ES8203912A1 - Procedimiento para preparar una solucion hidrocarbonada de compuestos de dialquilmagnesio - Google Patents
Procedimiento para preparar una solucion hidrocarbonada de compuestos de dialquilmagnesioInfo
- Publication number
- ES8203912A1 ES8203912A1 ES502103A ES502103A ES8203912A1 ES 8203912 A1 ES8203912 A1 ES 8203912A1 ES 502103 A ES502103 A ES 502103A ES 502103 A ES502103 A ES 502103A ES 8203912 A1 ES8203912 A1 ES 8203912A1
- Authority
- ES
- Spain
- Prior art keywords
- low viscosity
- obtention
- carbon atoms
- group
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- 125000002734 organomagnesium group Chemical group 0.000 title 1
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000004796 dialkyl magnesium compounds Chemical class 0.000 abstract 2
- 125000002524 organometallic group Chemical group 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000006193 liquid solution Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR UNA SOLUCION HIDROCARBONADA DE COMPUESTOS DE DIALQUILMAGNESIO. CONSTA DE LAS SIGUIENTES ETAPAS: 1 REACCION DE MAGNESIO METALICO CON AL MENOS UN HALURO DE ALQUILO, CON LO QUE SE OBTIENE UN COMPUESTO DE DIALQUILMAGNESIO SOLUBLE EN HIDROCARBUROS DE 4 A 20 ATOMOS DE CARBONO, EN PRESENCIA DE O SEGUIDO DE LA ADICION DE UN DISOLVENTE HIDROCARBONADO Y UN ADITIVO ORGANOMETALICO PARA PRODUCIR UN LIQUIDO HOMOGENEO Y SOLIDO. 2 SEPARACION DEL LIQUIDO DE LOS SOLIDOS. AMBAS ETAPAS SE EFECTUAN EN AUSENCIA DE HUMEDAD Y DE OXIGENO. EL DISOLVENTE SE ELIGE ENTRE HIDROCARBUROS ALIFATICOS, ALICICLICOS Y AROMATICOS. EL ADITIVO ORGANOMETALICO ESTA PRESENTE EN UNA RELACION MOLAR DE 0,001 : 1 A 0,25 RESPECTO AL COMPUESTO.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/148,650 US4299781A (en) | 1980-05-12 | 1980-05-12 | Organomagnesium solutions of low viscosity |
DD81231316A DD200226A5 (de) | 1980-05-12 | 1981-06-30 | Organomagnesiumloesungen geringer viskoesitaet |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8203912A1 true ES8203912A1 (es) | 1982-04-01 |
ES502103A0 ES502103A0 (es) | 1982-04-01 |
Family
ID=37719316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES502103A Granted ES502103A0 (es) | 1980-05-12 | 1981-05-11 | Procedimiento para preparar una solucion hidrocarbonada de compuestos de dialquilmagnesio |
Country Status (15)
Country | Link |
---|---|
US (1) | US4299781A (es) |
EP (1) | EP0040141B1 (es) |
JP (1) | JPS577486A (es) |
AR (1) | AR225511A1 (es) |
AU (1) | AU537290B2 (es) |
BR (1) | BR8102881A (es) |
CA (1) | CA1162932A (es) |
DD (1) | DD200226A5 (es) |
DE (1) | DE3161483D1 (es) |
ES (1) | ES502103A0 (es) |
IL (1) | IL62843A (es) |
IN (1) | IN154192B (es) |
NO (1) | NO811572L (es) |
PL (1) | PL129870B1 (es) |
ZA (1) | ZA813109B (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4396554A (en) * | 1981-12-28 | 1983-08-02 | Ethyl Corporation | Hydrocarbon soluble dialkyl magnesium composition |
US4447369A (en) * | 1982-04-16 | 1984-05-08 | Ethyl Corporation | Organomagnesium compounds |
US4547477A (en) * | 1984-03-21 | 1985-10-15 | Texas Alkyls, Inc. | Organomagnesium solutions of low viscosity |
US4615843A (en) * | 1984-09-05 | 1986-10-07 | Texas Alkyls, Inc. | Treatment of hydrocarbon solutions of dialkylmagnesium compounds to reduce the content of soluble chloride-containing complexes |
US4678614A (en) * | 1985-11-27 | 1987-07-07 | Lithium Corporation Of America, Inc. | Hydrocarbon-soluble organometallic complexes of magnesium and alkali metals and method of producing same |
US4976886A (en) * | 1987-03-30 | 1990-12-11 | Lithium Corporation Of America | Preparation of organometallic and organobimetallic compounds |
US5141667A (en) * | 1987-03-30 | 1992-08-25 | Fmc Corporation | Preparation of organometallic and organobimetallic compounds |
US5145600A (en) * | 1988-02-25 | 1992-09-08 | Fmc Corporation | Low viscosity hydrocarbon solution of dialkylmagnesium compounds |
EP0796859B1 (de) * | 1996-03-19 | 2002-07-31 | Crompton GmbH | Stabile homogene Formulierungen von oxidationsempfindlichen metallorganischen Verbindungen in Paraffinen und Verfahren zu deren Herstellung |
US5910270A (en) * | 1997-08-19 | 1999-06-08 | Akzo Nobel Nv | Viscosity reduction of organomagnesium solutions |
US20050197614A1 (en) * | 2004-03-04 | 2005-09-08 | Wilson Pritchard | Occlusive biomedical devices, punctum plugs, and methods of use thereof |
ES2308295T3 (es) * | 2004-11-12 | 2008-12-01 | Albemarle Corporation | Reduccion de la cantidad de halogenuro en mezclas que contienen un compuesto de dihidrocarbilmagnesio. |
WO2021233930A1 (en) | 2020-05-20 | 2021-11-25 | Lanxess Organometallics Gmbh | Novel organo-magnesium compounds and their use |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3452111A (en) * | 1966-12-09 | 1969-06-24 | Lithium Corp | Stabilization of secondary alkyllithiums |
US3646231A (en) * | 1970-03-05 | 1972-02-29 | Lithium Corp | Diorganomagnesium reagents and methods of preparing same |
US3742077A (en) * | 1970-07-23 | 1973-06-26 | Lithium Corp | Method of preparing telomers utilizing as catalysts hydrocarbon-soluble organometallic complexes of metals of groups i and iia of the periodic table |
US3755478A (en) * | 1971-08-18 | 1973-08-28 | Lithium Corp | Cyclic process for the preparation of diorganomagnesium compounds |
US4069267A (en) * | 1976-10-27 | 1978-01-17 | Lithium Corporation Of America | Stable diorganomagnesium compositions |
US4127507A (en) * | 1977-06-29 | 1978-11-28 | Texas Alkyls, Inc. | Hydrocarbon soluble straight-chain di-(lower alkyl) magnesium compositions |
US4222969A (en) * | 1979-04-05 | 1980-09-16 | Texas Alkyls, Inc. | Hydrocarbon soluble magnesium compositions of high magnesium content |
-
1980
- 1980-05-12 US US06/148,650 patent/US4299781A/en not_active Expired - Lifetime
-
1981
- 1981-05-06 EP EP81400720A patent/EP0040141B1/en not_active Expired
- 1981-05-06 DE DE8181400720T patent/DE3161483D1/de not_active Expired
- 1981-05-08 BR BR8102881A patent/BR8102881A/pt unknown
- 1981-05-08 NO NO811572A patent/NO811572L/no unknown
- 1981-05-08 CA CA000377217A patent/CA1162932A/en not_active Expired
- 1981-05-11 IL IL62843A patent/IL62843A/xx unknown
- 1981-05-11 AU AU70427/81A patent/AU537290B2/en not_active Ceased
- 1981-05-11 ZA ZA00813109A patent/ZA813109B/xx unknown
- 1981-05-11 ES ES502103A patent/ES502103A0/es active Granted
- 1981-05-11 AR AR285272A patent/AR225511A1/es active
- 1981-05-12 IN IN499/CAL/81A patent/IN154192B/en unknown
- 1981-05-12 PL PL1981231117A patent/PL129870B1/pl unknown
- 1981-05-12 JP JP7028081A patent/JPS577486A/ja active Pending
- 1981-06-30 DD DD81231316A patent/DD200226A5/de unknown
Also Published As
Publication number | Publication date |
---|---|
DE3161483D1 (en) | 1983-12-29 |
IL62843A (en) | 1984-10-31 |
ZA813109B (en) | 1982-07-28 |
AR225511A1 (es) | 1982-03-31 |
PL129870B1 (en) | 1984-06-30 |
DD200226A5 (de) | 1983-03-30 |
CA1162932A (en) | 1984-02-28 |
IN154192B (es) | 1984-09-29 |
AU7042781A (en) | 1981-11-19 |
BR8102881A (pt) | 1982-02-02 |
JPS577486A (en) | 1982-01-14 |
NO811572L (no) | 1981-11-13 |
EP0040141B1 (en) | 1983-11-23 |
IL62843A0 (en) | 1981-07-31 |
US4299781A (en) | 1981-11-10 |
EP0040141A1 (en) | 1981-11-18 |
ES502103A0 (es) | 1982-04-01 |
AU537290B2 (en) | 1984-06-14 |
PL231117A1 (es) | 1982-02-01 |
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