DE1168859B - Verfahren zum Bleichen von Chloriten nach dem Klotz-Daempf-Verfahren - Google Patents
Verfahren zum Bleichen von Chloriten nach dem Klotz-Daempf-VerfahrenInfo
- Publication number
- DE1168859B DE1168859B DEF24012A DEF0024012A DE1168859B DE 1168859 B DE1168859 B DE 1168859B DE F24012 A DEF24012 A DE F24012A DE F0024012 A DEF0024012 A DE F0024012A DE 1168859 B DE1168859 B DE 1168859B
- Authority
- DE
- Germany
- Prior art keywords
- bleaching
- acids
- acid
- salts
- chlorites
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 21
- 238000004061 bleaching Methods 0.000 title claims description 16
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical class OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 title claims description 15
- 239000002253 acid Substances 0.000 claims description 31
- 150000007513 acids Chemical class 0.000 claims description 18
- 150000003839 salts Chemical class 0.000 claims description 14
- 238000005470 impregnation Methods 0.000 claims description 7
- 238000010025 steaming Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000004753 textile Substances 0.000 claims description 3
- 229910001919 chlorite Inorganic materials 0.000 description 10
- 229910052619 chlorite group Inorganic materials 0.000 description 10
- 239000002585 base Substances 0.000 description 8
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000004913 activation Effects 0.000 description 5
- 239000004155 Chlorine dioxide Substances 0.000 description 4
- 235000019398 chlorine dioxide Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000003111 delayed effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 235000011054 acetic acid Nutrition 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000012928 buffer substance Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 2
- 229960002218 sodium chlorite Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001632422 Radiola linoides Species 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 235000019846 buffering salt Nutrition 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/20—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen
- D06L4/22—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents
- D06L4/24—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using chlorites or chlorine dioxide
- D06L4/26—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using chlorites or chlorine dioxide combined with specific additives
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL96757D NL96757C (en:Method) | 1957-09-24 | ||
BE571470D BE571470A (en:Method) | 1957-09-24 | ||
DEF24012A DE1168859B (de) | 1957-09-24 | 1957-09-24 | Verfahren zum Bleichen von Chloriten nach dem Klotz-Daempf-Verfahren |
US761936A US3065040A (en) | 1957-09-24 | 1958-09-19 | Textile bleaching process using chlorite bleaching baths |
GB30522/58A GB898677A (en) | 1957-09-24 | 1958-09-24 | Process for bleaching textile materials with chlorites |
FR1203379D FR1203379A (fr) | 1957-09-24 | 1958-09-24 | Procédé de blanchiment au moyen de chlorites selon le procédé combiné de foulardage et de vaporisage |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF24012A DE1168859B (de) | 1957-09-24 | 1957-09-24 | Verfahren zum Bleichen von Chloriten nach dem Klotz-Daempf-Verfahren |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1168859B true DE1168859B (de) | 1964-04-30 |
Family
ID=7091071
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEF24012A Pending DE1168859B (de) | 1957-09-24 | 1957-09-24 | Verfahren zum Bleichen von Chloriten nach dem Klotz-Daempf-Verfahren |
Country Status (6)
Country | Link |
---|---|
US (1) | US3065040A (en:Method) |
BE (1) | BE571470A (en:Method) |
DE (1) | DE1168859B (en:Method) |
FR (1) | FR1203379A (en:Method) |
GB (1) | GB898677A (en:Method) |
NL (1) | NL96757C (en:Method) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3238226A (en) * | 1962-02-19 | 1966-03-01 | Nat Polychemicals Inc | Synthesis of hydrazine, semi-carbazide, and hydrazinedicarbonamide |
USRE31779E (en) * | 1976-03-26 | 1984-12-25 | Alcide Corporation | Germ-killing composition and method |
US4236891A (en) * | 1979-02-05 | 1980-12-02 | Olin Corporation | Process for textile bleaching with dibasic magnesium hypochlorite |
US4310425A (en) * | 1980-04-17 | 1982-01-12 | Halabs, Incorporated | Inhibited oil field drilling fluid |
US4986990A (en) * | 1984-03-21 | 1991-01-22 | Alcide Corporation | Disinfection method and composition therefor |
US5185161A (en) * | 1984-03-21 | 1993-02-09 | Alcide Corporation | Disinfection method and composition therefor |
US4891216A (en) * | 1987-04-14 | 1990-01-02 | Alcide Corporation | Disinfecting compositions and methods therefor |
US4880556A (en) * | 1987-05-26 | 1989-11-14 | The Drackett Company | Aqueous alkali metal halogenite compositions containing a colorant |
US4963287A (en) * | 1987-05-26 | 1990-10-16 | The Drackett Company | Aqueous alkali metal halogenite compositions |
US4790950A (en) * | 1988-03-07 | 1988-12-13 | The Drackett Company | Aqueous alkali metal halogenite compositions containing a colorant stabilized by NH4 OH |
US4873013A (en) * | 1988-03-07 | 1989-10-10 | The Dracket Company | Aqueous alkali metal halogenite compositions containing a colorant stabilized by ammonium hydroxide |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH293680A (de) * | 1949-12-27 | 1953-10-15 | Hoechst Ag | Haltbares Hilfsmittel für die Bleiche mit wässerigen Lösungen von Chloriten oder Chlordioxyd. |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2521340A (en) * | 1945-05-16 | 1950-09-05 | Olin Mathieson | Bleaching of cellulosic textiles |
DE941665C (de) * | 1951-04-19 | 1956-04-19 | Val Mehler Segeltuchweberei Ag | Verfahren zum Bleichen von Textilien |
US2739032A (en) * | 1953-03-30 | 1956-03-20 | William K Wilson | Iron-catalyzed decomposition of sodium chlorite |
BE534142A (en:Method) * | 1953-12-15 | |||
US2810717A (en) * | 1955-02-07 | 1957-10-22 | Hercules Powder Co Ltd | Chlorite bleaching in the presence of a nitrogen compound employed as a corrosion inhibitor |
-
0
- BE BE571470D patent/BE571470A/xx unknown
- NL NL96757D patent/NL96757C/xx active
-
1957
- 1957-09-24 DE DEF24012A patent/DE1168859B/de active Pending
-
1958
- 1958-09-19 US US761936A patent/US3065040A/en not_active Expired - Lifetime
- 1958-09-24 GB GB30522/58A patent/GB898677A/en not_active Expired
- 1958-09-24 FR FR1203379D patent/FR1203379A/fr not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH293680A (de) * | 1949-12-27 | 1953-10-15 | Hoechst Ag | Haltbares Hilfsmittel für die Bleiche mit wässerigen Lösungen von Chloriten oder Chlordioxyd. |
Also Published As
Publication number | Publication date |
---|---|
GB898677A (en) | 1962-06-14 |
BE571470A (en:Method) | |
US3065040A (en) | 1962-11-20 |
FR1203379A (fr) | 1960-01-18 |
NL96757C (en:Method) |
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