DE1667409A1 - Verfahren zur Herstellung von Natriumaluminiumhydriden - Google Patents
Verfahren zur Herstellung von NatriumaluminiumhydridenInfo
- Publication number
- DE1667409A1 DE1667409A1 DE19671667409 DE1667409A DE1667409A1 DE 1667409 A1 DE1667409 A1 DE 1667409A1 DE 19671667409 DE19671667409 DE 19671667409 DE 1667409 A DE1667409 A DE 1667409A DE 1667409 A1 DE1667409 A1 DE 1667409A1
- Authority
- DE
- Germany
- Prior art keywords
- mol
- reaction
- theory
- carried out
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 13
- -1 sodium aluminum hydrides Chemical class 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 57
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 30
- 239000011734 sodium Substances 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 229910052708 sodium Inorganic materials 0.000 claims description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 18
- 239000011541 reaction mixture Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 150000004678 hydrides Chemical class 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000010 aprotic solvent Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 229920000151 polyglycol Polymers 0.000 claims description 5
- 239000010695 polyglycol Substances 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000002009 diols Chemical class 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 230000002152 alkylating effect Effects 0.000 claims description 3
- 150000001414 amino alcohols Chemical class 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- HNUALPPJLMYHDK-UHFFFAOYSA-N C[CH]C Chemical compound C[CH]C HNUALPPJLMYHDK-UHFFFAOYSA-N 0.000 claims description 2
- 150000005840 aryl radicals Chemical class 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 210000002837 heart atrium Anatomy 0.000 claims 1
- 238000003756 stirring Methods 0.000 description 14
- 238000002955 isolation Methods 0.000 description 12
- 239000007787 solid Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 150000001298 alcohols Chemical class 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910000104 sodium hydride Inorganic materials 0.000 description 3
- 239000012312 sodium hydride Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000005277 alkyl imino group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
- C01B6/243—Hydrides containing at least two metals; Addition complexes thereof containing only hydrogen, aluminium and alkali metals, e.g. Li(AlH4)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/12—Radicals substituted by oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Duct Arrangements (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS201066A CS157496B1 (enrdf_load_stackoverflow) | 1966-03-22 | 1966-03-22 | |
| CS200966A CS157495B1 (enrdf_load_stackoverflow) | 1966-03-22 | 1966-03-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1667409A1 true DE1667409A1 (de) | 1971-10-28 |
Family
ID=25745540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19671667409 Pending DE1667409A1 (de) | 1966-03-22 | 1967-03-23 | Verfahren zur Herstellung von Natriumaluminiumhydriden |
Country Status (11)
| Country | Link |
|---|---|
| BE (2) | BE696044A (enrdf_load_stackoverflow) |
| CH (2) | CH509229A (enrdf_load_stackoverflow) |
| DE (1) | DE1667409A1 (enrdf_load_stackoverflow) |
| DK (1) | DK131180B (enrdf_load_stackoverflow) |
| FI (1) | FI48741C (enrdf_load_stackoverflow) |
| FR (2) | FR1515581A (enrdf_load_stackoverflow) |
| GB (1) | GB1185707A (enrdf_load_stackoverflow) |
| IL (1) | IL27446A (enrdf_load_stackoverflow) |
| NL (2) | NL6704432A (enrdf_load_stackoverflow) |
| NO (2) | NO116036B (enrdf_load_stackoverflow) |
| SE (2) | SE317653B (enrdf_load_stackoverflow) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3758620A (en) * | 1969-11-06 | 1973-09-11 | Nat Patent Dev Corp | Process for the preparation of grignard reagents |
| US4010248A (en) | 1974-10-04 | 1977-03-01 | Ethyl Corporation | Process for producing trialkali metal aluminum hexahydride |
| JPS60500252A (ja) * | 1982-12-15 | 1985-02-28 | エシル コ−ポレ−シヨン | 水素化アルミニウムアルカリ金属の製法 |
| US4529580A (en) * | 1982-12-15 | 1985-07-16 | Ethyl Corporation | Alkali metal aluminum hydride production |
| US4563343A (en) * | 1982-12-15 | 1986-01-07 | Ethyl Corporation | Catalyzed alkali metal aluminum hydride production |
| US4528176A (en) * | 1982-12-15 | 1985-07-09 | Ethyl Corporation | Sodium aluminum hydride production |
| US4456584A (en) * | 1983-05-20 | 1984-06-26 | Ethyl Corporation | Synthesis of sodium aluminum hydride |
| US4512966A (en) * | 1983-12-02 | 1985-04-23 | Ethyl Corporation | Hydride production at moderate pressure |
| JPS62500564A (ja) * | 1984-10-24 | 1987-03-12 | スムスキ− フイリアル ハルコフスコボ ポリテフニチエスコボ インスチトウタ イメニ ヴイ・アイ・レ−ニナ | 投球装置 |
| US4790985A (en) * | 1986-10-16 | 1988-12-13 | Ethyl Corporation | Synthesis of sodium aluminum hydride |
| US5295581A (en) * | 1992-11-05 | 1994-03-22 | Ethyl Corporation | Process for preparing dry sodium aluminum hydride |
| US5986142A (en) * | 1997-09-23 | 1999-11-16 | Poli Industria Chimica Spa | Process for preparing bicycloheptanamine compounds |
| US6548708B1 (en) | 1998-08-05 | 2003-04-15 | Sri International | Preparation of biphosphine ligands for incorporation into catalytic complexes |
-
1967
- 1967-02-15 IL IL2744667A patent/IL27446A/xx unknown
- 1967-03-20 NO NO16737067A patent/NO116036B/no unknown
- 1967-03-20 NO NO16736967A patent/NO126273B/no unknown
- 1967-03-21 CH CH406067A patent/CH509229A/de not_active IP Right Cessation
- 1967-03-21 CH CH405967A patent/CH537949A/de not_active IP Right Cessation
- 1967-03-22 SE SE406667A patent/SE317653B/xx unknown
- 1967-03-22 SE SE406767A patent/SE335516B/xx unknown
- 1967-03-23 DE DE19671667409 patent/DE1667409A1/de active Pending
- 1967-03-24 BE BE696044D patent/BE696044A/xx unknown
- 1967-03-24 FR FR100162A patent/FR1515581A/fr not_active Expired
- 1967-03-24 FR FR100163A patent/FR1515582A/fr not_active Expired
- 1967-03-28 GB GB1393867A patent/GB1185707A/en not_active Expired
- 1967-03-28 NL NL6704432A patent/NL6704432A/xx unknown
- 1967-03-28 NL NL6704431A patent/NL6704431A/xx unknown
- 1967-03-28 BE BE696134D patent/BE696134A/xx unknown
- 1967-03-28 FI FI88567A patent/FI48741C/fi active
- 1967-03-28 DK DK157767A patent/DK131180B/da unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE696134A (enrdf_load_stackoverflow) | 1967-09-01 |
| NO126273B (enrdf_load_stackoverflow) | 1973-01-15 |
| NL6704432A (enrdf_load_stackoverflow) | 1967-09-27 |
| FR1515582A (fr) | 1968-03-01 |
| IL27446A (en) | 1972-04-27 |
| GB1185707A (en) | 1970-03-25 |
| FI48741C (fi) | 1974-12-10 |
| DK131180C (enrdf_load_stackoverflow) | 1975-11-10 |
| SE335516B (enrdf_load_stackoverflow) | 1971-06-01 |
| CH537949A (de) | 1973-06-15 |
| FR1515581A (fr) | 1968-03-01 |
| NL6704431A (enrdf_load_stackoverflow) | 1967-09-27 |
| DK131180B (da) | 1975-06-09 |
| SE317653B (enrdf_load_stackoverflow) | 1969-11-24 |
| CH509229A (de) | 1971-06-30 |
| FI48741B (enrdf_load_stackoverflow) | 1974-09-02 |
| NO116036B (enrdf_load_stackoverflow) | 1969-01-20 |
| BE696044A (enrdf_load_stackoverflow) | 1967-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1667409A1 (de) | Verfahren zur Herstellung von Natriumaluminiumhydriden | |
| DE69703909T2 (de) | Verbessertes Verfahren zur Umwandlung von Ethylen in 1-Buten unter Verwendung von Additiven die auf Polyethylenglycol und seinen Monoethern und Monoestern basieren | |
| DE1012460B (de) | Verfahren zur Herstellung von hochmolekularen Polyaethylenen | |
| DE69103188T2 (de) | Verfahren zur Herstellung von wenigstens einem tertiären Olefin durch Spaltung des übereinstimmenden Äthers. | |
| DE1593200A1 (de) | Verfahren zur Herstellung von Halbestern | |
| DE917006C (de) | Verfahren zur Darstellung organischer Verbindungen des Aluminiums und Berylliums | |
| EP0175896B1 (de) | Verfahren zur Herstellung von Aminen | |
| DE3111302C2 (de) | Verfahren zur Herstellung von 3-Pentensäureestern unter Rückgewinnung dabei verwendeter Kobaltkatalysatoren | |
| EP0592779A1 (de) | Verfahren zur Herstellung von Distannanen | |
| DE68918951T2 (de) | Verfahren zur herstellung eines mit einer organischen gruppe substituierten natriumaluminiumhydrids. | |
| DE2242387A1 (de) | Verfahren zur synthese von derivaten des spiro(4,5)-decans | |
| AT204528B (de) | Verfahren zur Herstellung von Alkali- und Erdalkaliborhydriden | |
| EP0387688B1 (de) | Verfahren zur Herstellung unsymmetrischer, endständig einfach ungesättigter Glykolether | |
| AT228228B (de) | Verfahren zur Umalkylierung von Grignardverbindungen oder Magnesiumdialkylverbindungen | |
| DE3000490C2 (de) | Verfahren zur Herstellung von Erdalkali-Alkoxyalanaten | |
| DE2151233B2 (de) | Verfahren zur umsetzung von trialkylboranen mit protonenhaltigen verbindungen | |
| AT333734B (de) | Verfahren zur herstellung von neuen carbonsaureestern von 3-(4-biphenylyl)-1-butanolen und 3-(4-biphenylyl)-2-buten-1-olen | |
| AT228800B (de) | Verfahren zur Abtrennung von Aluminiumtrialkylen aus ihren Gemischen mit nichtaromatischen Kohlenwasserstoffen, insbesondere Olefinen oder andern Metallalkylen, insbesondere Bleitetraalkylen | |
| DE2402426C3 (de) | Verfahren zur Herstellung von Dialkonboracetylacetonat enthaltenden Gemischen | |
| DE2914496C3 (de) | Verfahren zur Herstellung von olidomeren Iminoalanen mit einer dreidimensionalen offenen Käfig-Struktur | |
| DE1241813B (de) | Verfahren zur Herstellung von aliphatischen Aralkylketonen | |
| DE2329145B2 (de) | Verfahren zur herstellung von alkinolen | |
| DE2534471A1 (de) | Verfahren zur herstellung von poly(n-alkyliminoalanen) | |
| AT202566B (de) | Verfahren zur Herstellung von Borverbindungen oder Aluminiumverbindungen | |
| DE2515581C2 (de) | Verfahren zum Herstellen von tert.-Butylglycidyläther |