CN1800309A - 采用模拟移动床的含烃馏分的脱硫方法 - Google Patents
采用模拟移动床的含烃馏分的脱硫方法 Download PDFInfo
- Publication number
- CN1800309A CN1800309A CNA2005101315669A CN200510131566A CN1800309A CN 1800309 A CN1800309 A CN 1800309A CN A2005101315669 A CNA2005101315669 A CN A2005101315669A CN 200510131566 A CN200510131566 A CN 200510131566A CN 1800309 A CN1800309 A CN 1800309A
- Authority
- CN
- China
- Prior art keywords
- sulfur
- adsorption
- deep desulfurization
- tower
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 47
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 18
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 17
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 14
- 238000001179 sorption measurement Methods 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 28
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 21
- 230000023556 desulfurization Effects 0.000 claims abstract description 21
- 238000004821 distillation Methods 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 239000000284 extract Substances 0.000 claims abstract description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 48
- 239000003921 oil Substances 0.000 claims description 32
- 229910052717 sulfur Inorganic materials 0.000 claims description 22
- 239000011593 sulfur Substances 0.000 claims description 22
- 239000003463 adsorbent Substances 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 8
- 239000000446 fuel Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000003795 desorption Methods 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 2
- 238000007670 refining Methods 0.000 abstract 1
- 150000003464 sulfur compounds Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 30
- 239000005864 Sulphur Substances 0.000 description 27
- 238000004088 simulation Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- 239000002594 sorbent Substances 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000009835 boiling Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- -1 sulphur compound Chemical class 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- IYYZUPMFVPLQIF-ALWQSETLSA-N dibenzothiophene Chemical class C1=CC=CC=2[34S]C3=C(C=21)C=CC=C3 IYYZUPMFVPLQIF-ALWQSETLSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 150000000215 1-octanols Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- FCEHBMOGCRZNNI-UHFFFAOYSA-N thianaphthalene Natural products C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/06—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil
- C10G25/08—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil according to the "moving bed" method
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0412415 | 2004-11-23 | ||
| FR0412415A FR2878252B1 (fr) | 2004-11-23 | 2004-11-23 | Procede de desulfuration d'une coupe hydrocarbonee en lit mobile simule |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1800309A true CN1800309A (zh) | 2006-07-12 |
Family
ID=34952858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005101315669A Pending CN1800309A (zh) | 2004-11-23 | 2005-11-23 | 采用模拟移动床的含烃馏分的脱硫方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20060131217A1 (enExample) |
| EP (1) | EP1666568A1 (enExample) |
| JP (1) | JP2006144020A (enExample) |
| KR (1) | KR20060057510A (enExample) |
| CN (1) | CN1800309A (enExample) |
| FR (1) | FR2878252B1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349175A (zh) * | 2015-12-11 | 2016-02-24 | 中国海洋石油总公司 | 一种同时吸附脱除柴油中的硫化物和芳烃的方法 |
| CN105368482A (zh) * | 2015-12-11 | 2016-03-02 | 中国海洋石油总公司 | 一种多塔并联吸附脱除柴油中多环芳烃的方法 |
| CN105542835A (zh) * | 2015-12-11 | 2016-05-04 | 中国海洋石油总公司 | 一种模拟移动床吸附分离多环芳烃的方法 |
| CN105542849A (zh) * | 2015-12-11 | 2016-05-04 | 中国海洋石油总公司 | 一种由劣质柴油生产清洁柴油和轻质芳烃的方法 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102600808A (zh) * | 2006-01-30 | 2012-07-25 | 高级技术材料公司 | 纳米多孔碳材料,以及利用其的系统和方法 |
| US9315733B2 (en) * | 2006-10-20 | 2016-04-19 | Saudi Arabian Oil Company | Asphalt production from solvent deasphalting bottoms |
| FR2910457B1 (fr) * | 2006-12-22 | 2009-03-06 | Inst Francais Du Petrole | Procede de purification par adsorption d'hydrogene avec cogeneration d'un flux de co2 en pression |
| US20130270155A1 (en) * | 2010-11-19 | 2013-10-17 | Indian Oil Corporation Limited | Process for desulfurization of diesel with reduced hydrogen consumption |
| US8679231B2 (en) | 2011-01-19 | 2014-03-25 | Advanced Technology Materials, Inc. | PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same |
| CN106244225B (zh) * | 2016-08-12 | 2018-12-14 | 中国昆仑工程有限公司 | 实现重芳烃高效分离的模拟移动床吸附分离方法 |
| WO2020174610A1 (ja) * | 2019-02-27 | 2020-09-03 | 日揮グローバル株式会社 | 炭素系吸着材の再生方法及び炭素系吸着材の再生システム |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2985589A (en) * | 1957-05-22 | 1961-05-23 | Universal Oil Prod Co | Continuous sorption process employing fixed bed of sorbent and moving inlets and outlets |
| US4337156A (en) * | 1980-09-23 | 1982-06-29 | Uop Inc. | Adsorptive separation of contaminants from naphtha |
| US5454933A (en) * | 1991-12-16 | 1995-10-03 | Exxon Research And Engineering Company | Deep desulfurization of distillate fuels |
| US5710092A (en) * | 1993-10-25 | 1998-01-20 | Westvaco Corporation | Highly microporous carbon |
| US6482316B1 (en) * | 1999-06-11 | 2002-11-19 | Exxonmobil Research And Engineering Company | Adsorption process for producing ultra low hydrocarbon streams |
| FR2837212B1 (fr) | 2002-03-18 | 2004-10-01 | Total Raffinage Distribution | Procede de deazotation de charges hydrocarbonees en presence d'une masse polymerique |
| AU2003242363A1 (en) * | 2002-05-22 | 2003-12-02 | Japan Energy Corporation | Adsorption desulfurization agent for desulfurizing petroleum fraction and desulfurization method using the same |
| FR2852019B1 (fr) * | 2003-03-07 | 2007-04-27 | Inst Francais Du Petrole | Procede de desulfuration, de deazotation et/ou de desaromatisation d'une charge hydrocarbonee par adsorption par un solide adsorbant use |
-
2004
- 2004-11-23 FR FR0412415A patent/FR2878252B1/fr not_active Expired - Fee Related
-
2005
- 2005-11-08 EP EP05292374A patent/EP1666568A1/fr not_active Withdrawn
- 2005-11-21 KR KR1020050111294A patent/KR20060057510A/ko not_active Withdrawn
- 2005-11-22 US US11/284,406 patent/US20060131217A1/en not_active Abandoned
- 2005-11-23 CN CNA2005101315669A patent/CN1800309A/zh active Pending
- 2005-11-24 JP JP2005338111A patent/JP2006144020A/ja active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349175A (zh) * | 2015-12-11 | 2016-02-24 | 中国海洋石油总公司 | 一种同时吸附脱除柴油中的硫化物和芳烃的方法 |
| CN105368482A (zh) * | 2015-12-11 | 2016-03-02 | 中国海洋石油总公司 | 一种多塔并联吸附脱除柴油中多环芳烃的方法 |
| CN105542835A (zh) * | 2015-12-11 | 2016-05-04 | 中国海洋石油总公司 | 一种模拟移动床吸附分离多环芳烃的方法 |
| CN105542849A (zh) * | 2015-12-11 | 2016-05-04 | 中国海洋石油总公司 | 一种由劣质柴油生产清洁柴油和轻质芳烃的方法 |
| CN105368482B (zh) * | 2015-12-11 | 2017-07-28 | 中海油天津化工研究设计院有限公司 | 一种多塔并联吸附脱除柴油中多环芳烃的方法 |
| WO2017097271A3 (zh) * | 2015-12-11 | 2017-08-03 | 中国海洋石油总公司 | 一种模拟移动床吸附分离多环芳烃的方法 |
| CN105542835B (zh) * | 2015-12-11 | 2017-08-25 | 中国海洋石油总公司 | 一种模拟移动床吸附分离多环芳烃的方法 |
| US10619108B2 (en) | 2015-12-11 | 2020-04-14 | Cnooc Tianjin Chemical Research & Design Institute Co. Ltd. | Method for simulated moving bed to adsorb and separate polycyclic aromatic hydrocarbons |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2878252B1 (fr) | 2008-08-22 |
| KR20060057510A (ko) | 2006-05-26 |
| US20060131217A1 (en) | 2006-06-22 |
| JP2006144020A (ja) | 2006-06-08 |
| FR2878252A1 (fr) | 2006-05-26 |
| EP1666568A1 (fr) | 2006-06-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20060712 |