DE1289426B - Verfahren zum Fixieren von Bildern in einer Schicht aus photochromen stickstoffhaltigen Spiropyranverbindungen - Google Patents
Verfahren zum Fixieren von Bildern in einer Schicht aus photochromen stickstoffhaltigen SpiropyranverbindungenInfo
- Publication number
- DE1289426B DE1289426B DEN26162A DEN0026162A DE1289426B DE 1289426 B DE1289426 B DE 1289426B DE N26162 A DEN26162 A DE N26162A DE N0026162 A DEN0026162 A DE N0026162A DE 1289426 B DE1289426 B DE 1289426B
- Authority
- DE
- Germany
- Prior art keywords
- layer
- silver
- photochromic
- image
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 17
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 title claims description 4
- 150000001875 compounds Chemical class 0.000 title description 23
- 230000008569 process Effects 0.000 title description 5
- 229910052709 silver Inorganic materials 0.000 claims description 28
- 239000004332 silver Substances 0.000 claims description 28
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 16
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 14
- 239000012266 salt solution Substances 0.000 claims description 9
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 9
- -1 silver halide Chemical class 0.000 claims description 8
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 7
- 229910000039 hydrogen halide Inorganic materials 0.000 claims description 5
- 239000012433 hydrogen halide Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- 239000010410 layer Substances 0.000 description 37
- 235000019441 ethanol Nutrition 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- 239000011521 glass Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
- FAQVDANXTSFXGA-UHFFFAOYSA-N 2,3-dihydro-1h-benzo[g]indole Chemical compound C1=CC=CC2=C(NCC3)C3=CC=C21 FAQVDANXTSFXGA-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000006193 liquid solution Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- VCMLCMCXCRBSQO-UHFFFAOYSA-N 3h-benzo[f]chromene Chemical class C1=CC=CC2=C(C=CCO3)C3=CC=C21 VCMLCMCXCRBSQO-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004870 electrical engineering Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- UKLQKMNBHOMVOE-UHFFFAOYSA-N spiro[1,3-dihydrobenzo[g]indole-2,2'-pyran] Chemical class O1C2(C=CC=C1)NC1=C3C(=CC=C1C2)C=CC=C3 UKLQKMNBHOMVOE-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/56—Processes using photosensitive compositions covered by the groups G03C1/64 - G03C1/72 or agents therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/685—Compositions containing spiro-condensed pyran compounds or derivatives thereof, as photosensitive substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/163—Radiation-chromic compound
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US342492A US3364023A (en) | 1964-02-04 | 1964-02-04 | Formation of silver images from ultraviolet-light-induced benzoindolinospiropyran dye images |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1289426B true DE1289426B (de) | 1969-02-13 |
Family
ID=23342062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEN26162A Pending DE1289426B (de) | 1964-02-04 | 1965-02-04 | Verfahren zum Fixieren von Bildern in einer Schicht aus photochromen stickstoffhaltigen Spiropyranverbindungen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3364023A (en, 2012) |
| AT (1) | AT257356B (en, 2012) |
| BE (1) | BE659192A (en, 2012) |
| CH (1) | CH430767A (en, 2012) |
| DE (1) | DE1289426B (en, 2012) |
| DK (1) | DK116490B (en, 2012) |
| FR (1) | FR1423421A (en, 2012) |
| GB (1) | GB1030218A (en, 2012) |
| NL (1) | NL6500515A (en, 2012) |
| SE (1) | SE327332B (en, 2012) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3445225A (en) * | 1965-10-01 | 1969-05-20 | Xerox Corp | Electrophotographic imaging process |
| US3510308A (en) * | 1965-12-20 | 1970-05-05 | Ncr Co | Light sensitive complexes of benzoindolinospiropyrans and halides of group ii-b metals |
| US3532540A (en) * | 1967-10-26 | 1970-10-06 | Ncr Co | Differential adhesion process for making high resolution thin film patterns |
| GB1273746A (en) * | 1968-10-03 | 1972-05-10 | Agfa Gevaert | Unsaturated photochromic monomers and polymers prepared therefrom |
| US3884697A (en) * | 1969-03-31 | 1975-05-20 | Eiichi Inoue | Photographic process utilizing spiropyran compound dispersed in nitrocellulose films with high nitrogen content |
| ATE251316T1 (de) | 1999-07-08 | 2003-10-15 | Kromotek Ltd | Trockenverfahren zur herstellung photographischer abzüge |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3152903A (en) * | 1959-04-30 | 1964-10-13 | Minnesota Mining & Mfg | Reproduction system |
| US3212898A (en) * | 1962-11-21 | 1965-10-19 | American Cyanamid Co | Photosensitive compositions of matter comprising photochromic materials suspended in polyester binders |
-
1964
- 1964-02-04 US US342492A patent/US3364023A/en not_active Expired - Lifetime
- 1964-12-17 SE SE15273/64A patent/SE327332B/xx unknown
- 1964-12-21 GB GB51793/64A patent/GB1030218A/en not_active Expired
-
1965
- 1965-01-15 NL NL6500515A patent/NL6500515A/xx unknown
- 1965-01-18 DK DK25865AA patent/DK116490B/da unknown
- 1965-02-03 FR FR4182A patent/FR1423421A/fr not_active Expired
- 1965-02-03 CH CH150565A patent/CH430767A/fr unknown
- 1965-02-03 BE BE659192A patent/BE659192A/xx unknown
- 1965-02-03 AT AT94065A patent/AT257356B/de active
- 1965-02-04 DE DEN26162A patent/DE1289426B/de active Pending
Non-Patent Citations (1)
| Title |
|---|
| None * |
Also Published As
| Publication number | Publication date |
|---|---|
| US3364023A (en) | 1968-01-16 |
| NL6500515A (en, 2012) | 1965-08-05 |
| SE327332B (en, 2012) | 1970-08-17 |
| FR1423421A (fr) | 1966-01-03 |
| GB1030218A (en) | 1966-05-18 |
| AT257356B (de) | 1967-10-10 |
| CH430767A (fr) | 1967-02-28 |
| BE659192A (en, 2012) | 1965-05-28 |
| DK116490B (da) | 1970-01-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1572203C3 (de) | Verfahren zur Herstellung eines wärmeentwickelbaren Blattmaterials mit einem strahlungsempfindlichen Überzug | |
| DE737289C (de) | Lichtempfindliches photographisches Material | |
| DE1289426B (de) | Verfahren zum Fixieren von Bildern in einer Schicht aus photochromen stickstoffhaltigen Spiropyranverbindungen | |
| DE2436132A1 (de) | Verfahren und aufzeichnungstraeger fuer die aufzeichnung von abbildungen bzw. nachrichten | |
| DE1073306B (de) | Bildempfangsmaterial zur Verwendung im photographischen Silbersalzdiffusions-Ubertragungsverfahren und Verfahren zu dessen Herstellung | |
| DE1283092B (de) | Lichtempfindliche Schicht | |
| DE1572025A1 (de) | Photographische Erzeugnisse und Verfahren zur Herstellung sichtbarer Bilder durch Diffusionsuebertragung | |
| DE1003578B (de) | Verfahren zur Herstellung von photographischen Bildern und Mittel zur Durchfuehrung desselben | |
| DE1106171B (de) | Diazotypiematerial und Verfahren zur Herstellung von Lichtpausen | |
| DE1597540A1 (de) | Verwendung von Oniumhalogeniden als Silberhalogenidkomplexbildner zum Stabilisieren photographischer Silberhalogenidbilder | |
| DE1547902A1 (de) | Lichtempfindliche photographische Zubereitung | |
| DE2611334C2 (de) | Thermophotographisches Aufzeichnungsmaterial | |
| DE2105488A1 (de) | Verfahren zur Herstellung photographischer Bilder | |
| DE2406515B2 (de) | Photographisches material fuer die herstellung von direktpositiven | |
| DE896294C (de) | Verfahren zur Herstellung photographischer Registrierungen und lichtempfindliches Material zur Ausfuehrung des Verfahrens | |
| DE2111980C3 (de) | Verfahren zum Modifizieren von Vesikularbildern | |
| DE867053C (de) | Verfahren zur Herstellung von photographischen Kontrasten, welche aus Metallbildern bestehen, die durch physikalische Entwicklung von in photographischen Schichten erzeugten latenten Bildern erhalten worden sind | |
| DE2133515C3 (en, 2012) | ||
| AT156682B (de) | Verfahren zur Erzeugung von Kontrasten mittels einer Diazoniumverbindung und dazu geeignete Schichten. | |
| DE2038207C3 (de) | Verfahren zum Ausbleichen von Sensibillsierungsfarbstoffen in einer photoleitfähkjen Schicht | |
| DE1572141A1 (de) | Fotografisches Material | |
| DE2018063A1 (de) | Diffusionsübertragungsverfahren | |
| DE1597554C (de) | Photographisches Aufzeichnungsmaterial | |
| DE888045C (de) | Verfahren zur Herstellung lichtempfindlicher Schichten, deren latentes Bild durch Einwirkung von Waerme entwickelbar ist | |
| DE707461C (de) | Verfahren zur Erzeugung von Bildern mittels oertlicher Belichtung einer mit einer Diazoniumverbindung lichtempfindlich gemachten Schicht |