DE1745105C3 - Verfahren zur Herstellung eines Katalysators für die Isoprenpolymerisation - Google Patents
Verfahren zur Herstellung eines Katalysators für die IsoprenpolymerisationInfo
- Publication number
- DE1745105C3 DE1745105C3 DE1745105A DE1745105A DE1745105C3 DE 1745105 C3 DE1745105 C3 DE 1745105C3 DE 1745105 A DE1745105 A DE 1745105A DE 1745105 A DE1745105 A DE 1745105A DE 1745105 C3 DE1745105 C3 DE 1745105C3
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- titanium
- millimoles
- isoprene
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 title claims description 72
- 239000003054 catalyst Substances 0.000 title claims description 69
- 238000000034 method Methods 0.000 title claims description 22
- 238000006116 polymerization reaction Methods 0.000 title claims description 20
- 238000002360 preparation method Methods 0.000 title claims description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical group C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 54
- 239000010936 titanium Substances 0.000 claims description 37
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 29
- 229910052782 aluminium Inorganic materials 0.000 claims description 29
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 25
- 229910052719 titanium Inorganic materials 0.000 claims description 24
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 16
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 10
- 150000002430 hydrocarbons Chemical group 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000008378 aryl ethers Chemical class 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 42
- 239000000243 solution Substances 0.000 description 37
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
- 229920001195 polyisoprene Polymers 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 6
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 6
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 6
- -1 aluminum compound Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920003052 natural elastomer Polymers 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- SJVVUOJXRCWZLV-UHFFFAOYSA-N CC(=C)C=C.CCCCCC Chemical compound CC(=C)C=C.CCCCCC SJVVUOJXRCWZLV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- KXADPELPQCWDHL-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1.COC1=CC=CC=C1 KXADPELPQCWDHL-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/907—Specified means of reacting components of transition metal catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR63001856 | 1966-05-16 | ||
| FR94608A FR91844E (fr) | 1966-05-16 | 1967-02-10 | Perfectionnements à la polymérisation de l'isoprène |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1745105A1 DE1745105A1 (de) | 1972-02-24 |
| DE1745105B2 DE1745105B2 (de) | 1974-01-10 |
| DE1745105C3 true DE1745105C3 (de) | 1974-08-08 |
Family
ID=26174691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1745105A Expired DE1745105C3 (de) | 1966-05-16 | 1967-05-03 | Verfahren zur Herstellung eines Katalysators für die Isoprenpolymerisation |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3580899A (en:Method) |
| BE (1) | BE696957A (en:Method) |
| DE (1) | DE1745105C3 (en:Method) |
| ES (1) | ES340583A1 (en:Method) |
| FR (1) | FR91844E (en:Method) |
| GB (1) | GB1182935A (en:Method) |
| LU (1) | LU53680A1 (en:Method) |
| NL (2) | NL6703215A (en:Method) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7013366A (en:Method) * | 1969-09-27 | 1971-03-30 | ||
| GB1408620A (en) * | 1972-12-04 | 1975-10-01 | Shell Int Research | Isoprene polymerization and catalyst therefor |
| GB1479652A (en) * | 1974-01-31 | 1977-07-13 | Ici Ltd | Polymerisation catalyst |
| GB1479651A (en) * | 1974-01-31 | 1977-07-13 | Ici Ltd | Olefine polymerisation catalyst |
| US3900456A (en) * | 1974-01-31 | 1975-08-19 | Phillips Petroleum Co | Polyisoprene |
| US4128708A (en) * | 1977-01-19 | 1978-12-05 | Liakumovich Alexandr G | Process for preparing cis-polyisoprene |
| WO1993013089A1 (en) * | 1985-01-25 | 1993-07-08 | Urban Frank J | Macrocyclic polyether carboxylic acids |
-
0
- NL NL130580D patent/NL130580C/xx active
-
1967
- 1967-02-10 FR FR94608A patent/FR91844E/fr not_active Expired
- 1967-02-28 NL NL6703215A patent/NL6703215A/xx unknown
- 1967-04-13 BE BE696957D patent/BE696957A/xx not_active IP Right Cessation
- 1967-05-03 DE DE1745105A patent/DE1745105C3/de not_active Expired
- 1967-05-10 US US637327A patent/US3580899A/en not_active Expired - Lifetime
- 1967-05-15 GB GB22512/67A patent/GB1182935A/en not_active Expired
- 1967-05-16 ES ES340583A patent/ES340583A1/es not_active Expired
- 1967-05-16 LU LU53680D patent/LU53680A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE696957A (en:Method) | 1967-10-13 |
| GB1182935A (en) | 1970-03-04 |
| ES340583A1 (es) | 1968-06-01 |
| FR91844E (fr) | 1968-08-16 |
| DE1745105A1 (de) | 1972-02-24 |
| US3580899A (en) | 1971-05-25 |
| NL130580C (en:Method) | |
| LU53680A1 (en:Method) | 1968-02-12 |
| DE1745105B2 (de) | 1974-01-10 |
| NL6703215A (en:Method) | 1967-11-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 |