DE1568407B2 - - Google Patents
Info
- Publication number
- DE1568407B2 DE1568407B2 DE19511568407 DE1568407A DE1568407B2 DE 1568407 B2 DE1568407 B2 DE 1568407B2 DE 19511568407 DE19511568407 DE 19511568407 DE 1568407 A DE1568407 A DE 1568407A DE 1568407 B2 DE1568407 B2 DE 1568407B2
- Authority
- DE
- Germany
- Prior art keywords
- oxidation
- oxygen
- epoxides
- olefins
- dodecene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003647 oxidation Effects 0.000 claims description 19
- 238000007254 oxidation reaction Methods 0.000 claims description 19
- 150000001336 alkenes Chemical class 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims 1
- 150000002924 oxiranes Chemical class 0.000 description 12
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- MPGABYXKKCLIRW-UHFFFAOYSA-N 2-decyloxirane Chemical compound CCCCCCCCCCC1CO1 MPGABYXKKCLIRW-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229940069096 dodecene Drugs 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- WURFKUQACINBSI-UHFFFAOYSA-M ozonide Chemical compound [O]O[O-] WURFKUQACINBSI-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19511568407 DE1568407A1 (de) | 1951-01-28 | 1951-01-28 | Verfahren zur Herstellung von Epoxiden durch direkte Oxydation von Verbindungen mit olefinischer Doppelbindung |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19511568407 DE1568407A1 (de) | 1951-01-28 | 1951-01-28 | Verfahren zur Herstellung von Epoxiden durch direkte Oxydation von Verbindungen mit olefinischer Doppelbindung |
| DED0050918 | 1966-08-23 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1568407A1 DE1568407A1 (de) | 1970-04-30 |
| DE1568407B2 true DE1568407B2 (enrdf_load_stackoverflow) | 1974-05-22 |
| DE1568407C3 DE1568407C3 (enrdf_load_stackoverflow) | 1975-01-02 |
Family
ID=25753090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19511568407 Granted DE1568407A1 (de) | 1951-01-28 | 1951-01-28 | Verfahren zur Herstellung von Epoxiden durch direkte Oxydation von Verbindungen mit olefinischer Doppelbindung |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1568407A1 (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2081507C (en) * | 1991-10-30 | 2004-04-06 | Shun-Ichi Murahashi | Process for producing epoxide |
-
1951
- 1951-01-28 DE DE19511568407 patent/DE1568407A1/de active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE1568407A1 (de) | 1970-04-30 |
| DE1568407C3 (enrdf_load_stackoverflow) | 1975-01-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2404855C3 (de) | Verfahren zur Verhinderung von Emulsionsbildung bei der Aufbereitung von Butyraldehyden und Kobalt enthaltenden Reaktionsgemischen | |
| DE926426C (de) | Verfahren zur Herstellung von Isopropylbenzolperoxyd | |
| DE1043315B (de) | Verfahren zur Herstellung wasserfreier Peressig- oder Perpropionsaeureloesungen | |
| DE1443188C (enrdf_load_stackoverflow) | ||
| DE4332292A1 (de) | Verfahren zur direkten Hydroxylierung ungesättigter Carbonsäuren | |
| DE1219484B (de) | Verfahren zur Herstellung von Peroxycarbonsaeuren | |
| EP0286937A1 (de) | Verfahren zur Herstellung epoxidierter Fettalkohole | |
| DE1568407B2 (enrdf_load_stackoverflow) | ||
| DE1224283B (de) | Verfahren zur Rueckgewinnung von Borsaeure aus den Oxydationsgemischen der Fluessigphasen-oxydation von Kohlenwasserstoffen | |
| DE2141156A1 (de) | Verfahren zur herstellung organischer percarbonsaeureloesungen | |
| DE1254628B (de) | Verfahren zur Herstellung von gesaettigten aliphatischen oder alicyclischen Carbonsaeuren, Alkoholen und/oder Ketonen | |
| DE1959621C3 (de) | Verfahren zur Gewinnung von Adipinsäure aus 6-Hydroperoxyhexansäure | |
| DE962527C (de) | Verfahren zur Herstellung von Oxyhydroperoxyden | |
| DE1065846B (de) | Verfahren zur Herstellung von Carbonsäuren durch Oxydation von Aldehyden mit molekularem Sauerstoff | |
| DE2035504C3 (de) | Verfahren zur Herstellung von Cumolhydroperoxid | |
| DE2215362B2 (enrdf_load_stackoverflow) | ||
| DE1132114B (de) | Verfahren zur Herstellung von Gemischen gesaettigter aliphatischer Mono- und Dicarbonsaeuren aus ungesaettigten Fettsaeuren | |
| DE2063012A1 (en) | Epoxides purification - by steam distilln in the presence of inorganic bases | |
| DE2426863A1 (de) | Verfahren zur spaltung von cycloaliphatischen hdroperoxiden | |
| DE1268129B (de) | Verfahren zur Herstellung von Carbonsaeuren | |
| DE1951318C (de) | Verfahren zur Gewinnung von 6-Hydroperoxyhexansäure | |
| DE1793305C3 (de) | Verfahren zur Herstellung von Aldehyden und/oder Ketonen durch Umsetzung von Olefinen mit Ozon | |
| DE804566C (de) | Verfahren zur Gewinnung von Buttersaeure | |
| DE2159605C3 (de) | Verfahren zur Herstellung von sekundären Hydroperoxiden | |
| DE2125160B2 (de) | Verfahren zur Herstellung von aliphatischen Percarbonsäuren mit 2 bis 5 Kohlenstoffatomen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |