DD200226A5 - Organomagnesiumloesungen geringer viskoesitaet - Google Patents
Organomagnesiumloesungen geringer viskoesitaetInfo
- Publication number
- DD200226A5 DD200226A5 DD81231316A DD23131681A DD200226A5 DD 200226 A5 DD200226 A5 DD 200226A5 DD 81231316 A DD81231316 A DD 81231316A DD 23131681 A DD23131681 A DD 23131681A DD 200226 A5 DD200226 A5 DD 200226A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- item
- group
- organometallic additive
- alkyl
- magnesium
- Prior art date
Links
- 239000011777 magnesium Substances 0.000 claims abstract description 32
- 150000004796 dialkyl magnesium compounds Chemical class 0.000 claims abstract description 29
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000654 additive Substances 0.000 claims abstract description 28
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 28
- 230000000996 additive effect Effects 0.000 claims abstract description 24
- 125000002524 organometallic group Chemical group 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 19
- 150000001350 alkyl halides Chemical class 0.000 claims abstract description 15
- 125000002734 organomagnesium group Chemical group 0.000 claims abstract description 7
- 238000011065 in-situ storage Methods 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 26
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 239000000575 pesticide Substances 0.000 claims description 11
- 101000588924 Anthopleura elegantissima Delta-actitoxin-Ael1a Proteins 0.000 claims description 7
- 150000004820 halides Chemical class 0.000 claims description 7
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 claims description 7
- 125000002723 alicyclic group Chemical group 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 229910052733 gallium Inorganic materials 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001348 alkyl chlorides Chemical group 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 claims 2
- 241000607479 Yersinia pestis Species 0.000 claims 1
- 229940125898 compound 5 Drugs 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 28
- 239000007787 solid Substances 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000006116 polymerization reaction Methods 0.000 abstract description 4
- 239000006227 byproduct Substances 0.000 abstract description 3
- 239000002685 polymerization catalyst Substances 0.000 abstract description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 31
- 150000002902 organometallic compounds Chemical class 0.000 description 10
- -1 di-n-amylmagnesium Chemical compound 0.000 description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 150000002901 organomagnesium compounds Chemical class 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- ZKSADANYBSWZAB-UHFFFAOYSA-N CCCCCC[Mg]CCCCCC Chemical compound CCCCCC[Mg]CCCCCC ZKSADANYBSWZAB-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229960003750 ethyl chloride Drugs 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 3
- 150000002642 lithium compounds Chemical class 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- 102100040141 Aminopeptidase O Human genes 0.000 description 2
- 108050008333 Aminopeptidase O Proteins 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- NYEVYCIEQJOVQY-UHFFFAOYSA-N C1CCCCC1[Mg]C1CCCCC1 Chemical compound C1CCCCC1[Mg]C1CCCCC1 NYEVYCIEQJOVQY-UHFFFAOYSA-N 0.000 description 2
- DZDGGXISWFLINW-UHFFFAOYSA-N CCC[Mg]C Chemical compound CCC[Mg]C DZDGGXISWFLINW-UHFFFAOYSA-N 0.000 description 2
- UVJYLSUYJJRVRV-UHFFFAOYSA-N CC[Mg]CC(C)C Chemical compound CC[Mg]CC(C)C UVJYLSUYJJRVRV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000004795 grignard reagents Chemical class 0.000 description 2
- PSCMQHVBLHHWTO-UHFFFAOYSA-K indium(iii) chloride Chemical compound Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000007725 thermal activation Methods 0.000 description 2
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 1
- UXQAEOWCSOPBLF-UHFFFAOYSA-N 2,2,3,3-tetramethyloctane Chemical compound CCCCCC(C)(C)C(C)(C)C UXQAEOWCSOPBLF-UHFFFAOYSA-N 0.000 description 1
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Chemical class CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- XPVATDCOZDHQNL-UHFFFAOYSA-N CC(C)(C)[Mg]C(C)(C)C Chemical compound CC(C)(C)[Mg]C(C)(C)C XPVATDCOZDHQNL-UHFFFAOYSA-N 0.000 description 1
- ZSGJKBKUYXDVIE-UHFFFAOYSA-N CC(C)C[Mg] Chemical compound CC(C)C[Mg] ZSGJKBKUYXDVIE-UHFFFAOYSA-N 0.000 description 1
- SPXDYPYJHCSREL-UHFFFAOYSA-N CCC(C)[Mg]C(C)CC Chemical compound CCC(C)[Mg]C(C)CC SPXDYPYJHCSREL-UHFFFAOYSA-N 0.000 description 1
- HYLHFOVZFADXNK-UHFFFAOYSA-N CCCCCC[Mg]CC Chemical compound CCCCCC[Mg]CC HYLHFOVZFADXNK-UHFFFAOYSA-N 0.000 description 1
- YELRSUYYIQXYLP-UHFFFAOYSA-N CCCCCC[Mg]CCCC Chemical compound CCCCCC[Mg]CCCC YELRSUYYIQXYLP-UHFFFAOYSA-N 0.000 description 1
- KOKSWNUHZYGYDW-UHFFFAOYSA-N CCCC[Mg]C Chemical compound CCCC[Mg]C KOKSWNUHZYGYDW-UHFFFAOYSA-N 0.000 description 1
- ATLWBFARUNDGQS-UHFFFAOYSA-N C[Mg]CC(C)C Chemical compound C[Mg]CC(C)C ATLWBFARUNDGQS-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229910021617 Indium monochloride Inorganic materials 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 1
- 239000004914 cyclooctane Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000002259 gallium compounds Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010952 in-situ formation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002472 indium compounds Chemical class 0.000 description 1
- APHGZSBLRQFRCA-UHFFFAOYSA-M indium(1+);chloride Chemical compound [In]Cl APHGZSBLRQFRCA-UHFFFAOYSA-M 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- UBJFKNSINUCEAL-UHFFFAOYSA-N lithium;2-methylpropane Chemical compound [Li+].C[C-](C)C UBJFKNSINUCEAL-UHFFFAOYSA-N 0.000 description 1
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 1
- XBEREOHJDYAKDA-UHFFFAOYSA-N lithium;propane Chemical compound [Li+].CC[CH2-] XBEREOHJDYAKDA-UHFFFAOYSA-N 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- AWLITQJUQFXBFV-UHFFFAOYSA-N magnesium mercury Chemical group [Mg].[Hg] AWLITQJUQFXBFV-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- QIVLHVRZYONPSZ-UHFFFAOYSA-N tributylindigane Chemical compound CCCC[In](CCCC)CCCC QIVLHVRZYONPSZ-UHFFFAOYSA-N 0.000 description 1
- OTRPZROOJRIMKW-UHFFFAOYSA-N triethylindigane Chemical compound CC[In](CC)CC OTRPZROOJRIMKW-UHFFFAOYSA-N 0.000 description 1
- IBEFSUTVZWZJEL-UHFFFAOYSA-N trimethylindium Chemical compound C[In](C)C IBEFSUTVZWZJEL-UHFFFAOYSA-N 0.000 description 1
- JHUXFIPODALNAN-UHFFFAOYSA-N tris(2-methylpropyl)gallane Chemical compound CC(C)C[Ga](CC(C)C)CC(C)C JHUXFIPODALNAN-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/148,650 US4299781A (en) | 1980-05-12 | 1980-05-12 | Organomagnesium solutions of low viscosity |
| EP81400720A EP0040141B1 (en) | 1980-05-12 | 1981-05-06 | Organomagnesium solutions of low viscosity and process for their obtention |
| DE8181400720T DE3161483D1 (en) | 1980-05-12 | 1981-05-06 | Organomagnesium solutions of low viscosity and process for their obtention |
| NO811572A NO811572L (no) | 1980-05-12 | 1981-05-08 | Hydrokarbonloesning av en dialkylmagnesium-forbindelse, samt fremgangsmaate for fremstilling av en slik loesning |
| BR8102881A BR8102881A (pt) | 1980-05-12 | 1981-05-08 | Solucao liquida de baixa viscosidade e processo para a preparacao de solucao de hidrocaboneto de um composto dialquilmagnesio |
| CA000377217A CA1162932A (en) | 1980-05-12 | 1981-05-08 | Organomagnesium solutions of low viscosity |
| AU70427/81A AU537290B2 (en) | 1980-05-12 | 1981-05-11 | Organo magnesium solutions of low viscosity |
| ZA00813109A ZA813109B (en) | 1980-05-12 | 1981-05-11 | Organomagnesium solutions of low viscosity |
| AR285272A AR225511A1 (es) | 1980-05-12 | 1981-05-11 | Solucion liquida de organomagnesio de baja viscosidad util como catalizador y reactivo en reacciones quimicas y procedimiento para prepararla |
| ES502103A ES8203912A1 (es) | 1980-05-12 | 1981-05-11 | Procedimiento para preparar una solucion hidrocarbonada de compuestos de dialquilmagnesio |
| IL62843A IL62843A (en) | 1980-05-12 | 1981-05-11 | Dialkylmagnesium solutions of low viscosity and their manufacture |
| PL1981231117A PL129870B1 (en) | 1980-05-12 | 1981-05-12 | Organo-magnesium composition and method of making the same |
| JP7028081A JPS577486A (en) | 1980-05-12 | 1981-05-12 | Low viscosity liquid solution of organic magnesium compound and manufacture |
| IN499/CAL/81A IN154192B (pt) | 1980-05-12 | 1981-05-12 | |
| DD81231316A DD200226A5 (de) | 1980-05-12 | 1981-06-30 | Organomagnesiumloesungen geringer viskoesitaet |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/148,650 US4299781A (en) | 1980-05-12 | 1980-05-12 | Organomagnesium solutions of low viscosity |
| DD81231316A DD200226A5 (de) | 1980-05-12 | 1981-06-30 | Organomagnesiumloesungen geringer viskoesitaet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD200226A5 true DD200226A5 (de) | 1983-03-30 |
Family
ID=37719316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD81231316A DD200226A5 (de) | 1980-05-12 | 1981-06-30 | Organomagnesiumloesungen geringer viskoesitaet |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4299781A (pt) |
| EP (1) | EP0040141B1 (pt) |
| JP (1) | JPS577486A (pt) |
| AR (1) | AR225511A1 (pt) |
| AU (1) | AU537290B2 (pt) |
| BR (1) | BR8102881A (pt) |
| CA (1) | CA1162932A (pt) |
| DD (1) | DD200226A5 (pt) |
| DE (1) | DE3161483D1 (pt) |
| ES (1) | ES8203912A1 (pt) |
| IL (1) | IL62843A (pt) |
| IN (1) | IN154192B (pt) |
| NO (1) | NO811572L (pt) |
| PL (1) | PL129870B1 (pt) |
| ZA (1) | ZA813109B (pt) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4396554A (en) * | 1981-12-28 | 1983-08-02 | Ethyl Corporation | Hydrocarbon soluble dialkyl magnesium composition |
| US4447369A (en) * | 1982-04-16 | 1984-05-08 | Ethyl Corporation | Organomagnesium compounds |
| US4547477A (en) * | 1984-03-21 | 1985-10-15 | Texas Alkyls, Inc. | Organomagnesium solutions of low viscosity |
| US4615843A (en) * | 1984-09-05 | 1986-10-07 | Texas Alkyls, Inc. | Treatment of hydrocarbon solutions of dialkylmagnesium compounds to reduce the content of soluble chloride-containing complexes |
| US4678614A (en) * | 1985-11-27 | 1987-07-07 | Lithium Corporation Of America, Inc. | Hydrocarbon-soluble organometallic complexes of magnesium and alkali metals and method of producing same |
| US4976886A (en) * | 1987-03-30 | 1990-12-11 | Lithium Corporation Of America | Preparation of organometallic and organobimetallic compounds |
| US5141667A (en) * | 1987-03-30 | 1992-08-25 | Fmc Corporation | Preparation of organometallic and organobimetallic compounds |
| US5145600A (en) * | 1988-02-25 | 1992-09-08 | Fmc Corporation | Low viscosity hydrocarbon solution of dialkylmagnesium compounds |
| EP0796859B1 (de) * | 1996-03-19 | 2002-07-31 | Crompton GmbH | Stabile homogene Formulierungen von oxidationsempfindlichen metallorganischen Verbindungen in Paraffinen und Verfahren zu deren Herstellung |
| US5910270A (en) * | 1997-08-19 | 1999-06-08 | Akzo Nobel Nv | Viscosity reduction of organomagnesium solutions |
| US20050197614A1 (en) * | 2004-03-04 | 2005-09-08 | Wilson Pritchard | Occlusive biomedical devices, punctum plugs, and methods of use thereof |
| US7871547B2 (en) * | 2004-11-12 | 2011-01-18 | Albemarle Corporation | Halide reduction in dihydrocarbylmagnesium mixtures |
| US20230192725A1 (en) | 2020-05-20 | 2023-06-22 | Lanxess Organometallics Gmbh | Novel organo-magnesium compounds and their use |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3452111A (en) * | 1966-12-09 | 1969-06-24 | Lithium Corp | Stabilization of secondary alkyllithiums |
| US3646231A (en) * | 1970-03-05 | 1972-02-29 | Lithium Corp | Diorganomagnesium reagents and methods of preparing same |
| US3742077A (en) * | 1970-07-23 | 1973-06-26 | Lithium Corp | Method of preparing telomers utilizing as catalysts hydrocarbon-soluble organometallic complexes of metals of groups i and iia of the periodic table |
| US3755478A (en) * | 1971-08-18 | 1973-08-28 | Lithium Corp | Cyclic process for the preparation of diorganomagnesium compounds |
| US4069267A (en) * | 1976-10-27 | 1978-01-17 | Lithium Corporation Of America | Stable diorganomagnesium compositions |
| US4127507A (en) * | 1977-06-29 | 1978-11-28 | Texas Alkyls, Inc. | Hydrocarbon soluble straight-chain di-(lower alkyl) magnesium compositions |
| US4222969A (en) * | 1979-04-05 | 1980-09-16 | Texas Alkyls, Inc. | Hydrocarbon soluble magnesium compositions of high magnesium content |
-
1980
- 1980-05-12 US US06/148,650 patent/US4299781A/en not_active Expired - Lifetime
-
1981
- 1981-05-06 DE DE8181400720T patent/DE3161483D1/de not_active Expired
- 1981-05-06 EP EP81400720A patent/EP0040141B1/en not_active Expired
- 1981-05-08 NO NO811572A patent/NO811572L/no unknown
- 1981-05-08 CA CA000377217A patent/CA1162932A/en not_active Expired
- 1981-05-08 BR BR8102881A patent/BR8102881A/pt unknown
- 1981-05-11 IL IL62843A patent/IL62843A/xx unknown
- 1981-05-11 AU AU70427/81A patent/AU537290B2/en not_active Ceased
- 1981-05-11 ES ES502103A patent/ES8203912A1/es not_active Expired
- 1981-05-11 AR AR285272A patent/AR225511A1/es active
- 1981-05-11 ZA ZA00813109A patent/ZA813109B/xx unknown
- 1981-05-12 JP JP7028081A patent/JPS577486A/ja active Pending
- 1981-05-12 IN IN499/CAL/81A patent/IN154192B/en unknown
- 1981-05-12 PL PL1981231117A patent/PL129870B1/pl unknown
- 1981-06-30 DD DD81231316A patent/DD200226A5/de unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN154192B (pt) | 1984-09-29 |
| ES502103A0 (es) | 1982-04-01 |
| AU537290B2 (en) | 1984-06-14 |
| PL129870B1 (en) | 1984-06-30 |
| PL231117A1 (pt) | 1982-02-01 |
| AR225511A1 (es) | 1982-03-31 |
| BR8102881A (pt) | 1982-02-02 |
| CA1162932A (en) | 1984-02-28 |
| AU7042781A (en) | 1981-11-19 |
| EP0040141A1 (en) | 1981-11-18 |
| IL62843A0 (en) | 1981-07-31 |
| NO811572L (no) | 1981-11-13 |
| EP0040141B1 (en) | 1983-11-23 |
| ZA813109B (en) | 1982-07-28 |
| US4299781A (en) | 1981-11-10 |
| IL62843A (en) | 1984-10-31 |
| DE3161483D1 (en) | 1983-12-29 |
| ES8203912A1 (es) | 1982-04-01 |
| JPS577486A (en) | 1982-01-14 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C | Prov. exclusive patent (sect. 19) |