DE1417070A1 - Verfahren zur Herstellung eines Katalysators fuer die Polymerisation von alpha-Olefinen - Google Patents
Verfahren zur Herstellung eines Katalysators fuer die Polymerisation von alpha-OlefinenInfo
- Publication number
- DE1417070A1 DE1417070A1 DE19591417070 DE1417070A DE1417070A1 DE 1417070 A1 DE1417070 A1 DE 1417070A1 DE 19591417070 DE19591417070 DE 19591417070 DE 1417070 A DE1417070 A DE 1417070A DE 1417070 A1 DE1417070 A1 DE 1417070A1
- Authority
- DE
- Germany
- Prior art keywords
- aluminum
- diluent
- titanium
- catalyst
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 38
- 238000006116 polymerization reaction Methods 0.000 title claims description 21
- 238000000034 method Methods 0.000 title claims description 17
- 238000002360 preparation method Methods 0.000 title claims description 15
- 230000008569 process Effects 0.000 title claims description 12
- 239000004711 α-olefin Substances 0.000 title 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 39
- 239000003085 diluting agent Substances 0.000 claims description 37
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 34
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 32
- 229910052782 aluminium Inorganic materials 0.000 claims description 24
- 230000009467 reduction Effects 0.000 claims description 20
- -1 aluminum alkylene compound Chemical class 0.000 claims description 16
- 125000003118 aryl group Chemical group 0.000 claims description 11
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 238000009837 dry grinding Methods 0.000 claims 2
- 239000006104 solid solution Substances 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002902 organometallic compounds Chemical class 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- GWHJZXXIDMPWGX-UHFFFAOYSA-N 1,2,4-trimethylbenzene Chemical compound CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 229920001580 isotactic polymer Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- 101150038108 Art7 gene Proteins 0.000 description 1
- LRUNJVAFNFSJCW-UHFFFAOYSA-N C1=CC=CC=C1.ClC1=C(C=CC=C1)C Chemical compound C1=CC=CC=C1.ClC1=C(C=CC=C1)C LRUNJVAFNFSJCW-UHFFFAOYSA-N 0.000 description 1
- CMTOAZYCDKAFHL-UHFFFAOYSA-N CC1=CC=CC=C1.CC1=CC=CC=C1.CC1=CC=CC=C1 Chemical compound CC1=CC=CC=C1.CC1=CC=CC=C1.CC1=CC=CC=C1 CMTOAZYCDKAFHL-UHFFFAOYSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910010062 TiCl3 Inorganic materials 0.000 description 1
- 244000172533 Viola sororia Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- ZMKAVICCBWPNSR-UHFFFAOYSA-G aluminum;tetrachlorotitanium;trichloride Chemical compound [Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Ti+4] ZMKAVICCBWPNSR-UHFFFAOYSA-G 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- XDLDASNSMGOEMX-UHFFFAOYSA-N benzene benzene Chemical compound C1=CC=CC=C1.C1=CC=CC=C1 XDLDASNSMGOEMX-UHFFFAOYSA-N 0.000 description 1
- GNHQSAUHXKRQMC-UHFFFAOYSA-N benzene;chlorine Chemical compound [Cl].C1=CC=CC=C1 GNHQSAUHXKRQMC-UHFFFAOYSA-N 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
- 238000002288 cocrystallisation Methods 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229930007927 cymene Natural products 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229920000576 tactic polymer Polymers 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- GBECUEIQVRDUKB-UHFFFAOYSA-M thallium monochloride Chemical compound [Tl]Cl GBECUEIQVRDUKB-UHFFFAOYSA-M 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/02—Halides of titanium
- C01G23/026—Titanium trichloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/02—Halides of titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US766376A US3032513A (en) | 1958-10-10 | 1958-10-10 | Catalyst preparation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1417070A1 true DE1417070A1 (de) | 1968-10-03 |
Family
ID=25076251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19591417070 Pending DE1417070A1 (de) | 1958-10-10 | 1959-09-24 | Verfahren zur Herstellung eines Katalysators fuer die Polymerisation von alpha-Olefinen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3032513A (en, 2012) |
| BE (1) | BE583479A (en, 2012) |
| CH (1) | CH410011A (en, 2012) |
| DE (1) | DE1417070A1 (en, 2012) |
| DK (2) | DK108322C (en, 2012) |
| FR (1) | FR1237413A (en, 2012) |
| GB (1) | GB878373A (en, 2012) |
| NL (1) | NL243666A (en, 2012) |
| SE (1) | SE300710B (en, 2012) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3161604A (en) * | 1964-12-15 | Novel copper containing polymerization | ||
| US3109822A (en) * | 1963-11-05 | catalyst composition | ||
| US3128252A (en) * | 1956-04-16 | 1964-04-07 | Exxon Research Engineering Co | Preparation of partially reduced transition metal halide catalyst compositions |
| GB888709A (en) * | 1959-07-17 | 1962-01-31 | Exxon Research Engineering Co | Cocrystallized vanadium-titanium catalyst components |
| US3174958A (en) * | 1960-05-04 | 1965-03-23 | Nat Distillers Chem Corp | Copolymerization process |
| DE1240050B (de) * | 1960-10-12 | 1967-05-11 | Allied Chem | Verfahren zur Herstellung eines zur Polymerisation von Propylen geeigneten Katalysators |
| DE1570353C2 (de) * | 1965-05-19 | 1973-10-18 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von Polybuten 1 |
| US3461083A (en) * | 1965-11-25 | 1969-08-12 | Montedison Spa | Crystalline ticl3 and method of preparing same |
| US3531420A (en) * | 1966-10-19 | 1970-09-29 | Exxon Research Engineering Co | Tetrahalides of transition metals reduced with activated aluminum powder |
| US3466140A (en) * | 1967-03-31 | 1969-09-09 | Goodyear Tire & Rubber | Process for producing reduced transition metal halides |
| US3923687A (en) * | 1970-07-14 | 1975-12-02 | Chisso Corp | Process for activating catalyst component useful for polymerizing propylene |
| BE791441A (fr) * | 1971-11-24 | 1973-05-16 | Solvay | Procede pour la polymerisation des alpha-olefines |
| DE2306667C3 (de) * | 1973-02-10 | 1979-11-08 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von weitgehend amorphen Buten-1-polymeren |
| US3926848A (en) * | 1973-04-19 | 1975-12-16 | Exxon Research Engineering Co | Process for increasing activity of heavy transition metal halide stereospecific catalysts |
| DE2658937A1 (de) * | 1976-12-24 | 1978-07-06 | Basf Ag | Verfahren zum herstellen einer titan enthaltenden komponente fuer katalysatoren des ziegler-natta-typs |
| US4578179A (en) * | 1983-11-18 | 1986-03-25 | Phillips Petroleum Company | Hydrofining process for hydrocarbon containing feed streams |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2577591A (en) * | 1947-12-10 | 1951-12-04 | Phillips Petroleum Co | Preparation of a supported aluminum-halide-carbon catalyst |
| US2634260A (en) * | 1949-11-18 | 1953-04-07 | Du Pont | Metal molybdite catalyzed polymerization |
| US2678923A (en) * | 1951-03-19 | 1954-05-18 | Socony Vacuum Oil Co Inc | Reforming catalyst |
| US2864749A (en) * | 1951-05-09 | 1958-12-16 | Timax Corp | Process for the production of titanium metal |
| US2745802A (en) * | 1952-09-18 | 1956-05-15 | Reynolds Metals Co | Inorganic molten electrolyte for the electrolysis of titanium |
| US2745735A (en) * | 1953-04-28 | 1956-05-15 | Kaiser Aluminium Chem Corp | Method of producing titanium |
| IT565268A (en, 2012) * | 1954-02-25 | |||
| US2925392A (en) * | 1956-04-02 | 1960-02-16 | Exxon Research Engineering Co | Catalyst and preparation thereof |
| US2880199A (en) * | 1956-11-02 | 1959-03-31 | Sun Oil Co | Manufacture of polyolefins |
-
0
- NL NL243666D patent/NL243666A/xx unknown
- BE BE583479D patent/BE583479A/xx unknown
-
1958
- 1958-10-10 US US766376A patent/US3032513A/en not_active Expired - Lifetime
-
1959
- 1959-09-07 GB GB30456/59A patent/GB878373A/en not_active Expired
- 1959-09-24 DE DE19591417070 patent/DE1417070A1/de active Pending
- 1959-10-02 FR FR806640A patent/FR1237413A/fr not_active Expired
- 1959-10-10 CH CH7927759A patent/CH410011A/de unknown
- 1959-10-10 DK DK362759AA patent/DK108322C/da active
-
1964
- 1964-10-09 DK DK498864AA patent/DK112903B/da unknown
-
1966
- 1966-10-24 SE SE14571/66A patent/SE300710B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US3032513A (en) | 1962-05-01 |
| NL243666A (en, 2012) | 1900-01-01 |
| SE300710B (sv) | 1968-05-06 |
| DK112903B (da) | 1969-01-27 |
| GB878373A (en) | 1961-09-27 |
| BE583479A (en, 2012) | 1900-01-01 |
| DK108322C (da) | 1967-11-13 |
| FR1237413A (fr) | 1960-07-29 |
| CH410011A (de) | 1966-03-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2522336C2 (de) | Katalysator für die Polymerisation oder Copolymerisation von Äthylen und/oder α-Olefinen sowie seine Herstellung und Verwendung | |
| DE1939074C3 (de) | Verfahren zur katalytischen Polymerisation oder Mischpolymerisation von Olefinen | |
| DE1958488C3 (de) | Polymerisationskatalysatoren, ihre Herstellung und Verwendung | |
| DE1417070A1 (de) | Verfahren zur Herstellung eines Katalysators fuer die Polymerisation von alpha-Olefinen | |
| DE2153520A1 (de) | Verfahren zur selektiven Polymerisation von alpha-Olefinen | |
| DE2701647B2 (de) | Verfahren zur Polymerisation von Olefinen und hierfür verwendbare feste titanhaltige Katalysatorkomponente | |
| DE2904598C2 (en, 2012) | ||
| DE2021831A1 (de) | Verfahren zur Herstellung von Polymerisationskatalysatoren | |
| DE1770726B1 (de) | Verfahren zur polymerisation von aethylen | |
| DE2703557C2 (en, 2012) | ||
| DE1912706B2 (de) | Verfahren zur polymerisation von aethylen | |
| DE2711300A1 (de) | Katalysator und verfahren zur herstellung von polyolefinen | |
| DE2346471C3 (de) | Verfahren zur Homopolymerisation von Äthylen oder Propylen und zur Mischpolymerisation von Äthylen mit einem α-Olefin und/oder Diolefin und Katalysatorzusammensetzung hierfür | |
| DE69216825T2 (de) | Magnesiumchlorid-Komplexe, Verfahren und Verwendung | |
| DE3027956C2 (de) | Feste titanhaltige Katalysatorkomponente | |
| DE1177346B (de) | Verfahren zur Polymerisation von ª‡-olefinischen Kohlenwasserstoffen mit mindestens drei Kohlenstoffatomen | |
| DE1803434B2 (de) | Verfahren zur Dimerisation bzw. Codimerisation von Äthylen und/oder Propylen | |
| DE1917086A1 (de) | Verfahren zur Herstellung von festen,hochmolekularen,hochkristallinen Polyolefinen | |
| DE1266978B (de) | Verfahren zur Polymerisation oder Mischpolymerisation von alpha-Olefinen mit 2 bis 6 Kohlenstoffatomen | |
| DE1442528C3 (de) | Katalysator zum Polymerisieren von alpha-Olefinen und Verfahren zu seiner Herstellung | |
| AT226733B (de) | Verfahren zur Herstellung kristalliner Titanchlorid-Aluminiumchlorid-Katalysatoren | |
| DE2614325A1 (de) | Verfahren zur herstellung von polyolefinen | |
| DE2047140A1 (de) | Verfahren zur Herstellung von Polypropylen und/oder Polybutylen Ölen | |
| DE1770730C2 (de) | Verfahren zur Homo- und Mischpolymerisation von Äthylen | |
| DE2924650A1 (de) | Verfahren zur herstellung von polymeren oder copolymeren von alphaolefinen mit hohem isotaktizitaetsindex |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SH | Request for examination between 03.10.1968 and 22.04.1971 |