JP2006144020A - 模擬移動床での炭化水素留分の脱硫方法 - Google Patents
模擬移動床での炭化水素留分の脱硫方法 Download PDFInfo
- Publication number
- JP2006144020A JP2006144020A JP2005338111A JP2005338111A JP2006144020A JP 2006144020 A JP2006144020 A JP 2006144020A JP 2005338111 A JP2005338111 A JP 2005338111A JP 2005338111 A JP2005338111 A JP 2005338111A JP 2006144020 A JP2006144020 A JP 2006144020A
- Authority
- JP
- Japan
- Prior art keywords
- sulfur
- desorbent
- moving bed
- simulated moving
- point
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 59
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 28
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 27
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 17
- 238000006477 desulfuration reaction Methods 0.000 title claims description 34
- 230000023556 desulfurization Effects 0.000 title claims description 34
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 73
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 72
- 239000011593 sulfur Substances 0.000 claims abstract description 72
- 238000001179 sorption measurement Methods 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- 238000004821 distillation Methods 0.000 claims abstract description 28
- 239000003463 adsorbent Substances 0.000 claims abstract description 21
- 238000000605 extraction Methods 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011148 porous material Substances 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims description 48
- 239000007788 liquid Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000446 fuel Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 239000000295 fuel oil Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 abstract description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 4
- 230000003009 desulfurizing effect Effects 0.000 abstract description 4
- 239000001257 hydrogen Substances 0.000 abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000002283 diesel fuel Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- IYYZUPMFVPLQIF-ALWQSETLSA-N dibenzothiophene Chemical class C1=CC=CC=2[34S]C3=C(C=21)C=CC=C3 IYYZUPMFVPLQIF-ALWQSETLSA-N 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000895 extractive distillation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/06—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil
- C10G25/08—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil according to the "moving bed" method
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0412415A FR2878252B1 (fr) | 2004-11-23 | 2004-11-23 | Procede de desulfuration d'une coupe hydrocarbonee en lit mobile simule |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006144020A true JP2006144020A (ja) | 2006-06-08 |
| JP2006144020A5 JP2006144020A5 (enExample) | 2009-01-15 |
Family
ID=34952858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005338111A Pending JP2006144020A (ja) | 2004-11-23 | 2005-11-24 | 模擬移動床での炭化水素留分の脱硫方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20060131217A1 (enExample) |
| EP (1) | EP1666568A1 (enExample) |
| JP (1) | JP2006144020A (enExample) |
| KR (1) | KR20060057510A (enExample) |
| CN (1) | CN1800309A (enExample) |
| FR (1) | FR2878252B1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010513201A (ja) * | 2006-12-22 | 2010-04-30 | イエフペ | 圧力下のco2流の同時発生を伴う水素吸着による精製法 |
| WO2020174610A1 (ja) * | 2019-02-27 | 2020-09-03 | 日揮グローバル株式会社 | 炭素系吸着材の再生方法及び炭素系吸着材の再生システム |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102600808A (zh) * | 2006-01-30 | 2012-07-25 | 高级技术材料公司 | 纳米多孔碳材料,以及利用其的系统和方法 |
| US9315733B2 (en) * | 2006-10-20 | 2016-04-19 | Saudi Arabian Oil Company | Asphalt production from solvent deasphalting bottoms |
| US20130270155A1 (en) * | 2010-11-19 | 2013-10-17 | Indian Oil Corporation Limited | Process for desulfurization of diesel with reduced hydrogen consumption |
| US8679231B2 (en) | 2011-01-19 | 2014-03-25 | Advanced Technology Materials, Inc. | PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same |
| CN105542849B (zh) * | 2015-12-11 | 2017-06-23 | 中国海洋石油总公司 | 一种由劣质柴油生产清洁柴油和轻质芳烃的方法 |
| CN105542835B (zh) | 2015-12-11 | 2017-08-25 | 中国海洋石油总公司 | 一种模拟移动床吸附分离多环芳烃的方法 |
| CN105368482B (zh) * | 2015-12-11 | 2017-07-28 | 中海油天津化工研究设计院有限公司 | 一种多塔并联吸附脱除柴油中多环芳烃的方法 |
| CN105349175B (zh) * | 2015-12-11 | 2018-03-13 | 中海油天津化工研究设计院有限公司 | 一种同时吸附脱除柴油中的硫化物和芳烃的方法 |
| CN106244225B (zh) * | 2016-08-12 | 2018-12-14 | 中国昆仑工程有限公司 | 实现重芳烃高效分离的模拟移动床吸附分离方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003097771A1 (en) * | 2002-05-22 | 2003-11-27 | Japan Energy Corporation | Adsorption desulfurization agent for desulfurizing petroleum fraction and desulfurization method using the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2985589A (en) * | 1957-05-22 | 1961-05-23 | Universal Oil Prod Co | Continuous sorption process employing fixed bed of sorbent and moving inlets and outlets |
| US4337156A (en) * | 1980-09-23 | 1982-06-29 | Uop Inc. | Adsorptive separation of contaminants from naphtha |
| US5454933A (en) * | 1991-12-16 | 1995-10-03 | Exxon Research And Engineering Company | Deep desulfurization of distillate fuels |
| US5710092A (en) * | 1993-10-25 | 1998-01-20 | Westvaco Corporation | Highly microporous carbon |
| US6482316B1 (en) * | 1999-06-11 | 2002-11-19 | Exxonmobil Research And Engineering Company | Adsorption process for producing ultra low hydrocarbon streams |
| FR2837212B1 (fr) | 2002-03-18 | 2004-10-01 | Total Raffinage Distribution | Procede de deazotation de charges hydrocarbonees en presence d'une masse polymerique |
| FR2852019B1 (fr) * | 2003-03-07 | 2007-04-27 | Inst Francais Du Petrole | Procede de desulfuration, de deazotation et/ou de desaromatisation d'une charge hydrocarbonee par adsorption par un solide adsorbant use |
-
2004
- 2004-11-23 FR FR0412415A patent/FR2878252B1/fr not_active Expired - Fee Related
-
2005
- 2005-11-08 EP EP05292374A patent/EP1666568A1/fr not_active Withdrawn
- 2005-11-21 KR KR1020050111294A patent/KR20060057510A/ko not_active Withdrawn
- 2005-11-22 US US11/284,406 patent/US20060131217A1/en not_active Abandoned
- 2005-11-23 CN CNA2005101315669A patent/CN1800309A/zh active Pending
- 2005-11-24 JP JP2005338111A patent/JP2006144020A/ja active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003097771A1 (en) * | 2002-05-22 | 2003-11-27 | Japan Energy Corporation | Adsorption desulfurization agent for desulfurizing petroleum fraction and desulfurization method using the same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010513201A (ja) * | 2006-12-22 | 2010-04-30 | イエフペ | 圧力下のco2流の同時発生を伴う水素吸着による精製法 |
| WO2020174610A1 (ja) * | 2019-02-27 | 2020-09-03 | 日揮グローバル株式会社 | 炭素系吸着材の再生方法及び炭素系吸着材の再生システム |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2878252B1 (fr) | 2008-08-22 |
| KR20060057510A (ko) | 2006-05-26 |
| US20060131217A1 (en) | 2006-06-22 |
| FR2878252A1 (fr) | 2006-05-26 |
| CN1800309A (zh) | 2006-07-12 |
| EP1666568A1 (fr) | 2006-06-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20081121 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20081121 |
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| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110907 |
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| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111004 |
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| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20120228 |