CN1764676A - 茂金属催化剂及用其制备聚烯烃的方法 - Google Patents

茂金属催化剂及用其制备聚烯烃的方法 Download PDF

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Publication number
CN1764676A
CN1764676A CNA200480007915XA CN200480007915A CN1764676A CN 1764676 A CN1764676 A CN 1764676A CN A200480007915X A CNA200480007915X A CN A200480007915XA CN 200480007915 A CN200480007915 A CN 200480007915A CN 1764676 A CN1764676 A CN 1764676A
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bis
alkyl
dibenzyl
metallocene
polymerization
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CNA200480007915XA
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Chinese (zh)
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詹尼·马拉南
朱尼·霍伊卡
索伊尔·劳蒂奥
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Borealis Technology Oy
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Borealis Technology Oy
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNA200480007915XA 2003-03-25 2004-03-24 茂金属催化剂及用其制备聚烯烃的方法 Pending CN1764676A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03251855A EP1462464A1 (en) 2003-03-25 2003-03-25 Metallocene catalysts and preparation of polyolefins therewith
EP03251855.7 2003-03-25

Publications (1)

Publication Number Publication Date
CN1764676A true CN1764676A (zh) 2006-04-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNA200480007915XA Pending CN1764676A (zh) 2003-03-25 2004-03-24 茂金属催化剂及用其制备聚烯烃的方法

Country Status (7)

Country Link
US (1) US20070037939A1 (enExample)
EP (2) EP1462464A1 (enExample)
JP (1) JP2006521436A (enExample)
KR (1) KR20050109582A (enExample)
CN (1) CN1764676A (enExample)
BR (1) BRPI0408714A (enExample)
WO (1) WO2004085499A2 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008006314A1 (fr) * 2006-07-05 2008-01-17 Huawei Technologies Co., Ltd. Système de passerelle et procédé de mise en oeuvre de nombreux accès multimédias
CN101970565B (zh) * 2008-06-02 2012-08-29 博里利斯股份公司 具有改进的均匀度和气味的聚合物组合物及其制造方法和由其制成的管
CN103890070A (zh) * 2011-09-09 2014-06-25 切弗朗菲利浦化学公司 聚乙烯添加剂组合物和由其制造的制品
CN114364735A (zh) * 2019-07-17 2022-04-15 博里利斯股份公司 制备聚合物组合物的方法

Families Citing this family (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0423212D0 (en) * 2004-10-19 2004-11-24 Borealis Tech Oy Polymer
PL2072586T3 (pl) 2007-12-20 2021-05-31 Borealis Technology Oy Powlekane rury o ulepszonych właściwościach mechanicznych i sposób ich wytwarzania
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EP2072589A1 (en) 2007-12-20 2009-06-24 Borealis Technology Oy Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof
EP2072588B1 (en) 2007-12-20 2012-10-10 Borealis Technology Oy Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof
EP2119732A1 (en) 2008-05-16 2009-11-18 Borealis Technology Oy Metallocene catalyst compositions with improved properties, process for its preparation and use for preparing polyolefin homo- or copolymers
EP2130862A1 (en) 2008-06-02 2009-12-09 Borealis AG Polymer compositions and pressure-resistant pipes made thereof
EP2130863A1 (en) 2008-06-02 2009-12-09 Borealis AG High density polymer compositions, a method for their preparation and pressure-resistant pipes made therefrom
EP2182526A1 (en) 2008-10-31 2010-05-05 Borealis AG Cable and polymer composition comprising an multimodal ethylene copolymer
EP2182524A1 (en) 2008-10-31 2010-05-05 Borealis AG Cable and Polymer composition comprising a multimodal ethylene copolymer
EP2182525A1 (en) 2008-10-31 2010-05-05 Borealis AG Cable and polymer composition comprising a multimodal ethylene copolymer
EP2471077B2 (en) 2009-08-26 2023-07-19 Borealis AG Cable and polymer composition
US8501881B2 (en) 2009-11-13 2013-08-06 Borealis Ag Process for olefin polymerization
EP2322568B1 (en) 2009-11-13 2013-05-15 Borealis AG Process for producing an olefin polymerization catalyst
WO2011058089A1 (en) 2009-11-13 2011-05-19 Borealis Ag Process for producing a polymerization catalyst
EP2499169B1 (en) 2009-11-13 2014-04-02 Borealis AG Process for recovering a transition metal compound
EP2330135B1 (en) 2009-12-02 2012-11-07 Borealis AG Process for producing polyolefins
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
EP2528970B1 (en) 2010-01-29 2015-07-29 Borealis AG Improving homogeneity in polyethylene blends
EP2354184B1 (en) 2010-01-29 2012-08-22 Borealis AG Polyethylene moulding composition with improved stress crack/stiffness relationship and impact resistance
EP2354183B1 (en) 2010-01-29 2012-08-22 Borealis AG Moulding composition
HUE052511T2 (hu) 2011-03-02 2021-05-28 Borealis Ag Eljárás polimerek elõállítására
EP2495037B1 (en) 2011-03-02 2020-08-19 Borealis AG High throughput reactor assembly for polymerization of olefins
JP5966555B2 (ja) * 2011-04-18 2016-08-10 株式会社Ihi 吸収塔及びそれを用いた生物脱臭装置
EP2520625A1 (en) 2011-05-06 2012-11-07 Borealis AG Coating composition
WO2014032794A1 (en) 2012-08-29 2014-03-06 Borealis Ag Reactor assembly and method for polymerization of olefins
RU2529020C2 (ru) 2012-10-17 2014-09-27 ЭлДжи КЕМ, ЛТД. Новое металлоценовое соединение, содержащая его каталитическая композиция и способ получения полимеров на основе олефинов с ее применением
EP2740748B1 (en) 2012-12-07 2015-06-10 Borealis AG Method of polymerizing olefins in slurry reactors
CN104837848B (zh) 2012-12-11 2017-09-22 株式会社Lg化学 新的配体化合物及其制备方法,包括该配体化合物的过渡金属化合物及其制备方法
KR20140075589A (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법
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WO2015190831A1 (ko) * 2014-06-10 2015-12-17 주식회사 엘지화학 프로필렌계 엘라스토머
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EP3257879A1 (en) 2016-06-17 2017-12-20 Borealis AG Bi- or multimodal polyethylene with low unsaturation level
KR20190021324A (ko) 2016-06-17 2019-03-05 보레알리스 아게 향상된 유동학적 특성을 갖는 바이모달 또는 멀티모달 폴리에틸렌 삼원공중합체
ES2799148T3 (es) 2016-06-17 2020-12-15 Borealis Ag Polietileno bi- o multimodal con bajo nivel de insaturación
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US10982019B2 (en) 2016-06-23 2021-04-20 Borealis Ag Process for catalyst deactivation
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EP3486261B1 (en) 2017-11-17 2020-06-24 Borealis AG Method for improving the cooling capacity of a gas solids olefin polymerization reactor
ES2795985T3 (es) 2017-11-17 2020-11-25 Borealis Ag Procedimiento de división del gas de fluidización de retorno en un reactor de polimerización de olefinas de gas sólidos
WO2019166652A1 (en) 2018-03-02 2019-09-06 Borealis Ag Process
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EP4116091A1 (en) 2021-07-07 2023-01-11 Borealis AG Multilayer film
CA3226016A1 (en) 2021-07-08 2023-01-12 Borealis Ag Polyethylene for use in the production of crosslinked polyethylene (pex)
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EP4257640B1 (en) 2022-04-04 2024-08-28 Borealis AG Pipe comprising a polypropylene composition
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EP4389414A1 (en) 2022-12-19 2024-06-26 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer collation shrink film
EP4389418A1 (en) 2022-12-19 2024-06-26 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer collation shrink film
WO2024223777A1 (en) 2023-04-26 2024-10-31 Borealis Ag Layer element suitable as integrated backsheet for a bifacial photovoltaic module
WO2024223775A1 (en) 2023-04-26 2024-10-31 Borealis Ag Layer element suitable as integrated backsheet for a bifacial photovoltaic module
EP4455170A1 (en) 2023-04-28 2024-10-30 Borealis AG Cable compositions comprising a multimodal ethylene-butene-hexene terpolymer
EP4541583A1 (en) 2023-10-18 2025-04-23 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer film
WO2025125458A1 (en) 2023-12-12 2025-06-19 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Modified polyethylene having improved hydrostatic pressure resistance and slow crack growth resistance
EP4574848A1 (en) 2023-12-19 2025-06-25 Borealis AG Polypropylene copolymer composition having high molecular weight
WO2025219499A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Processes for polymerising olefins

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
EP0474391B1 (en) * 1990-08-21 1995-10-25 Nippon Oil Co. Ltd. Polyolefins
US5171919A (en) * 1990-10-17 1992-12-15 Idemitsu Kosan Co., Ltd. Process for producing propylene based oligomers
FI96216C (fi) * 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
US5767208A (en) * 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
EP0889911B1 (en) * 1996-03-29 2000-11-02 The Dow Chemical Company Metallocene cocatalyst
FI990003L (fi) * 1999-01-04 2000-07-05 Borealis Polymers Oy Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot
US20020107344A1 (en) * 2000-12-07 2002-08-08 Peterson Thomas Henry Supprt materials for use with polymerization catalysts

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008006314A1 (fr) * 2006-07-05 2008-01-17 Huawei Technologies Co., Ltd. Système de passerelle et procédé de mise en oeuvre de nombreux accès multimédias
CN101970565B (zh) * 2008-06-02 2012-08-29 博里利斯股份公司 具有改进的均匀度和气味的聚合物组合物及其制造方法和由其制成的管
CN103890070A (zh) * 2011-09-09 2014-06-25 切弗朗菲利浦化学公司 聚乙烯添加剂组合物和由其制造的制品
CN114364735A (zh) * 2019-07-17 2022-04-15 博里利斯股份公司 制备聚合物组合物的方法
CN114364735B (zh) * 2019-07-17 2024-04-26 博里利斯股份公司 制备聚合物组合物的方法

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