DE1568305A1 - Verfahren und Vorrichtung zur selektiven Chlorierung von Kohlenwasserstoffen - Google Patents
Verfahren und Vorrichtung zur selektiven Chlorierung von KohlenwasserstoffenInfo
- Publication number
- DE1568305A1 DE1568305A1 DE19661568305 DE1568305A DE1568305A1 DE 1568305 A1 DE1568305 A1 DE 1568305A1 DE 19661568305 DE19661568305 DE 19661568305 DE 1568305 A DE1568305 A DE 1568305A DE 1568305 A1 DE1568305 A1 DE 1568305A1
- Authority
- DE
- Germany
- Prior art keywords
- chlorine
- reactor
- paraffin
- reaction
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 31
- 238000005660 chlorination reaction Methods 0.000 title claims description 21
- 229930195733 hydrocarbon Natural products 0.000 title claims description 17
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 17
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 73
- 229910052801 chlorine Inorganic materials 0.000 claims description 67
- 239000000460 chlorine Substances 0.000 claims description 66
- 238000006243 chemical reaction Methods 0.000 claims description 63
- 239000012188 paraffin wax Substances 0.000 claims description 52
- 239000000203 mixture Substances 0.000 claims description 45
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 32
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000007791 liquid phase Substances 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 4
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 4
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims 1
- 239000000047 product Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 150000001804 chlorine Chemical class 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 229930195734 saturated hydrocarbon Natural products 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 125000003963 dichloro group Chemical group Cl* 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- -1 aliphatic chlorinated hydrocarbons Chemical class 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 201000006747 infectious mononucleosis Diseases 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2425—Tubular reactors in parallel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00099—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor the reactor being immersed in the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR26790A FR1456655A (fr) | 1965-07-30 | 1965-07-30 | Procédé de chloration sélective des hydrocarbures |
| FR68638A FR90579E (fr) | 1965-07-30 | 1966-07-07 | Procédé de chloration sélective des hydrocarbures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1568305A1 true DE1568305A1 (de) | 1970-03-12 |
Family
ID=26165158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661568305 Pending DE1568305A1 (de) | 1965-07-30 | 1966-07-19 | Verfahren und Vorrichtung zur selektiven Chlorierung von Kohlenwasserstoffen |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE684802A (enrdf_load_html_response) |
| DE (1) | DE1568305A1 (enrdf_load_html_response) |
| FR (2) | FR1456655A (enrdf_load_html_response) |
| GB (1) | GB1148251A (enrdf_load_html_response) |
| NL (1) | NL6610731A (enrdf_load_html_response) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113578246B (zh) * | 2021-09-07 | 2025-01-24 | 宁夏优维生物科技有限公司 | 连续氯化管道反应装置及制备4-氯乙酰乙酸乙酯的方法 |
-
1965
- 1965-07-30 FR FR26790A patent/FR1456655A/fr not_active Expired
-
1966
- 1966-07-07 FR FR68638A patent/FR90579E/fr not_active Expired
- 1966-07-19 DE DE19661568305 patent/DE1568305A1/de active Pending
- 1966-07-26 GB GB3346166A patent/GB1148251A/en not_active Expired
- 1966-07-29 NL NL6610731A patent/NL6610731A/xx unknown
- 1966-07-29 BE BE684802D patent/BE684802A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1148251A (en) | 1969-04-10 |
| BE684802A (enrdf_load_html_response) | 1967-01-30 |
| FR90579E (fr) | 1968-01-05 |
| NL6610731A (enrdf_load_html_response) | 1967-01-31 |
| FR1456655A (fr) | 1966-07-08 |
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