DE112015002533B4 - Kupfer-enthaltendes Siliciummaterial, Verfahren für dessen Herstellung, Negativelektrodenaktivmaterial und Sekundärbatterie - Google Patents
Kupfer-enthaltendes Siliciummaterial, Verfahren für dessen Herstellung, Negativelektrodenaktivmaterial und Sekundärbatterie Download PDFInfo
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- DE112015002533B4 DE112015002533B4 DE112015002533.2T DE112015002533T DE112015002533B4 DE 112015002533 B4 DE112015002533 B4 DE 112015002533B4 DE 112015002533 T DE112015002533 T DE 112015002533T DE 112015002533 B4 DE112015002533 B4 DE 112015002533B4
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- Prior art keywords
- copper
- silicon
- calcium
- silicon material
- source
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- 239000010949 copper Substances 0.000 title claims abstract description 159
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 139
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 134
- 239000002210 silicon-based material Substances 0.000 title claims abstract description 71
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000007773 negative electrode material Substances 0.000 title claims description 36
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 230000008569 process Effects 0.000 title description 2
- 239000011575 calcium Substances 0.000 claims abstract description 55
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 55
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000010703 silicon Substances 0.000 claims abstract description 46
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 38
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910021346 calcium silicide Inorganic materials 0.000 claims abstract description 31
- 239000002253 acid Substances 0.000 claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 claims abstract description 19
- 239000012686 silicon precursor Substances 0.000 claims abstract description 19
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000002844 melting Methods 0.000 claims abstract description 5
- 230000008018 melting Effects 0.000 claims abstract description 5
- 230000001590 oxidative effect Effects 0.000 claims abstract description 5
- 239000000284 extract Substances 0.000 claims abstract description 4
- JUZTWRXHHZRLED-UHFFFAOYSA-N [Si].[Cu].[Cu].[Cu].[Cu].[Cu] Chemical compound [Si].[Cu].[Cu].[Cu].[Cu].[Cu] JUZTWRXHHZRLED-UHFFFAOYSA-N 0.000 claims description 8
- 229910021360 copper silicide Inorganic materials 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 6
- 229910004265 CaCuxSiy Inorganic materials 0.000 abstract 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 26
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 24
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 22
- 229910001416 lithium ion Inorganic materials 0.000 description 22
- 239000011230 binding agent Substances 0.000 description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 16
- 229910052744 lithium Inorganic materials 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 12
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- 239000003575 carbonaceous material Substances 0.000 description 9
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- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 3
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- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- DXIGZHYPWYIZLM-UHFFFAOYSA-J tetrafluorozirconium;dihydrofluoride Chemical compound F.F.F[Zr](F)(F)F DXIGZHYPWYIZLM-UHFFFAOYSA-J 0.000 description 1
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/06—Metal silicides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/50—Electrodes characterised by their material specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Silicon Compounds (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-110821 | 2014-05-29 | ||
| JP2014110821A JP6318859B2 (ja) | 2014-05-29 | 2014-05-29 | 銅含有シリコン材料及びその製造方法と負極活物質及び二次電池 |
| PCT/JP2015/002647 WO2015182120A1 (ja) | 2014-05-29 | 2015-05-26 | 銅含有シリコン材料及びその製造方法と負極活物質及び二次電池 |
Publications (2)
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|---|---|
| DE112015002533T5 DE112015002533T5 (de) | 2017-02-23 |
| DE112015002533B4 true DE112015002533B4 (de) | 2018-01-11 |
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| DE112015002533.2T Expired - Fee Related DE112015002533B4 (de) | 2014-05-29 | 2015-05-26 | Kupfer-enthaltendes Siliciummaterial, Verfahren für dessen Herstellung, Negativelektrodenaktivmaterial und Sekundärbatterie |
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| US (1) | US20170200949A1 (enExample) |
| JP (1) | JP6318859B2 (enExample) |
| CN (1) | CN106458610B (enExample) |
| DE (1) | DE112015002533B4 (enExample) |
| WO (1) | WO2015182120A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10135067B2 (en) | 2014-09-19 | 2018-11-20 | Kabushiki Kaisha Toyota Jidoshokki | MSix-containing silicon material (M is at least one element selected from group 3 to 9 elements. ⅓<=x<=3) and method for producing same |
| JPWO2016199358A1 (ja) * | 2015-06-12 | 2018-04-05 | 株式会社豊田自動織機 | シリコン材料およびその製造方法 |
| JP6642822B2 (ja) * | 2015-12-25 | 2020-02-12 | 株式会社豊田自動織機 | MSix(Mは第3〜9族元素から選択される少なくとも一元素。ただし、1/3≦x≦3)含有シリコン材料およびその製造方法 |
| WO2019053983A1 (ja) * | 2017-09-14 | 2019-03-21 | 株式会社豊田自動織機 | Al含有シリコン材料を含む負極活物質 |
| JP6852689B2 (ja) * | 2017-09-14 | 2021-03-31 | 株式会社豊田自動織機 | Al含有シリコン材料 |
| WO2019053984A1 (ja) * | 2017-09-14 | 2019-03-21 | 株式会社豊田自動織機 | Al含有シリコン材料を含む負極活物質 |
| JP6859930B2 (ja) * | 2017-09-14 | 2021-04-14 | 株式会社豊田自動織機 | Al含有シリコン材料 |
| JP6926873B2 (ja) * | 2017-09-14 | 2021-08-25 | 株式会社豊田自動織機 | Al及びO含有シリコン材料 |
| CN109950542A (zh) * | 2019-04-03 | 2019-06-28 | 西安交通大学 | 一类含硅氧烷基团的接枝共聚物粘合剂及其应用以及基于其的二次电池 |
| JP7666259B2 (ja) * | 2021-09-16 | 2025-04-22 | 株式会社豊田中央研究所 | Cu5Ca系粉末及びその製造方法 |
| CN114613957B (zh) * | 2022-03-11 | 2023-08-11 | 山东大学 | 基于熔盐制备锂离子电池铜包覆硅负极材料的方法及应用 |
| CN115212882B (zh) * | 2022-06-30 | 2023-12-19 | 浙江工业大学 | 一种多孔硅化铜金属间化合物材料及其制备和应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3403091A1 (de) * | 1983-02-07 | 1984-08-09 | Elkem A/S, Oslo | Verfahren zur herstellung von silicium hoher reinheit |
| JP2011034839A (ja) * | 2009-08-03 | 2011-02-17 | Furukawa Electric Co Ltd:The | ナノサイズ粒子、ナノサイズ粒子を含むリチウムイオン二次電池用負極材料、リチウムイオン二次電池用負極、リチウムイオン二次電池、ナノサイズ粒子の製造方法 |
| EP2605315A1 (en) * | 2011-12-13 | 2013-06-19 | Samsung SDI Co., Ltd. | Negative electrode active material and Secondary battery including the same |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69942362D1 (de) * | 1998-09-18 | 2010-06-24 | Canon Kk | Elektrodenmaterial für den negativen pol einer lithiumsekundärzelle, elektrodenstruktur die dieses verwendet, lithiumsekundärzelle mit dieser struktur und verfahren zur herstellung der zelle und der struktur |
| JP2005235397A (ja) * | 2000-01-25 | 2005-09-02 | Sanyo Electric Co Ltd | リチウム電池用電極並びにこれを用いたリチウム電池及びリチウム二次電池 |
| WO2004086539A1 (en) * | 2003-03-26 | 2004-10-07 | Canon Kabushiki Kaisha | Electrode material for lithium secondary battery and electrode structure having the electrode material |
| JP4368139B2 (ja) * | 2003-05-08 | 2009-11-18 | パナソニック株式会社 | 非水電解質二次電池用負極材料 |
| WO2006100837A1 (ja) * | 2005-03-23 | 2006-09-28 | Pionics Co., Ltd. | リチウム二次電池用負極活物質粒子と負極及びそれらの製造方法 |
| JP5128873B2 (ja) * | 2007-08-10 | 2013-01-23 | 株式会社豊田自動織機 | 二次電池用電極及びその製造方法 |
| US8426065B2 (en) * | 2008-12-30 | 2013-04-23 | Lg Chem, Ltd. | Anode active material for secondary battery |
| JP5471284B2 (ja) * | 2009-10-20 | 2014-04-16 | 株式会社豊田中央研究所 | リチウム二次電池用電極及びそれを備えたリチウム二次電池 |
| JP5387613B2 (ja) * | 2010-09-03 | 2014-01-15 | 株式会社豊田中央研究所 | 遷移金属シリサイド−Si複合粉末及びその製造方法、並びに、遷移金属シリサイド−Si複合粉末製造用CaSiy系粉末及びその製造方法 |
| JP2013122905A (ja) * | 2011-11-10 | 2013-06-20 | Sanyo Special Steel Co Ltd | 鱗片状Si系合金負極材料 |
-
2014
- 2014-05-29 JP JP2014110821A patent/JP6318859B2/ja active Active
-
2015
- 2015-05-26 CN CN201580027663.5A patent/CN106458610B/zh not_active Expired - Fee Related
- 2015-05-26 DE DE112015002533.2T patent/DE112015002533B4/de not_active Expired - Fee Related
- 2015-05-26 WO PCT/JP2015/002647 patent/WO2015182120A1/ja not_active Ceased
- 2015-05-26 US US15/314,421 patent/US20170200949A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3403091A1 (de) * | 1983-02-07 | 1984-08-09 | Elkem A/S, Oslo | Verfahren zur herstellung von silicium hoher reinheit |
| JP2011034839A (ja) * | 2009-08-03 | 2011-02-17 | Furukawa Electric Co Ltd:The | ナノサイズ粒子、ナノサイズ粒子を含むリチウムイオン二次電池用負極材料、リチウムイオン二次電池用負極、リチウムイオン二次電池、ナノサイズ粒子の製造方法 |
| EP2605315A1 (en) * | 2011-12-13 | 2013-06-19 | Samsung SDI Co., Ltd. | Negative electrode active material and Secondary battery including the same |
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| Title |
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| Hor, W. J. ; Sung, H. H. ; Lee, W. H.: Superconductivity in the copper-poor region of the Ca(Cu,Si)2-x system. In: Physica C, Superconductivity and its applications, Vol 434, 2006, H. 1, S. 121-124. - ISSN 0921-4534 * |
| JP 2011 034 839 A (Maschinenübersetzung), AIPN [online] JPO [abgerufen am 10.04.2017] und Derwent-abstract, AN_WPI : 2011B74813 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6318859B2 (ja) | 2018-05-09 |
| WO2015182120A1 (ja) | 2015-12-03 |
| JP2015224164A (ja) | 2015-12-14 |
| CN106458610A (zh) | 2017-02-22 |
| US20170200949A1 (en) | 2017-07-13 |
| DE112015002533T5 (de) | 2017-02-23 |
| CN106458610B (zh) | 2019-03-12 |
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