DE1160304B - Verfahren zur Herstellung lichtleitfaehiger Schichten aus Poly-(N-vinylcarbazol) - Google Patents

Verfahren zur Herstellung lichtleitfaehiger Schichten aus Poly-(N-vinylcarbazol)

Info

Publication number
DE1160304B
DE1160304B DEG33483A DEG0033483A DE1160304B DE 1160304 B DE1160304 B DE 1160304B DE G33483 A DEG33483 A DE G33483A DE G0033483 A DEG0033483 A DE G0033483A DE 1160304 B DE1160304 B DE 1160304B
Authority
DE
Germany
Prior art keywords
vinylcarbazole
poly
production
light
conductive layers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEG33483A
Other languages
English (en)
Inventor
Dr-Chem Paul Maria Cassiers
Dr-Chem Rene Maurice Hart
Dr-Chem Jean Marie Nys
Dr-Chem Jozef Frans Willems
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gevaert Photo Producten NV
Original Assignee
Gevaert Photo Producten NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gevaert Photo Producten NV filed Critical Gevaert Photo Producten NV
Priority claimed from BE589995A external-priority patent/BE589995R/fr
Priority claimed from BE589994A external-priority patent/BE589994R/fr
Publication of DE1160304B publication Critical patent/DE1160304B/de
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/14Inert intermediate or cover layers for charge-receiving layers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F26/12N-Vinyl-carbazole
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/02Alkylation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/28Condensation with aldehydes or ketones
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/72Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
    • G03C1/73Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705 containing organic compounds
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G13/00Electrographic processes using a charge pattern
    • G03G13/04Exposing, i.e. imagewise exposure by optically projecting the original image on a photoconductive recording material
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/026Layers in which during the irradiation a chemical reaction occurs whereby electrically conductive patterns are formed in the layers, e.g. for chemixerography
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/043Photoconductive layers characterised by having two or more layers or characterised by their composite structure
    • G03G5/047Photoconductive layers characterised by having two or more layers or characterised by their composite structure characterised by the charge-generation layers or charge transport layers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0601Acyclic or carbocyclic compounds
    • G03G5/0612Acyclic or carbocyclic compounds containing nitrogen
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0601Acyclic or carbocyclic compounds
    • G03G5/0618Acyclic or carbocyclic compounds containing oxygen and nitrogen
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0622Heterocyclic compounds
    • G03G5/0624Heterocyclic compounds containing one hetero ring
    • G03G5/0627Heterocyclic compounds containing one hetero ring being five-membered
    • G03G5/0629Heterocyclic compounds containing one hetero ring being five-membered containing one hetero atom
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0622Heterocyclic compounds
    • G03G5/0624Heterocyclic compounds containing one hetero ring
    • G03G5/0627Heterocyclic compounds containing one hetero ring being five-membered
    • G03G5/0633Heterocyclic compounds containing one hetero ring being five-membered containing three hetero atoms
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0622Heterocyclic compounds
    • G03G5/0624Heterocyclic compounds containing one hetero ring
    • G03G5/0635Heterocyclic compounds containing one hetero ring being six-membered
    • G03G5/0637Heterocyclic compounds containing one hetero ring being six-membered containing one hetero atom
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/07Polymeric photoconductive materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Graft Or Block Polymers (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Description

Die Erfindung bezieht sich auf ein elektrophotographisches Material, das aus einem Träger und einer lichtleitfähigen Schicht aus Poly-(N-vinylcarbazol) besteht.
Bringt man zur Herstellung elektrisch isolierender, photoleitfähiger Schichten für elektrophotographische Zwecke Polymerisate von N-Vinylcarbazol in Form von Lösungen in geeigneten Lösungsmitteln, z. B. Benzol, Methylenchlorid, Dioxan, Trichloräthylen und Cloroform, oder in Form von Dispersionen in einem geeigneten Dispersionsmittel, z. B. Glykolmonoäthyläther, Wasser und Butanol, auf Träger auf, so erhält man Materialien, deren Schichthaftung nach dem Trocknen je nach dem verwendeten Träger mehr oder weniger gering ist. Die Haftung ist insbesondere dann unzureichend, wenn als Träger für die lichtleitende polymere Schicht eine Aluminiumfolie verwendet wird. Eine derart beschichtete Aluminiumfolie darf nicht scharf gebogen oder geknickt werden, da dabei meist eine Beschädigung der lichtleitenden Schicht eintritt.
Diesem Nachteil will die Erfindung abhelfen.
Erfindungsgemäß wird ein elektrophotographisches Material, das aus einem Träger und einer auf diesem Träger aufgebrachten lichtleitfähigen Schicht aus Poly-CN-vinylcarbazol) besteht, dadurch hergestellt, daß Vinylcarbazol in situ auf der Oberfläche des Trägers polymerisiert wird. Zu diesem Zweck bringt man Vinylcarbazol oder Mischungen von Vinylcarbazol und Poly-(N-vinylcarbazol) auf die zu beschichtende Oberfläche auf und ruft dann nach einer der in der polymeren Chemie bekannten Methoden eine Polymerisation, Kondensation oder Brückenbildung hervor. Die auf diese Weise erzeugten lichtleitfähigen Schichten haften fest auf dem Träger, auf den sie aufgetragen wurden.
Die Erfindung ist im nachstehenden beispielsweise veranschaulicht.
Beispiel 1
Die Oberfläche eines hohlen Aluminiumzylinders wird durch Sandstrahlen leicht aufgerauht, gründlich entfettet und mit einer Schicht aus einer Lösung der folgenden Zusammensetzung beschichtet:
Monomeres N-Vinylcarbazol 200 g
Methylenchlorid 1000 ml
Azo-bis-isobutyronitril 2 g
Nach der Trocknung wird der Zylinder in einen Ofen mit einer Stickstoffatmosphäre gebracht, die Ofentemperatur wird im Laufe von 2 Stunden auf Verfahren zur Herstellung
lichtleitfähiger Schichten
aus Poly-(N-vinylcarbazol)
Anmelder:
Gevaert Photo-Producten N. V.,
Mortsel, Antwerpen (Belgien)
Vertreter: Dr. W. Müller-Bore
und Dipl.-Ing. H. Gralfs, Patentanwälte,
Braunschweig, Am Bürgerpark 8
Beanspruchte Priorität:
Großbritannien vom 26. Februar 1959 (Nr. 6790)
Dr.-Chem. Paul Maria Cassiers, Mortsel, Antwerpen, Dr.-Chem. Rene Maurice Hart, Wilrijk, Antwerpen, Dr.-Chem. Jean Marie Nys, Mortsel, Antwerpen,
und Dr.-Chem. Jozef Frans Willems,
Wilrijk, Antwerpen (Belgien),
sind als Erfinder genannt worden
120 bis 130° C erhöht und 15 Stunden auf dieser Höhe gehalten.
Die entstandene Schicht hat eine Dicke von 5 πΐμ. Der Zylinder eignet sich vorzüglich als Aufzeichnungsmaterial in elektrophotographischen Kopierapparaten, in denen auf den aufgeladenen Zylinder ein Bild projiziert, dieses Bild entwickelt und auf ein geeignetes Empfangsmaterial übertragen wird. Die PoIy-(N-vinylcarbazol)-Schicht haftet hervorragend auf dem Zylinder.
Beispiel 2
Es wird wie im Beispiel 1 verfahren, jedoch mit dem Unterschied, daß statt eines hohlen Aluminiumzylinders eine glatte Aluminiumfolie verwendet wird. Auch in diesem Fall erzielt man eine hervorragende Haftung der Poly-(N-vinylcarbazol)-Schicht auf der Oberfläche der Aluminiumfolie, so daß diese Folie scharf geknickt werden kann, ohne der lichtleitfähigen Schicht zu schaden.
Wenn dagegen ein bereits hergestelltes Polymerisat von N-Vinylcarbazol in Lösung auf die Aluminium-
309 770/369
folie aufgetragen wird, tritt bei einem scharfen Knicken der Folie eine Beschädigung ein.

Claims (2)

PATENTANSPRÜCHE:
1. Verfahren zur Herstellung eines elektrophotographischen Materials mit einem leitfähigen Träger und einer lichtleitfähigen Schicht aus Poly-(N-vinylcarbazol), dadurch gekennzeichnet, daß monomeres N-Vinylcarbazol oder eine Mischung von monomerem N-Vinylcarbazol und Poly-(N-vinylcarbazol) auf die Oberfläche des Trägers aufgebracht und in situ polymerisiert wird.
2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß als Träger ein Material aus Aluminium verwendet wird.
© 309 770/369 12.63
DEG33483A 1959-02-26 1960-02-26 Verfahren zur Herstellung lichtleitfaehiger Schichten aus Poly-(N-vinylcarbazol) Pending DE1160304B (de)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
GB679059A GB964871A (en) 1959-02-26 1959-02-26 Improvements in or relating to electrophotography
GB1375359A GB964872A (en) 1959-02-26 1959-04-22 Electrophotographic processes
GB332660 1960-01-29
BE589995A BE589995R (fr) 1960-04-22 1960-04-22 Elektrofotografisch materiaal.
BE589994A BE589994R (fr) 1960-04-22 1960-04-22 Elektrofotografisch materiaal.
BE590299 1960-04-29
BE2039740 1960-04-29

Publications (1)

Publication Number Publication Date
DE1160304B true DE1160304B (de) 1963-12-27

Family

ID=27560769

Family Applications (10)

Application Number Title Priority Date Filing Date
DEG29112A Pending DE1160303B (de) 1959-02-26 1960-02-26 Elektrophotographisches Material
DEG33483A Pending DE1160304B (de) 1959-02-26 1960-02-26 Verfahren zur Herstellung lichtleitfaehiger Schichten aus Poly-(N-vinylcarbazol)
DEG29113A Pending DE1173797B (de) 1959-02-26 1960-02-26 Elektrophotographisches Material
DE1472950A Expired DE1472950C3 (de) 1959-02-26 1960-02-26 Verwendung polymerer organischer Verbindungen als Photoleiter
DE19601797536 Pending DE1797536A1 (de) 1959-02-26 1960-02-26 Verwendung von organischen substanzen als photohalbleiterschicht in einem elektrophotographischen aufzeichnungsmaterial
DEG35491A Pending DE1158367B (de) 1959-02-26 1960-02-26 Verfahren zur Herstellung von elektrophotographischem Material mit photoleitfaehiger Schicht aus Poly-(N-vinylcarbazol)
DEG29511A Pending DE1253051B (de) 1959-02-26 1960-04-22 Verfahren zur Herstellung von elektrophotographischen Bildern
DEG30051A Pending DE1233265B (de) 1959-02-26 1960-07-13 Sensibilisiertes elektrophotographisches Aufzeichnungsmaterial
DEG30052A Pending DE1194255B (de) 1959-02-26 1960-07-13 Sensibilisiertes elektrophotographisches Aufzeichnungsmaterial
DE1961G0031492 Pending DE1288914B (de) 1959-02-26 1961-01-30 Photoleitfaehige Schicht mit einem polymeren Photoleiter

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DEG29112A Pending DE1160303B (de) 1959-02-26 1960-02-26 Elektrophotographisches Material

Family Applications After (8)

Application Number Title Priority Date Filing Date
DEG29113A Pending DE1173797B (de) 1959-02-26 1960-02-26 Elektrophotographisches Material
DE1472950A Expired DE1472950C3 (de) 1959-02-26 1960-02-26 Verwendung polymerer organischer Verbindungen als Photoleiter
DE19601797536 Pending DE1797536A1 (de) 1959-02-26 1960-02-26 Verwendung von organischen substanzen als photohalbleiterschicht in einem elektrophotographischen aufzeichnungsmaterial
DEG35491A Pending DE1158367B (de) 1959-02-26 1960-02-26 Verfahren zur Herstellung von elektrophotographischem Material mit photoleitfaehiger Schicht aus Poly-(N-vinylcarbazol)
DEG29511A Pending DE1253051B (de) 1959-02-26 1960-04-22 Verfahren zur Herstellung von elektrophotographischen Bildern
DEG30051A Pending DE1233265B (de) 1959-02-26 1960-07-13 Sensibilisiertes elektrophotographisches Aufzeichnungsmaterial
DEG30052A Pending DE1194255B (de) 1959-02-26 1960-07-13 Sensibilisiertes elektrophotographisches Aufzeichnungsmaterial
DE1961G0031492 Pending DE1288914B (de) 1959-02-26 1961-01-30 Photoleitfaehige Schicht mit einem polymeren Photoleiter

Country Status (8)

Country Link
US (2) US3113022A (de)
BE (2) BE588049A (de)
DE (10) DE1160303B (de)
DK (2) DK118752B (de)
FR (6) FR1254023A (de)
GB (8) GB964875A (de)
NL (2) NL250781A (de)
SE (2) SE310309B (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2410841A1 (fr) * 1977-12-05 1979-06-29 Honeywell Inc Procede pour l'obtention d'un support d'enregistrement holographique thermoplastique photoconducteur

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3287115A (en) * 1959-05-29 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
BE612087A (de) * 1960-12-29
US3228769A (en) * 1961-05-04 1966-01-11 Minnesota Mining & Mfg Photosensitive copy-sheet comprising zinc oxide and a diazonium compound and method of copying
US3218163A (en) * 1961-05-05 1965-11-16 Bunker Ramo Electro-optical image producing method and apparatus
US3287113A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287117A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductros
US3287121A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287120A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287116A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287122A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287114A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287123A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287118A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3287119A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3220830A (en) * 1961-10-02 1965-11-30 Kenffel & Esser Company Method of developing a negative electrostatic latent image
US3468660A (en) * 1963-02-15 1969-09-23 Azoplate Corp Electrophotographic material comprising a multilayer support having a barrier layer over a duplex paper base
GB1053941A (de) * 1963-06-18
NL140992B (nl) * 1963-07-06 1974-01-15 Kalle Ag Kopieermateriaal, dat een lichtgevoelig diazoniumzout bevat en werkwijze voor het bereiden van dat zout.
US3377165A (en) * 1964-01-22 1968-04-09 Minnesota Mining & Mfg Process of copying utilizing a blush lacquer coating and a photodecomposable progenitor of a plasticizer
US3493369A (en) * 1964-04-03 1970-02-03 Appleton Coated Paper Co Low electrical resistance varnish coatings on an insulating base
US3322540A (en) * 1964-04-16 1967-05-30 Rca Corp Electrophotographic developing method utilizing a thermoplastic photo-conductive layer having entrapped solvent therein
US3410686A (en) * 1964-06-30 1968-11-12 Ibm Development of images
US3411903A (en) * 1964-11-23 1968-11-19 Xerox Corp Xerographic method and plate comprising photoconductive insulating fibers
DE1572058A1 (de) * 1964-12-30 1970-03-05 Keuffel & Esser Co Reprographisches Verfahren
US3443937A (en) * 1965-04-20 1969-05-13 Xerox Corp Image resolution
GB1166451A (en) * 1965-06-16 1969-10-08 Kodak Ltd Photographic Reproduction
US3441410A (en) * 1965-07-01 1969-04-29 Xerox Corp Deformation imaging processes using electrically photosensitive photochromic materials
FR1486795A (de) * 1965-07-16 1967-10-05
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FR1254023A (fr) 1961-02-17
GB988362A (en) 1965-04-07
FR1259087A (fr) 1961-04-21
GB964872A (en) 1964-07-22
GB988361A (en) 1965-04-07
GB964875A (en) 1964-07-22
GB964877A (en) 1964-07-22
NL250781A (de) 1964-02-25
DE1472950C3 (de) 1974-10-31
DE1158367B (de) 1963-11-28
DE1160303B (de) 1963-12-27
GB964871A (en) 1964-07-22
BE588049A (de) 1960-08-26
GB964879A (en) 1964-07-22
DE1472950B2 (de) 1974-03-28
NL7017826A (de) 1971-03-25
DE1194255B (de) 1965-06-03
DE1173797B (de) 1964-07-09
GB988363A (en) 1965-04-07
SE301587B (de) 1968-06-10
DE1253051B (de) 1967-10-26
FR1291570A (fr) 1962-04-27
FR79760E (de) 1963-04-24
DE1288914B (de) 1969-02-06
US3113022A (en) 1963-12-03
FR79707E (fr) 1963-01-11
DE1233265B (de) 1967-01-26
DE1797536A1 (de) 1973-04-19
FR79647E (fr) 1962-12-28
DK117469B (da) 1970-04-27
DK118752B (da) 1970-09-28
DE1472950A1 (de) 1972-03-09
SE310309B (de) 1969-04-21
US3122435A (en) 1964-02-25
BE590299A (de) 1960-10-31

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