch Kataphorese - Google Patents
Überzugsmittel zum Beschichten von Oberflächen durch KataphoreseInfo
- Publication number
- DE1814072C3 DE1814072C3 DE1814072A DE1814072A DE1814072C3 DE 1814072 C3 DE1814072 C3 DE 1814072C3 DE 1814072 A DE1814072 A DE 1814072A DE 1814072 A DE1814072 A DE 1814072A DE 1814072 C3 DE1814072 C3 DE 1814072C3
- Authority
- DE
- Germany
- Prior art keywords
- coating
- acid
- acids
- dispersion
- cataphoresis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011248 coating agent Substances 0.000 title claims description 29
- 238000000576 coating method Methods 0.000 title claims description 29
- 238000001962 electrophoresis Methods 0.000 title claims description 6
- 239000006185 dispersion Substances 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 11
- 150000007513 acids Chemical class 0.000 claims description 8
- 239000004593 Epoxy Chemical class 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 239000000463 material Substances 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 125000003700 epoxy group Chemical group 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 125000003277 amino group Chemical group 0.000 description 6
- 239000008199 coating composition Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 229920002857 polybutadiene Polymers 0.000 description 6
- 239000005062 Polybutadiene Substances 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- OQEBBZSWEGYTPG-UHFFFAOYSA-N 3-aminobutanoic acid Chemical compound CC(N)CC(O)=O OQEBBZSWEGYTPG-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 3
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- 235000010469 Glycine max Nutrition 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical group OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 235000004347 Perilla Nutrition 0.000 description 1
- 244000124853 Perilla frutescens Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000001243 acetic acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- -1 fatty acid amines Chemical class 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/4423—Polyesters, esterified polyepoxides
- C09D5/4426—Esterified polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB56426/67A GB1235293A (en) | 1967-12-12 | 1967-12-12 | Cationic electrodeposition systems |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1814072A1 DE1814072A1 (de) | 1969-08-07 |
| DE1814072B2 DE1814072B2 (de) | 1974-10-31 |
| DE1814072C3 true DE1814072C3 (de) | 1979-06-28 |
Family
ID=10476593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1814072A Expired DE1814072C3 (de) | 1967-12-12 | 1968-12-11 | Überzugsmittel zum Beschichten von Oberflächen durch Kataphorese |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3617458A (enExample) |
| JP (1) | JPS507632B1 (enExample) |
| BE (1) | BE725367A (enExample) |
| DE (1) | DE1814072C3 (enExample) |
| FR (1) | FR1594426A (enExample) |
| GB (1) | GB1235293A (enExample) |
| NL (1) | NL6817739A (enExample) |
| SE (1) | SE358177B (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928156A (en) * | 1969-07-10 | 1975-12-23 | Ppg Industries Inc | Process for the electrodeposition of zwitterion-containing compositions |
| AU472873B2 (en) * | 1971-07-29 | 1976-06-10 | Ppg Industries Inc | Zwitterion-containing compositions |
| US3947338A (en) * | 1971-10-28 | 1976-03-30 | Ppg Industries, Inc. | Method of electrodepositing self-crosslinking cationic compositions |
| US3947339A (en) * | 1971-12-01 | 1976-03-30 | Ppg Industries, Inc. | Method of electrodepositing primary amine group-containing cationic resins |
| US3925180A (en) * | 1972-04-28 | 1975-12-09 | Ppg Industries Inc | Electrodeposition process using a novel pigment dispersant |
| US3928157A (en) * | 1972-05-15 | 1975-12-23 | Shinto Paint Co Ltd | Cathodic treatment of chromium-plated surfaces |
| US3936405A (en) * | 1972-08-16 | 1976-02-03 | Ppg Industries, Inc. | Novel pigment grinding vehicles |
| US4120768A (en) * | 1973-06-04 | 1978-10-17 | Dulux Australia Ltd. | Process for electrocoating aqueous coating composition comprising dispersion in water of ionizable salt of epoxy amine adduct |
| CA1111598A (en) * | 1976-01-14 | 1981-10-27 | Joseph R. Marchetti | Amine acide salt-containing polymers for cationic electrodeposition |
| BE857754A (fr) * | 1976-08-18 | 1978-02-13 | Celanese Polymer Special Co | Composition de resine pour revetements, notamment par electrodeposition cathodique |
| AT348636B (de) * | 1977-02-18 | 1979-02-26 | Vianova Kunstharz Ag | Verwendung von wasserverduennbaren ueberzugs- mitteln fuer die kathodische abscheidung nach dem elektrotauchlackierverfahren |
| SE7807179L (sv) * | 1977-06-27 | 1978-12-28 | Polymer Investments Nv | Framstellning av med vatten spedbara polymera kompositioner samt katodisk beleggning av metalliska underlag |
| USRE31803E (en) * | 1977-12-12 | 1985-01-15 | Wyandotte Paint Products Company | Method for cathodic electrodeposition of coating compositions containing diels-alder adducts |
| USRE31616E (en) * | 1977-12-12 | 1984-06-26 | Wyandotte Paint Products | Cathodic electrodeposition coating compositions containing diels-alder adducts |
| US4167499A (en) * | 1978-05-09 | 1979-09-11 | E. I. Du Pont De Nemours And Company | Graft copolymer useful in electrodeposition |
| US4177124A (en) * | 1978-05-09 | 1979-12-04 | E. I. Du Pont De Nemours And Company | Process for electrodeposition of graft copolymer |
| US4339368A (en) * | 1978-11-22 | 1982-07-13 | Wyandotte Paint Products Company | Cationic coating compositions containing nitrogen heterocyclic materials |
| US4231907A (en) * | 1978-12-22 | 1980-11-04 | Grow Group Inc. | Cathodic electrodeposition compositions employing fatty acid derivatives |
| DE2907094A1 (de) * | 1979-02-23 | 1980-09-04 | Metallgesellschaft Ag | Phosphatierungsloesungen |
| US4335031A (en) * | 1979-12-21 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Electrocoating composition with polyhydroxyamine and polybutadiene |
| US4338235A (en) * | 1979-12-21 | 1982-07-06 | E. I. Du Pont De Nemours And Company | Electrocoating composition with polyhydroxyamine and acrylic or methacrylic polymers |
| US4308121A (en) * | 1979-12-21 | 1981-12-29 | E. I. Du Pont De Nemours And Company | Electrocoating process using polyhydroxyamine and second polymers |
| US4340523A (en) * | 1979-12-21 | 1982-07-20 | E. I. Dupont De Nemours And Company | Electrocoating composition with polyhydroxyamine and epoxy |
| DE3013912A1 (de) | 1980-04-11 | 1981-10-29 | Röhm GmbH, 6100 Darmstadt | Polymerprodukte zur behandlung von bloessen und leder |
| JPS56160572U (enExample) * | 1980-04-30 | 1981-11-30 | ||
| US4501855A (en) * | 1981-10-29 | 1985-02-26 | Desoto, Inc. | Comb cationic polymers and aqueous dispersions thereof |
| GB8315609D0 (en) * | 1983-06-07 | 1983-07-13 | Ici Plc | Coating compositions |
| JPS607863U (ja) * | 1983-06-27 | 1985-01-19 | アリガ産業株式会社 | アイススケ−トリンクのコ−ナ−部構造 |
| DE19541230A1 (de) | 1995-11-06 | 1997-05-07 | Basf Lacke & Farben | Elektrisch abscheidbares Überzugsmittel |
| DE19606706A1 (de) | 1996-02-23 | 1997-08-28 | Basf Lacke & Farben | Verfahren zur mehrlagigen Beschichtung von Substraten mit Elektrotauchlack und Pulverlack |
| BR0009360A (pt) | 1999-03-26 | 2002-02-19 | David A Lapoint | Artigos revestidos com revestimentos resistente à abrasão, composições de revestimento resistentes a abrasão, processos para fabricação das mesmas, e artigos revestidos com as mesmas |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3230162A (en) * | 1963-08-14 | 1966-01-18 | Ford Motor Co | Electropainting process and paint binder concentrate composition therefor |
| US3304250A (en) * | 1965-03-17 | 1967-02-14 | Ford Motor Co | Continuous electrocoating process utilizing electrodialysis to control the bath composition |
| FR1486212A (enExample) * | 1965-07-09 | 1967-10-04 |
-
1967
- 1967-12-12 GB GB56426/67A patent/GB1235293A/en not_active Expired
-
1968
- 1968-12-04 US US781257A patent/US3617458A/en not_active Expired - Lifetime
- 1968-12-11 SE SE16954/68A patent/SE358177B/xx unknown
- 1968-12-11 NL NL6817739A patent/NL6817739A/xx unknown
- 1968-12-11 DE DE1814072A patent/DE1814072C3/de not_active Expired
- 1968-12-12 FR FR1594426D patent/FR1594426A/fr not_active Expired
- 1968-12-12 JP JP43090607A patent/JPS507632B1/ja active Pending
- 1968-12-12 BE BE725367D patent/BE725367A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US3617458A (en) | 1971-11-02 |
| DE1814072B2 (de) | 1974-10-31 |
| NL6817739A (enExample) | 1969-06-16 |
| DE1814072A1 (de) | 1969-08-07 |
| BE725367A (enExample) | 1969-06-12 |
| SE358177B (enExample) | 1973-07-23 |
| FR1594426A (enExample) | 1970-06-01 |
| GB1235293A (en) | 1971-06-09 |
| JPS507632B1 (enExample) | 1975-03-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |