CN1835992A - 使基材与物体接合的方法 - Google Patents

使基材与物体接合的方法 Download PDF

Info

Publication number
CN1835992A
CN1835992A CNA2004800230760A CN200480023076A CN1835992A CN 1835992 A CN1835992 A CN 1835992A CN A2004800230760 A CNA2004800230760 A CN A2004800230760A CN 200480023076 A CN200480023076 A CN 200480023076A CN 1835992 A CN1835992 A CN 1835992A
Authority
CN
China
Prior art keywords
case independently
compound
amine
alkyl
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2004800230760A
Other languages
English (en)
Other versions
CN1835992B (zh
Inventor
K·舍罕诺比希
D·J·法拉
S·吴
M·F·索南夏因
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34193234&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1835992(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Priority claimed from PCT/US2004/026275 external-priority patent/WO2005017005A1/en
Publication of CN1835992A publication Critical patent/CN1835992A/zh
Application granted granted Critical
Publication of CN1835992B publication Critical patent/CN1835992B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112—Single lapped joints
    • B29C66/1122—Single lap to lap joints, i.e. overlap joints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
    • B29C65/485—Multi-component adhesives, i.e. chemically curing as a result of the mixing of said multi-components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/78—Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
    • B29C65/7802—Positioning the parts to be joined, e.g. aligning, indexing or centring
    • B29C65/782—Positioning the parts to be joined, e.g. aligning, indexing or centring by setting the gap between the parts to be joined
    • B29C65/7823—Positioning the parts to be joined, e.g. aligning, indexing or centring by setting the gap between the parts to be joined by using distance pieces, i.e. by using spacers positioned between the parts to be joined and forming a part of the joint
    • B29C65/7829—Positioning the parts to be joined, e.g. aligning, indexing or centring by setting the gap between the parts to be joined by using distance pieces, i.e. by using spacers positioned between the parts to be joined and forming a part of the joint said distance pieces being integral with at least one of the parts to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1222—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1224—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a butt joint-segment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/52—Joining tubular articles, bars or profiled elements
    • B29C66/522—Joining tubular articles
    • B29C66/5221—Joining tubular articles for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/55—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles sealing elements being incorporated into the joints, e.g. gaskets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L13/00—Non-disconnectible pipe-joints, e.g. soldered, adhesive or caulked joints
    • F16L13/10—Adhesive or cemented joints
    • F16L13/103—Adhesive joints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/723—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered
    • B29C66/7232—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered comprising a non-plastics layer
    • B29C66/72321—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered comprising a non-plastics layer consisting of metals or their alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/737—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined
    • B29C66/7377—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined amorphous, semi-crystalline or crystalline
    • B29C66/73773—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined amorphous, semi-crystalline or crystalline the to-be-joined area of at least one of the parts to be joined being semi-crystalline
    • B29C66/73774—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined amorphous, semi-crystalline or crystalline the to-be-joined area of at least one of the parts to be joined being semi-crystalline the to-be-joined areas of both parts to be joined being semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7394—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoset
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7394—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoset
    • B29C66/73941—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoset characterised by the materials of both parts being thermosets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00—Use of unspecified macromolecular compounds as moulding material
    • B29K2101/10—Thermosetting resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00—Use of unspecified macromolecular compounds as moulding material
    • B29K2101/12—Thermoplastic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00—Tubular articles
    • B29L2023/22—Tubes or pipes, i.e. rigid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/712—Containers; Packaging elements or accessories, Packages
    • B29L2031/7172—Fuel tanks, jerry cans
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/10—Presence of inorganic materials
    • C09J2400/16—Metal
    • C09J2400/166—Metal in the pretreated surface to be joined
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/22—Presence of unspecified polymer
    • C09J2400/226—Presence of unspecified polymer in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/006—Presence of polyolefin in the substrate

Abstract

本发明公开了一种使用可固化一元或二元粘合剂组合物将基材与物体接合的方法，该组合物包括有效量的稳定有机硼烷胺络合物引发剂和一种或多种含有能够通过自由基聚合进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物。

Description

使基材与物体接合的方法
本发明主要涉及将具有第一表面的基材与具有第二表面的物体接合的方法。该方法对于将屋顶膜接合在一起、将屋顶膜与屋顶基材接合和对于接合管件尤为有效。该方法使用一种可固化的一元或二元(one or two part)粘合剂组合物，该组合物包括有机硼络合物引发剂体系和一种或多种含有能够通过自由基聚合进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物。
热塑性聚合物被广泛用于制造屋顶膜之类的制品。需要良好耐腐蚀性和耐化学性、低重量和良好可塑性的用于压力和无压条件下的气体、液体、固体、浆料或类似物的输送或用于保护敏感部件(例如光导纤维或光缆)的制品如管材或接管零件也是由热塑性聚合物制成的。这些应用常常需要层、管和/或其它物体之间的连接。热塑性材料制成的制品的接合可以通过机械方法(例如螺纹接头、接口、法兰)；化学方法(例如溶剂胶接)；或通过热方法(例如熔融粘结)实现。
对于小直径管和无压用途，机械接头通常能很好地发挥作用，但是它们对于大直径管和/或耐压管系统缺乏成本竞争力或技术上不适合。
溶剂胶接广泛地用于一些热塑性塑料，例如聚氯乙烯管和配件。通常，溶剂粘合使用一种溶剂基底漆或清洁剂处理待粘合表面，并连同过盈配合连接一起使用含有一种或多种溶剂和树脂的液状粘固剂系统。液状粘固剂可以不与底漆或清洁剂一起使用，然而接合完整性可能受损。然而，过盈配合连接限制了在胶接之前精确布置管材和配件的能力。粘合剂底漆广泛地与聚(氯乙烯)和氯化聚(氯乙烯)管道系统的溶剂基粘固剂一起使用以确保可接受的接头粘合。然而，底漆向环境中释放多达650克/升的挥发性有机化合物(VOC)。此外，粘合强度不一致，且溶剂基系统不能很好地用于许多热塑性管材和配件材料，例如聚烯烃。
对于屋顶系统，所选材料通常是聚氯乙稀(PVC)和聚烯烃。屋顶工业中层板的主要粘合是热形成的，也就是通过空气加热枪进行的。手持空气加热枪的使用是一种非常缓慢的工艺并通常产生很差的密封，即使这些材料如果被适当并经济地密封，就可以承受环境状态。不幸的是，该方法在复杂区域、边缘和弯曲处不能很好地发挥作用。聚乙烯和聚丙烯之类的低表面能材料(在24℃表面能为16至30mJ/m2)用的现有粘合剂体系不能充分粘合这些材料。然而，本文提出的粘合密封可用于缝隙接合以及屋顶上的遮雨板、管道和其它障碍物周围的膜敷设。本文提出的粘合剂体系可以改进密封完整性、减少涂底漆和清洁操作，并降低劳动力成本。在将简单的屋顶层板粘合到复杂弯曲处时，本发明的粘合剂体系提供了高强度、韧度和挠性、耐化学性、简单和独特的接合完整性、最少的长期维护、和快速简单的敷设。
相应地，需要一种在热塑性(尤其是聚烯烃)制品之间形成大面积连续经济和牢固接合的方法，其具有较低VOC排放并且方便经济。本发明满足了这一需求。
本发明公开了一种将具有第一表面的基材与具有第二表面的物体接合的方法，包括下列步骤：
(i)在基材的第一表面和/或物体的第二表面上涂敷有效量的可固化粘合剂组合物，其中粘合剂包括
(b)有效量的有机硼烷胺络合物引发剂和
(b)一种或多种含有能够通过自由基聚合法进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物和
(ii)将基材的第一表面与物体的第二表面接触。
本发明的另一具体实施方式是一种修补具有一个或多个需要修补的表面的新的或现有基材、物体或基材/物体接合处的方法，包括下列步骤：
(i)在需要修补的表面和/或补片上涂敷有效量的可固化一元或二元粘合剂组合物，其中粘合剂包括
(a)有效量的有机硼烷胺络合物引发剂和
(b)一种或多种含有能够通过自由基聚合法进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物和
(ii)将补片粘合到需要修补的表面上。
本发明的又一具体实施方式是具有第一表面的基材，该基材与具有第二表面的物体粘合，其中用有效量的可固化一元或二元粘合剂组合物将第一表面与第二表面粘合，其中粘合剂包括
(a)有效量的有机硼烷胺络合物引发剂和
(b)一种或多种含有能够通过自由基聚合法进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物。
有机硼烷胺络合物引发剂可以表示为下式
                       B-(R2)3其中B代表硼；R2在每种情况下独立地为C1-10烷基、C3-10环烷基，或两个或更多个R2可结合形成一个脂环族环。优选地，R2是C1-4烷基，更优选为C2-4烷基，最优选为C3-4烷基。优选的有机硼烷包括三乙基硼烷、三异丙基硼烷和三正丁基硼烷。
胺可以是伯胺；仲胺；含有伯胺和/或仲胺的多胺；氨；聚氧化烯胺；二胺与含有能够与胺反应的部分的双官能化合物的反应产物，其中该反应产物含有末端胺基；芳胺；杂环胺；具有脒结构组分的化合物；在杂环中含有至少一个仲氮的脂族杂环，其中该杂环化合物还可以在杂环中含有一个或多个其它仲氮或叔氮原子、氧原子、硫原子或双键；脂环族化合物，其含有一个或多个键接到脂环上的含胺部分的取代基；共轭亚胺或它们的混合物。
在本发明的又一具体实施方式中，粘合剂组合物进一步含有有效量的含异氰酸酯的化合物；一种或多种含有开环杂环部分的未聚合的或部分聚合的化合物，且任选含有一种能够引发含杂环部分的化合物聚合的路易斯酸催化剂；一种或多种能够聚合的在骨架中含有硅氧烷基团和反应性部分的化合物、低聚物或预聚物；一种或多种在骨架中含有硅氧烷基团的化合物、低聚物或预聚物，其含有在暴露于潮湿环境时形成能够将有机硼烷胺络合物解络合的酸的部分；或它们的混合物。
任何能够用于接合的基材和物体都适合本发明。接合在一起的膜(例如屋顶膜)、接合到基材(例如屋顶材料)上的膜、或接合在一起或接合到接管零件上的管特别适合本发明。
屋顶膜之类的膜可以包括如上所述的各种热塑性聚合物，而且可以由这些聚合物的掺合物制成。在WO 03/033585(PCT/US02/27968)和WO 00/69965(PCT/US00/13359)中列出了这些膜的例子。
聚乙烯特别适合用于本发明，优选低密度聚乙烯(LDPE)、线型低密度聚乙烯(LLDPE)、中密度聚乙烯(MDPE)、高密度聚乙烯(HDPE)、交联聚乙烯(PEX)。聚乙烯可以是均聚物、与α-烯烃的共聚物或它们的混合物。聚乙烯的混合物可以包括齐格勒-纳塔聚合的聚乙烯和金属茂聚乙烯的混合物，例如USP 5,844,045中所公开的。优选的α-烯烃是C3至C20α-烯烃，更优选丙烯、1-丁烯、甲基-4-戊烯、1-己烯、和2-辛烯。乙烯/α-烯烃/二烯聚合物也可用于本发明。这些常被称作EPDM。二烯可以是能有效地与乙烯和α-烯烃共聚的任何二烯，其中亚乙基降冰片烯是优选的。
制造聚乙烯的方法是公知的，并包括使用各种聚合技术，包括高压自由基聚合法、溶液法、浆料法和气相法。如USP 4,076,698中所公开的溶液法是合适的。USP 4,076,698公开了具有相对较宽分子量分布(MWD)的不均匀支化的聚乙烯。用于各种聚合方法的催化剂体系包括齐格勒纳塔催化剂技术，如USP 4,076,698中所示的技术，也包括单点催化剂技术，例如USP 3,645,992和5,064,802中所公开的技术(约束几何结构催化剂技术)。USP 3,645,992中公开的技术产生具有非常窄MWD的均匀支化的线型聚乙烯。USP 5,064,802的催化剂技术在连续聚合法中使用时，产生基本线型聚乙烯(长链支化程度为每1000个碳原子0.01-3个长链分支，还具有非常窄的MWD)。其它(金属茂)催化剂技术包括USP 5,026,798和5,055,438中公开的技术。基本线型聚乙烯的例子可以在USP 5,272,236、5,278,272和5,665,800中找到。所列举的所有美国专利都全文经此引用并入本文。在经此引用并入本文的未决美国申请10/222273中公开了优选的聚乙烯。
较低粘度的聚乙烯优选用于例如注射成型。可用于本发明的低粘度聚乙烯的熔体流动速率(MFR)通常等于或大于1克/10分钟(克/10分钟)，优选等于或大于2克/10分钟，更优选等于或大于5克/10分钟，最优选等于或大于10克/10分钟。可用于本发明的低粘度聚乙烯的熔体流动速率通常等于或小于1000克/10分钟，优选等于或小于500克/10分钟，最优选等于或小于50克/10分钟。除非另行指明，按照ASTMD1238在190℃和2.16千克(kg)的施加载荷下测定低粘度PE树脂的熔体流动速率。
或者，较高粘度的聚乙烯优选用于例如吹塑、旋转模塑和挤出。可用于本发明的高粘度聚乙烯的MFR通常等于或大于0.1克/10分钟，优选等于或大于0.2克/10分钟，更优选等于或大于0.3克/10分钟，最优选等于或大于0.4克/10分钟。此处可用于挤出的高粘度聚乙烯的熔体流动速率通常等于或小于2克/10分钟，优选等于或小于1克/10分钟，更优选等于或小于0.8克/10分钟，最优选等于或小于0.6克/10分钟。按照ASTM D1238在190℃和5千克的施加载荷下测定高粘度PE的熔体流动速率。
类似地，可以使用本发明粘合官能化聚合物。这些官能化聚合物包括马来酸酐接枝的聚烯烃、羧酸官能化聚合物，例如乙烯/丙烯酸和乙烯/甲基丙烯酸，和由其制成的离子交联聚合物。
适用于本发明的聚丙烯是文献中公知的，而且可以通过已知技术制备。一般而言，聚丙烯是全同立构形式的，尽管也可以使用其它形式(例如间同立构或无规立构的)。用于本发明的聚丙烯优选是聚丙烯均聚物或丙烯与α-烯烃(优选C2或C4-C20α-烯烃)的共聚物，例如无规或嵌段共聚物。构成丙烯与α-烯烃共聚物的优选α-烯烃包括乙烯、1-丁烯、4-甲基戊烯、1-己烯和1-辛烯。α-烯烃在本发明的聚丙烯中的存在量等于或小于20摩尔％，优选等于或小于15摩尔％，更优选等于或小于10摩尔％，最优选等于或小于5摩尔％。
优选聚丙烯是具有高结晶度的全同立构聚丙烯。测定聚丙烯结晶度的优选方法是差示扫描量热法(DSC)。如本文所述，通过DSC测定的高结晶度为聚丙烯重量的至少40wt％，更优选至少50wt％，再优选至少62wt％，再优选至少64wt％，最优选至少68wt％。通过DSC测定的聚丙烯的结晶度小于或等于聚丙烯重量的100wt％，优选小于或等于90wt％，更优选小于或等于80wt％，最优选小于或等于70wt％。
优选的聚丙烯是偶联聚丙烯。为了进行偶联，聚丙烯与能够向碳-氢键中进行插入反应的多官能化合物反应。此处优选作为偶联剂的是含有至少两个能够插入聚合物链的CH、CH2或CH3基团(脂族和芳族)的碳-氢键中的官能团的化合物。优选的偶联剂是聚(磺酰基叠氮)，更优选二(磺酰基叠氮)。在WO 99/10424中描述了可用于本发明的聚(磺酰基叠氮)的例子。优选的聚(磺酰基叠氮)包括4，4’-氧-双-(磺酰叠氮基)苯、2，7-萘双(磺酰叠氮基)、4，4’-双(磺酰叠氮基)联苯、4，4’-二苯醚双(磺酰叠氮)和双(4-磺酰叠氮基苯基)甲烷，和它们的混合物。
本领域技术人员了解，偶联剂的有效量取决于所选偶联剂和聚丙烯的平均分子量。通常，聚丙烯的分子量越低，就需要越多偶联剂。偶联剂的有效量为足以产生形成管和/或配件所需的充足熔体强度的量，但小于交联量。通常，以聚丙烯重量为基数，用于偶联的聚(磺酰基叠氮)的有效量等于或大于50份/百万份(ppm)，优选等于或大于75ppm，更优选等于或大于100ppm，最优选等于或大于150ppm。必须避免交联聚丙烯的形成，因此，以聚丙烯重量为基数，双(磺酰基叠氮)的量限于等于或小于2000ppm，优选等于或小于1500ppm，更优选等于或小于1300ppm。
低粘度聚丙烯优选用于例如注射成型。可用于本发明的低粘度聚丙烯的MFR通常等于或大于1克/10分钟，优选等于或大于5克/10分钟，最优选等于或大于10克/10分钟。此处可用于注射成型的低粘度聚丙烯的熔体流动速率通常等于或小于50克/10分钟，优选等于或小于40克/10分钟，最优选等于或小于35克/10分钟。除非另行指明，按照ASTM D1238在230℃和2.16千克(kg)的施加载荷下测定聚丙烯的熔体流动速率。
或者，高粘度聚丙烯优选用于例如吹塑、旋转模塑和挤出。可用于本发明的高粘度聚丙烯的MFR通常等于或大于0.1克/10分钟，优选等于或大于0.2克/10分钟，最优选等于或大于0.5克/10分钟。此处可用的高粘度聚丙烯的熔体流动速率通常等于或小于10克/10分钟，优选等于或小于5克/10分钟，最优选等于或小于1克/10分钟。
本发明的接合基材和物体用的粘合剂可以是一元可固化组合物或二元可固化组合物，这些术语是本领域已知的。一元粘合剂组合物含有有效量的稳定的有机硼烷胺络合物引发剂和可聚合单体。二元粘合剂组合物在一个部分中含有有效量的稳定有机硼烷胺络合物引发剂，在另一部分中含有可聚合单体。这些粘合剂是本领域已知的，参看USP5,106,928、5,286,821、5,310,835、5,376,746、5,539,070、5,690,780、5,691,065、5,616,796、5,621,143、5,681,910、5,686,544、5,718,977、5,795,657、5,686,544和美国专利申请系列号09/466321、10/012629、10/095326和10/377440。
该络合物中使用的有机硼烷是三烷基硼烷或烷基环烷基硼烷。优选地，这种硼烷符合下式
                      B-(R2)3其中B代表硼；R2在每种情况下独立地为C1-10烷基、C3-10环烷基，或两个或更多个R2可结合形成一个脂环族环。优选地，R2是C1-4烷基，更优选为C2-4烷基，最优选为C3-4烷基。优选的有机硼烷包括三乙基硼烷、三异丙基硼烷和三正丁基硼烷。
用于使有机硼烷化合物络合的胺可以是使有机硼烷络合并在接触到解络合剂时可以解络合的任何胺或胺混合物。可以根据路易斯酸-碱络合物与分离的路易斯酸(有机硼烷)和碱(胺)的能量总和之间的能量差(被称作结合能)来计算给定胺在胺/有机硼烷络合物中的合意性。结合能越低，络合物越稳定。
优选的胺包括伯胺；仲胺；含有伯胺和/或仲胺的多胺；氨；聚氧化烯胺；二胺与含有能够与胺反应的部分的双官能化合物的反应产物，其中该反应产物含有末端胺基；芳胺；杂环胺；具有脒结构组分的化合物；在杂环中含有至少一个仲氮的脂族杂环，其中该杂环化合物还可以在杂环中含有一个或多个其它仲氮或叔氮原子、氧原子、硫原子或双键；脂环族化合物，其含有一个或多个键接到脂环上的含胺部分的取代基；共轭亚胺或它们的混合物。
最优选的胺选自：含有脒结构组分的胺；在杂环中含有至少一个氮的脂族杂环，其中该杂环化合物还可以在杂环中含有一个或多个氮原子、氧原子、硫原子或双键；脂环族化合物，其含有一个键接到脂环上的含胺部分的取代基，其中脂环族化合物可以含有一个第二取代基，其可以含有一个或多个氮、氧或硫原子和/或一个或两个双键；如下的伯胺，其除伯胺外还含有一个或多个醚、聚醚、硫醚或卤素的氢键接受基团，其中在伯胺和氢键接受基团之间有一条含至少两个碳原子的亚烷基链；和共轭亚胺。例如，有机硼烷和伯胺的络合物符合下式
有机硼烷杂环胺络合物符合下式
Figure A20048002307600152
有机脒络合物符合下式
有机共轭亚胺络合物符合下式
且胺取代的脂环族化合物络合物符合下式
Figure A20048002307600155
其中
B是硼；
R1在每种情况下独立地为氢、C1-10烷基或C3-10环烷基；
R2在每种情况下独立地为C1-10烷基、C3-10环烷基，或两个或更多个R2可结合形成一个脂环结构；
R3在每种情况下独立地为氢、C1-10烷基、C3-10环烷基，或与相邻原子上的R3或R4形成双键；
R4在每种情况下独立地为氢、C1-10烷基、C3-10环烷基、C6-10芳基或C6-10烷芳基；
R5和R6在每种情况下独立地为氢、C1-10烷基、C3-10环烷基、N(R4)2，其中R7在每种情况下独立地为氢、C1-10烷基、C3-10环烷基，或R5、R6和R7中两个或更多个可任意结合形成环结构，其可以是单环或多环结构，并且该环结构可以在环结构中包含一个或多个氮、氧或不饱和部分。
R9在每种情况下独立地为氢、C1-10烷基或C3-10环烷基、Y、-(C(R9)2-(CR9＝CR9)c-Y，或两个或更多个R9可结合形成环结构，或一个或多个R9可与Y形成环结构，条件是该环结构与亚胺氮的双键共轭。
R10在每种情况下独立地为C1-10烷基、C3-10环烷基或-(C(R1)2)d-W；
W在每种情况下独立地为氢、C1-10烷基或X；
X是OR10、SR10或卤素；
Y在每种情况下独立地为氢、SR4、N(R4)2、OR4、C(O)OR4、卤素或亚烷基，其与R7或R9形成环；
Z在每种情况下独立地为氧或-NR4；
a在每种情况下独立地为1至10的整数；
b在每种情况下独立地为0或1，条件是a和b之和应为2至10；
c在每种情况下独立地为1至10的整数；
d在每种情况下独立地为1至4的整数；
x在每种情况下独立地为1至10的整数，条件是所有地方的x之和为2至10；且
y在每种情况下独立地为0或1。
在另一优选具体实施方式中，胺进一步含有硅氧烷，也就是氨基硅氧烷。可以使用含有胺和硅氧烷单元的任何化合物，其中胺具有如上所述足够的与有机硼烷的结合能。优选地，硅氧烷部分允许该组分在硅氧烷单体、低聚物和/或聚合物的聚合过程中沉淀。含硅氧烷的单体、低聚物和/或聚合物可以是含有硅氧烷的任何化合物。优选地，硅氧烷化合物具有反应性官能度。优选的反应性官能度包括氢化物、不饱和烯键、羟基、和能够水解形成硅烷醇部分的可水解部分。粘合剂组合物可以进一步含有一种催化剂，其用于一种或多种含有硅氧烷骨架与能够进行聚合的反应性部分的化合物、低聚物或预聚物的聚合。
优选氨基硅氧烷表示为下式之一：
(R2)3-B←NH2(CH2)b-(C(R12)2)a-Si-((R11)q(Q)p)-或
其中
B是硼；
R2在每种情况下独立地为C1-10烷基、C3-10环烷基，或两个或更多个R2可结合形成一个脂环族环；
Q是可水解部分；
R11在每种情况下独立地为氢、烷基、烷氧基、链烯基、烷基氨基，或符合式((CR14H)rO)n-(NR4)-(CH2)o-NH2，条件是至少(R11)’是伯胺(leave this as is)；
R12在每种情况下独立地为氢、烷基、芳基、烷氧基，而且可以进一步含有一种或多种伯胺、仲胺或叔胺；
R14在每种情况下独立地为氢或烷基；
R4是氢、C1-10烷基、C6-10芳基或C7-10烷芳基；
a是1至10的数；
b是0至1的数；
m在每种情况下独立地为1或更大的整数；
p在每种情况下独立地为1至3的数；
q在每种情况下独立地为1至2的整数，其中每个硅原子上的p和q之和为3；
n在每种情况下独立地为4至400的整数；
o在每种情况下独立地为1至9的整数；和
r在每种情况下独立地为2或4的整数。
可在本发明的粘合剂组合物中使用的可聚合化合物包括含有可通过自由基聚合法进行聚合的不饱和烯键的任何单体、低聚物、聚合物或它们的混合物。这些化合物是本领域技术人员公知的，而且在USP3,275,611中有所描述。优选的含有不饱和烯键的化合物是由丙烯酸酯和甲基丙烯酸酯生成的单体、低聚物、聚合物和它们的混合物，和一种或多种具有硅氧烷骨架并含有丙烯酸酯官能部分的单体、低聚物或聚合物。最优选的丙烯酸酯和甲基丙烯酸酯化合物包括丙烯酸甲酯、丙烯酸乙酯、丙烯酸2-羟乙酯、丙烯酸4-羟乙酯、丙烯酸2-羧乙酯、乙二醇甲醚丙烯酸酯、丙烯酸2，2，2三氟乙酯、甲基丙烯酸甲酯、甲基丙烯酸丁酯、甲基丙烯酸2-乙基己酯、甲基丙烯酸异冰片酯、甲基丙烯酸四氢呋喃酯和甲基丙烯酸环己基甲酯。
在一些具体实施方式中，本发明的粘合剂组合物可以进一步含有有效量的能与胺反应的化合物以释放出有机硼烷，从而引发聚合(解络合剂)。胺反应性化合物通过与胺反应释放出有机硼烷，由此从与胺的化学连接中释放出有机硼烷。合意的胺反应性化合物是在优选室温20℃至22℃下容易与胺形成反应产物的那些材料，从而提供在环境条件下容易使用并固化的组合物。这些化合物的一般类型包括酸、醛、异氰酸酯、酰基氯、磺酰氯、它们的混合物。在一个具体实施方式中，优选的胺反应性化合物是酸。可以使用布朗斯台德和路易斯酸。Pocius，美国专利5,718,977在第9栏，第1至15行描述了优选的酸化合物。最优选的酸是丙烯酸和甲基丙烯酸。
在另一优选具体实施方式中，本发明的粘合剂组合物进一步含有有效量的含异氰酸酯的化合物(解络合剂)，其可与络合胺反应以释放出有机硼烷并引发聚合。胺反应性化合物通过与胺反应释放出有机硼烷，由此从与胺的化学连接中释放出有机硼烷。含异氰酸酯的化合物与组合物中存在的胺反应形成脲、聚脲或聚氨酯/脲相。当使用过量含异氰酸酯的化合物，所得产物中几乎或完全不存在游离胺。通过去除游离胺，防止了胺的增塑影响。此外，存在的脲或聚脲提高了所得产物的耐热性。
含异氰酸酯的化合物(如果使用的话)可以是能使有机硼烷胺络合物解络合的任何异氰酸酯化合物。优选地，该异氰酸酯是每化合物标称上含有2个或更多异氰酸酯部分的聚异氰酸酯。在USP 5,872,197中公开了可用的异氰酸酯化合物。更优选的含异氰酸酯的化合物包括二异氰酸亚甲基二苯酯、异佛尔酮二异氰酸酯、二异氰酸六亚甲酯、甲苯二异氰酸酯、异构体、或二异氰酸甲基环己烷、二异氰酸四甲基二甲苯酯的聚合形式。
优选地，所得聚合产物中脲或聚脲的存在量为5wt％或更高，更优选为10wt％或更高，最优选为15wt％或更高。优选地，所得聚合产物中聚脲的存在量为50wt％或更低，更优选为45wt％或更低，最优选为40wt％或更低。脲百分比是指脲/尿烷(氨基甲酸乙酯)相在最终产物中的重量百分比。其测定通常如下：将异氰酸酯和胺(和存在的任何其它异氰酸酯反应性化合物)的重量相加并将该和除以这些成分的总重量。
在另一具体实施方式中，粘合剂是二元可固化粘合剂，其含有包括能够自由基聚合的可聚合化合物的第一部分，和包括有机硼烷胺络合物和一种或多种具有开环杂环部分的未聚合或部分聚合化合物的第二部分。在一个优选具体实施方式中，通过使杂环化合物与路易斯酸催化剂接触来引发杂环化合物的开环聚合。这两部分可以是可混溶的、部分可混溶的或不混溶的。在一个优选具体实施方式中，可聚合组合物含有两相，一相基于通过烯键聚合的化合物，第二相通过杂环部分的开环反应聚合。本发明的固化组合物优选含有在多数情况下不混溶的两个区域。在一些具体实施方式中，这两个区域是分离相或是两种不同聚合物的互穿网络。如果该组合物含有交联化合物，这两个区域就可以互相化学键接。
含有杂环开环部分的化合物可以是含有能够进行开环和聚合的杂环部分的任何单体、低聚物或预聚物。杂环部分中的杂原子优选为氮、氧或硫，其中氮和氧是优选的，氧最优选。优选地，杂环部分是3元环。优选的杂环部分是环氧乙烷和氮丙啶，其中环氧乙烷部分最优选。这种含环氧乙烷的材料的例子是双酚A的二环氧甘油醚、三2-3-环氧丙基异氰脲酸酯、四苯酚(phenylol)乙烷环氧甘油醚、聚(苯基缩水甘油醚并甲醛)、聚(苯基缩水甘油醚并二环戊二烯)、以及三羟甲基丙烷三缩水甘油醚、任何其它缩水甘油基改性的脂族含环氧乙烷的材料、四缩水甘油基亚甲基氨苯、缩水甘油醚改性的聚(二甲基硅氧烷)、和任何其它缩水甘油醚、缩水甘油酯或缩水甘油胺。此处所用的氮丙啶是指环中含有氮的三元环。可用的含氮丙啶的分子的例子是三羟甲基丙烷三[2-甲基-1-氮丙啶丙酸酯]、季戊四醇三[3-(1-吖丙啶基)丙酸酯]、2，4，6-三吖丙啶-1-基-(1，3，5)三嗪、2，3二苯基氮丙啶、和1-丁酰基氮丙啶。
本发明的粘合剂组合物可以包含一种或多种含有硅氧烷骨架和能够聚合的反应性部分的化合物、低聚物或预聚物，并任选包含一种用于一种或多种含有硅氧烷骨架和能够聚合的反应性部分的化合物、低聚物和预聚物的聚合的催化剂。
或者，适用于本发明的粘合剂是一元组合物，其含有有机硼烷胺络合物；一种或多种含有能够通过自由基聚合法进行聚合的不饱和烯键的单体、低聚物或聚合物；和在其骨架中含有硅氧烷基团并含有在接触湿气时释放出能够使有机硼烷胺络合物解络合的酸的部分的化合物。该组合物可以如下聚合：使该组合物在部分分解形成酸的条件下接触大气湿度，这导致有机硼烷胺络合物分离并引发聚合。
本发明中可用的含有硅氧烷骨架和能够聚合的反应性部分的化合物、低聚物或预聚物包括在其骨架中含有硅氧烷单元的如下任何化合物、低聚物或预聚物，其含有能够在适当反应条件下聚合的反应性基团。此处所用的低聚物是指一些可识别的通过反应性部分连接在一起的化学单元。低聚物可以被认为是仅含少数单元的小聚合物，例如二聚物、三聚物、四聚物或五聚物。基体(mer)用于指低聚物或聚合物的一个基本的可识别化学单元，并通常是生成低聚物或聚合物用的化合物的残余部分。预聚物是指含有数个基本的可识别化学单元的化合物，其包括聚合物，也就是数个基体，它们还含有能够使化合物进一步反应的反应性基团。实践中，预聚物是含有不同数量的基本可识别化学单元的聚合物的混合物，并且可以含有一定量的低聚物。术语“含有硅氧烷骨架”此处是指化合物、低聚物和/或聚合物的骨架在骨架中含有带硅和氧原子的基本的可识别化学单元。优选地，硅氧烷的基本的可识别化学单元符合下式
Figure A20048002307600211
其中R在每种情况下独立地为氢、烷基、链烯基、芳基、烷芳基、或含最多20，优选最多8个碳原子的烷芳基，且当R为氢时，其可进一步含有一种或多种能够聚合的反应性部分。术语能够聚合的反应性部分是指互相反应或与其它反应性部分反应形成低聚物、预聚物或聚合物的任何部分。优选的能够聚合的反应性部分的例子包括乙烯基部分、可水解部分、羟基部分、氢化物、异氰酸酯部分、胺，或在环状硅氧烷的情况下，其是通过开环形成反应性末端。更优选的能够聚合的反应性部分包括乙烯基部分、可水解部分、羟基部分、氢化物。当每个反应性硅基团中存在两个或更多个能够聚合的反应性部分时，它们可以相同或不同。
可用于本发明的实践的一类硅氧烷聚合物包括乙烯基官能化硅氧烷，它们可以通过自由基或加成机理进一步聚合。乙烯基官能化硅氧烷包括骨架中含有硅氧烷单元并含有可聚合烯烃部分的化合物、低聚物和预聚物。乙烯基官能化硅氧烷可以在骨架中含有亚烃基(hydrocarbylene)和/或氟代亚烃基(fluorocarbylene)单元。
本发明中可用的另一类含硅氧烷的化合物、低聚物或预聚物是含有末端硅烷醇基团或可水解基团的硅氧烷，其在接触湿气时形成硅烷醇基团。硅氧烷链上的末端硅烷醇基团可以使化合物、低聚物或预聚物在催化时通过缩合进行反应。这些反应在室温下作为一部分或两部分聚合系统进行。在存在硅烷醇缩合催化剂的情况下，该反应在室温下发生。硅烷醇缩合催化剂是本领域公知的。
粘合剂组合物可以进一步含有其它添加剂，例如增稠剂，优选中至高分子量(10,000至1,000,000)聚甲基丙烯酸甲酯；弹性材料，例如氯化或氯磺化聚乙烯、苯乙烯和共轭二烯的嵌段共聚物、和某些接枝共聚物树脂，例如，含有被相对较硬的壳围绕的橡胶或类橡胶芯或网络的颗粒，这些材料通常被称作“芯-壳”聚合物；交联剂；过氧化物；抑制剂；色料；填料；溶剂，等等。粘合剂组合物还可以含有反应性或非反应性稀释剂以平衡该组合物两部分的体积，从而实现两种组分在商业上可接受的体积比。还可能合意的是添加溶剂(例如甲基乙基酮、乙酸乙酯、乙酸丙酯和二氯甲烷)以提高润湿性和/或平衡挥发性，使得蒸发最优化，使该材料不会过度刺鼻。
在将基材和物体接合之前，可以通过电晕、火焰、磺化、等离子之类的方法处理接合表面。然而，在本发明中，在接合之前可以不要求对接合表面进行表面处理。
能够提供足够表面积(用以通过本发明的方法将该物体与基材接合)的任何物体都是合适的。例如，基材可以是完整屋顶膜或可以与需要修补的屋顶接合的补片。应该理解的是，这些材料被互换作为物体或基材，这种指定并不重要。例如，当与膜粘合时，屋顶可以被看成基材或物体。
优选地，本发明的粘合剂组合物具有等于或小于650克/升(g/l)，优选等于或小于520克/升，更优选等于或小于510克/升，再优选等于或小于490克/升，再优选等于或小于400克/升，再优选等于或小于285克/升，再优选等于或小于270克/升，再优选等于或小于250克/升，最优选等于或小于17克/升的VOC排放。
当使用本发明的方法时，预计基材会与物体保持粘合(也就是没有任何粘合失效)达至少三十年。对于屋顶系统，这意味着该膜在大气条件(温度范围-40℃至90℃，相对湿度0-100％)下预计会与屋顶粘合至少30年。
尽管已经详细展示和描述了本发明的具体实施方式以说明本发明的原理，要理解的是，还可以在不背离这些原理的情况下以其它方式具体实施本发明。

Claims (26)

1.一种将具有第一表面的基材与具有第二表面的物体接合的方法，包括下列步骤：
(i)在基材的第一表面和/或物体的第二表面上涂敷有效量的可固化粘合剂组合物，其中粘合剂包括
(a)有效量的有机硼烷胺络合物引发剂和
(b)一种或多种含有能够通过自由基聚合法进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物和
(ii)将基材的第一表面与物体的第二表面接触。
2.根据权利要求1的方法，其中所述基材是屋顶膜。
3.根据权利要求1的方法，其中所述基材和物体独立地包括金属、多层塑料、多层复合材料、热塑性塑料、热固性材料；或它们的混合物。
4.根据权利要求1的方法，其中所述基材和物体是热塑性的。
5.根据权利要求1的方法，其中所述基材和物体独立地包括聚烯烃；丙烯腈、丁二烯和苯乙烯三元共聚物；聚氯乙烯；氯化聚氯乙烯；氯化/磺化聚乙烯；乙烯/α-烯烃/二烯三元共聚物；或它们的掺合物。
6.根据权利要求1的方法，其中所述基材和物体包括丙烯聚合物。
7.根据权利要求1的方法，其中所述基材和物体包括乙烯聚合物。
8.根据权利要求1的方法，其中所述基材是第一热塑性塑料，而物体是与第一热塑性塑料不同的第二热塑性塑料。
9.根据权利要求1的方法，其中所述有机硼烷胺络合物包括具有下述结构的有机硼烷
                     B-(R2)3
其中B代表硼；R2在每种情况下独立地为C1-10烷基、C3-10环烷基，或两个或更多个R2可结合形成一个脂环族环。
10.根据权利要求1的方法，其中所述有机硼烷胺络合物包括下述胺，该胺是伯胺；仲胺；含有伯胺和/或仲胺的多胺；氨；聚氧化烯胺；二胺与含有与胺反应的部分的双官能化合物的反应产物，其中该反应产物含有末端胺基；芳胺；杂环胺；具有脒结构组分的化合物；在杂环中含有至少一个仲氮的脂族杂环，其中该杂环化合物还可以在杂环中含有一个或多个其它仲氮或叔氮原子、氧原子、硫原子或双键；脂环族化合物，其含有一个或多个键接到脂环上的含胺部分的取代基；共轭亚胺或它们的混合物。
11.根据权利要求1的方法，其中所述有机硼烷胺络合物具有下列结构
Figure A2004800230760003C1
或
其中
B是硼；
R1在每种情况下独立地为氢、C1-10烷基或C3-10环烷基；
R2在每种情况下独立地为C1-10烷基、C3-10环烷基，或两个或更多个R2可结合形成一个脂环结构；
R3在每种情况下独立地为氢、C1-10烷基、C3-10环烷基，或与相邻原子上的R3或R4形成双键；
R4在每种情况下独立地为氢、C1-10烷基、C3-10环烷基、C6-10芳基或C6-10烷芳基；
R5和R6在每种情况下独立地为氢、C1-10烷基、C3-10环烷基、N(R4)2，其中R7在每种情况下独立地为氢、C1-10烷基、C3-10环烷基，或R5、R6和R7中两个或更多个可任意结合形成环结构，其可以是单环或多环结构，并且该环结构可以在环结构中包含一个或多个氮、氧或不饱和部分。
R9在每种情况下独立地为氢、C1-10烷基或C3-10环烷基、Y、-(C(R9)2-(CR9＝CR9)c-Y，或两个或更多个R9可结合形成环结构，或一个或多个R9可与Y形成环结构而条件是该环结构与亚胺氮的双键共轭。
R10在每种情况下独立地为C1-10烷基、C3-10环烷基或-(C(R1)2)d-W；
W在每种情况下独立地为氢、C1-10烷基或X；
X是OR10、SR10或卤素；
Y在每种情况下独立地为氢、SR4、N(R4)2、OR4、C(O)OR4、卤素或亚烷基，其与R7或R9形成环；
Z在每种情况下独立地为氧或-NR4；
a在每种情况下独立地为1至10的整数；
b在每种情况下独立地为0或1，条件是a和b之和应为2至10；
c在每种情况下独立地为1至10的整数；
d在每种情况下独立地为1至4的整数；
x在每种情况下独立地为1至10的整数，条件是所有地方的x之和为2至10；且
y在每种情况下独立地为0或1。
12.根据权利要求1的方法，其中所述有机硼烷胺络合物具有下列结构
(R2)3-B←NH2(CH2)b-(C(R12)2)a-Si-((R11)q(Q)p)-
或
其中
B是硼；
R2在每种情况下独立地为C1-10烷基、C3-10环烷基，或两个或更多个R2可结合形成一个脂环族环；
Q是可水解部分；
R11在每种情况下独立地为氢、烷基、烷氧基、链烯基、烷基氨基，或符合式((CR14H)rO)n-(NR4)-(CH2)o-NH2，条件是至少(R11)’是伯胺；
R12在每种情况下独立地为氢、烷基、芳基、烷氧基，而且可以进一步含有一种或多种伯胺、仲胺或叔胺；
R14在每种情况下独立地为氢或烷基；
R4是氢、C1-10烷基、C6-10芳基或C7-10烷芳基；
a是1至10的数；
b是0至1的数；
m在每种情况下独立地为1或更大的整数；
p在每种情况下独立地为1至3的数；
q在每种情况下独立地为1至2的整数，其中每个硅原子上的p和q之和为3；
n在每种情况下独立地为4至400的整数；
o在每种情况下独立地为1至9的整数；
r在每种情况下独立地为2或4的整数。
13.根据权利要求1的方法，其中所述粘合剂进一步含有：有效量的含异氰酸酯的化合物；一种或多种含有开环杂环部分的未聚合的或部分聚合的化合物，并任选含有一种能够引发含杂环部分的化合物聚合的路易斯酸催化剂；一种或多种能够聚合的在骨架中含有硅氧烷基团和反应性部分的化合物、低聚物或预聚物；一种或多种在骨架中含有硅氧烷基团的化合物、低聚物或预聚物，其含有在接触湿气时形成能够将有机硼烷胺络合物解络合的酸的部分；或它们的混合物。
14.根据权利要求1的方法，其中所述粘合剂含有可聚合丙烯酸酯单体。
15.根据权利要求1的方法，其中所述粘合剂具有低于650克/升的VOC排放。
16.根据权利要求1的方法，其中所述粘合剂具有低于270克/升的VOC排放。
17.一种修补具有一个或多个需要修补的表面的新的或现有基材、物体或基材/物体接合处的方法，包括下列步骤：
(i)在需要修补的表面和/或补片上涂敷有效量的可固化粘合剂组合物，其中所述粘合剂包括
(a)有效量的有机硼烷胺络合物引发剂
和
(b)一种或多种含有能够通过自由基聚合法进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物
和
(ii)将补片粘合到需要修补的表面上。
18.根据权利要求1的方法，其中所述粘合剂进一步包括液体。
19.根据权利要求18的方法，其中所述液体包括水。
20.一种具有第一表面的基材，该基材与具有第二表面的物体粘合，其中粘合包括：
(i)在基材的第一表面和/或物体的第二表面上涂敷有效量的可固化一元或二元粘合剂组合物，其中所述粘合剂包括
(a)有效量的有机硼烷胺络合物引发剂
和
(b)一种或多种含有能够通过自由基聚合法进行聚合的不饱和烯键的单体、低聚物、聚合物或它们的混合物。
21.根据权利要求1的方法，其进一步包括对基材/粘合剂/物体施加有效量的压力以使该粘合剂固化的步骤。
22.根据权利要求1的方法，在步骤(ii)之前进一步包括使粘合剂在空气中暴露足够时间以产生粘合剂原始强度的步骤。
23.根据权利要求1的方法，其中所述可固化粘合剂化合物是一元化合物。
24.根据权利要求1的方法，其中所述可固化粘合剂化合物是二元化合物。
25.根据权利要求1的方法，在步骤(i)之前进一步包括确保第一和第二表面基本不含水的步骤。
26.根据权利要求1的方法，在步骤(i)之前进一步包括确保第一和第二表面基本不含油的步骤。
CN2004800230760A 2003-08-13 2004-08-13 使基材与物体接合的方法 Expired - Fee Related CN1835992B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US49472303P 2003-08-13 2003-08-13
US60/494,723 2003-08-13
US51587303P 2003-10-30 2003-10-30
US60/515,873 2003-10-30
PCT/US2004/026275 WO2005017005A1 (en) 2003-08-13 2004-08-13 Method for joining substrates and objects

Publications (2)

Publication Number Publication Date
CN1835992A true CN1835992A (zh) 2006-09-20
CN1835992B CN1835992B (zh) 2010-10-06

Family

ID=34193234

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2004800230760A Expired - Fee Related CN1835992B (zh) 2003-08-13 2004-08-13 使基材与物体接合的方法
CNA2004800230794A Pending CN1835993A (zh) 2003-08-13 2004-08-13 将管道系统和管道连接到装备、固定物、设备、结构和器具的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNA2004800230794A Pending CN1835993A (zh) 2003-08-13 2004-08-13 将管道系统和管道连接到装备、固定物、设备、结构和器具的方法

Country Status (9)

Country Link
US (2) US7510623B2 (zh)
EP (1) EP1656414B1 (zh)
JP (1) JP2007502352A (zh)
KR (1) KR20060064618A (zh)
CN (2) CN1835992B (zh)
BR (1) BRPI0412956B1 (zh)
CA (1) CA2534825A1 (zh)
MX (1) MXPA06001639A (zh)
WO (1) WO2005017006A1 (zh)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1878797B (zh) * 2003-11-11 2011-05-25 亨斯迈先进材料（瑞士）有限公司 用于可聚合组合物的引发剂体系
CN103160237A (zh) * 2011-12-16 2013-06-19 日立化成工业株式会社 粘接剂组合物、膜状粘接剂、粘接片材、以及连接结构体
WO2013156892A1 (en) * 2012-04-20 2013-10-24 Basf Se Process for graft polymerization on polymer surfaces using organoborane-amine complexes as radical initiators
CN103574191A (zh) * 2012-07-18 2014-02-12 台湾优派普环保科技有限公司 复合式管接头
CN103635501A (zh) * 2011-06-23 2014-03-12 3M创新有限公司 道路标记组合物体系
CN103827242A (zh) * 2011-09-29 2014-05-28 3M创新有限公司 催化氨基取代的有机硅烷酯底漆
CN106497440A (zh) * 2016-11-11 2017-03-15 台州吉谷胶业股份有限公司 一种环保型常温固化双组分聚烯烃胶粘剂
CN112771299A (zh) * 2018-09-28 2021-05-07 3M创新有限公司 具有粘合接头的管状元件和其接合管状元件的方法
CN115151420A (zh) * 2018-03-12 2022-10-04 唐纳德·W·迈耶斯 聚合物键合过程

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090090454A1 (en) * 2003-08-13 2009-04-09 Lutz William G Method for joining piping systems and piping to equipment, fixtures, devices, structures, and appliances
BRPI0412961A (pt) * 2003-08-13 2006-09-26 Dow Global Technologies Inc método para unir uma membrana para telhado e membrana para telhado
EP1714341A4 (en) * 2004-01-22 2007-08-01 Henkel Corp POLYMERIZABLE COMPOSITIONS FOR BONDING AND SEALING SUBSTRATES WITH LOW SURFACE ENERGY FOR FUEL CELLS
US7341285B2 (en) 2004-03-24 2008-03-11 Ips Corporation Weld-On Division Chemical fusion of non-metallic pipe joints
US8746747B2 (en) 2004-03-24 2014-06-10 IPS Corporation—Weld-On Division Pipe joints
CN101031614B (zh) 2004-10-28 2011-07-27 陶氏康宁公司 传导性可固化组合物
KR101249708B1 (ko) * 2005-01-04 2013-04-05 다우 코닝 코포레이션 오가노실리콘 관능성 붕소 아민 촉매 착물 및 이로부터 제조한 경화성 조성물
US7732543B2 (en) * 2005-01-04 2010-06-08 Dow Corning Corporation Siloxanes and silanes cured by organoborane amine complexes
JP2009509026A (ja) 2005-09-21 2009-03-05 ダウ・コーニング・コーポレイション 有機ボランアミン錯体を使用しての、常温リトグラフィー方法
US7816562B2 (en) * 2005-10-07 2010-10-19 Dow Global Technologies Inc. Amido-organoborate initiator systems
US8083268B2 (en) 2005-10-21 2011-12-27 Mueller Industries, Inc. Coupling, joint and method for fixedly and sealingly securing components to one another
DE112007000621T5 (de) * 2006-03-13 2009-02-12 Cooper-Standard Automotive Inc., Novi Schlauchverbindung mit Klebstoff
US8097689B2 (en) 2006-06-20 2012-01-17 Dow Corning Corporation Curable organosilicon composition
CN101473153B (zh) * 2006-06-20 2010-12-08 国际壳牌研究有限公司 接合一对管件端部的方法
US7524907B2 (en) * 2006-10-12 2009-04-28 Dow Global Technologies, Inc. Accelerated organoborane initiated polymerizable compositions
DE102007008644A1 (de) * 2007-02-20 2008-08-21 Walter Söhner GmbH & Co. Präzisionskunststoffteile Leitungsvorrichtung und Baukastensystem zum Aufbau einer Leitungsvorrichtung
US20140262189A1 (en) * 2008-01-25 2014-09-18 Henkel US IP LLC Curable compositions and fluid connections made therewith
US20090188269A1 (en) * 2008-01-25 2009-07-30 Henkel Corporation High pressure connection systems and methods for their manufacture
US20090189321A1 (en) * 2008-01-29 2009-07-30 Dow Global Technologies Inc. Thermoplastic composition and use for large parison blow molding applications
CN102084167B (zh) * 2008-02-13 2015-04-01 汉高美国知识产权有限责任公司 高压连接系统及其制备方法
WO2009108751A1 (en) * 2008-02-28 2009-09-03 Lubrizol Advanced Materials, Inc. Adhesively secured, fluid-tight pipe joint of pvc/cpvc pipe and fitting
US7896568B2 (en) * 2008-03-05 2011-03-01 Richard Warren Atkinson Articulite
DE102008023276A1 (de) * 2008-05-13 2009-11-19 Henkel Ag & Co. Kgaa Verbinden von Rohren mit thermisch härtbaren Klebstoffen
US8925978B2 (en) 2008-07-31 2015-01-06 Mueller Industries, Inc. Coupling and joint for fixedly and sealingly securing components to one another
US20110104508A1 (en) * 2008-08-29 2011-05-05 Dow Global Technologies Inc. Adhesive for bonding to flexible polymer surfaces
US20120186099A1 (en) * 2009-01-23 2012-07-26 Henkel Corporation Connection systems for refrigeration filter dryer units and methods for their manufacture
JP2010249155A (ja) * 2009-04-10 2010-11-04 Shin Etsu Polymer Co Ltd 暗渠パイプ用の変換継手、分岐継手および可撓性管ならびにこれらを用いた暗渠パイプ
DE102009026548A1 (de) * 2009-05-28 2011-03-24 Henkel Ag & Co. Kgaa Klebefolie oder Klebeband auf Basis von Epoxiden
US8967674B2 (en) * 2009-06-02 2015-03-03 Prinsco, Inc. Rib construction for large diameter pipe fittings
RU2535697C2 (ru) * 2009-06-26 2014-12-20 Басф Се Система красочного покрытия и способ получения многослойного красочного покрытия
BR112012017971A2 (pt) * 2010-01-29 2016-03-29 3M Innovative Properties Co dispositivo de aquecimento por indução, sistema de reparo de tubulação e método de reparo de um tubo danificado
US20110227721A1 (en) * 2010-03-22 2011-09-22 Khaled Mezghani Leak detection system for pipes
EP2397288A1 (en) * 2010-06-14 2011-12-21 Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO A method for joining at least two elements
CN103492257B (zh) * 2011-03-17 2017-03-15 泽菲罗斯公司 结合组件
US8328241B1 (en) 2011-07-27 2012-12-11 Duane D. Robertson Clampless fitting for plastic pipes
DE102011088123A1 (de) 2011-12-09 2013-06-13 Henkel Ag & Co. Kgaa Verfahren zum stoffschlüssigen Verbinden von Kunststoff-Rohren
JP5858805B2 (ja) * 2012-01-26 2016-02-10 三菱電機株式会社 異種金属管接合構造及び空調機器
EP2834314A1 (en) 2012-04-06 2015-02-11 Ips Corporation Adhesive composition for bonding low surface energy polyolefin substrates
JP6274112B2 (ja) * 2012-12-12 2018-02-07 株式会社ニコン 組成物、積層体、積層体の製造方法、トランジスタおよびトランジスタの製造方法
EP2945994B1 (en) 2013-01-18 2018-07-11 Basf Se Acrylic dispersion-based coating compositions
US9285063B2 (en) 2013-06-22 2016-03-15 Mark L. Jones Connection fitting for connecting thermoplastic pipes
WO2015094350A1 (en) * 2013-12-20 2015-06-25 The Penn State Research Foundation Polymer initiator system based on organic hydroxide and disubstituted borane
JP6181774B2 (ja) * 2013-12-27 2017-08-16 株式会社日立製作所 ラジカル重合開始剤、多分岐ポリマー、ワニス、接着剤、塗料、封止材、半導体及び電子機器
KR20150137003A (ko) * 2014-05-28 2015-12-08 보르그워너 인코퍼레이티드 음향적으로 활성적인 불완전부를 갖는 배기-가스 터보차저
US9757898B2 (en) 2014-08-18 2017-09-12 Lord Corporation Method for low temperature bonding of elastomers
CA2863272C (en) * 2014-09-12 2016-10-18 G.B.D. Corp. Method of joining pipes and fittings
CN104526946A (zh) * 2014-12-04 2015-04-22 安徽恒源煤电股份有限公司 一种pvc水沟槽的生产方法
CN105509184A (zh) * 2015-12-18 2016-04-20 珠海格力电器股份有限公司 空调冷媒管路及空调冷媒管路的制造方法
US10655767B2 (en) 2016-05-27 2020-05-19 John O. Roper Rotatable pipe adapter
WO2017205445A1 (en) * 2016-05-27 2017-11-30 Ips Corporation Polyurea-poly(meth)acrylate interpenetrating polymer network adhesive compositions and methods of using the same
US10221973B2 (en) 2016-05-27 2019-03-05 John O. Roper Rotatable pipe adapter
CN106308936B (zh) * 2016-08-31 2018-12-07 北京术锐技术有限公司 一种包含驱动骨的柔性手术工具系统
USD848378S1 (en) * 2016-09-16 2019-05-14 Cummings Electrical, L.P. Conduit section
CN106838500A (zh) * 2017-01-22 2017-06-13 合肥华凌股份有限公司 管路粘接工艺和制冷设备
CN111284021B (zh) * 2018-12-10 2022-01-25 中国科学院宁波材料技术与工程研究所 一种复合材料管件与金属件的胶接连接方法及其装置
WO2020163414A1 (en) * 2019-02-07 2020-08-13 Ips Corporation Gasketed pipe joint formed in place and method of making same
WO2021003244A1 (en) 2019-07-01 2021-01-07 Saint-Gobain Performance Plastics Corporation Profile connection
US20210199226A1 (en) * 2019-12-27 2021-07-01 Saint-Gobain Performance Plastics Corporation Profile connection
CN115916510A (zh) 2020-06-19 2023-04-04 美国圣戈班性能塑料公司 复合制品和形成复合制品的方法
EP4263736A1 (en) * 2020-12-18 2023-10-25 3M Innovative Properties Company Methods of bonding metal articles and articles formed thereby
US11879576B2 (en) * 2021-01-07 2024-01-23 Evan S. Greenberg Dryer vent accessories

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USB632416I5 (zh) 1956-03-01 1976-03-09
US3275611A (en) 1960-12-30 1966-09-27 Monsanto Co Process for polymerizing unsaturated monomers with a catalyst comprising an organoboron compound, a peroxygen compound and an amine
DE1924206U (de) * 1965-08-06 1965-09-23 Anger Kunststoff Kunststoffrohrverbindung.
CA849081A (en) 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
ZA775528B (en) * 1977-09-15 1979-04-25 Aeci Ltd Plastics pipes and their manufacture
GB2003243A (en) 1978-08-07 1979-03-07 Johns Manville Bell end of a bell and spigot joint and method of making the same
JPS606434A (ja) * 1983-06-24 1985-01-14 Fuji Kako Kk パイプユニツトの接合方法
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
CA2018011A1 (en) * 1989-06-30 1990-12-31 Dennis L. Levens Method of attaching a rubber sheeting to rigid insulation using a pressure-sensitive adhesive and corresponding articles
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5106928A (en) 1991-04-29 1992-04-21 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5525695A (en) 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5286821A (en) 1992-03-17 1994-02-15 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5310835A (en) 1993-09-30 1994-05-10 National Starch And Chemical Investment Holding Corporation Transparent two-part acrylic adhesive composition and the method of use thereof
DE69427411T2 (de) 1994-02-22 2002-06-06 Minnesota Mining & Mfg Polymerisierbare zusammensetzung die polymerisationsinitiatorsysteme auf basis von organoboran-amin-komplexen enthält
EP1029906B1 (en) * 1994-02-22 2004-12-08 Minnesota Mining And Manufacturing Company Bonded composite containing polymerisable acrylic composition made with polymerisation initiator systems based on organoborane amine complexes
US5691065A (en) 1995-02-22 1997-11-25 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5621143A (en) 1995-04-14 1997-04-15 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5616796A (en) 1995-04-14 1997-04-01 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive composition made therewith
US5686544A (en) 1995-08-11 1997-11-11 Minnesota Mining And Manufacturing Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
WO1997007171A1 (en) 1995-08-11 1997-02-27 Minnesota Mining And Manufacturing Company Initiator system and adhesive composition made therewith
US5912433A (en) * 1997-01-17 1999-06-15 Minnesota Mining And Manufacturing Company Cable closure injection sealed with low surface energy adhesive
JP2001514290A (ja) 1997-08-27 2001-09-11 ザ ダウ ケミカル カンパニー ポリオレフィンのインサイチュー流動変性
JPH11311392A (ja) * 1998-04-28 1999-11-09 Seibu Gas Co Ltd 管または線の補修・防護用シート
US6486090B1 (en) 1999-11-04 2002-11-26 3M Innovative Properties Company Initiator/hydroxide and initiator/alkoxide complexes, systems comprising the complexes, and polymerized compositions made therewith
US6806330B1 (en) * 1999-12-17 2004-10-19 Dow Global Technologies Inc. Amine organoborane complex polymerization initiators and polymerizable compositions
US6286821B1 (en) 2000-05-30 2001-09-11 Ford Global Technologies, Inc. Extruded stabilizer bar pivot bushing having plastic shear plates and method of making same
JP2001343094A (ja) * 2000-06-01 2001-12-14 Mitsubishi Plastics Ind Ltd 管の接続方法
EP1201722A1 (en) 2000-10-23 2002-05-02 Loctite (R & D) Limited Polymerisation initiators, polymerisable compositions, and uses thereof
WO2003041985A1 (en) 2001-05-02 2003-05-22 Dow Global Technologies Inc. Fuel tanks and fuel transport lines
EP1417260B1 (en) 2001-08-17 2005-08-03 Dow Global Technologies Inc. Bimodal polyethylene composition and articles made therefrom
US20030044553A1 (en) * 2001-08-23 2003-03-06 Ravi Ramanathan Fuel tanks
US6740716B2 (en) * 2001-10-30 2004-05-25 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
US6630555B2 (en) 2001-11-06 2003-10-07 Lord Corporation Internally blocked organoborate initiators and adhesives therefrom
JP2003207087A (ja) * 2002-01-09 2003-07-25 Sekisui Chem Co Ltd 複層管の接合構造および接合方法
US6762260B2 (en) 2002-03-05 2004-07-13 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
WO2003089536A2 (en) 2002-04-19 2003-10-30 Loctite (R & D) Limited Polymerisation initiators based on ammonium tetraalkyl boranes, polymerisable compositions, and uses thereof for bonding low surface energy substrates
US6777512B1 (en) 2003-02-28 2004-08-17 Dow Global Technologies Inc. Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1878797B (zh) * 2003-11-11 2011-05-25 亨斯迈先进材料（瑞士）有限公司 用于可聚合组合物的引发剂体系
CN103635501A (zh) * 2011-06-23 2014-03-12 3M创新有限公司 道路标记组合物体系
CN103827242A (zh) * 2011-09-29 2014-05-28 3M创新有限公司 催化氨基取代的有机硅烷酯底漆
CN103827242B (zh) * 2011-09-29 2015-12-02 3M创新有限公司 催化氨基取代的有机硅烷酯底漆
CN103160237A (zh) * 2011-12-16 2013-06-19 日立化成工业株式会社 粘接剂组合物、膜状粘接剂、粘接片材、以及连接结构体
CN103160237B (zh) * 2011-12-16 2016-09-28 日立化成株式会社 粘接剂组合物、膜状粘接剂、粘接片材、以及连接结构体
WO2013156892A1 (en) * 2012-04-20 2013-10-24 Basf Se Process for graft polymerization on polymer surfaces using organoborane-amine complexes as radical initiators
CN103574191A (zh) * 2012-07-18 2014-02-12 台湾优派普环保科技有限公司 复合式管接头
CN106497440A (zh) * 2016-11-11 2017-03-15 台州吉谷胶业股份有限公司 一种环保型常温固化双组分聚烯烃胶粘剂
CN115151420A (zh) * 2018-03-12 2022-10-04 唐纳德·W·迈耶斯 聚合物键合过程
CN112771299A (zh) * 2018-09-28 2021-05-07 3M创新有限公司 具有粘合接头的管状元件和其接合管状元件的方法

Also Published As

Publication number Publication date
CN1835993A (zh) 2006-09-20
BRPI0412956B1 (pt) 2014-12-02
US7510623B2 (en) 2009-03-31
WO2005017006A1 (en) 2005-02-24
CA2534825A1 (en) 2005-02-24
CN1835992B (zh) 2010-10-06
EP1656414A1 (en) 2006-05-17
JP2007502352A (ja) 2007-02-08
KR20060064618A (ko) 2006-06-13
US20060191623A1 (en) 2006-08-31
MXPA06001639A (es) 2006-05-12
BRPI0412956A (pt) 2006-09-26
US20090173441A1 (en) 2009-07-09
EP1656414B1 (en) 2013-04-10

Similar Documents

Publication Publication Date Title
CN1835992A (zh) 使基材与物体接合的方法
RU2361890C2 (ru) Способ соединения субстратов и объектов
US8247053B2 (en) Adhesive composition containing grafted polyethylene
EP3176191B1 (en) Curable petroleum resin and method for preparing same
US8241753B2 (en) Composite thermoplastic elastomer structures with high adhesion performance and uses for the same
CN1276043C (zh) 一种耐高温防腐的聚烯烃组合物及其用途
US20100183881A1 (en) Laminate
US8481638B2 (en) High temperature PP adhesive
TW200530032A (en) Use of a structure based on a grafted fluoropolymer for storing and transporting chemicals
US20090090454A1 (en) Method for joining piping systems and piping to equipment, fixtures, devices, structures, and appliances
CN1170854C (zh) 粘合用树脂、胶粘方法和层压制品
JP2004115780A (ja) 硬化性組成物
JP6527852B2 (ja) ナノ構造の熱可塑性ポリオレフィングラフトポリアミド組成物
WO1999054420A1 (en) Improved pressure-sensitive roofing tape
KR20200015452A (ko) 접착제 조성물, 접착 시트, 및 봉지체
Farajpour et al. Improvement in adhesion between ethylene–propylene–diene terpolymer (EPDM)-based elastomer and polyurethane coating using epoxy–polysulfide copolymer as adhesion promoter
CN116640540A (zh) 3lpp管道补口防腐用玛蹄脂胶、热缩带及其制备方法
CN114761509A (zh) 聚烯烃系粘合剂组合物以及层叠体
JP2004202979A (ja) 剥離基体ならびにその製造方法および剥離性積層体

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CI02 Correction of invention patent application

Correction item: Priority

Correct: 2003.10.30 US 60/515,873

False: Lack of priority second

Number: 38

Page: The title page

Volume: 22

COR Change of bibliographic data

Free format text: CORRECT: PRIORITY; FROM: MISSING THE SECOND ARTICLE OF PRIORITY TO: 2003.10.30 US 60/515,873

C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20101006

Termination date: 20120813