DE1157617C2 - Verfahren zur Herstellung von einheitlichen Zinnalkylverbindungen - Google Patents
Verfahren zur Herstellung von einheitlichen ZinnalkylverbindungenInfo
- Publication number
- DE1157617C2 DE1157617C2 DE1959Z0007297 DEZ0007297A DE1157617C2 DE 1157617 C2 DE1157617 C2 DE 1157617C2 DE 1959Z0007297 DE1959Z0007297 DE 1959Z0007297 DE Z0007297 A DEZ0007297 A DE Z0007297A DE 1157617 C2 DE1157617 C2 DE 1157617C2
- Authority
- DE
- Germany
- Prior art keywords
- tin
- aluminum
- reaction
- ether
- tin tetrachloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 40
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 25
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 25
- 229910052782 aluminium Inorganic materials 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 20
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 19
- 150000003512 tertiary amines Chemical class 0.000 claims description 9
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
- 150000002170 ethers Chemical class 0.000 claims description 7
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000012074 organic phase Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 16
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 239000011541 reaction mixture Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 239000007795 chemical reaction product Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RWWNQEOPUOCKGR-UHFFFAOYSA-N tetraethyltin Chemical group CC[Sn](CC)(CC)CC RWWNQEOPUOCKGR-UHFFFAOYSA-N 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- -1 aluminum compound Chemical class 0.000 description 2
- PIMYDFDXAUVLON-UHFFFAOYSA-M chloro(triethyl)stannane Chemical compound CC[Sn](Cl)(CC)CC PIMYDFDXAUVLON-UHFFFAOYSA-M 0.000 description 2
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 2
- YFAXVVMIXZAKSR-UHFFFAOYSA-L dichloro(diethyl)stannane Chemical compound CC[Sn](Cl)(Cl)CC YFAXVVMIXZAKSR-UHFFFAOYSA-L 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- GURLNXRFQUUOMW-UHFFFAOYSA-K [Al](Cl)(Cl)Cl.[AlH3] Chemical compound [Al](Cl)(Cl)Cl.[AlH3] GURLNXRFQUUOMW-UHFFFAOYSA-K 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SOGXWMAAMKKQCB-UHFFFAOYSA-M chloroalumane Chemical class Cl[AlH2] SOGXWMAAMKKQCB-UHFFFAOYSA-M 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- WADSLQQIOJIXTB-UHFFFAOYSA-L dichloroalumane Chemical class Cl[AlH]Cl WADSLQQIOJIXTB-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- ANOBYBYXJXCGBS-UHFFFAOYSA-L stannous fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 description 1
- 229960002799 stannous fluoride Drugs 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical group CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- MEBRQLCKPRKBOH-UHFFFAOYSA-K trichloro(ethyl)stannane Chemical compound CC[Sn](Cl)(Cl)Cl MEBRQLCKPRKBOH-UHFFFAOYSA-K 0.000 description 1
- CPRPKIMXLHBUGA-UHFFFAOYSA-N triethyltin Chemical compound CC[Sn](CC)CC CPRPKIMXLHBUGA-UHFFFAOYSA-N 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B13/00—Optical objectives specially designed for the purposes specified below
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE590209D BE590209A (enrdf_load_stackoverflow) | 1959-04-30 | ||
| NL113921D NL113921C (enrdf_load_stackoverflow) | 1959-04-30 | ||
| NL251065D NL251065A (enrdf_load_stackoverflow) | 1959-04-30 | ||
| DE1959Z0007297 DE1157617C2 (de) | 1959-04-30 | 1959-04-30 | Verfahren zur Herstellung von einheitlichen Zinnalkylverbindungen |
| GB13359/60D GB923179A (en) | 1959-04-30 | 1960-04-20 | Process for the production of alkyl tin compounds |
| CH442160A CH408000A (de) | 1959-04-30 | 1960-04-20 | Verfahren zur Herstellung von reinen Zinnalkylverbindungen |
| CH470960A CH447161A (de) | 1959-04-30 | 1960-04-25 | Verfahren zur Herstellung von halogenhaltigen Zinnalkylverbindungen |
| US24670A US3287386A (en) | 1959-04-30 | 1960-04-26 | Process for the production of tin alkyl compounds |
| FR825572A FR1298316A (fr) | 1959-04-30 | 1960-04-28 | Procédé de fabrication de composés alcoylés de l'étain |
| CH609662A CH393769A (de) | 1959-04-30 | 1962-05-20 | Photographisches Objektiv |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1959Z0007297 DE1157617C2 (de) | 1959-04-30 | 1959-04-30 | Verfahren zur Herstellung von einheitlichen Zinnalkylverbindungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1157617B DE1157617B (de) | 1963-11-21 |
| DE1157617C2 true DE1157617C2 (de) | 1973-05-24 |
Family
ID=7620074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1959Z0007297 Expired DE1157617C2 (de) | 1959-04-30 | 1959-04-30 | Verfahren zur Herstellung von einheitlichen Zinnalkylverbindungen |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE590209A (enrdf_load_stackoverflow) |
| CH (3) | CH408000A (enrdf_load_stackoverflow) |
| DE (1) | DE1157617C2 (enrdf_load_stackoverflow) |
| GB (1) | GB923179A (enrdf_load_stackoverflow) |
| NL (2) | NL113921C (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0446703A3 (en) * | 1990-03-12 | 1992-08-19 | Th. Goldschmidt Ag | Process for the preparation of dialkyl tin dichlorides |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1084076A (enrdf_load_stackoverflow) * | 1964-04-08 | 1900-01-01 | ||
| EP1743898A1 (en) | 2005-07-12 | 2007-01-17 | Arkema Vlissingen B.V. | Process for the preparation of monoalkyl tin trihalides and dialkyl tin dihalides |
| EP3184532B1 (en) | 2015-12-22 | 2018-09-26 | Arkema B.V. | Process for making alkyltin trihalides and their use |
-
0
- NL NL251065D patent/NL251065A/xx unknown
- BE BE590209D patent/BE590209A/xx unknown
- NL NL113921D patent/NL113921C/xx active
-
1959
- 1959-04-30 DE DE1959Z0007297 patent/DE1157617C2/de not_active Expired
-
1960
- 1960-04-20 CH CH442160A patent/CH408000A/de unknown
- 1960-04-20 GB GB13359/60D patent/GB923179A/en not_active Expired
- 1960-04-25 CH CH470960A patent/CH447161A/de unknown
-
1962
- 1962-05-20 CH CH609662A patent/CH393769A/de unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0446703A3 (en) * | 1990-03-12 | 1992-08-19 | Th. Goldschmidt Ag | Process for the preparation of dialkyl tin dichlorides |
Also Published As
| Publication number | Publication date |
|---|---|
| CH447161A (de) | 1967-11-30 |
| GB923179A (en) | 1963-04-10 |
| CH393769A (de) | 1965-06-15 |
| DE1157617B (de) | 1963-11-21 |
| BE590209A (enrdf_load_stackoverflow) | 1900-01-01 |
| NL251065A (enrdf_load_stackoverflow) | 1900-01-01 |
| CH408000A (de) | 1966-02-28 |
| NL113921C (enrdf_load_stackoverflow) | 1900-01-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C2 | Grant after previous publication (2nd publication) |