CN1681594A - 中孔材料及其选择性氧化有机化合物的用途 - Google Patents

中孔材料及其选择性氧化有机化合物的用途 Download PDF

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Publication number
CN1681594A
CN1681594A CNA038222310A CN03822231A CN1681594A CN 1681594 A CN1681594 A CN 1681594A CN A038222310 A CNA038222310 A CN A038222310A CN 03822231 A CN03822231 A CN 03822231A CN 1681594 A CN1681594 A CN 1681594A
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transition metal
metal
catalyst
inorganic oxide
mesopore
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Chinese (zh)
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单志平
托马斯·马施迈尔
雅各布斯·格尼留斯·扬森
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Lummus Technology LLC
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ABB Lummus Global Inc
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103204769A (zh) * 2012-01-13 2013-07-17 中国石油化工股份有限公司 一种由环己醇生产环己酮的方法
CN109894119A (zh) * 2017-12-08 2019-06-18 中国石油化工股份有限公司 由丁烯制备1,3-丁二烯催化剂的制备方法
CN110065989A (zh) * 2019-06-04 2019-07-30 温州大学 一种利用微孔结构的金属有机骨架材uio-67衍生物吸附水中有机染料的方法

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6930219B2 (en) * 1999-09-07 2005-08-16 Abb Lummus Global Inc. Mesoporous material with active metals
US6906208B2 (en) * 1999-09-07 2005-06-14 Abb Lummus Global Inc. Mesoporous material and use thereof for the selective oxidation of organic compounds
US7608747B2 (en) * 1999-09-07 2009-10-27 Lummus Technology Inc. Aromatics hydrogenolysis using novel mesoporous catalyst system
US6835686B2 (en) * 2001-07-05 2004-12-28 Millennium Specialty Chemicals Catalyst system and process for rearrangement of epoxides to allylic alcohols
US7132093B2 (en) * 2002-06-05 2006-11-07 UNIVERSITé LAVAL Mesoporous mixed oxide materials as a new class of SO2 resistant catalysts for hydrocarbon oxidation
US7985400B2 (en) * 2004-01-26 2011-07-26 Lummus Technology Inc. Method for making mesoporous or combined mesoporous and microporous inorganic oxides
US7091365B2 (en) * 2004-03-08 2006-08-15 Abb Lummus Global Inc. Process for olefin epoxidation and co-production of nylon precursor
US7678955B2 (en) 2005-10-13 2010-03-16 Exxonmobil Chemical Patents Inc Porous composite materials having micro and meso/macroporosity
US7655827B2 (en) * 2006-05-16 2010-02-02 Chevron Phillips Chemical Company Lp Selective isomerization of olefins to alkenes using a mesoporous catalyst
KR100709557B1 (ko) * 2007-01-02 2007-04-20 한국과학기술연구원 입상 지르코늄 나노 메조구조체의 제조방법
JP5176426B2 (ja) * 2007-03-16 2013-04-03 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
RU2474470C2 (ru) 2007-05-18 2013-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Реакторная система, абсорбент и способ осуществления реакции в подаваемом материале
US20090050535A1 (en) * 2007-05-18 2009-02-26 Wayne Errol Evans Reactor system, and a process for preparing an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate and an alkanolamine
EP2092980A1 (en) * 2008-02-22 2009-08-26 ExxonMobil Research and Engineering Company Aromatic hydrogenation catalysts comprising Ti-MCM-41 and platinum group metals and aromatic hydrogenation process
US8193374B2 (en) * 2008-05-15 2012-06-05 Shell Oil Company Process for the preparation of alkylene carbonate and/or alkylene glycol
WO2009140318A1 (en) * 2008-05-15 2009-11-19 Shell Oil Company Process for the preparation of an alkylene carbonate and an alkylene glycol
US7812201B2 (en) 2008-10-01 2010-10-12 Targa Resources, Inc. Process and catalyst for converting alkanes
CN101703932B (zh) * 2009-10-23 2011-07-27 北京工业大学 用于催化消除VOCs的Pd和Pt负载介孔氧化锰的制备方法
EP2493837B1 (en) * 2009-10-29 2014-04-23 University College Cardiff Consultants Ltd. Hydrocarbon selective oxidation with heterogenous gold catalysts
KR101841689B1 (ko) * 2009-10-30 2018-03-29 삼성전자주식회사 메조 기공성 복합 촉매 및 그의 제조방법
WO2012005824A1 (en) * 2010-07-09 2012-01-12 Sumitomo Chemical Company, Limited Process for producing olefin oxide
WO2012005825A1 (en) * 2010-07-09 2012-01-12 Sumitomo Chemical Company, Limited Process for producing olefin oxide
US8791040B2 (en) 2010-11-03 2014-07-29 Fina Technology, Inc. Catalysts containing nano-materials and methods of making and using same
WO2012094120A1 (en) * 2011-01-05 2012-07-12 Sumitomo Chemical Company, Limited Process for producing olefin oxide
WO2012094121A1 (en) * 2011-01-05 2012-07-12 Sumitomo Chemical Company, Limited Process for producing olefin oxide
EP2682206A4 (en) * 2011-03-04 2014-09-17 Toyota Motor Co Ltd METAL PARTS, CATALYST FOR THE PURIFICATION OF PURIFICATION AND MANUFACTURING METHOD THEREFOR
JP6060902B2 (ja) * 2011-07-13 2017-01-18 宇部興産株式会社 イソシアネート化合物の製造方法
CN103781548B (zh) 2011-08-23 2016-05-04 丰田自动车株式会社 排气用净化催化剂及其制造方法
CN102527408B (zh) * 2011-12-26 2013-11-27 广州自远生物科技有限公司 一种二甲基砜的制备方法及其固体催化剂
EP2866931A4 (en) * 2012-06-27 2016-04-13 Univ Kansas ALKYLENEPOXIDATION OF MESOPOROUS CATALYSTS
US20140016234A1 (en) * 2012-07-13 2014-01-16 Darin D. Lindig Hardened layer on a drive head
AU2013298173B2 (en) * 2012-08-02 2016-11-24 Sasol Technology (Proprietary) Limited Catalysts
EP2988865A2 (en) 2013-04-24 2016-03-02 Saudi Basic Industries Corporation High productivity catalyst for alkane oxidation to unsaturated carboxylic acids and alkenes
EP2988864A2 (en) 2013-04-24 2016-03-02 Saudi Basic Industries Corporation Supported catalyst for production of unsaturated carboxylic acids from alkanes
TW201512180A (zh) * 2013-05-16 2015-04-01 Scient Design Co 用於乙烯氧化物觸媒之載體
KR101460348B1 (ko) * 2013-10-02 2014-11-13 서울대학교산학협력단 중형기공성 니켈-인-알루미나 에어로젤 촉매, 그 제조 방법 및 상기 촉매를 이용한 액화천연가스의 수증기 개질 반응에 의한 수소 가스 제조 방법
CN105688906B (zh) * 2016-01-14 2018-02-09 同济大学 一种用于生物柴油副产物甘油氢解产1,3‑丙二醇的催化剂的制备方法
KR101713279B1 (ko) * 2016-03-24 2017-03-07 삼성전자주식회사 메조 기공성 복합 촉매 및 그의 제조방법
CN107051438B (zh) * 2017-05-12 2019-07-05 中自环保科技股份有限公司 一种含铑催化剂的制备方法及其催化剂
US10809220B1 (en) * 2019-07-10 2020-10-20 Najran University Method for chemical sensing and photocatalysis with silver nanoparticles/mesoporous silicon nanocomposite

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3959174A (en) 1971-08-24 1976-05-25 W. R. Grace & Co. Method of selectively producing high pore volume silica gel
EP0987220A1 (en) 1998-09-17 2000-03-22 Technische Universiteit Delft Mesoporous amorphous silicate materials and process for the preparation thereof
US5108725A (en) 1990-01-25 1992-04-28 Mobil Oil Corp. Synthesis of mesoporous crystalline material
US5102643A (en) 1990-01-25 1992-04-07 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis
US5110572A (en) 1990-01-25 1992-05-05 Mobil Oil Corp. Synthesis of mesoporous crystalline material using organometallic reactants
US5264203A (en) 1990-01-25 1993-11-23 Mobil Oil Corporation Synthetic mesoporous crystalline materials
US5057296A (en) 1990-12-10 1991-10-15 Mobil Oil Corp. Method for synthesizing mesoporous crystalline material
US5191148A (en) 1991-05-06 1993-03-02 Mobil Oil Corporation Isoparaffin/olefin alkylation
US5191134A (en) 1991-07-18 1993-03-02 Mobil Oil Corporation Aromatics alkylation process
JPH05242603A (ja) 1992-02-28 1993-09-21 Hitachi Ltd 光ディスクシステム
NL9300737A (nl) 1993-04-29 1994-11-16 Meern Bv Engelhard De Werkwijze voor het selectief oxideren van koolwaterstoffen.
US5374747A (en) 1993-12-23 1994-12-20 Arco Chemical Technology, L.P. Epoxidation process and catalyst therefore
US5672556A (en) 1994-08-22 1997-09-30 Board Of Trustees Operating Michigan State University Crystalline silicate compositions and method of preparation
US5795555A (en) 1994-11-24 1998-08-18 Alive; Keshavaraja Micro-meso porous amorphous titanium silicates and a process for preparing the same
IN190356B (enExample) 1994-12-30 2003-07-19 Council Scient Ind Res
US5622684A (en) 1995-06-06 1997-04-22 Board Of Trustees Operating Michigan State University Porous inorganic oxide materials prepared by non-ionic surfactant templating route
US5853566A (en) * 1995-11-28 1998-12-29 Shell Oil Company Zeolite-beta containing catalyst compositions and their use in hydrocarbon conversion processes for producing low boiling point materials
US5849258A (en) 1996-06-06 1998-12-15 Intevep, S.A. Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same
DE19624340A1 (de) 1996-06-19 1998-01-08 Degussa Verfahren zur Herstellung von kristallinen mikro- und mesoporösen Metallsilicaten, verfahrensgemäß erhältliche Produkte und deren Verwendung
DE69708880T2 (de) 1996-07-01 2002-04-11 The Dow Chemical Co., Midland Verfahren zur direkten oxidation von olefinen zu olefinoxiden
DE19639016A1 (de) 1996-09-23 1998-03-26 Basf Ag Mesoporöses Siliciumdioxid, Verfahren zu seiner Herstellung und seiner Verwendung
US6133186A (en) 1997-03-06 2000-10-17 Shell Oil Company Process for the preparation of a catalyst composition
US5948683A (en) 1997-10-18 1999-09-07 Engelhard Corporation Catalyst for selective oxidation of unsaturated hydrocarbons and methods of making and using the same
DE19841142A1 (de) 1998-09-09 2000-03-23 Degussa Kieselsäuren und Metallsilikate mit regelmäßiger Mesoporenstruktur
US6906208B2 (en) 1999-09-07 2005-06-14 Abb Lummus Global Inc. Mesoporous material and use thereof for the selective oxidation of organic compounds
EP1134189A1 (de) 2000-03-16 2001-09-19 Degussa AG Formkörper amorpher, poröser (Metall-)Silikate
ES2181528B1 (es) 2000-03-28 2004-06-16 Universitat De Valencia (Estudi General ) Procedimiento de preparacion de oxidos mixtos porosos, materiales asi obtenidos y sus usos.
FR2816609B1 (fr) 2000-11-14 2003-01-10 Ceca Sa Solides inorganiques mesoporeux, leur procede de preparation et leurs utilisations notamment comme catalyseurs et absorbants

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103204769A (zh) * 2012-01-13 2013-07-17 中国石油化工股份有限公司 一种由环己醇生产环己酮的方法
CN103204769B (zh) * 2012-01-13 2015-03-18 中国石油化工股份有限公司 一种由环己醇生产环己酮的方法
CN109894119A (zh) * 2017-12-08 2019-06-18 中国石油化工股份有限公司 由丁烯制备1,3-丁二烯催化剂的制备方法
CN109894119B (zh) * 2017-12-08 2022-02-08 中国石油化工股份有限公司 由丁烯制备1,3-丁二烯催化剂的制备方法
CN110065989A (zh) * 2019-06-04 2019-07-30 温州大学 一种利用微孔结构的金属有机骨架材uio-67衍生物吸附水中有机染料的方法
CN110065989B (zh) * 2019-06-04 2021-07-06 温州大学 一种利用微孔结构的金属有机骨架材uio-67衍生物吸附水中有机染料的方法

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