DE1294013B - - Google Patents
Info
- Publication number
- DE1294013B DE1294013B DE1959M0043734 DEM0043734A DE1294013B DE 1294013 B DE1294013 B DE 1294013B DE 1959M0043734 DE1959M0043734 DE 1959M0043734 DE M0043734 A DEM0043734 A DE M0043734A DE 1294013 B DE1294013 B DE 1294013B
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- reaction zone
- initiator
- injected
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 74
- 239000005977 Ethylene Substances 0.000 claims description 74
- 238000006243 chemical reaction Methods 0.000 claims description 50
- 239000003999 initiator Substances 0.000 claims description 30
- 238000006116 polymerization reaction Methods 0.000 claims description 26
- 238000002347 injection Methods 0.000 claims description 20
- 239000007924 injection Substances 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 11
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 7
- 230000000052 comparative effect Effects 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 6
- 239000001294 propane Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000002474 experimental method Methods 0.000 claims description 4
- 239000003607 modifier Substances 0.000 claims description 4
- -1 oxygen Chemical class 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 210000004072 lung Anatomy 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 238000012360 testing method Methods 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 9
- 229920001577 copolymer Polymers 0.000 claims 4
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 10
- 230000008901 benefit Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78095358A | 1958-12-17 | 1958-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1294013B true DE1294013B (cg-RX-API-DMAC10.html) | 1969-04-30 |
| DE1294013C2 DE1294013C2 (de) | 1980-07-03 |
Family
ID=25121193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1959M0043734 Expired DE1294013C2 (de) | 1958-12-17 | 1959-12-17 | Verfahren zur polymerisation von aethylen und mischpolymerisation desselben mit anderen olefinen oder vinylverbindungen |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE585741A (cg-RX-API-DMAC10.html) |
| DE (1) | DE1294013C2 (cg-RX-API-DMAC10.html) |
| FR (1) | FR1248159A (cg-RX-API-DMAC10.html) |
| GB (1) | GB934444A (cg-RX-API-DMAC10.html) |
| NL (1) | NL246540A (cg-RX-API-DMAC10.html) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3725378A (en) * | 1958-12-17 | 1973-04-03 | Monsanto Co | Polymerization of ethylene |
| NL126425C (cg-RX-API-DMAC10.html) * | 1961-07-21 | |||
| BE621998A (cg-RX-API-DMAC10.html) * | 1961-09-01 | |||
| DE2124221B2 (de) * | 1971-05-15 | 1980-10-30 | Imhausen International Co. Reg. Trust, Vaduz | Verfahren zur kontinuierlichen Polymerisation von Äthylen |
| DE3308804A1 (de) * | 1983-03-12 | 1984-09-13 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von ethylenpolymerisaten bei druecken oberhalb von 500 bar in einem zweizonen-rohrreaktor |
| KR101971308B1 (ko) | 2011-10-19 | 2019-04-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 저 밀도 에틸렌계 중합체의 제조를 위한 프레쉬 에틸렌 분포를 사용한 중합 방법 |
| RU2694046C2 (ru) * | 2014-10-01 | 2019-07-09 | Базелл Полиолефин Гмбх | Полиэтилен низкой плотности с высоким значением продольного упрочнения |
| MX2018007698A (es) * | 2015-12-22 | 2018-11-09 | Braskem Sa | Dispositivo inyector iniciador de polimerizacion en un reactor tubular, reactor tubular para polimerizacion continua de olefinas, y un proceso para la produccion de polimeros y copolimeros de etileno. |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB772890A (en) * | 1954-06-30 | 1957-04-17 | Esso Res | Improvements in or relating to polymerization process |
-
0
- NL NL246540D patent/NL246540A/xx unknown
- BE BE585741D patent/BE585741A/xx unknown
-
1959
- 1959-12-14 GB GB4238359A patent/GB934444A/en not_active Expired
- 1959-12-15 FR FR813119A patent/FR1248159A/fr not_active Expired
- 1959-12-17 DE DE1959M0043734 patent/DE1294013C2/de not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB772890A (en) * | 1954-06-30 | 1957-04-17 | Esso Res | Improvements in or relating to polymerization process |
Also Published As
| Publication number | Publication date |
|---|---|
| NL246540A (cg-RX-API-DMAC10.html) | |
| GB934444A (en) | 1963-08-21 |
| BE585741A (cg-RX-API-DMAC10.html) | |
| FR1248159A (fr) | 1960-12-09 |
| DE1294013C2 (de) | 1980-07-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C2 | Grant after previous publication (2nd publication) |