CN1323099C - 使用双金属氰化物(dmc)催化剂生成具有窄多分散性的聚合物多元醇 - Google Patents

使用双金属氰化物(dmc)催化剂生成具有窄多分散性的聚合物多元醇 Download PDF

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Publication number
CN1323099C
CN1323099C CNB2003801102290A CN200380110229A CN1323099C CN 1323099 C CN1323099 C CN 1323099C CN B2003801102290 A CNB2003801102290 A CN B2003801102290A CN 200380110229 A CN200380110229 A CN 200380110229A CN 1323099 C CN1323099 C CN 1323099C
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China
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chain
transfer agent
polyvalent alcohol
molar concentration
volumetric molar
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Expired - Fee Related
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CNB2003801102290A
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Chinese (zh)
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CN1759133A (zh
Inventor
W·赫因兹
J·维尔德森
E·M·德克斯哈姆尔
R·A·内夫
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BASF Corp
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BASF Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18—Block or graft polymers
    • C08G64/183—Block or graft polymers containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
CNB2003801102290A 2003-03-31 2003-10-17 使用双金属氰化物(dmc)催化剂生成具有窄多分散性的聚合物多元醇 Expired - Fee Related CN1323099C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/403,197 2003-03-31
US10/403,197 US6713599B1 (en) 2003-03-31 2003-03-31 Formation of polymer polyols with a narrow polydispersity using double metal cyanide (DMC) catalysts

Publications (2)

Publication Number Publication Date
CN1759133A CN1759133A (zh) 2006-04-12
CN1323099C true CN1323099C (zh) 2007-06-27

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Country Status (6)

Country Link
US (1) US6713599B1 (ko)
EP (1) EP1611183A1 (ko)
KR (1) KR100973732B1 (ko)
CN (1) CN1323099C (ko)
AU (1) AU2003274027A1 (ko)
WO (1) WO2004087788A1 (ko)

Cited By (2)

* Cited by examiner, † Cited by third party
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CN103097425A (zh) * 2010-07-05 2013-05-08 拜耳知识产权有限责任公司 制备多元醇混合物的方法
CN104837885A (zh) * 2012-10-16 2015-08-12 拜耳材料科技股份有限公司 基于聚醚碳酸酯多元醇的新型热塑性聚氨酯弹性体的制造和用途

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US7268204B2 (en) * 2005-03-29 2007-09-11 Basf Corporation Complex of a multimetal cyanide compound and methods of forming polyethercarbonate polyols
US20060223973A1 (en) * 2005-03-29 2006-10-05 Basf Corporation Method of forming a polyethercarbonate polyol
DE102006006696A1 (de) * 2006-02-14 2007-08-23 Clariant International Limited Polyalkylenglykol-Schmiermittelbasisöle mit enger Molmassenverteilung
US7977501B2 (en) * 2006-07-24 2011-07-12 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (DMC) catalysis
US8093351B2 (en) * 2006-08-24 2012-01-10 Cornell Research Foundation, Inc. Copolymerization of propylene oxide and carbon dioxide and homopolymerization of propylene oxide
EP2115032B2 (de) † 2007-01-30 2014-10-22 Basf Se Verfahren zur herstellung von polyethercarbonatpolyolen
DE102007057146A1 (de) 2007-11-28 2009-06-04 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Polyetheralkoholen mit DMC-Katalysatoren unter Verwendung von speziellen Additiven mit aromatischer Hydroxy-Funktionalisierung
DE102007057145A1 (de) 2007-11-28 2009-06-04 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Polyetheralkoholen mit DMC-Katalysatoren unter Verwendung von SiH-Gruppen tragenden Verbindungen als Additive
EP2112187A1 (en) * 2008-04-21 2009-10-28 Stichting Dutch Polymer Institute Process for the preparation of polycarbonates
KR102089887B1 (ko) 2008-09-08 2020-03-16 사우디 아람코 테크놀로지스 컴퍼니 폴리카보네이트 폴리올 조성물
CN101633731B (zh) * 2009-08-14 2011-08-03 广州市达志化工科技有限公司 一种脂肪族聚碳酸酯多元醇的制备方法
SG183823A1 (en) * 2010-03-24 2012-10-30 Bayer Ip Gmbh Method for producing polyether carbonate polyols
CN101942081B (zh) * 2010-08-13 2012-05-09 浙江大学 金属氰化物配位催化剂催化制备脂肪族聚碳酸酯的方法
WO2012019405A1 (zh) 2010-08-13 2012-02-16 浙江大学 一种金属氰化物配位催化剂及其制备方法和应用
US9458354B2 (en) 2010-10-06 2016-10-04 Resinate Technologies, Inc. Polyurethane dispersions and methods of making and using same
KR101385933B1 (ko) * 2010-12-17 2014-04-21 에스케이이노베이션 주식회사 폴리프로필렌카보네이트 도료조성물
CN103547368B (zh) 2011-04-04 2017-10-27 汉高股份有限及两合公司 用于环氧化物聚合以及用于环氧化物与二氧化碳的共聚合的催化剂
KR101507696B1 (ko) 2011-06-10 2015-04-07 크리스토퍼 엠. 펠리체 투명 코팅, 아크릴 코팅
EP2604641A1 (de) 2011-12-16 2013-06-19 Bayer Intellectual Property GmbH Verfahren zur Herstellung von Polyetherestercarbonatpolyolen
EP2604642A1 (de) 2011-12-16 2013-06-19 Bayer Intellectual Property GmbH Verfahren zur Herstellung von Polyethercarbonatpolyolen
US10066047B2 (en) 2012-02-02 2018-09-04 Covestro Llc Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams
US20140024795A1 (en) * 2012-04-25 2014-01-23 Novomer, Inc. Aliphatic polycarbonate polyols containing silyl groups
DE102012218848A1 (de) * 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
CN103433065B (zh) * 2013-09-04 2015-07-29 万华化学集团股份有限公司 一种双金属氰化物催化剂的制备方法及其应用
US9777189B2 (en) * 2014-11-03 2017-10-03 Kaneka North America Llc Curable composition
US9951174B2 (en) 2015-05-20 2018-04-24 Covestro Llc Polyol compositions, a process for the production of these polyol compositions, and their use in the production of open celled polyurethane foams having high airflow
ES2912776T3 (es) 2015-06-15 2022-05-27 Univ King Abdullah Sci & Tech Uso de aditivos para afinar la composición de unidades de carbonato en el polímero formado mediante la copolimerización de CO2 con epóxido: aplicación a la síntesis de copolímeros de bloque a base de policarbonato y de telequélicos
CN105111425B (zh) * 2015-09-21 2016-09-07 河北工业大学 一种低分子量聚碳酸酯-聚醚多元醇及其制备方法
JP7162609B2 (ja) 2017-03-15 2022-10-28 コベストロ・エルエルシー 温度感度が低減した改良粘弾性フォーム用ポリオール
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CN114514257A (zh) 2019-10-09 2022-05-17 科思创有限公司 使用光学和红外成像的生产聚氨酯泡沫产品的方法、系统和计算机程序产品
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* Cited by examiner, † Cited by third party
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CN103097425A (zh) * 2010-07-05 2013-05-08 拜耳知识产权有限责任公司 制备多元醇混合物的方法
CN103097425B (zh) * 2010-07-05 2015-10-07 拜耳知识产权有限责任公司 制备多元醇混合物的方法
CN104837885A (zh) * 2012-10-16 2015-08-12 拜耳材料科技股份有限公司 基于聚醚碳酸酯多元醇的新型热塑性聚氨酯弹性体的制造和用途
CN104837885B (zh) * 2012-10-16 2017-08-11 科思创德国股份有限公司 基于聚醚碳酸酯多元醇的新型热塑性聚氨酯弹性体的制造和用途

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Publication number Publication date
CN1759133A (zh) 2006-04-12
AU2003274027A1 (en) 2004-10-25
KR100973732B1 (ko) 2010-08-04
EP1611183A1 (en) 2006-01-04
KR20050113651A (ko) 2005-12-02
WO2004087788A1 (en) 2004-10-14
US6713599B1 (en) 2004-03-30

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