CN1957028A - 具有金属效果的难燃片材 - Google Patents

具有金属效果的难燃片材 Download PDF

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Publication number
CN1957028A
CN1957028A CNA2005800165944A CN200580016594A CN1957028A CN 1957028 A CN1957028 A CN 1957028A CN A2005800165944 A CNA2005800165944 A CN A2005800165944A CN 200580016594 A CN200580016594 A CN 200580016594A CN 1957028 A CN1957028 A CN 1957028A
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pigment
iriodin
flame
sheet material
fire
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CN1957028B (zh
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D·布曼
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ROUEM GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/02—Ingredients treated with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2481/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2481/06—Polysulfones; Polyethersulfones

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

本发明涉及由聚苯砜(PPSU)或聚碳酸酯(PC)组成的防火塑料模制品，其用Iriodin颜料按一定方式着色，使得其具有金属效果。所述效果相对于飞机座舱中的常见应力不敏感并满足每种情况下的防火要求。

Description

具有金属效果的难燃片材
技术领域
本发明涉及具有金属效果表面的塑料模制品以及它们在飞机内部装璜(Innenausbau)中的应用。
背景技术
用于飞机内部装璜的塑料模制品是已知的并且由Rhm GmbH & Co.KG以商品名EuroplexF和EuroplexPPSU销售。
EuroplexF是经不透明着色的抗冲击的、防火聚碳酸酯(PC)类型，类似地，EuroplexPPSU是经不透明着色的抗冲击的、防火聚苯砜(PPSU)，这些材料满足OSU 65/65试验(根据FAR 25.853的放热试验)。PC满足FAR 25.853(a)(1)(i)，(a)(1)(ii)，还符合关于烟密度和毒性的要求，并且PPSU另外满足FAR 25.853(c)。
以0.8到8.0毫米的厚度供应板材，宽度为最大1400毫米。由该板材尤其制成座椅外罩、托盘、门护板、门框护板和灯罩。
发明内容
目的
金属效果的涂层至今通常用以为基于不透明模塑组合物的并且由EuroplexF或EuroplexPPSU组成的不透明塑料模制品提供金属效果的装饰。然而，该涂层的缺点在于，不是太耐擦划和耐碰撞，结果是飞机座舱的日常运行中该涂漆制品很快变得不美观。
传统金属颜料在遮盖性或不透明的基础模塑组合物中的使用必然不会获得涂层的效果。另外，基于细磨的金属颗粒的传统金属效果颜料由于它们具有灯心效应而损害用其装备的塑料模制品的防火行为。
目的
因此，本发明目的是开发一种具有例如对于塑料模制品而言典型的金属效果的模塑组合物，其不会将塑料模制品的防火性能损害到这些塑料模制品不能用于飞机装璜的程度。此外，该金属效果表面相对于飞机座舱中的常见应力应该是牢固的。金属效果表面的颜色印象应该，例如，与色调RAL 9006/9007对应。所用颜料在PPSU的加工温度下(在挤出期间大约为350到380℃螺杆温度)应该是稳定的。
采用不透明着色的基础材料(或不透明的基础材料)没有获得足够的金属效果(该效果被覆盖)。基于透明基础模塑组合物，起始情况是更好的，但是在此也存在对防火特性有影响的问题。
解决方案
该目的经由具有金属效果表面的基于透明防火PC和PPSU模塑组合物的防火塑料模制品而达到，在此所用颜料是Iriodin颜料，以及如果需要的话，影响色调的着色剂。
发明详述
合适的用于塑料模制品的塑料不仅包括透明的防火聚碳酸酯(PC)而且包括聚砜(PSU)、聚苯砜(PPSU)和聚醚砜(PES)(制造商：Bayer AG，BASF，Solvay)。
颜料Iriodin由Merck KGaA销售。
例如，Iriodin颜料以由相应的塑料和Iriodin颜料组成的母料形式引入。该母料由以下物质组成：2到50wt％的Iriofin颜料，其余是塑料颗粒。如果需要的话，还可以添加常规助剂或赋色着色剂。
为了挤出该塑料模制品，将适量的母料添加到该塑料模塑组合物中，以使Iriodin颜料的量与配方中预先规定的量相对应。
使用常用挤出机来挤出本发明的组合物以产生片材。在PPSU的情况下熔体温度大约是350-380℃，并且砑光机组的温度大约是180℃，在聚碳酸酯的情况下熔体温度大约是270-280℃并且砑光机组的温度大约是120℃。
可以通过常规方法例如深度拉伸或热成形来进一步使该塑料模制品变形。
可以通过Iriodin颜料的浓度和颜色的变化来模仿金属金、银、暗银(Altsilber)或铜。
具体实施方式
实施例：
实施例1
组成
PPSU模塑组合物，透明                  98.799％
(Europlex PPSU 99470)
Iriodin 123，亮缎光泽                 1％
Colortek OT-0005-BON                  0.2％
Printex60(Degussa)                 0.001％
由该混合物挤出得到厚度为1.5毫米的片材。
实施例2
由与实施例1中相同的混合物挤出厚度1毫米的片材。
实施例3
由与实施例1中相同的混合物挤出厚度2.0毫米的片材。
对比实施例4
组成
PPSU模塑组合物，透明的                  99.00％
(Europlex PPSU 99470)
金属颜料                                1.0％
在实施例4中，将可商购的研磨金属粉末(金属颜料)代替Iriodin引入到与实施例1中相同的混合物中，并且挤出得到厚度1.5毫米的片材。
对比实施例5
将与实施例4中的混合物相同的包括金属颜料的混合物挤出得到厚度1.5毫米的片材。
根据FAR 25.853的放热试验的结果
  实施例   样品   HR极限值(kW min/m2)   HRR极限值(kW/m2)   各要求得到：
  123对比实施例4对比实施例5   123123123123123   17.2122.634.6616.80l0.9533.60-5.92-0.45-3.30144.68125.28144.15158.63173.26123.61   52.2248.0434.2737.4822.6441.0850.0358.5956.94157.73137.70162.67154.31179.95131.62   满足满足满足不满足不满足
当使用本发明组成时，这些样品的放热(按kW min/m2/kW/m2计测量)明显地低于65/65kW min/m2/kW/m2(HR/HRR)的规定极限值。

Claims (6)

1.具有金属效果表面的由透明防火聚碳酸酯PC或聚苯砜PPSU组成的防火塑料模制品，其特征在于使用Iriodin颜料作为颜料。
2.根据权利要求1的防火塑料模制品，其特征在于基于用于制备该塑料模制品的模塑组合物计，Iriodin颜料的量为0.1到10wt％。
3.制备根据权利要求1的防火塑料模制品的方法，其特征在于将所需用量的在母料中的Iriodin颜料添加到模塑组合物中并且以本身已知的方式挤出得到塑料模制品。
4.根据权利要求3的方法，其特征在于塑料模制品的厚度为1.0到12毫米。
5.根据权利要求1的防火塑料模制品，其特征在于其具有按照RAL9007HR的颜色印象。
6.根据权利要求1的防火塑料模制品，其特征在于其具有按照RAL9006HR的颜色印象。
CN2005800165944A 2004-08-30 2005-06-16 具有金属效果的难燃片材 Expired - Fee Related CN1957028B (zh)

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DE102004042095A DE102004042095A1 (de) 2004-08-30 2004-08-30 Schwer entflammbare Plattenmaterialien mit Metallic-Effekt
DE102004042095.5 2004-08-30
PCT/EP2005/006452 WO2006024331A1 (de) 2004-08-30 2005-06-16 Schwer entflammbare plattenmaterialien mit metallic-effekt

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EP (1) EP1789485B1 (zh)
JP (1) JP4838801B2 (zh)
KR (2) KR100914804B1 (zh)
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AT (1) ATE413429T1 (zh)
AU (1) AU2005279502A1 (zh)
BR (1) BRPI0514754A (zh)
CA (1) CA2570290C (zh)
DE (2) DE102004042095A1 (zh)
DK (1) DK1789485T3 (zh)
ES (1) ES2317248T3 (zh)
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US9526403B2 (en) * 2015-02-04 2016-12-27 Karl Storz Imaging, Inc. Polymeric material for use in and with sterilizable medical devices

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AU2005279502A1 (en) 2006-03-09
BRPI0514754A (pt) 2008-06-24
US8303864B2 (en) 2012-11-06
RU2382797C2 (ru) 2010-02-27
EP1789485B1 (de) 2008-11-05
TWI298727B (en) 2008-07-11
TW200609274A (en) 2006-03-16
ES2317248T3 (es) 2009-04-16
ZA200701734B (en) 2008-08-27
US20070228342A1 (en) 2007-10-04
CA2570290C (en) 2011-08-23
DE102004042095A1 (de) 2006-03-02
CA2570290A1 (en) 2006-03-09
KR100914804B1 (ko) 2009-09-02
KR20080108355A (ko) 2008-12-12
PL1789485T3 (pl) 2009-04-30
ATE413429T1 (de) 2008-11-15
JP2008511696A (ja) 2008-04-17
JP4838801B2 (ja) 2011-12-14
WO2006024331A1 (de) 2006-03-09
EP1789485A1 (de) 2007-05-30
RU2007111554A (ru) 2008-10-10
DK1789485T3 (da) 2009-03-02
CN1957028B (zh) 2012-02-22
DE502005005907D1 (de) 2008-12-18
HK1104311A1 (en) 2008-01-11

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