DE1256411C2 - Thermoplastische formmassen mit antistatischen eigenschaften - Google Patents
Thermoplastische formmassen mit antistatischen eigenschaftenInfo
- Publication number
- DE1256411C2 DE1256411C2 DE1966F0048594 DEF0048594A DE1256411C2 DE 1256411 C2 DE1256411 C2 DE 1256411C2 DE 1966F0048594 DE1966F0048594 DE 1966F0048594 DE F0048594 A DEF0048594 A DE F0048594A DE 1256411 C2 DE1256411 C2 DE 1256411C2
- Authority
- DE
- Germany
- Prior art keywords
- percent
- weight
- styrene
- acrylonitrile
- graft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title claims description 8
- 238000009757 thermoplastic moulding Methods 0.000 title claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 120
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 42
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 40
- 229920001577 copolymer Polymers 0.000 claims description 34
- 229920001451 polypropylene glycol Polymers 0.000 claims description 33
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 23
- 229920000570 polyether Polymers 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- 150000001993 dienes Chemical class 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 9
- 238000007600 charging Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 229920000578 graft copolymer Polymers 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- -1 arylalkyl phosphates Chemical class 0.000 claims description 4
- 239000001530 fumaric acid Substances 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 claims 3
- 238000007786 electrostatic charging Methods 0.000 claims 3
- 229920001515 polyalkylene glycol Polymers 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000000428 dust Substances 0.000 claims 2
- 229920000098 polyolefin Polymers 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 229920008347 Cellulose acetate propionate Polymers 0.000 claims 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 229920006218 cellulose propionate Polymers 0.000 claims 1
- 230000001268 conjugating effect Effects 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000002334 glycols Chemical class 0.000 claims 1
- 230000001771 impaired effect Effects 0.000 claims 1
- 210000003734 kidney Anatomy 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 claims 1
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 229920000151 polyglycol Polymers 0.000 claims 1
- 239000010695 polyglycol Substances 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- 150000005846 sugar alcohols Polymers 0.000 claims 1
- 239000000047 product Substances 0.000 description 48
- 239000004816 latex Substances 0.000 description 33
- 229920000126 latex Polymers 0.000 description 33
- 238000006116 polymerization reaction Methods 0.000 description 20
- 239000000839 emulsion Substances 0.000 description 18
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 8
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 6
- 229920002292 Nylon 6 Polymers 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 229920002239 polyacrylonitrile Polymers 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000004429 atom Chemical class 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 125000004494 ethyl ester group Chemical group 0.000 description 2
- 238000010559 graft polymerization reaction Methods 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000010626 work up procedure Methods 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
- LLQHSBBZNDXTIV-UHFFFAOYSA-N 6-[5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-4,5-dihydro-1,2-oxazol-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC1CC(=NO1)C1=CC2=C(NC(O2)=O)C=C1 LLQHSBBZNDXTIV-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000251730 Chondrichthyes Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1966F0048594 DE1256411C2 (de) | 1966-03-05 | 1966-03-05 | Thermoplastische formmassen mit antistatischen eigenschaften |
| US612084A US3502744A (en) | 1966-03-05 | 1967-01-27 | Antistatic molding compositions based on thermoplastic graft copolymer mixtures |
| GB6033/67A GB1111369A (en) | 1966-03-05 | 1967-02-08 | Antistatic thermoplastic copolymers |
| SE02390/67A SE337694B (https=) | 1966-03-05 | 1967-02-21 | |
| ES337350A ES337350A1 (es) | 1966-03-05 | 1967-02-28 | Procedimiento para la obtencion de masas moldeables anties-taticas. |
| AT206467A AT271884B (de) | 1966-03-05 | 1967-03-03 | Antistatische Formmassen |
| CH314567A CH490433A (de) | 1966-03-05 | 1967-03-03 | Antistatische Formmasse |
| NL676703475A NL151420B (nl) | 1966-03-05 | 1967-03-03 | Werkwijze voor het bereiden van antistatische vormmassa's. |
| BE694988D BE694988A (https=) | 1966-03-05 | 1967-03-03 | |
| FR97347A FR1513032A (fr) | 1966-03-05 | 1967-03-03 | Copolymères thermoplastiques antistatiques |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1966F0048594 DE1256411C2 (de) | 1966-03-05 | 1966-03-05 | Thermoplastische formmassen mit antistatischen eigenschaften |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1256411B DE1256411B (de) | 1967-12-14 |
| DE1256411C2 true DE1256411C2 (de) | 1977-02-24 |
Family
ID=7102348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1966F0048594 Expired DE1256411C2 (de) | 1966-03-05 | 1966-03-05 | Thermoplastische formmassen mit antistatischen eigenschaften |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3502744A (https=) |
| AT (1) | AT271884B (https=) |
| BE (1) | BE694988A (https=) |
| CH (1) | CH490433A (https=) |
| DE (1) | DE1256411C2 (https=) |
| ES (1) | ES337350A1 (https=) |
| FR (1) | FR1513032A (https=) |
| GB (1) | GB1111369A (https=) |
| NL (1) | NL151420B (https=) |
| SE (1) | SE337694B (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3676526A (en) * | 1967-06-02 | 1972-07-11 | Eugene G Sommerfeld | Polymeric dispersion of a diene-acrylonitrite graft copolymer with a different graft copolymer |
| US3891584A (en) * | 1974-02-22 | 1975-06-24 | Nat Starch Chem Corp | Water-dispersible hot melt adhesives and products using same |
| JPS5536238A (en) * | 1978-09-06 | 1980-03-13 | Kureha Chem Ind Co Ltd | Antistatic resin composition |
| US4250271A (en) * | 1979-05-15 | 1981-02-10 | Cosden Technology, Inc. | ABS-Type polyblend compositions |
| US4389505A (en) * | 1981-12-16 | 1983-06-21 | Mobil Oil Corporation | Plasticized polyacrylonitrile, a film thereof and a process for film preparation and plasticization |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1410262A (fr) * | 1963-07-11 | 1965-09-10 | Bayer Ag | Copolymères élastiques-thermoplastiques à propriétés antistatiques |
| DE1244398B (de) * | 1963-07-11 | 1967-07-13 | Bayer Ag | Antistatische thermoplastische Formmassen |
| US3354108A (en) * | 1964-06-19 | 1967-11-21 | Monsanto Co | Graft blend of diene rubber polymeric compositions having improved toughness |
-
1966
- 1966-03-05 DE DE1966F0048594 patent/DE1256411C2/de not_active Expired
-
1967
- 1967-01-27 US US612084A patent/US3502744A/en not_active Expired - Lifetime
- 1967-02-08 GB GB6033/67A patent/GB1111369A/en not_active Expired
- 1967-02-21 SE SE02390/67A patent/SE337694B/xx unknown
- 1967-02-28 ES ES337350A patent/ES337350A1/es not_active Expired
- 1967-03-03 BE BE694988D patent/BE694988A/xx unknown
- 1967-03-03 NL NL676703475A patent/NL151420B/xx unknown
- 1967-03-03 FR FR97347A patent/FR1513032A/fr not_active Expired
- 1967-03-03 AT AT206467A patent/AT271884B/de active
- 1967-03-03 CH CH314567A patent/CH490433A/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES337350A1 (es) | 1968-02-16 |
| GB1111369A (en) | 1968-04-24 |
| BE694988A (https=) | 1967-08-14 |
| DE1256411B (de) | 1967-12-14 |
| AT271884B (de) | 1969-06-25 |
| SE337694B (https=) | 1971-08-16 |
| NL151420B (nl) | 1976-11-15 |
| US3502744A (en) | 1970-03-24 |
| CH490433A (de) | 1970-05-15 |
| NL6703475A (https=) | 1967-09-06 |
| FR1513032A (fr) | 1968-02-09 |
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