DE1203473B - Verfahren zur Polymerisation von Aethylen - Google Patents
Verfahren zur Polymerisation von AethylenInfo
- Publication number
- DE1203473B DE1203473B DEP18251A DEP0018251A DE1203473B DE 1203473 B DE1203473 B DE 1203473B DE P18251 A DEP18251 A DE P18251A DE P0018251 A DEP0018251 A DE P0018251A DE 1203473 B DE1203473 B DE 1203473B
- Authority
- DE
- Germany
- Prior art keywords
- reactor
- catalyst
- polymer
- ethylene
- cyclohexane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 26
- 239000005977 Ethylene Substances 0.000 title claims description 26
- 238000000034 method Methods 0.000 title claims description 12
- 238000006116 polymerization reaction Methods 0.000 title claims description 11
- 239000003054 catalyst Substances 0.000 claims description 43
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 229920000642 polymer Polymers 0.000 claims description 26
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 9
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 3
- 238000000975 co-precipitation Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 238000002474 experimental method Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 239000000725 suspension Substances 0.000 claims 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 9
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241001026509 Kata Species 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- -1 η-decane Chemical compound 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US57460956A | 1956-03-29 | 1956-03-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1203473B true DE1203473B (de) | 1965-10-21 |
Family
ID=24296849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEP18251A Pending DE1203473B (de) | 1956-03-29 | 1957-03-29 | Verfahren zur Polymerisation von Aethylen |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE556107A (enrdf_load_stackoverflow) |
| DE (1) | DE1203473B (enrdf_load_stackoverflow) |
| FR (1) | FR1173074A (enrdf_load_stackoverflow) |
| GB (1) | GB834933A (enrdf_load_stackoverflow) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE858394C (de) * | 1938-12-23 | 1952-12-08 | Basf Ag | Verfahren zur Polymerisation von Olefinen zu Kohlenwasserstoffoelen |
| DE879099C (de) * | 1951-03-31 | 1953-06-11 | Basf Ag | Verfahren zur Herstellung von kieselsaeurehaltigen Katalysatoren |
| US2710854A (en) * | 1952-12-06 | 1955-06-14 | Standard Oil Co | Ethylene polymerization with catalyst composed of a group via metal oxide and an alkaline earth carbide |
| US2780617A (en) * | 1952-05-17 | 1957-02-05 | Standard Oil Co | Ethylene polymerization with conditioned molybdena catalyst |
-
0
- BE BE556107D patent/BE556107A/xx unknown
-
1957
- 1957-03-15 GB GB858557A patent/GB834933A/en not_active Expired
- 1957-03-19 FR FR1173074D patent/FR1173074A/fr not_active Expired
- 1957-03-29 DE DEP18251A patent/DE1203473B/de active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE858394C (de) * | 1938-12-23 | 1952-12-08 | Basf Ag | Verfahren zur Polymerisation von Olefinen zu Kohlenwasserstoffoelen |
| DE879099C (de) * | 1951-03-31 | 1953-06-11 | Basf Ag | Verfahren zur Herstellung von kieselsaeurehaltigen Katalysatoren |
| US2780617A (en) * | 1952-05-17 | 1957-02-05 | Standard Oil Co | Ethylene polymerization with conditioned molybdena catalyst |
| US2710854A (en) * | 1952-12-06 | 1955-06-14 | Standard Oil Co | Ethylene polymerization with catalyst composed of a group via metal oxide and an alkaline earth carbide |
Also Published As
| Publication number | Publication date |
|---|---|
| GB834933A (enrdf_load_stackoverflow) | 1960-05-11 |
| BE556107A (enrdf_load_stackoverflow) | |
| FR1173074A (fr) | 1959-02-19 |
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