JP2006521436A - 方法 - Google Patents
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- Publication number
- JP2006521436A JP2006521436A JP2006504840A JP2006504840A JP2006521436A JP 2006521436 A JP2006521436 A JP 2006521436A JP 2006504840 A JP2006504840 A JP 2006504840A JP 2006504840 A JP2006504840 A JP 2006504840A JP 2006521436 A JP2006521436 A JP 2006521436A
- Authority
- JP
- Japan
- Prior art keywords
- bis
- polymerization
- dibenzyl
- alkyl
- metallocene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 238000000034 method Methods 0.000 title claims description 59
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 239000003446 ligand Substances 0.000 claims abstract description 20
- 239000002002 slurry Substances 0.000 claims abstract description 18
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims abstract description 15
- 125000001424 substituent group Chemical group 0.000 claims abstract description 15
- 150000001336 alkenes Chemical class 0.000 claims abstract description 13
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 9
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000004429 atom Chemical group 0.000 claims abstract description 7
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 7
- 150000002367 halogens Chemical class 0.000 claims abstract description 7
- 229920001519 homopolymer Polymers 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 4
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims abstract description 3
- 125000003936 heterocyclopentadienyl group Chemical group 0.000 claims abstract description 3
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 3
- 150000003624 transition metals Chemical class 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 52
- -1 tetrahydroindenyl Chemical group 0.000 claims description 38
- 229920000642 polymer Polymers 0.000 claims description 23
- 239000007789 gas Substances 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 21
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 claims description 15
- 239000005977 Ethylene Substances 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 238000012685 gas phase polymerization Methods 0.000 claims description 6
- 125000006649 (C2-C20) alkynyl group Chemical group 0.000 claims description 5
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 5
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 claims description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 3
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 3
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 3
- 229920001038 ethylene copolymer Polymers 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 42
- 239000003054 catalyst Substances 0.000 description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 26
- 239000000243 solution Substances 0.000 description 21
- 239000000377 silicon dioxide Substances 0.000 description 13
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical group C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000012968 metallocene catalyst Substances 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 229910052735 hafnium Inorganic materials 0.000 description 6
- 239000004711 α-olefin Substances 0.000 description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- MZRVEZGGRBJDDB-UHFFFAOYSA-N n-Butyllithium Substances [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 4
- KBGJIKKXNIQHQH-UHFFFAOYSA-N potassium;methanidylbenzene Chemical compound [K+].[CH2-]C1=CC=CC=C1 KBGJIKKXNIQHQH-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000002902 bimodal effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- VJLWKQJUUKZXRZ-UHFFFAOYSA-N 2,4,5,5,6,6-hexakis(2-methylpropyl)oxaluminane Chemical compound CC(C)CC1C[Al](CC(C)C)OC(CC(C)C)(CC(C)C)C1(CC(C)C)CC(C)C VJLWKQJUUKZXRZ-UHFFFAOYSA-N 0.000 description 2
- WBZVXZGPXBXMSC-UHFFFAOYSA-N 2,5,6,6-tetrakis(2-methylpropyl)oxaluminane Chemical compound CC(C)CC1CC[Al](CC(C)C)OC1(CC(C)C)CC(C)C WBZVXZGPXBXMSC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- DLEDOFVPSDKWEF-UHFFFAOYSA-N lithium butane Chemical compound [Li+].CCC[CH2-] DLEDOFVPSDKWEF-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VJHGSLHHMIELQD-UHFFFAOYSA-N nona-1,8-diene Chemical compound C=CCCCCCC=C VJHGSLHHMIELQD-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- WJRQLRSESLJZBF-UHFFFAOYSA-N 1h-cyclopenta[c]pyridazine Chemical compound C1=NNC2=CC=CC2=C1 WJRQLRSESLJZBF-UHFFFAOYSA-N 0.000 description 1
- NMXLXQGHBSPIDR-UHFFFAOYSA-N 2-(2-methylpropyl)oxaluminane Chemical compound CC(C)C[Al]1CCCCO1 NMXLXQGHBSPIDR-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- ZIQCCIAIROIHHR-UHFFFAOYSA-N benzene;boric acid Chemical compound OB(O)O.C1=CC=CC=C1 ZIQCCIAIROIHHR-UHFFFAOYSA-N 0.000 description 1
- 238000005574 benzylation reaction Methods 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 150000002362 hafnium Chemical class 0.000 description 1
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- KVWLUDFGXDFFON-UHFFFAOYSA-N lithium;methanidyl(trimethyl)silane Chemical compound [Li+].C[Si](C)(C)[CH2-] KVWLUDFGXDFFON-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03251855A EP1462464A1 (en) | 2003-03-25 | 2003-03-25 | Metallocene catalysts and preparation of polyolefins therewith |
| PCT/EP2004/003112 WO2004085499A2 (en) | 2003-03-25 | 2004-03-24 | Metallocene catalysts and preparation of polyolefins therewith |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006521436A true JP2006521436A (ja) | 2006-09-21 |
| JP2006521436A5 JP2006521436A5 (enExample) | 2007-05-17 |
Family
ID=32799070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006504840A Withdrawn JP2006521436A (ja) | 2003-03-25 | 2004-03-24 | 方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20070037939A1 (enExample) |
| EP (2) | EP1462464A1 (enExample) |
| JP (1) | JP2006521436A (enExample) |
| KR (1) | KR20050109582A (enExample) |
| CN (1) | CN1764676A (enExample) |
| BR (1) | BRPI0408714A (enExample) |
| WO (1) | WO2004085499A2 (enExample) |
Families Citing this family (109)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0423212D0 (en) * | 2004-10-19 | 2004-11-24 | Borealis Tech Oy | Polymer |
| CN101102189B (zh) * | 2006-07-05 | 2011-06-22 | 华为技术有限公司 | 一种实现多种媒体接入的网关系统和方法 |
| PL2072586T3 (pl) | 2007-12-20 | 2021-05-31 | Borealis Technology Oy | Powlekane rury o ulepszonych właściwościach mechanicznych i sposób ich wytwarzania |
| PL2072587T3 (pl) | 2007-12-20 | 2020-11-02 | Borealis Technology Oy | Powlekane rury o ulepszonych właściwościach mechanicznych w wysokich temperaturach i sposób ich wytwarzania |
| EP2072589A1 (en) | 2007-12-20 | 2009-06-24 | Borealis Technology Oy | Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof |
| EP2072588B1 (en) | 2007-12-20 | 2012-10-10 | Borealis Technology Oy | Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof |
| EP2119732A1 (en) | 2008-05-16 | 2009-11-18 | Borealis Technology Oy | Metallocene catalyst compositions with improved properties, process for its preparation and use for preparing polyolefin homo- or copolymers |
| EP2130862A1 (en) | 2008-06-02 | 2009-12-09 | Borealis AG | Polymer compositions and pressure-resistant pipes made thereof |
| EP2130859A1 (en) * | 2008-06-02 | 2009-12-09 | Borealis AG | Polymer compositions having improved homogeneity and odour, a method for making them and pipes made thereof |
| EP2130863A1 (en) | 2008-06-02 | 2009-12-09 | Borealis AG | High density polymer compositions, a method for their preparation and pressure-resistant pipes made therefrom |
| EP2182526A1 (en) | 2008-10-31 | 2010-05-05 | Borealis AG | Cable and polymer composition comprising an multimodal ethylene copolymer |
| EP2182524A1 (en) | 2008-10-31 | 2010-05-05 | Borealis AG | Cable and Polymer composition comprising a multimodal ethylene copolymer |
| EP2182525A1 (en) | 2008-10-31 | 2010-05-05 | Borealis AG | Cable and polymer composition comprising a multimodal ethylene copolymer |
| EP2471077B2 (en) | 2009-08-26 | 2023-07-19 | Borealis AG | Cable and polymer composition |
| US8501881B2 (en) | 2009-11-13 | 2013-08-06 | Borealis Ag | Process for olefin polymerization |
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| WO2011058089A1 (en) | 2009-11-13 | 2011-05-19 | Borealis Ag | Process for producing a polymerization catalyst |
| EP2499169B1 (en) | 2009-11-13 | 2014-04-02 | Borealis AG | Process for recovering a transition metal compound |
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| EP2330136B1 (en) | 2009-12-07 | 2013-08-28 | Borealis AG | Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins |
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| EP2354183B1 (en) | 2010-01-29 | 2012-08-22 | Borealis AG | Moulding composition |
| HUE052511T2 (hu) | 2011-03-02 | 2021-05-28 | Borealis Ag | Eljárás polimerek elõállítására |
| EP2495037B1 (en) | 2011-03-02 | 2020-08-19 | Borealis AG | High throughput reactor assembly for polymerization of olefins |
| JP5966555B2 (ja) * | 2011-04-18 | 2016-08-10 | 株式会社Ihi | 吸収塔及びそれを用いた生物脱臭装置 |
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| EP2753659B1 (en) * | 2011-09-09 | 2021-10-27 | Chevron Phillips Chemical Company LP | Polyethylene additive compositions and articles made from same |
| WO2014032794A1 (en) | 2012-08-29 | 2014-03-06 | Borealis Ag | Reactor assembly and method for polymerization of olefins |
| RU2529020C2 (ru) | 2012-10-17 | 2014-09-27 | ЭлДжи КЕМ, ЛТД. | Новое металлоценовое соединение, содержащая его каталитическая композиция и способ получения полимеров на основе олефинов с ее применением |
| EP2740748B1 (en) | 2012-12-07 | 2015-06-10 | Borealis AG | Method of polymerizing olefins in slurry reactors |
| CN104837848B (zh) | 2012-12-11 | 2017-09-22 | 株式会社Lg化学 | 新的配体化合物及其制备方法，包括该配体化合物的过渡金属化合物及其制备方法 |
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| EP2745927A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Fluidized bed reactor with internal moving bed reaction unit |
| EP2745926A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor |
| EP2913346B1 (en) | 2014-02-28 | 2016-11-02 | Borealis AG | Process for polymerizing olefins in a fluidized bed |
| EP2913345B1 (en) | 2014-02-28 | 2016-11-02 | Borealis AG | Gas phase polymerization process |
| WO2015190831A1 (ko) * | 2014-06-10 | 2015-12-17 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| KR101580591B1 (ko) | 2014-06-10 | 2015-12-28 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| ES2635519T3 (es) | 2014-11-21 | 2017-10-04 | Borealis Ag | Procedimiento para producir gránulos de copolímeros blandos |
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| CN107000406B (zh) | 2014-11-26 | 2021-10-08 | 博里利斯股份公司 | 薄膜层 |
| CN107112071A (zh) | 2014-12-19 | 2017-08-29 | 博里利斯股份公司 | 包含热塑性塑料并且具有有利性质的电力缆线聚合物组合物 |
| FI3234954T3 (fi) | 2014-12-19 | 2025-10-17 | Borealis Gmbh | Edulliset sähköominaisuudet omaava polymeerikoostumus johto- & kaapelisovelluksiin (W&C) |
| EP3298067B1 (en) | 2015-05-20 | 2019-07-17 | Borealis AG | Process for producing polyethylene composition |
| PT3103818T (pt) | 2015-06-12 | 2018-10-19 | Borealis Ag | Processo e aparelho para polimerização de olefinas em fase gasosa |
| EP3173442A1 (en) | 2015-11-27 | 2017-05-31 | Borealis AG | Semiconductive polyethylene composition |
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| EP3178853B1 (en) | 2015-12-07 | 2018-07-25 | Borealis AG | Process for polymerising alpha-olefin monomers |
| EP3184167B8 (en) | 2015-12-22 | 2022-03-30 | Borealis AG | A method for returning polymer to a fluidised bed reactor |
| EP3184166A1 (en) | 2015-12-22 | 2017-06-28 | Borealis AG | A method for withdrawing agglomerates from a fluidised bed reactor |
| EP3243622B1 (en) | 2016-05-13 | 2020-09-09 | Borealis AG | Process for hydraulic conveying of polyolefin pellets |
| EP3257879A1 (en) | 2016-06-17 | 2017-12-20 | Borealis AG | Bi- or multimodal polyethylene with low unsaturation level |
| KR20190021324A (ko) | 2016-06-17 | 2019-03-05 | 보레알리스 아게 | 향상된 유동학적 특성을 갖는 바이모달 또는 멀티모달 폴리에틸렌 삼원공중합체 |
| ES2799148T3 (es) | 2016-06-17 | 2020-12-15 | Borealis Ag | Polietileno bi- o multimodal con bajo nivel de insaturación |
| EP3257895A1 (en) | 2016-06-17 | 2017-12-20 | Borealis AG | Bi- or multimodal polyethylene terpolymer with enhanced rheological properties |
| US20190338111A1 (en) | 2016-06-17 | 2019-11-07 | Borealis Ag | Bi- or multimodal polyethylene with enhanced rheological properties |
| US10982019B2 (en) | 2016-06-23 | 2021-04-20 | Borealis Ag | Process for catalyst deactivation |
| EP3418308B1 (en) | 2017-06-20 | 2020-03-11 | Borealis AG | A method, an arrangement and use of an arrangement for olefin polymerisation |
| EP3418309A1 (en) | 2017-06-20 | 2018-12-26 | Borealis AG | A method, an arrangement and use of an arrangement of preparing polymer |
| ES2786567T3 (es) | 2017-06-23 | 2020-10-13 | Borealis Ag | Procedimiento y aparato para la retirada de material polimérico de un reactor de polimerización de olefinas con gases y sólido |
| ES2913629T3 (es) | 2017-10-24 | 2022-06-03 | Borealis Ag | Película de polímero de varias capas |
| EP3479896A1 (en) | 2017-11-03 | 2019-05-08 | Borealis AG | Polymerization reactor system comprising at least one withdrawal valve |
| EP3483189A1 (en) | 2017-11-14 | 2019-05-15 | Borealis AG | Automated method for terminating an olefin polymerization reaction under emergency conditions |
| EP3486261B1 (en) | 2017-11-17 | 2020-06-24 | Borealis AG | Method for improving the cooling capacity of a gas solids olefin polymerization reactor |
| ES2795985T3 (es) | 2017-11-17 | 2020-11-25 | Borealis Ag | Procedimiento de división del gas de fluidización de retorno en un reactor de polimerización de olefinas de gas sólidos |
| WO2019166652A1 (en) | 2018-03-02 | 2019-09-06 | Borealis Ag | Process |
| CN111684006B (zh) | 2018-03-21 | 2023-08-11 | 博里利斯股份公司 | 双峰或多峰聚乙烯组合物 |
| CN112135845B (zh) | 2018-06-14 | 2024-07-09 | 博里利斯股份公司 | 用于在具有改善的热均质性的气相反应器中聚合烯烃的方法 |
| EP3830140A1 (en) | 2018-08-02 | 2021-06-09 | Borealis AG | Process for polymerizing ethylene in a multi-stage polymerization process |
| EP3877464B1 (en) | 2018-11-07 | 2022-10-12 | Borealis AG | Polyolefin composition with improved impact and whitening resistance |
| MY195282A (en) | 2018-11-15 | 2023-01-12 | Abu Dhabi Polymers Co Ltd Borouge | Polymer Composition For Blow Molding Applications |
| EP3887411A1 (en) | 2018-11-29 | 2021-10-06 | Borealis AG | Polymer composition and process for making the same |
| WO2020109563A1 (en) | 2018-11-29 | 2020-06-04 | Borealis Ag | Process to produce a polymer and polymer |
| WO2020109452A1 (en) | 2018-11-30 | 2020-06-04 | Borealis Ag | Washing process |
| US20220177616A1 (en) | 2019-06-04 | 2022-06-09 | Borealis Ag | Process and reactor assembly for the enhancement of hydrodynamics in a gas-solids fluidized bed reactor |
| CN113950368B (zh) | 2019-06-04 | 2024-05-24 | 北欧化工股份公司 | 用于生产聚烯烃的方法和多级反应器组件 |
| CN114008089B (zh) | 2019-06-24 | 2023-08-29 | 博里利斯股份公司 | 回收率提高的聚丙烯制备方法 |
| CN114402003B (zh) * | 2019-07-17 | 2023-04-18 | 博里利斯股份公司 | 制备聚合物组合物的方法 |
| WO2021009190A1 (en) * | 2019-07-17 | 2021-01-21 | Borealis Ag | Process for producing a polymer composition |
| EP4004066A1 (en) | 2019-07-22 | 2022-06-01 | Abu Dhabi Polymers Co. Ltd (Borouge) Llc. | Single site catalysed multimodal polyethylene composition |
| EP3838984A1 (en) | 2019-12-20 | 2021-06-23 | Borealis AG | Polymer composition and article |
| EP3868793A1 (en) | 2020-02-24 | 2021-08-25 | Borealis AG | Process for producing alpha-olefin polymers in a multistage polymerization process |
| EP4126993A1 (en) | 2020-03-24 | 2023-02-08 | Borealis AG | Polyethylene composition for a film layer |
| WO2021191019A1 (en) | 2020-03-24 | 2021-09-30 | Borealis Ag | Polyethylene composition for a film layer |
| US20230203286A1 (en) | 2020-05-20 | 2023-06-29 | Borealis Ag | Polymer for cable jacket |
| FI4153676T3 (fi) | 2020-05-20 | 2025-10-22 | Borealis Gmbh | Polymeeri sähkökaapelieristettä varten |
| US20230227637A1 (en) | 2020-07-23 | 2023-07-20 | Borealis Ag | Multimodal ethylene copolymer |
| EP4029914B1 (en) | 2021-01-14 | 2025-03-05 | Borealis AG | Heterophasic polyolefin composition |
| US20240317901A1 (en) | 2021-06-24 | 2024-09-26 | Borealis Ag | Utilization of 1-hexene in multi-stage polyolefin production |
| CA3224759A1 (en) | 2021-06-24 | 2022-12-29 | Borealis Ag | Use of a swelling agent in multi-stage polyolefin production |
| JP2024525010A (ja) | 2021-06-24 | 2024-07-09 | ボレアリス エージー | オレフィン重合触媒の圧縮特性を決定する方法 |
| WO2022268959A1 (en) | 2021-06-24 | 2022-12-29 | Borealis Ag | Improving catalyst performance in multi-stage polyolefin production |
| EP4116091A1 (en) | 2021-07-07 | 2023-01-11 | Borealis AG | Multilayer film |
| CA3226016A1 (en) | 2021-07-08 | 2023-01-12 | Borealis Ag | Polyethylene for use in the production of crosslinked polyethylene (pex) |
| EP4144435A1 (en) | 2021-09-01 | 2023-03-08 | Borealis AG | Gas phase polymerization process with improved gas recycling |
| EP4163309A1 (en) | 2021-10-07 | 2023-04-12 | Borealis AG | Hdpe |
| EP4163334A1 (en) | 2021-10-10 | 2023-04-12 | Borealis AG | Polyethylene composition for a film layer |
| EP4257640B1 (en) | 2022-04-04 | 2024-08-28 | Borealis AG | Pipe comprising a polypropylene composition |
| EP4317216A1 (en) | 2022-08-03 | 2024-02-07 | Abu Dhabi Polymers Co. Ltd (Borouge) LLC | Low density ethylene terpolymer composition |
| EP4389414A1 (en) | 2022-12-19 | 2024-06-26 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Multilayer collation shrink film |
| EP4389418A1 (en) | 2022-12-19 | 2024-06-26 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Multilayer collation shrink film |
| WO2024223777A1 (en) | 2023-04-26 | 2024-10-31 | Borealis Ag | Layer element suitable as integrated backsheet for a bifacial photovoltaic module |
| WO2024223775A1 (en) | 2023-04-26 | 2024-10-31 | Borealis Ag | Layer element suitable as integrated backsheet for a bifacial photovoltaic module |
| EP4455170A1 (en) | 2023-04-28 | 2024-10-30 | Borealis AG | Cable compositions comprising a multimodal ethylene-butene-hexene terpolymer |
| EP4541583A1 (en) | 2023-10-18 | 2025-04-23 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Multilayer film |
| WO2025125458A1 (en) | 2023-12-12 | 2025-06-19 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Modified polyethylene having improved hydrostatic pressure resistance and slow crack growth resistance |
| EP4574848A1 (en) | 2023-12-19 | 2025-06-25 | Borealis AG | Polypropylene copolymer composition having high molecular weight |
| WO2025219499A1 (en) | 2024-04-18 | 2025-10-23 | Borealis Gmbh | Processes for polymerising olefins |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2538595B2 (ja) * | 1987-05-13 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒 |
| EP0474391B1 (en) * | 1990-08-21 | 1995-10-25 | Nippon Oil Co. Ltd. | Polyolefins |
| US5171919A (en) * | 1990-10-17 | 1992-12-15 | Idemitsu Kosan Co., Ltd. | Process for producing propylene based oligomers |
| FI96216C (fi) * | 1994-12-16 | 1996-05-27 | Borealis Polymers Oy | Prosessi polyeteenin valmistamiseksi |
| US5767208A (en) * | 1995-10-20 | 1998-06-16 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| EP0889911B1 (en) * | 1996-03-29 | 2000-11-02 | The Dow Chemical Company | Metallocene cocatalyst |
| FI990003L (fi) * | 1999-01-04 | 2000-07-05 | Borealis Polymers Oy | Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot |
| US20020107344A1 (en) * | 2000-12-07 | 2002-08-08 | Peterson Thomas Henry | Supprt materials for use with polymerization catalysts |
-
2003
- 2003-03-25 EP EP03251855A patent/EP1462464A1/en not_active Withdrawn
-
2004
- 2004-03-24 KR KR1020057017314A patent/KR20050109582A/ko not_active Withdrawn
- 2004-03-24 CN CNA200480007915XA patent/CN1764676A/zh active Pending
- 2004-03-24 US US10/550,237 patent/US20070037939A1/en not_active Abandoned
- 2004-03-24 BR BRPI0408714-3A patent/BRPI0408714A/pt not_active IP Right Cessation
- 2004-03-24 JP JP2006504840A patent/JP2006521436A/ja not_active Withdrawn
- 2004-03-24 EP EP04722852A patent/EP1606327A2/en not_active Withdrawn
- 2004-03-24 WO PCT/EP2004/003112 patent/WO2004085499A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN1764676A (zh) | 2006-04-26 |
| US20070037939A1 (en) | 2007-02-15 |
| KR20050109582A (ko) | 2005-11-21 |
| EP1462464A1 (en) | 2004-09-29 |
| BRPI0408714A (pt) | 2006-03-07 |
| WO2004085499A2 (en) | 2004-10-07 |
| WO2004085499A3 (en) | 2005-01-20 |
| EP1606327A2 (en) | 2005-12-21 |
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