DE1645463A1 - Verfahren zum Pyrolysieren von Mischpolymerisaten von AEthylen und Vinylestern - Google Patents
Verfahren zum Pyrolysieren von Mischpolymerisaten von AEthylen und VinylesternInfo
- Publication number
- DE1645463A1 DE1645463A1 DE19661645463 DE1645463A DE1645463A1 DE 1645463 A1 DE1645463 A1 DE 1645463A1 DE 19661645463 DE19661645463 DE 19661645463 DE 1645463 A DE1645463 A DE 1645463A DE 1645463 A1 DE1645463 A1 DE 1645463A1
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- pyrolysis
- copolymers
- pressure
- vinyl esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001577 copolymer Polymers 0.000 title claims description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 21
- 239000005977 Ethylene Substances 0.000 title claims description 21
- 238000000034 method Methods 0.000 title claims description 17
- 238000000197 pyrolysis Methods 0.000 title claims description 17
- 229920001567 vinyl ester resin Polymers 0.000 title claims description 14
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims description 9
- 239000003085 diluting agent Substances 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 230000006855 networking Effects 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- -1 aliphatic organic acids Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000006238 High Abrasion Furnace Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6505800A NL6505800A (en, 2012) | 1965-05-07 | 1965-05-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1645463A1 true DE1645463A1 (de) | 1970-07-16 |
Family
ID=19793104
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661645463 Pending DE1645463A1 (de) | 1965-05-07 | 1966-05-06 | Verfahren zum Pyrolysieren von Mischpolymerisaten von AEthylen und Vinylestern |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3451983A (en, 2012) |
| AT (1) | AT265631B (en, 2012) |
| BE (1) | BE680491A (en, 2012) |
| CH (1) | CH466577A (en, 2012) |
| DE (1) | DE1645463A1 (en, 2012) |
| ES (1) | ES326351A1 (en, 2012) |
| FR (1) | FR1478150A (en, 2012) |
| GB (1) | GB1125832A (en, 2012) |
| NL (2) | NL6505800A (en, 2012) |
| SE (1) | SE327080B (en, 2012) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1206795A (fr) * | 1958-05-16 | 1960-02-11 | Resines Et Vernis Artificiels | Procédé de polymérisation en masse continue de dérivés vinyliques |
| JPS5075690A (en, 2012) * | 1973-11-06 | 1975-06-20 | ||
| US4626588A (en) * | 1984-06-26 | 1986-12-02 | Director-General Of The Agency Of Industrial Science And Technology | Conjugated polymer film and pyrolyzed product thereof |
| US9012542B2 (en) * | 2009-04-01 | 2015-04-21 | Saudi Arabian Oil Company | Sulfur extended polymer for use in asphalt binder and road maintenance |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB499333A (en) * | 1944-01-24 | 1939-01-23 | Eric William Fawcett | Manufacture of pressed shapes of new thermoplastic material |
| US2935502A (en) * | 1958-02-05 | 1960-05-03 | Union Carbide Corp | Process for the high temperature, high pressure shear degradation of solid polyethylene |
| US3087922A (en) * | 1958-05-13 | 1963-04-30 | Phillips Petroleum Co | Method and apparatus for pyrolyzing polymers |
| BE616207A (en, 2012) * | 1961-04-12 | |||
| DE1203958B (de) * | 1963-05-29 | 1965-10-28 | Hoechst Ag | Verfahren zur Herstellung von vollstaendig oder teilweise verseiften Vinylacetat-AEthylen- Mischpolymerisaten |
-
0
- NL NL124891D patent/NL124891C/xx active
-
1965
- 1965-05-07 NL NL6505800A patent/NL6505800A/xx unknown
-
1966
- 1966-05-02 FR FR59878A patent/FR1478150A/fr not_active Expired
- 1966-05-02 US US546564A patent/US3451983A/en not_active Expired - Lifetime
- 1966-05-02 GB GB19312/66A patent/GB1125832A/en not_active Expired
- 1966-05-03 AT AT416566A patent/AT265631B/de active
- 1966-05-04 BE BE680491D patent/BE680491A/xx unknown
- 1966-05-04 CH CH644266A patent/CH466577A/de unknown
- 1966-05-05 ES ES0326351A patent/ES326351A1/es not_active Expired
- 1966-05-06 DE DE19661645463 patent/DE1645463A1/de active Pending
- 1966-05-06 SE SE06300/66A patent/SE327080B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH466577A (de) | 1968-12-15 |
| NL124891C (en, 2012) | |
| SE327080B (en, 2012) | 1970-08-10 |
| GB1125832A (en) | 1968-09-05 |
| US3451983A (en) | 1969-06-24 |
| FR1478150A (fr) | 1967-04-21 |
| ES326351A1 (es) | 1967-03-01 |
| AT265631B (de) | 1968-10-25 |
| BE680491A (en, 2012) | 1966-11-04 |
| NL6505800A (en, 2012) | 1966-11-08 |
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