CN1957028B - 具有金属效果的难燃片材 - Google Patents

具有金属效果的难燃片材 Download PDF

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CN1957028B
CN1957028B CN2005800165944A CN200580016594A CN1957028B CN 1957028 B CN1957028 B CN 1957028B CN 2005800165944 A CN2005800165944 A CN 2005800165944A CN 200580016594 A CN200580016594 A CN 200580016594A CN 1957028 B CN1957028 B CN 1957028B
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pigment
ppsu
flame
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fire
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CN1957028A (zh
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D·布曼
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Evonik Roehm GmbH
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/02Ingredients treated with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J3/00Processes of treating or compounding macromolecular substances
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    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
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    • C08J2481/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
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Abstract

本发明涉及由聚苯砜(PPSU)或聚碳酸酯(PC)组成的防火塑料模制品,其用Iriodin

Description

具有金属效果的难燃片材
技术领域
本发明涉及具有金属效果表面的塑料模制品以及它们在飞机内部装璜(Innenausbau)中的应用。
背景技术
用于飞机内部装璜的塑料模制品是已知的并且由R
Figure 058165944_3
hm GmbH&Co.KG以商品名Europlex
Figure 058165944_4
F和Europlex
Figure 058165944_5
PPSU销售。
Europlex
Figure 058165944_6
F是经不透明着色的抗冲击的、防火聚碳酸酯(PC)类型,类似地,EuroplexPPSU是经不透明着色的抗冲击的、防火聚苯砜(PPSU),这些材料满足OSU 65/65试验(根据FAR 25.853的放热试验)。PC满足FAR 25.853(a)(1)(i),(a)(1)(ii),还符合关于烟密度和毒性的要求,并且PPSU另外满足FAR 25.853(c)。
以0.8到8.0毫米的厚度供应板材,宽度为最大1400毫米。由该板材尤其制成座椅外罩、托盘、门护板、门框护板和灯罩。
发明内容
目的
金属效果的涂层至今通常用以为基于不透明模塑组合物的并且由EuroplexF或Europlex
Figure 058165944_9
PPSU组成的不透明塑料模制品提供金属效果的装饰。然而,该涂层的缺点在于,不是太耐擦划和耐碰撞,结果是飞机座舱的日常运行中该涂漆制品很快变得不美观。
传统金属颜料在遮盖性或不透明的基础模塑组合物中的使用必然不会获得涂层的效果。另外,基于细磨的金属颗粒的传统金属效果颜料由于它们具有灯心效应而损害用其装备的塑料模制品的防火行为。
目的
因此,本发明目的是开发一种具有例如对于塑料模制品而言典型的金属效果的模塑组合物,其不会将塑料模制品的防火性能损害到这些塑料模制品不能用于飞机装璜的程度。此外,该金属效果表面相对于飞机座舱中的常见应力应该是牢固的。金属效果表面的颜色印象应该,例如,与色调RAL 9006/9007对应。所用颜料在PPSU的加工温度下(在挤出期间大约为350到380℃螺杆温度)应该是稳定的。
采用不透明着色的基础材料(或不透明的基础材料)没有获得足够的金属效果(该效果被覆盖)。基于透明基础模塑组合物,起始情况是更好的,但是在此也存在对防火特性有影响的问题。
解决方案
该目的经由具有金属效果表面的基于透明防火PC和PPSU模塑组合物的防火塑料模制品而达到,在此所用颜料是Iriodin
Figure 058165944_10
颜料,以及如果需要的话,影响色调的着色剂。
发明详述
合适的用于塑料模制品的塑料不仅包括透明的防火聚碳酸酯(PC)而且包括聚砜(PSU)、聚苯砜(PPSU)和聚醚砜(PES)(制造商:Bayer AG,BASF,Solvay)。
颜料Iriodin
Figure 058165944_11
由Merck KGaA销售。
例如,Iriodin颜料以由相应的塑料和Iriodin
Figure 058165944_13
颜料组成的母料形式引入。该母料由以下物质组成:2到50wt%的Iriodin
Figure 058165944_14
颜料,其余是塑料颗粒。如果需要的话,还可以添加常规助剂或赋色着色剂。
为了挤出该塑料模制品,将适量的母料添加到该塑料模塑组合物中,以使Iriodin颜料的量与配方中预先规定的量相对应。
使用常用挤出机来挤出本发明的组合物以产生片材。在PPSU的情况下熔体温度大约是350-380℃,并且砑光机组的温度大约是180℃,在聚碳酸酯的情况下熔体温度大约是270-280℃并且砑光机组的温度大约是120℃。
可以通过常规方法例如深度拉伸或热成形来进一步使该塑料模制品变形。
可以通过Iriodin颜料的浓度和颜色的变化来模仿金属金、银、暗银(Altsilber)或铜。
具体实施方式
实施例:
实施例1
组成
PPSU模塑组合物,透明  98.799%
(Europlex PPSU 99470)
Iriodin 123,亮缎光泽 1%
Colortek OT-0005-BON  0.2%
Printex
Figure 058165944_17
60(Degussa)  0.001%
由该混合物挤出得到厚度为1.5毫米的片材。
实施例2
由与实施例1中相同的混合物挤出厚度1毫米的片材。
实施例3
由与实施例1中相同的混合物挤出厚度2.0毫米的片材。
对比实施例4
组成
PPSU模塑组合物,透明的  99.00%
(Europlex PPSU 99470)
金属颜料                1.0%
在实施例4中,将可商购的研磨金属粉末(金属颜料)代替Iriodin引入到与实施例1中相同的混合物中,并且挤出得到厚度1.5毫米的片材。
对比实施例5
将与实施例4中的混合物相同的包括金属颜料的混合物挤出得到厚度1.5毫米的片材。
根据FAR 25.853的放热试验的结果
  实施例   样品   HR极限值(kW min/m2)   HRR极限值(kW/m2)   各要求得到:
  1   123   17.2122.634.66   52.2248.0434.27   满足
  2   123   16.8010.9533.60   37.4822.6441.08   满足
  3   123   -5.92-0.45-3.30   50.0358.5956.94   满足
  对比实施例4   123   144.68125.28144.15   157.73137.70162.67   不满足
  对比实施例5   123   158.63173.26123.61   154.31179.95131.62   不满足
当使用本发明组成时,这些样品的放热(按kW min/m2/kW/m2计测量)明显地低于65/65kW min/m2/kW/m2(HR/HRR)的规定极限值。

Claims (6)

1.具有金属效果表面的基于透明防火聚碳酸酯PC或聚苯砜PPSU的防火塑料模制品,其特征在于使用
Figure FSB00000687500200011
颜料作为颜料。
2.根据权利要求1的防火塑料模制品,其特征在于基于用于制备该塑料模制品的模塑组合物计,颜料的量为0.1到10wt%。
3.根据权利要求1的防火塑料模制品,其特征在于其具有按照RAL9007HR的颜色印象。
4.根据权利要求1的防火塑料模制品,其特征在于其具有按照RAL9006HR的颜色印象。
5.制备根据权利要求1的防火塑料模制品的方法,其特征在于将所需用量的在母料中的
Figure FSB00000687500200013
颜料添加到模塑组合物中并且以本身已知的方式挤出得到塑料模制品。
6.根据权利要求5的方法,其特征在于塑料模制品的厚度为1.0到12毫米。
CN2005800165944A 2004-08-30 2005-06-16 具有金属效果的难燃片材 Expired - Fee Related CN1957028B (zh)

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WO2013070296A2 (en) * 2011-08-19 2013-05-16 Aerovironment, Inc. Aircraft system for reduced observer visibility
RU2502599C1 (ru) * 2012-11-14 2013-12-27 Станислав Васильевич Володин Способ изготовления пластмассовых изделий
US9526403B2 (en) * 2015-02-04 2016-12-27 Karl Storz Imaging, Inc. Polymeric material for use in and with sterilizable medical devices

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0932024A1 (de) * 1998-01-21 1999-07-28 Bayerische Mass-Industrie Arno Keller Gmbh Verfahren und Anordnung zum Markieren eines Kunststoff-Flüssigkeitsbehältnisses
CN1318578A (zh) * 2000-04-14 2001-10-24 默克专利股份有限公司 激光可标记的塑料
CN1359969A (zh) * 2000-12-18 2002-07-24 默克专利股份有限公司 可激光标记的塑料及其制备和用途
CN1369517A (zh) * 2001-02-10 2002-09-18 默克专利股份有限公司 包含光泽颜料和填料体的塑料元件
CN1416451A (zh) * 2000-02-15 2003-05-07 拜尔公司 含聚碳酸酯和颜料的组合物
CN1422309A (zh) * 2000-04-11 2003-06-04 默克专利股份有限公司 具有选择角度透射或反射性能和/或吸收性能的透明介质

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3739765A1 (de) * 1987-11-24 1989-06-08 Bayer Ag Beschichtete formkoerper und ein verfahren zu ihrer herstellung
US5391600A (en) * 1992-10-26 1995-02-21 Idemitsu Petrochemical Co., Ltd. Polycarbonate resin composition
JPH06322250A (ja) 1993-05-13 1994-11-22 Idemitsu Petrochem Co Ltd ポリカーボネート樹脂組成物
US5837757A (en) * 1996-06-18 1998-11-17 Idemitsu Petrochemical Co., Ltd. Flame-retardant polycarbonate compositions
DE19629675A1 (de) * 1996-07-23 1998-01-29 Merck Patent Gmbh Lasermarkierbare Kunststoffe
SE515734C2 (sv) * 1996-10-21 2001-10-01 Abb Ab System för montage och underhåll av kopplingsmoduler i ett högspänningsställverk, förfarande härför samt systemkomponent
JP4262831B2 (ja) * 1999-05-19 2009-05-13 帝人化成株式会社 着色マスター用樹脂組成物
US6376075B1 (en) * 2000-06-17 2002-04-23 General Electric Company Article having reflecting coating and process for the manufacture
DE10057165A1 (de) * 2000-11-16 2002-05-23 Basf Ag Pigmentzubereitungen
JP3939656B2 (ja) 2001-02-08 2007-07-04 出光興産株式会社 熱可塑性樹脂組成物及び成形品
DE10117785A1 (de) * 2001-04-10 2002-10-17 Bayer Ag Wärmeabsorbierendes Schichtsystem
JP4948722B2 (ja) * 2001-08-31 2012-06-06 Sabicイノベーティブプラスチックスジャパン合同会社 金属調光沢を有する樹脂組成物
DE10160569A1 (de) * 2001-12-10 2003-06-26 Bayer Ag Mehrschichtiges Erzeugnis
EP1488923A1 (en) * 2002-03-01 2004-12-22 C. I. Kasei Company, Limited Decorative sheet and process for producing the same
DE10209497A1 (de) * 2002-03-05 2003-09-25 Roehm Gmbh Problemlos thermisch umformbare Kunststofftafel mit Kennzeichnungen in der Schutzfolie
DE202004003362U1 (de) * 2004-03-04 2004-05-13 Degussa Ag Hochtransparente lasermarkierbare und laserschweißbare Kunststoffmaterialien

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0932024A1 (de) * 1998-01-21 1999-07-28 Bayerische Mass-Industrie Arno Keller Gmbh Verfahren und Anordnung zum Markieren eines Kunststoff-Flüssigkeitsbehältnisses
CN1416451A (zh) * 2000-02-15 2003-05-07 拜尔公司 含聚碳酸酯和颜料的组合物
CN1422309A (zh) * 2000-04-11 2003-06-04 默克专利股份有限公司 具有选择角度透射或反射性能和/或吸收性能的透明介质
CN1318578A (zh) * 2000-04-14 2001-10-24 默克专利股份有限公司 激光可标记的塑料
CN1359969A (zh) * 2000-12-18 2002-07-24 默克专利股份有限公司 可激光标记的塑料及其制备和用途
CN1369517A (zh) * 2001-02-10 2002-09-18 默克专利股份有限公司 包含光泽颜料和填料体的塑料元件

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