CS274253B2 - Emulsion-type explosive mixture and method of its production - Google Patents
Emulsion-type explosive mixture and method of its production Download PDFInfo
- Publication number
- CS274253B2 CS274253B2 CS25980A CS25980A CS274253B2 CS 274253 B2 CS274253 B2 CS 274253B2 CS 25980 A CS25980 A CS 25980A CS 25980 A CS25980 A CS 25980A CS 274253 B2 CS274253 B2 CS 274253B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- fatty acid
- emulsion
- hydroxide
- salt
- mixture
- Prior art date
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000000194 fatty acid Substances 0.000 claims abstract description 81
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 73
- 229930195729 fatty acid Natural products 0.000 claims abstract description 73
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 43
- -1 e.g. Chemical class 0.000 claims abstract description 41
- 150000003839 salts Chemical class 0.000 claims abstract description 31
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 30
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 30
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000005642 Oleic acid Substances 0.000 claims abstract description 30
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000007864 aqueous solution Substances 0.000 claims abstract description 18
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 13
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 13
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008117 stearic acid Substances 0.000 claims abstract description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 10
- 230000001590 oxidative effect Effects 0.000 claims abstract description 10
- 238000011065 in-situ storage Methods 0.000 claims abstract description 8
- 239000007762 w/o emulsion Substances 0.000 claims abstract description 7
- 239000007791 liquid phase Substances 0.000 claims abstract description 3
- 239000000839 emulsion Substances 0.000 claims description 92
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 39
- 239000000446 fuel Substances 0.000 claims description 29
- 239000012071 phase Substances 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 229910001868 water Inorganic materials 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 17
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 16
- 230000003647 oxidation Effects 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 16
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 13
- 239000000908 ammonium hydroxide Substances 0.000 claims description 13
- 239000003995 emulsifying agent Substances 0.000 claims description 13
- 229940049964 oleate Drugs 0.000 claims description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- FVFJGQJXAWCHIE-UHFFFAOYSA-N [4-(bromomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CBr)C=C1 FVFJGQJXAWCHIE-UHFFFAOYSA-N 0.000 claims description 5
- 229910001963 alkali metal nitrate Inorganic materials 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001447 alkali salts Chemical class 0.000 claims 1
- 229940088990 ammonium stearate Drugs 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 20
- 230000000087 stabilizing effect Effects 0.000 abstract description 4
- 230000001804 emulsifying effect Effects 0.000 abstract description 3
- 238000013019 agitation Methods 0.000 abstract description 2
- 150000002888 oleic acid derivatives Chemical class 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 29
- 235000021313 oleic acid Nutrition 0.000 description 28
- 239000007788 liquid Substances 0.000 description 27
- 239000008346 aqueous phase Substances 0.000 description 15
- 239000000344 soap Substances 0.000 description 15
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 14
- 239000007789 gas Substances 0.000 description 13
- 230000006835 compression Effects 0.000 description 11
- 238000007906 compression Methods 0.000 description 11
- 238000004880 explosion Methods 0.000 description 11
- 239000004005 microsphere Substances 0.000 description 8
- 239000004317 sodium nitrate Substances 0.000 description 7
- 235000010344 sodium nitrate Nutrition 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000010881 fly ash Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 235000020778 linoleic acid Nutrition 0.000 description 4
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 4
- OYHQOLUKZRVURQ-HZJYTTRNSA-N linoleic acid group Chemical group C(CCCCCCC\C=C/C\C=C/CCCCC)(=O)O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000000015 trinitrotoluene Substances 0.000 description 4
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000005474 detonation Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- 229940114926 stearate Drugs 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000003139 buffering effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 235000021588 free fatty acids Nutrition 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- HZTVIZREFBBQMG-UHFFFAOYSA-N 2-methyl-1,3,5-trinitrobenzene;[3-nitrooxy-2,2-bis(nitrooxymethyl)propyl] nitrate Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O.[O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O HZTVIZREFBBQMG-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 229910001964 alkaline earth metal nitrate Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- KQLYFVFFPVJGRM-NBTZWHCOSA-N azanium;(9z,12z)-octadeca-9,12-dienoate Chemical compound [NH4+].CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O KQLYFVFFPVJGRM-NBTZWHCOSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000012669 compression test Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012035 limiting reagent Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- MAQCMFOLVVSLLK-UHFFFAOYSA-N methyl 4-(bromomethyl)pyridine-2-carboxylate Chemical compound COC(=O)C1=CC(CBr)=CC=N1 MAQCMFOLVVSLLK-UHFFFAOYSA-N 0.000 description 1
- PTIUDKQYXMFYAI-UHFFFAOYSA-N methylammonium nitrate Chemical compound NC.O[N+]([O-])=O PTIUDKQYXMFYAI-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000002911 mydriatic effect Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Colloid Chemistry (AREA)
- Lubricants (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/064,172 US4287010A (en) | 1979-08-06 | 1979-08-06 | Emulsion-type explosive composition and method for the preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS25980A2 CS25980A2 (en) | 1990-09-12 |
| CS274253B2 true CS274253B2 (en) | 1991-04-11 |
Family
ID=22054055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS25980A CS274253B2 (en) | 1979-08-06 | 1980-01-11 | Emulsion-type explosive mixture and method of its production |
Country Status (32)
| Country | Link |
|---|---|
| US (1) | US4287010A (no) |
| JP (1) | JPS5828240B2 (no) |
| KR (1) | KR830000374B1 (no) |
| AT (1) | AT380231B (no) |
| AU (1) | AU523413B2 (no) |
| BE (1) | BE880733A (no) |
| BR (1) | BR8000143A (no) |
| CA (1) | CA1133702A (no) |
| CH (1) | CH630325A5 (no) |
| CS (1) | CS274253B2 (no) |
| DE (1) | DE2951905C2 (no) |
| ES (1) | ES488318A0 (no) |
| FR (1) | FR2463110A1 (no) |
| GB (1) | GB2055358B (no) |
| GR (1) | GR73908B (no) |
| HK (1) | HK38484A (no) |
| IE (1) | IE49322B1 (no) |
| IL (1) | IL58920A (no) |
| IN (1) | IN152693B (no) |
| IT (1) | IT1193350B (no) |
| MA (1) | MA18706A1 (no) |
| MX (1) | MX155262A (no) |
| MY (1) | MY8500433A (no) |
| NO (1) | NO145757C (no) |
| NZ (1) | NZ192373A (no) |
| OA (1) | OA06460A (no) |
| PL (1) | PL221639A1 (no) |
| PT (1) | PT70652A (no) |
| SE (1) | SE437259B (no) |
| TR (1) | TR20808A (no) |
| YU (1) | YU41494B (no) |
| ZA (1) | ZA80874B (no) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1162744A (en) * | 1982-02-02 | 1984-02-28 | Howard A. Bampfield | Emulsion explosive compositions and method of preparation |
| US4453989A (en) * | 1982-04-05 | 1984-06-12 | Atlas Powder Company | Solid sensitizers for water-in-oil emulsion explosives |
| US4439254A (en) * | 1982-04-05 | 1984-03-27 | Atlas Powder Company | Solid sensitizers in water gel explosives and method |
| CA1181593A (en) * | 1982-06-21 | 1985-01-29 | William E. Cribb | Bulk manufacture of emulsion explosives |
| ZW23383A1 (en) * | 1982-11-03 | 1985-06-12 | Aeci Ltd | A method of making an explosive in the form of an emulsion |
| US4409044A (en) * | 1982-11-18 | 1983-10-11 | Indian Explosives Limited | Water-in-oil emulsion explosives and a method for the preparation of the same |
| US4428784A (en) | 1983-03-07 | 1984-01-31 | Ireco Chemicals | Blasting compositions containing sodium nitrate |
| JPS59207889A (ja) * | 1983-05-10 | 1984-11-26 | 日本油脂株式会社 | 油中水型エマルシヨン爆薬組成物 |
| ZM2484A1 (en) * | 1983-05-12 | 1986-01-23 | Du Pont | Stable an/emulsion explosives and emulsion for use therein |
| BR8402200A (pt) * | 1983-05-12 | 1984-12-18 | Du Pont | Processo para preparar uma composicao explosiva,produto explosivo envelhecido,embalado e com estabilidade de armazenagem;emulsao de agua em oleo;processo para distribuir o produto explosivo |
| GB2139616B (en) * | 1983-05-13 | 1987-04-01 | Glaverbel | Gas-filled glass beads |
| SE452003B (sv) * | 1983-06-10 | 1987-11-09 | Fluidcrystal I Malmo Ab | Sett for stabilisering av emulsionssprengemnen |
| JPH0633212B2 (ja) * | 1983-09-01 | 1994-05-02 | 日本油脂株式会社 | 油中水型エマルション爆薬組成物 |
| JPS6090887A (ja) * | 1983-10-21 | 1985-05-22 | 日本油脂株式会社 | 油中水型エマルシヨン爆薬組成物 |
| US4555278A (en) * | 1984-02-03 | 1985-11-26 | E. I. Du Pont De Nemours And Company | Stable nitrate/emulsion explosives and emulsion for use therein |
| GB2156799B (en) * | 1984-03-21 | 1987-12-16 | Ici Plc | Emulsion explosive |
| JPS60232223A (ja) * | 1984-04-28 | 1985-11-18 | Seibu Giken:Kk | フイルタ−素子 |
| FR2563825B1 (fr) * | 1984-05-07 | 1991-10-11 | Glaverbel | Procede de fabrication de perles de verre creuses remplies de gaz, notamment pour compositions explosives |
| SE459419B (sv) * | 1985-05-08 | 1989-07-03 | Nitro Nobel Ab | Foerfarande foer framstaellning av ett emulsionsspraengaemne av typen vatten-i-olja, en braenslefas foer anvaendning vid saadant foerfarande samt ett spraengaemnessystem |
| US4844756A (en) * | 1985-12-06 | 1989-07-04 | The Lubrizol Corporation | Water-in-oil emulsions |
| US4708753A (en) * | 1985-12-06 | 1987-11-24 | The Lubrizol Corporation | Water-in-oil emulsions |
| SE451196B (sv) * | 1985-12-23 | 1987-09-14 | Nitro Nobel Ab | Forfarande for framstellning av ett emulsionssprengemne av typ vatten-i-olja och en oxidationskomposition for anvendning av forfarandet |
| JPH0717473B2 (ja) * | 1986-01-14 | 1995-03-01 | 三洋化成工業株式会社 | 油中水滴型エマルジヨン爆薬 |
| US5527491A (en) * | 1986-11-14 | 1996-06-18 | The Lubrizol Corporation | Emulsifiers and explosive emulsions containing same |
| US4863534A (en) * | 1987-12-23 | 1989-09-05 | The Lubrizol Corporation | Explosive compositions using a combination of emulsifying salts |
| US4828633A (en) * | 1987-12-23 | 1989-05-09 | The Lubrizol Corporation | Salt compositions for explosives |
| US5047175A (en) * | 1987-12-23 | 1991-09-10 | The Lubrizol Corporation | Salt composition and explosives using same |
| US4840687A (en) * | 1986-11-14 | 1989-06-20 | The Lubrizol Corporation | Explosive compositions |
| ZW5188A1 (en) * | 1987-05-20 | 1989-09-27 | Aeci Ltd | Explosive |
| US5129972A (en) * | 1987-12-23 | 1992-07-14 | The Lubrizol Corporation | Emulsifiers and explosive emulsions containing same |
| ZA891501B (en) * | 1988-03-02 | 1989-11-29 | Ici Australia Operations | Explosive composition |
| US5114858A (en) * | 1990-06-26 | 1992-05-19 | E. I. Du Pont De Nemours And Company | Cellular component extraction process in a disposable filtration vessel |
| US5834533A (en) * | 1996-11-20 | 1998-11-10 | Phillips Petroleum Company | Stable liquid suspension compositions |
| US6002080A (en) * | 1997-06-17 | 1999-12-14 | Yahama Corporation | Electronic wind instrument capable of diversified performance expression |
| ES2123468B1 (es) * | 1997-06-26 | 2000-02-01 | Espanola Explosivos | Procedimiento e instalacion para la sensibilizacion in situ de explosivos de base acuosa. |
| DE19823999C2 (de) * | 1998-05-28 | 2002-07-18 | Nico Pyrotechnik | Verfahren zur Herstellung von pyrotechnischen Anzündern |
| JP3799241B2 (ja) * | 2001-03-29 | 2006-07-19 | 日本碍子株式会社 | ハニカム構造体の製造方法 |
| JP3799240B2 (ja) * | 2001-03-29 | 2006-07-19 | 日本碍子株式会社 | ハニカム構造体の製造方法 |
| US6808573B2 (en) * | 2002-09-23 | 2004-10-26 | Dyno Nobel Inc. | Emulsion phase having improved stability |
| US6955731B2 (en) | 2003-01-28 | 2005-10-18 | Waldock Kevin H | Explosive composition, method of making an explosive composition, and method of using an explosive composition |
| US8167964B2 (en) * | 2009-04-09 | 2012-05-01 | Lau Ying Wai | Cyclonic chamber for air filtration devices |
| CN103755503B (zh) * | 2014-01-23 | 2016-03-30 | 葛洲坝易普力股份有限公司 | 一种混装乳化炸药用高分子乳化剂及其制备方法 |
| CN114478144B (zh) * | 2022-01-21 | 2023-10-13 | 陕西北方民爆集团有限公司 | 一种顶孔用粘性粉状乳化炸药及制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3161551A (en) * | 1961-04-07 | 1964-12-15 | Commercial Solvents Corp | Ammonium nitrate-containing emulsion sensitizers for blasting agents |
| DE1141572B (de) * | 1961-05-24 | 1962-12-20 | Dynamit Nobel Ag | Detonationsfaehiges wasserhaltiges Sprenggemisch |
| FR1302057A (fr) * | 1961-08-25 | 1962-08-24 | Albright & Wilson | Nouvel agent explosif de mine |
| US3447978A (en) * | 1967-08-03 | 1969-06-03 | Atlas Chem Ind | Ammonium nitrate emulsion blasting agent and method of preparing same |
| FR1544937A (fr) * | 1967-11-13 | 1968-11-08 | Du Pont | Explosifs de sautage |
| US3674578A (en) * | 1970-02-17 | 1972-07-04 | Du Pont | Water-in-oil emulsion type blasting agent |
| US3770522A (en) * | 1970-08-18 | 1973-11-06 | Du Pont | Emulsion type explosive composition containing ammonium stearate or alkali metal stearate |
| US3715247A (en) * | 1970-09-03 | 1973-02-06 | Ici America Inc | Water-in-oil emulsion explosive containing entrapped gas |
| US3706607A (en) * | 1971-01-21 | 1972-12-19 | Du Pont | Chemical foaming of water-bearing explosives |
| US3765964A (en) * | 1972-10-06 | 1973-10-16 | Ici America Inc | Water-in-oil emulsion type explosive compositions having strontium-ion detonation catalysts |
| US3926698A (en) * | 1974-02-21 | 1975-12-16 | Ireco Chemicals | Explosive compositions containing metallic fuel particles and method of preparation thereof |
| US3930911A (en) * | 1974-03-05 | 1976-01-06 | Clark Jared W | Blasting composition and method of making same |
| US4008108A (en) * | 1975-04-22 | 1977-02-15 | E. I. Du Pont De Nemours And Company | Formation of foamed emulsion-type blasting agents |
| US4102240A (en) * | 1977-01-03 | 1978-07-25 | Cook Merrill A | Blasting slurry pump truck |
| AU515896B2 (en) * | 1976-11-09 | 1981-05-07 | Atlas Powder Company | Water-in-oil explosive |
| US4104092A (en) * | 1977-07-18 | 1978-08-01 | Atlas Powder Company | Emulsion sensitized gelled explosive composition |
| US4111727A (en) * | 1977-09-19 | 1978-09-05 | Clay Robert B | Water-in-oil blasting composition |
| US4149917A (en) * | 1977-11-03 | 1979-04-17 | Atlas Powder Company | Cap sensitive emulsions without any sensitizer other than occluded air |
| US4138281A (en) * | 1977-11-04 | 1979-02-06 | Olney Robert S | Production of explosive emulsions |
| US4141767A (en) * | 1978-03-03 | 1979-02-27 | Ireco Chemicals | Emulsion blasting agent |
-
1979
- 1979-08-06 US US06/064,172 patent/US4287010A/en not_active Expired - Lifetime
- 1979-12-11 SE SE7910197A patent/SE437259B/sv not_active IP Right Cessation
- 1979-12-11 IL IL58920A patent/IL58920A/xx unknown
- 1979-12-11 IN IN1294/CAL/79A patent/IN152693B/en unknown
- 1979-12-11 AU AU53702/79A patent/AU523413B2/en not_active Ceased
- 1979-12-11 NO NO794043A patent/NO145757C/no unknown
- 1979-12-12 NZ NZ192373A patent/NZ192373A/xx unknown
- 1979-12-14 GB GB7943194A patent/GB2055358B/en not_active Expired
- 1979-12-17 GR GR60780A patent/GR73908B/el unknown
- 1979-12-17 YU YU3078/79A patent/YU41494B/xx unknown
- 1979-12-19 IE IE2469/79A patent/IE49322B1/en not_active IP Right Cessation
- 1979-12-19 IT IT28199/79A patent/IT1193350B/it active
- 1979-12-19 BE BE0/198646A patent/BE880733A/fr not_active IP Right Cessation
- 1979-12-21 DE DE2951905A patent/DE2951905C2/de not_active Expired
- 1979-12-24 JP JP54166973A patent/JPS5828240B2/ja not_active Expired
- 1979-12-26 TR TR20808A patent/TR20808A/xx unknown
- 1979-12-31 KR KR1019790004718A patent/KR830000374B1/ko not_active Expired
- 1979-12-31 PT PT70652A patent/PT70652A/pt unknown
-
1980
- 1980-01-02 AT AT0000780A patent/AT380231B/de not_active IP Right Cessation
- 1980-01-10 BR BR800143A patent/BR8000143A/pt unknown
- 1980-01-10 FR FR8000506A patent/FR2463110A1/fr active Granted
- 1980-01-11 CS CS25980A patent/CS274253B2/cs unknown
- 1980-01-11 CH CH22180A patent/CH630325A5/de not_active IP Right Cessation
- 1980-01-21 MA MA18903A patent/MA18706A1/fr unknown
- 1980-01-28 PL PL22163980A patent/PL221639A1/xx unknown
- 1980-02-04 MX MX181077A patent/MX155262A/es unknown
- 1980-02-06 OA OA57020A patent/OA06460A/xx unknown
- 1980-02-06 ES ES488318A patent/ES488318A0/es active Granted
- 1980-02-15 ZA ZA00800874A patent/ZA80874B/xx unknown
- 1980-04-03 CA CA349,219A patent/CA1133702A/en not_active Expired
-
1984
- 1984-05-03 HK HK384/84A patent/HK38484A/xx unknown
-
1985
- 1985-12-30 MY MY433/85A patent/MY8500433A/xx unknown
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CS274253B2 (en) | Emulsion-type explosive mixture and method of its production | |
| EP0004160B1 (en) | Explosive compositions and method for their manufacture | |
| JPS6214518B2 (no) | ||
| NO168097B (no) | Formgitt sprengstoffpreparat og fremgangsmaate for fremstilling av dette | |
| US4997494A (en) | Chemically gassed emulsion explosive | |
| AU2607688A (en) | Methods and compositions related to emulsified gassing agents for sensitizing explosive compositions | |
| NZ197739A (en) | Water-in-oil emulsion blasting agents wherein the discontinuous phase consists of urea perchlorte | |
| PH26097A (en) | Aromatic hydrocarbon-based emulsion explosive composition | |
| CA2040346C (en) | Explosive comprising a foamed sensitizer | |
| JPH072591A (ja) | 鋳込まれたプライマーと小経爆薬の組成 | |
| CZ9902408A3 (cs) | Výbušná emulze pro náložky | |
| KR830000373B1 (ko) | 에멀젼 형태의 폭발성 조성물의 제조방법 | |
| EP4086237B1 (en) | Composition for forming a hydrogen peroxide based emulsion explosive | |
| JP2673832B2 (ja) | 油中水滴型エマルジョン爆薬 | |
| GB2091714A (en) | An Explosive | |
| KR100356127B1 (ko) | 강력한 카트리지 폭발성 유제 | |
| JPS5815468B2 (ja) | 油中水型エマルシヨン爆薬組成物 | |
| JPS6222959B2 (no) | ||
| JPS58120589A (ja) | 油中水型エマルシヨン爆薬組成物 | |
| JPH09208357A (ja) | 油中水型エマルション爆薬組成物 |