CN1239762C - 可染色的聚烯烃纤维和织物 - Google Patents
可染色的聚烯烃纤维和织物 Download PDFInfo
- Publication number
- CN1239762C CN1239762C CNB018202306A CN01820230A CN1239762C CN 1239762 C CN1239762 C CN 1239762C CN B018202306 A CNB018202306 A CN B018202306A CN 01820230 A CN01820230 A CN 01820230A CN 1239762 C CN1239762 C CN 1239762C
- Authority
- CN
- China
- Prior art keywords
- fiber
- butyl
- silk
- acid
- tert
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 105
- 239000004744 fabric Substances 0.000 title claims abstract description 46
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 36
- -1 aromatic diol Chemical class 0.000 claims abstract description 162
- 239000000203 mixture Substances 0.000 claims abstract description 75
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 claims abstract description 56
- 239000000155 melt Substances 0.000 claims abstract description 7
- 239000000975 dye Substances 0.000 claims description 66
- 238000000034 method Methods 0.000 claims description 53
- 239000004743 Polypropylene Substances 0.000 claims description 38
- 229920001155 polypropylene Polymers 0.000 claims description 34
- 229930185605 Bisphenol Natural products 0.000 claims description 24
- 239000004952 Polyamide Substances 0.000 claims description 24
- 229920002647 polyamide Polymers 0.000 claims description 24
- 125000004432 carbon atom Chemical group C* 0.000 claims description 23
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 14
- 150000001721 carbon Chemical group 0.000 claims description 14
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 12
- 125000001118 alkylidene group Chemical group 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 11
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 150000002367 halogens Chemical group 0.000 claims description 10
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 8
- 239000001361 adipic acid Substances 0.000 claims description 7
- 235000011037 adipic acid Nutrition 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 6
- 238000009941 weaving Methods 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
- 239000001294 propane Substances 0.000 claims description 5
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 206010021639 Incontinence Diseases 0.000 claims description 3
- 238000009954 braiding Methods 0.000 claims description 3
- 239000004746 geotextile Substances 0.000 claims description 3
- 239000005022 packaging material Substances 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 239000002250 absorbent Substances 0.000 abstract description 4
- 230000002745 absorbent Effects 0.000 abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 41
- 239000000654 additive Substances 0.000 description 34
- 230000000996 additive effect Effects 0.000 description 32
- 238000004043 dyeing Methods 0.000 description 32
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 31
- 150000001412 amines Chemical class 0.000 description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 20
- 239000002585 base Substances 0.000 description 20
- 229920001577 copolymer Polymers 0.000 description 20
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 14
- 239000000986 disperse dye Substances 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 11
- 239000012964 benzotriazole Substances 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical group NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
- 239000004700 high-density polyethylene Substances 0.000 description 10
- 229920001684 low density polyethylene Polymers 0.000 description 10
- 239000004702 low-density polyethylene Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 9
- 229920001903 high density polyethylene Polymers 0.000 description 9
- 239000000049 pigment Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 8
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 150000008301 phosphite esters Chemical class 0.000 description 8
- 238000007639 printing Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 7
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 7
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000003078 antioxidant effect Effects 0.000 description 6
- 235000006708 antioxidants Nutrition 0.000 description 6
- 239000007859 condensation product Substances 0.000 description 6
- 125000005702 oxyalkylene group Chemical group 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- HTSVYUUXJSMGQC-UHFFFAOYSA-N 2-chloro-1,3,5-triazine Chemical class ClC1=NC=NC=N1 HTSVYUUXJSMGQC-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 5
- 229920002614 Polyether block amide Polymers 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 239000000980 acid dye Substances 0.000 description 5
- 150000001565 benzotriazoles Chemical class 0.000 description 5
- 239000004305 biphenyl Substances 0.000 description 5
- 229940035422 diphenylamine Drugs 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
- QYSPWTBYSZPOCJ-UHFFFAOYSA-N 1-hydroxypentadecane-3-sulfonic acid Chemical compound CCCCCCCCCCCCC(CCO)S(O)(=O)=O QYSPWTBYSZPOCJ-UHFFFAOYSA-N 0.000 description 4
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 4
- GLDQAMYCGOIJDV-UHFFFAOYSA-N 2,3-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1O GLDQAMYCGOIJDV-UHFFFAOYSA-N 0.000 description 4
- BGQNNKZAJXZSPQ-UHFFFAOYSA-N 5,6-dimethylheptane-1,6-diol Chemical compound CC(O)(C)C(C)CCCCO BGQNNKZAJXZSPQ-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical group O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Substances OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 150000003951 lactams Chemical class 0.000 description 4
- COVMBDWAODLWIB-UHFFFAOYSA-N n'-(2-hydroxyethyl)oxamide Chemical class NC(=O)C(=O)NCCO COVMBDWAODLWIB-UHFFFAOYSA-N 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
- 229950006389 thiodiglycol Drugs 0.000 description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 3
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- ODGYWRBCQWKSSH-UHFFFAOYSA-N n'-ethylpropane-1,3-diamine Chemical compound CCNCCCN ODGYWRBCQWKSSH-UHFFFAOYSA-N 0.000 description 3
- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 3
- 229940038384 octadecane Drugs 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 3
- GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 description 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 2
- JEFSTMHERNSDBC-UHFFFAOYSA-N 1,2-dimethylcyclohexa-2,4-dien-1-ol Chemical compound CC1=CC=CCC1(C)O JEFSTMHERNSDBC-UHFFFAOYSA-N 0.000 description 2
- VNQNXQYZMPJLQX-UHFFFAOYSA-N 1,3,5-tris[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CN2C(N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C(=O)N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C2=O)=O)=C1 VNQNXQYZMPJLQX-UHFFFAOYSA-N 0.000 description 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 2
- LEVFXWNQQSSNAC-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexoxyphenol Chemical compound OC1=CC(OCCCCCC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 LEVFXWNQQSSNAC-UHFFFAOYSA-N 0.000 description 2
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 2
- JINGUCXQUOKWKH-UHFFFAOYSA-N 2-aminodecanoic acid Chemical compound CCCCCCCCC(N)C(O)=O JINGUCXQUOKWKH-UHFFFAOYSA-N 0.000 description 2
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 2
- PTIJEHALOMSCIN-UHFFFAOYSA-N 2h-oxaphosphocine Chemical compound C1=CC=CPOC=C1 PTIJEHALOMSCIN-UHFFFAOYSA-N 0.000 description 2
- SXGXVOZDLWXVKM-UHFFFAOYSA-N 3-dodecylpyrrolidine-2,5-dione Chemical compound CCCCCCCCCCCCC1CC(=O)NC1=O SXGXVOZDLWXVKM-UHFFFAOYSA-N 0.000 description 2
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- MSGFMKMFGGXSTO-UHFFFAOYSA-N C(C)(C)(C)C=1C=C(C(=CC1O)CN)CCCC Chemical compound C(C)(C)(C)C=1C=C(C(=CC1O)CN)CCCC MSGFMKMFGGXSTO-UHFFFAOYSA-N 0.000 description 2
- GUSBVGGUBAAZAP-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCC Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCC GUSBVGGUBAAZAP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000010014 continuous dyeing Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 150000002690 malonic acid derivatives Chemical class 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- VEZIKIAGFYZTCI-UHFFFAOYSA-N methyl 3-(4-methoxyphenyl)prop-2-enoate Chemical compound COC(=O)C=CC1=CC=C(OC)C=C1 VEZIKIAGFYZTCI-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- GXELTROTKVKZBQ-UHFFFAOYSA-N n,n-dibenzylhydroxylamine Chemical compound C=1C=CC=CC=1CN(O)CC1=CC=CC=C1 GXELTROTKVKZBQ-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- RQVGZVZFVNMBGS-UHFFFAOYSA-N n-octyl-n-phenylaniline Chemical compound C=1C=CC=CC=1N(CCCCCCCC)C1=CC=CC=C1 RQVGZVZFVNMBGS-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000003431 oxalo group Chemical group 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 229940116351 sebacate Drugs 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
- 229960005137 succinic acid Drugs 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000010023 transfer printing Methods 0.000 description 2
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 2
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 2
- GZIFEOYASATJEH-VHFRWLAGSA-N δ-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-VHFRWLAGSA-N 0.000 description 2
- BJGZXKKYBXZLAM-UHFFFAOYSA-N (2,4-ditert-butyl-6-methylphenyl) 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CC1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1OC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BJGZXKKYBXZLAM-UHFFFAOYSA-N 0.000 description 1
- KJYSXRBJOSZLEL-UHFFFAOYSA-N (2,4-ditert-butylphenyl) 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 KJYSXRBJOSZLEL-UHFFFAOYSA-N 0.000 description 1
- HQEPZWYPQQKFLU-UHFFFAOYSA-N (2,6-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC(O)=C1C(=O)C1=CC=CC=C1 HQEPZWYPQQKFLU-UHFFFAOYSA-N 0.000 description 1
- ATLWFAZCZPSXII-UHFFFAOYSA-N (2-octylphenyl) 2-hydroxybenzoate Chemical compound CCCCCCCCC1=CC=CC=C1OC(=O)C1=CC=CC=C1O ATLWFAZCZPSXII-UHFFFAOYSA-N 0.000 description 1
- ZEBMSMUPGIOANU-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methylphosphonic acid Chemical compound CC(C)(C)C1=CC(CP(O)(O)=O)=CC(C(C)(C)C)=C1O ZEBMSMUPGIOANU-UHFFFAOYSA-N 0.000 description 1
- KWXSCYIIFPGCNI-UHFFFAOYSA-N (4-tert-butylphenyl)-(2,6-dihydroxyphenyl)methanone Chemical compound C1=CC(C(C)(C)C)=CC=C1C(=O)C1=C(O)C=CC=C1O KWXSCYIIFPGCNI-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical class ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- LNZBQIBHNKDRIL-UHFFFAOYSA-N 1-(3-amino-4-hydroxyphenyl)octadecan-1-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)C1=CC=C(O)C(N)=C1 LNZBQIBHNKDRIL-UHFFFAOYSA-N 0.000 description 1
- MQQKTNDBASEZSD-UHFFFAOYSA-N 1-(octadecyldisulfanyl)octadecane Chemical compound CCCCCCCCCCCCCCCCCCSSCCCCCCCCCCCCCCCCCC MQQKTNDBASEZSD-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 description 1
- XDDLRVYDQACVBC-UHFFFAOYSA-N 10-oxo-10-(1,2,2,6,6-pentamethylpiperidin-4-yl)oxydecanoic acid Chemical compound CN1C(C)(C)CC(OC(=O)CCCCCCCCC(O)=O)CC1(C)C XDDLRVYDQACVBC-UHFFFAOYSA-N 0.000 description 1
- PJSZEJYVBCJGNO-UHFFFAOYSA-N 10-oxo-10-(2,2,6,6-tetramethyl-1-octoxypiperidin-4-yl)oxydecanoic acid Chemical compound CCCCCCCCON1C(C)(C)CC(OC(=O)CCCCCCCCC(O)=O)CC1(C)C PJSZEJYVBCJGNO-UHFFFAOYSA-N 0.000 description 1
- HEJCZAMFVMNFLC-UHFFFAOYSA-N 10-oxo-10-(2,2,6,6-tetramethylpiperidin-4-yl)oxydecanoic acid Chemical compound CC1(C)CC(OC(=O)CCCCCCCCC(O)=O)CC(C)(C)N1 HEJCZAMFVMNFLC-UHFFFAOYSA-N 0.000 description 1
- VJHDPVWEDUCKRQ-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O.NCCCCCCCCCCCC(O)=O VJHDPVWEDUCKRQ-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 1
- STHGLRYNMROMHZ-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)-11-methyl-3-(8-methylnonyl)dodecane-1,3-diol Chemical compound C(CCCCCCC(C)C)C(O)(C(CO)(CO)CO)CCCCCCCC(C)C STHGLRYNMROMHZ-UHFFFAOYSA-N 0.000 description 1
- ZZNRIAJJKFZXIX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)henicosane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.C(CCCCCCCCCCCCCCCCC)C(O)C(CO)(CO)CO ZZNRIAJJKFZXIX-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 1
- FLLRQABPKFCXSO-UHFFFAOYSA-N 2,5-ditert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C=C1C(C)(C)C FLLRQABPKFCXSO-UHFFFAOYSA-N 0.000 description 1
- JFGVTUJBHHZRAB-UHFFFAOYSA-N 2,6-Di-tert-butyl-1,4-benzenediol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1O JFGVTUJBHHZRAB-UHFFFAOYSA-N 0.000 description 1
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 1
- DBUIEJOYSZZSGV-UHFFFAOYSA-N 2,6-ditert-butyl-4-(1,3,5-triazin-2-yloxy)phenol Chemical class CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(OC=2N=CN=CN=2)=C1 DBUIEJOYSZZSGV-UHFFFAOYSA-N 0.000 description 1
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- LBOGPIWNHXHYHN-UHFFFAOYSA-N 2-(2-hydroxy-5-octylphenyl)sulfanyl-4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C(SC=2C(=CC=C(CCCCCCCC)C=2)O)=C1 LBOGPIWNHXHYHN-UHFFFAOYSA-N 0.000 description 1
- HOHDYZFUHAZLIT-UHFFFAOYSA-N 2-(aminomethyl)-n-ethylaniline Chemical compound CCNC1=CC=CC=C1CN HOHDYZFUHAZLIT-UHFFFAOYSA-N 0.000 description 1
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 1
- ITLDHFORLZTRJI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-5-octoxyphenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1N1N=C2C=CC=CC2=N1 ITLDHFORLZTRJI-UHFFFAOYSA-N 0.000 description 1
- BSLJCKJBKOLWJD-UHFFFAOYSA-N 2-[(2-hydroxyphenyl)methyl]-3-(trifluoromethyl)phenol Chemical compound OC1=CC=CC=C1CC1=C(O)C=CC=C1C(F)(F)F BSLJCKJBKOLWJD-UHFFFAOYSA-N 0.000 description 1
- WFNXYMSIAASORV-UHFFFAOYSA-N 2-[1-(2-hydroxyphenyl)cyclohexyl]phenol Chemical compound OC1=CC=CC=C1C1(C=2C(=CC=CC=2)O)CCCCC1 WFNXYMSIAASORV-UHFFFAOYSA-N 0.000 description 1
- VARDNKCBWBOEBW-UHFFFAOYSA-N 2-[4-(4-methoxyphenyl)-6-phenyl-1,3,5-triazin-2-yl]phenol Chemical class C1=CC(OC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C(=CC=CC=2)O)=N1 VARDNKCBWBOEBW-UHFFFAOYSA-N 0.000 description 1
- PMRTXCQELXDQEH-UHFFFAOYSA-N 2-[carboxymethyl-[2-oxo-2-(2,2,6,6-tetramethylpiperidin-4-yl)oxyethyl]amino]acetic acid Chemical compound CC1(C)CC(OC(=O)CN(CC(O)=O)CC(O)=O)CC(C)(C)N1 PMRTXCQELXDQEH-UHFFFAOYSA-N 0.000 description 1
- HHPDFYDITNAMAM-UHFFFAOYSA-N 2-[cyclohexyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)C1CCCCC1 HHPDFYDITNAMAM-UHFFFAOYSA-N 0.000 description 1
- NVKDNDRCUYIBLB-UHFFFAOYSA-N 2-amino-4-butylphenol Chemical compound CCCCC1=CC=C(O)C(N)=C1 NVKDNDRCUYIBLB-UHFFFAOYSA-N 0.000 description 1
- UIXRDRQSWYSVNK-UHFFFAOYSA-N 2-butyl-4,6-dimethylphenol Chemical compound CCCCC1=CC(C)=CC(C)=C1O UIXRDRQSWYSVNK-UHFFFAOYSA-N 0.000 description 1
- AKNMPWVTPUHKCG-UHFFFAOYSA-N 2-cyclohexyl-6-[(3-cyclohexyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound OC=1C(C2CCCCC2)=CC(C)=CC=1CC(C=1O)=CC(C)=CC=1C1CCCCC1 AKNMPWVTPUHKCG-UHFFFAOYSA-N 0.000 description 1
- KDHONNUUDHJCID-UHFFFAOYSA-N 2-cyclopentyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C2CCCC2)=C1 KDHONNUUDHJCID-UHFFFAOYSA-N 0.000 description 1
- XSXYESVZDBAKKT-UHFFFAOYSA-N 2-hydroxybenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1O XSXYESVZDBAKKT-UHFFFAOYSA-N 0.000 description 1
- WBJWXIQDBDZMAW-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carbonyl chloride Chemical compound C1=CC=CC2=C(C(Cl)=O)C(O)=CC=C21 WBJWXIQDBDZMAW-UHFFFAOYSA-N 0.000 description 1
- CNXZMGRWEYQCOQ-UHFFFAOYSA-N 2-methoxy-3-phenylprop-2-enoic acid Chemical compound COC(C(O)=O)=CC1=CC=CC=C1 CNXZMGRWEYQCOQ-UHFFFAOYSA-N 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- KZVQUHCNMYILNO-UHFFFAOYSA-N 2-nonan-4-ylphenol Chemical compound CCCCCC(CCC)C1=CC=CC=C1O KZVQUHCNMYILNO-UHFFFAOYSA-N 0.000 description 1
- ZFMFIBDSZCASNS-UHFFFAOYSA-N 2-pentylbenzene-1,4-diol Chemical compound CCCCCC1=CC(O)=CC=C1O ZFMFIBDSZCASNS-UHFFFAOYSA-N 0.000 description 1
- PKRSYEPBQPFNRB-UHFFFAOYSA-N 2-phenoxybenzoic acid Chemical class OC(=O)C1=CC=CC=C1OC1=CC=CC=C1 PKRSYEPBQPFNRB-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- RAADBCJYJHQQBI-UHFFFAOYSA-N 2-sulfoterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(S(O)(=O)=O)=C1 RAADBCJYJHQQBI-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- DBHUTHZPCWZNRW-UHFFFAOYSA-N 3-(3,5-dicyclohexyl-4-hydroxyphenyl)propanoic acid Chemical compound OC=1C(C2CCCCC2)=CC(CCC(=O)O)=CC=1C1CCCCC1 DBHUTHZPCWZNRW-UHFFFAOYSA-N 0.000 description 1
- PZMWHOITXWIHBP-UHFFFAOYSA-N 3-[hydroxy(phenyl)methoxy]-3-oxopropanoic acid Chemical compound OC(=O)CC(=O)OC(O)C1=CC=CC=C1 PZMWHOITXWIHBP-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- RYAIMSPHUVXLQI-UHFFFAOYSA-N 4-(aminomethyl)-2-(benzotriazol-2-yl)phenol Chemical compound NCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RYAIMSPHUVXLQI-UHFFFAOYSA-N 0.000 description 1
- BCZQMWDTKGBZFG-UHFFFAOYSA-N 4-[(4-hydroxy-2,6-dimethylphenyl)disulfanyl]-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1SSC1=C(C)C=C(O)C=C1C BCZQMWDTKGBZFG-UHFFFAOYSA-N 0.000 description 1
- WPSWDCBWMRJJED-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;oxirane Chemical compound C1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 WPSWDCBWMRJJED-UHFFFAOYSA-N 0.000 description 1
- QVXGXGJJEDTQSU-UHFFFAOYSA-N 4-[4-hydroxy-2,5-di(pentan-2-yl)phenyl]sulfanyl-2,5-di(pentan-2-yl)phenol Chemical compound C1=C(O)C(C(C)CCC)=CC(SC=2C(=CC(O)=C(C(C)CCC)C=2)C(C)CCC)=C1C(C)CCC QVXGXGJJEDTQSU-UHFFFAOYSA-N 0.000 description 1
- WTWGHNZAQVTLSQ-UHFFFAOYSA-N 4-butyl-2,6-ditert-butylphenol Chemical compound CCCCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 WTWGHNZAQVTLSQ-UHFFFAOYSA-N 0.000 description 1
- UXMKUNDWNZNECH-UHFFFAOYSA-N 4-methyl-2,6-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC(C)=CC(CCCCCCCCC)=C1O UXMKUNDWNZNECH-UHFFFAOYSA-N 0.000 description 1
- OILMLWAZYNVPMG-UHFFFAOYSA-N 4-methyl-2-nonylphenol Chemical compound CCCCCCCCCC1=CC(C)=CC=C1O OILMLWAZYNVPMG-UHFFFAOYSA-N 0.000 description 1
- PPLHJYOTUIILGX-UHFFFAOYSA-N 4-n-(5-methylheptan-3-yl)benzene-1,4-diamine Chemical compound CCC(C)CC(CC)NC1=CC=C(N)C=C1 PPLHJYOTUIILGX-UHFFFAOYSA-N 0.000 description 1
- MNDJKTIGCWCQIG-UHFFFAOYSA-N 4-n-naphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1NC1=CC=C(C=CC=C2)C2=C1 MNDJKTIGCWCQIG-UHFFFAOYSA-N 0.000 description 1
- ZEZSYLKJRJYGEQ-UHFFFAOYSA-N 4-n-octan-2-ylbenzene-1,4-diamine Chemical compound CCCCCCC(C)NC1=CC=C(N)C=C1 ZEZSYLKJRJYGEQ-UHFFFAOYSA-N 0.000 description 1
- GHUDTURWNYDCKX-UHFFFAOYSA-N 4-oxo-4-(2,2,6,6-tetramethylpiperidin-4-yl)oxybutanoic acid Chemical compound CC1(C)CC(OC(=O)CCC(O)=O)CC(C)(C)N1 GHUDTURWNYDCKX-UHFFFAOYSA-N 0.000 description 1
- BVNWQSXXRMNYKH-UHFFFAOYSA-N 4-phenyl-2h-benzotriazole Chemical compound C1=CC=CC=C1C1=CC=CC2=C1NN=N2 BVNWQSXXRMNYKH-UHFFFAOYSA-N 0.000 description 1
- DBOSBRHMHBENLP-UHFFFAOYSA-N 4-tert-Butylphenyl Salicylate Chemical compound C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC=CC=C1O DBOSBRHMHBENLP-UHFFFAOYSA-N 0.000 description 1
- HQQTZCPKNZVLFF-UHFFFAOYSA-N 4h-1,2-benzoxazin-3-one Chemical compound C1=CC=C2ONC(=O)CC2=C1 HQQTZCPKNZVLFF-UHFFFAOYSA-N 0.000 description 1
- CYHYIIFODCKQNP-UHFFFAOYSA-N 5,7-ditert-butyl-3-(3,4-dimethylphenyl)-3h-1-benzofuran-2-one Chemical compound C1=C(C)C(C)=CC=C1C1C(C=C(C=C2C(C)(C)C)C(C)(C)C)=C2OC1=O CYHYIIFODCKQNP-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- OWXXKGVQBCBSFJ-UHFFFAOYSA-N 6-n-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[2-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]ami Chemical compound N=1C(NCCCN(CCN(CCCNC=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC(N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)N(C)C(C)(C)C1 OWXXKGVQBCBSFJ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OGBVRMYSNSKIEF-UHFFFAOYSA-N Benzylphosphonic acid Chemical compound OP(O)(=O)CC1=CC=CC=C1 OGBVRMYSNSKIEF-UHFFFAOYSA-N 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- YPIIVMUYRMGFSW-UHFFFAOYSA-N C(C)(C)(C)C(CC(=O)NCCCCCCN)(C1=CC=CC(=C1)C(C)(C)C)O Chemical class C(C)(C)(C)C(CC(=O)NCCCCCCN)(C1=CC=CC(=C1)C(C)(C)C)O YPIIVMUYRMGFSW-UHFFFAOYSA-N 0.000 description 1
- CPUMIQKFVWMTKY-UHFFFAOYSA-N C(C)(C)(C)C=1C(=CC(=C(C1)CCCCC)CN)O Chemical compound C(C)(C)(C)C=1C(=CC(=C(C1)CCCCC)CN)O CPUMIQKFVWMTKY-UHFFFAOYSA-N 0.000 description 1
- XZSFMUXHGZLQKT-UHFFFAOYSA-N C(C)(C)(C)C=1C=C(C=C(C1O)CN)C1=C(CC=C1)C1=CC=CC1 Chemical compound C(C)(C)(C)C=1C=C(C=C(C1O)CN)C1=C(CC=C1)C1=CC=CC1 XZSFMUXHGZLQKT-UHFFFAOYSA-N 0.000 description 1
- RTJUWEUCUSQYAV-UHFFFAOYSA-N C(C)(C)(C)C=1C=C(C=C(C1O)CN)CCC(=O)O Chemical compound C(C)(C)(C)C=1C=C(C=C(C1O)CN)CCC(=O)O RTJUWEUCUSQYAV-UHFFFAOYSA-N 0.000 description 1
- VGILZURIYBMWSO-UHFFFAOYSA-N CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)OP(O)OC)CN Chemical compound CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)OP(O)OC)CN VGILZURIYBMWSO-UHFFFAOYSA-N 0.000 description 1
- KQUSDDJETNLGLD-UHFFFAOYSA-N CC(C)(C)C1=CC(=CC=C1)C(CC(=O)NCCCN)(C(C)(C)C)O Chemical class CC(C)(C)C1=CC(=CC=C1)C(CC(=O)NCCCN)(C(C)(C)C)O KQUSDDJETNLGLD-UHFFFAOYSA-N 0.000 description 1
- BTKLMGGKCQZDNC-UHFFFAOYSA-N CC(C)CCCCCCC[O] Chemical compound CC(C)CCCCCCC[O] BTKLMGGKCQZDNC-UHFFFAOYSA-N 0.000 description 1
- CEUXPJDCOUPKKA-UHFFFAOYSA-N CCCCCCCCC1=C(C(=C(C(=C1)C)O)CCCCCCCC)CS Chemical compound CCCCCCCCC1=C(C(=C(C(=C1)C)O)CCCCCCCC)CS CEUXPJDCOUPKKA-UHFFFAOYSA-N 0.000 description 1
- KKHPNFFXPHROHG-UHFFFAOYSA-N CCCCCCCCC1=C(C(=C(C(=C1)CC)O)CCCCCCCC)CS Chemical compound CCCCCCCCC1=C(C(=C(C(=C1)CC)O)CCCCCCCC)CS KKHPNFFXPHROHG-UHFFFAOYSA-N 0.000 description 1
- ZWZUZWPNERTEDN-UHFFFAOYSA-N CCCCCCCCC1=CC(=C(C(=C1CS)CCCCCCCC)O)C(C)(C)C Chemical compound CCCCCCCCC1=CC(=C(C(=C1CS)CCCCCCCC)O)C(C)(C)C ZWZUZWPNERTEDN-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- GZIFEOYASATJEH-UHFFFAOYSA-N D-delta tocopherol Natural products OC1=CC(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- 229930194542 Keto Natural products 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- NEOAPJDNCBHDIO-UHFFFAOYSA-N N(C(=O)C(=O)N)CCOC(CCC1=C(C(=CC(=C1)C(C)(C)C)C(C)(C)C)O)=O Chemical class N(C(=O)C(=O)N)CCOC(CCC1=C(C(=CC(=C1)C(C)(C)C)C(C)(C)C)O)=O NEOAPJDNCBHDIO-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- IWGBGUINMSOOKP-UHFFFAOYSA-N OC1=C(C(=O)CCCCCCCCCCC)C=NN1C1=CC=CC=C1 Chemical class OC1=C(C(=O)CCCCCCCCCCC)C=NN1C1=CC=CC=C1 IWGBGUINMSOOKP-UHFFFAOYSA-N 0.000 description 1
- GUKVZEMNDHZQQE-UHFFFAOYSA-N OC1=C(C=C(C=C1CCCCCCCCCCCC)CN)N1N=C2C(=N1)C=CC=C2 Chemical compound OC1=C(C=C(C=C1CCCCCCCCCCCC)CN)N1N=C2C(=N1)C=CC=C2 GUKVZEMNDHZQQE-UHFFFAOYSA-N 0.000 description 1
- PLYGVHXICXLDQL-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C(C)(C)C)CN)C(O)C(CO)(CO)CO Chemical class OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C(C)(C)C)CN)C(O)C(CO)(CO)CO PLYGVHXICXLDQL-UHFFFAOYSA-N 0.000 description 1
- PLAFTLBFNIMFNQ-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)CN)C(C)(C)C)C(O)C(CO)(CO)CO Chemical class OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)CN)C(C)(C)C)C(O)C(CO)(CO)CO PLAFTLBFNIMFNQ-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 238000001792 White test Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229940087168 alpha tocopherol Drugs 0.000 description 1
- PYHXGXCGESYPCW-UHFFFAOYSA-N alpha-phenylbenzeneacetic acid Natural products C=1C=CC=CC=1C(C(=O)O)C1=CC=CC=C1 PYHXGXCGESYPCW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229940066595 beta tocopherol Drugs 0.000 description 1
- 150000004283 biguanides Chemical class 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
- BVFSYZFXJYAPQJ-UHFFFAOYSA-N butyl(oxo)tin Chemical compound CCCC[Sn]=O BVFSYZFXJYAPQJ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001723 carbon free-radicals Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- CCRCUPLGCSFEDV-UHFFFAOYSA-N cinnamic acid methyl ester Natural products COC(=O)C=CC1=CC=CC=C1 CCRCUPLGCSFEDV-UHFFFAOYSA-N 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 description 1
- 125000004979 cyclopentylene group Chemical group 0.000 description 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000010389 delta-tocopherol Nutrition 0.000 description 1
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- ZMOXKCINJLBMGB-UHFFFAOYSA-N docosanoic acid;magnesium Chemical compound [Mg].CCCCCCCCCCCCCCCCCCCCCC(O)=O ZMOXKCINJLBMGB-UHFFFAOYSA-N 0.000 description 1
- RSNDQTNQQQNXRN-UHFFFAOYSA-N dodecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCOP(O)O RSNDQTNQQQNXRN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000001050 dyes by color Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006025 fining agent Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000010382 gamma-tocopherol Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- NZYMWGXNIUZYRC-UHFFFAOYSA-N hexadecyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NZYMWGXNIUZYRC-UHFFFAOYSA-N 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JISVIRFOSOKJIU-UHFFFAOYSA-N hexylidene Chemical group [CH2+]CCCC[CH-] JISVIRFOSOKJIU-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000000640 hydroxylating effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000009981 jet dyeing Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229960003511 macrogol Drugs 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- YVYHWOZEQUFKOB-UHFFFAOYSA-N n'-[3-(dimethylamino)propyl]oxamide Chemical class CN(C)CCCNC(=O)C(N)=O YVYHWOZEQUFKOB-UHFFFAOYSA-N 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
- DHXOCDLHWYUUAG-UHFFFAOYSA-N n,n-didodecylhydroxylamine Chemical compound CCCCCCCCCCCCN(O)CCCCCCCCCCCC DHXOCDLHWYUUAG-UHFFFAOYSA-N 0.000 description 1
- ITUWQZXQRZLLCR-UHFFFAOYSA-N n,n-dioctadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCCCCCC ITUWQZXQRZLLCR-UHFFFAOYSA-N 0.000 description 1
- WQAJFRSBFZAUPB-UHFFFAOYSA-N n,n-dioctylhydroxylamine Chemical compound CCCCCCCCN(O)CCCCCCCC WQAJFRSBFZAUPB-UHFFFAOYSA-N 0.000 description 1
- JVKWTDRHWOSRFT-UHFFFAOYSA-N n-(4-hydroxyphenyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)NC1=CC=C(O)C=C1 JVKWTDRHWOSRFT-UHFFFAOYSA-N 0.000 description 1
- UBINNYMQZVKNFF-UHFFFAOYSA-N n-benzyl-1-phenylmethanimine oxide Chemical compound C=1C=CC=CC=1C=[N+]([O-])CC1=CC=CC=C1 UBINNYMQZVKNFF-UHFFFAOYSA-N 0.000 description 1
- FWFBCOSKYDQTSS-UHFFFAOYSA-N n-butyl-1,2,2,6,6-pentamethyl-3-(1,3,5-triazin-2-yl)piperidin-4-amine Chemical compound CCCCNC1CC(C)(C)N(C)C(C)(C)C1C1=NC=NC=N1 FWFBCOSKYDQTSS-UHFFFAOYSA-N 0.000 description 1
- BYYFPVDBAHOLDX-UHFFFAOYSA-N n-dodecyl-n-phenylaniline Chemical compound C=1C=CC=CC=1N(CCCCCCCCCCCC)C1=CC=CC=C1 BYYFPVDBAHOLDX-UHFFFAOYSA-N 0.000 description 1
- GBMIPYGHTZRCRH-UHFFFAOYSA-N n-ethylethanimine oxide Chemical compound CC[N+]([O-])=CC GBMIPYGHTZRCRH-UHFFFAOYSA-N 0.000 description 1
- ZRPOKHXBOZQSOX-UHFFFAOYSA-N n-heptadecyl-n-octadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCCCCC ZRPOKHXBOZQSOX-UHFFFAOYSA-N 0.000 description 1
- DBCWENWKZARTGU-UHFFFAOYSA-N n-heptadecyloctadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC=[N+]([O-])CCCCCCCCCCCCCCCCC DBCWENWKZARTGU-UHFFFAOYSA-N 0.000 description 1
- WGCBLWIBXXQTAW-UHFFFAOYSA-N n-hexadecyl-n-octadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCCCC WGCBLWIBXXQTAW-UHFFFAOYSA-N 0.000 description 1
- GCDJFNYVSDFWDB-UHFFFAOYSA-N n-hexadecylhexadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCCCC GCDJFNYVSDFWDB-UHFFFAOYSA-N 0.000 description 1
- HQYHEBGVNAJVAA-UHFFFAOYSA-N n-hexadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCNO HQYHEBGVNAJVAA-UHFFFAOYSA-N 0.000 description 1
- FHAFFFSIDLDWQA-UHFFFAOYSA-N n-hexadecyloctadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC=[N+]([O-])CCCCCCCCCCCCCCCC FHAFFFSIDLDWQA-UHFFFAOYSA-N 0.000 description 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
- LVZUNTGFCXNQAF-UHFFFAOYSA-N n-nonyl-n-phenylaniline Chemical compound C=1C=CC=CC=1N(CCCCCCCCC)C1=CC=CC=C1 LVZUNTGFCXNQAF-UHFFFAOYSA-N 0.000 description 1
- ZXGDIORKSOYRMQ-UHFFFAOYSA-N n-octadecylheptadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCCCCC ZXGDIORKSOYRMQ-UHFFFAOYSA-N 0.000 description 1
- MCMMSXFAWOGWQE-UHFFFAOYSA-N n-octadecylhexadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCCCC MCMMSXFAWOGWQE-UHFFFAOYSA-N 0.000 description 1
- TWHQPVYYDWEGRT-UHFFFAOYSA-N n-octadecylhydroxylamine Chemical class CCCCCCCCCCCCCCCCCCNO TWHQPVYYDWEGRT-UHFFFAOYSA-N 0.000 description 1
- HORBOHJHQGXXOR-UHFFFAOYSA-N n-octadecyloctadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCCCCCC HORBOHJHQGXXOR-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- CVVFFUKULYKOJR-UHFFFAOYSA-N n-phenyl-4-propan-2-yloxyaniline Chemical compound C1=CC(OC(C)C)=CC=C1NC1=CC=CC=C1 CVVFFUKULYKOJR-UHFFFAOYSA-N 0.000 description 1
- CDZOGLJOFWFVOZ-UHFFFAOYSA-N n-propylaniline Chemical compound CCCNC1=CC=CC=C1 CDZOGLJOFWFVOZ-UHFFFAOYSA-N 0.000 description 1
- KISSZQOBOUCLMH-UHFFFAOYSA-N n-tetradecylhydroxylamine Chemical class CCCCCCCCCCCCCCNO KISSZQOBOUCLMH-UHFFFAOYSA-N 0.000 description 1
- SLYJXPKHTZCZOG-UHFFFAOYSA-N n-tetradecyltetradecan-1-imine oxide Chemical compound CCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCC SLYJXPKHTZCZOG-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- CSWFWSPPZMEYAY-UHFFFAOYSA-N octadecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(O)O CSWFWSPPZMEYAY-UHFFFAOYSA-N 0.000 description 1
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- PBLZLIFKVPJDCO-UHFFFAOYSA-N omega-Aminododecanoic acid Natural products NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 1
- 238000009994 optical bleaching Methods 0.000 description 1
- WUAFXSLROUSYBI-UHFFFAOYSA-N oxaphosphirane Chemical compound C1OP1 WUAFXSLROUSYBI-UHFFFAOYSA-N 0.000 description 1
- BHAAPTBBJKJZER-UHFFFAOYSA-N p-anisidine Chemical compound COC1=CC=C(N)C=C1 BHAAPTBBJKJZER-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical group [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000001051 pigments by color Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 238000009977 space dyeing Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- CDVLCTOFEIEUDH-UHFFFAOYSA-K tetrasodium;phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O CDVLCTOFEIEUDH-UHFFFAOYSA-K 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 125000005301 thienylmethyl group Chemical group [H]C1=C([H])C([H])=C(S1)C([H])([H])* 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2915—Rod, strand, filament or fiber including textile, cloth or fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3146—Strand material is composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3146—Strand material is composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/3171—Strand material is a blend of polymeric material and a filler material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/444—Strand is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Nonwoven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
- Multicomponent Fibers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Materials For Medical Uses (AREA)
- Knitting Of Fabric (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Coloring (AREA)
Abstract
本发明涉及包含熔体共混物的聚烯烃纤维、丝以及由其制造的织物,它们具有优异耐久的染色性,该共混物包含(A)聚烯烃;和(B)至少一种含有衍生自芳香族二醇的部分的聚醚酯酰胺。这些纤维可用于织造服、地毯、家具和汽车套、织造工业织物、一次性尿布中使用的非织造吸收材料、非织造服包括一次性医护服、过滤介质、合成纸等。
Description
本发明涉及具有优异染色性的新型烯烃聚合物纤维和织物。此类纤维可用于服装、地毯、家具套、一次性医用服、尿布等。
聚烯烃,比如聚丙烯,具有许多适宜的物理性能。但是,其本身的着色能力很差。一直以来都渴求而又未能实现的是可染色的聚烯烃组合物,特别是聚丙烯纤维。
纤维形式的着色聚丙烯在大多数情况下是通过添加固体颜料而获得的。不幸的是,含固体颜料的纤维根本不及染色纤维有竞争力。而且,同染料相比,由于种类有限,颜料可供选择的范围也相当有限。还有,使用颜料会对可以向由聚丙烯制造的衣物制品上施用的图案构成限制。另外,某些颜料会影响聚丙烯纤维的牵引能力和最终性能。其它聚烯烃比如聚乙烯也有类似的缺点。一直存在着对可染色聚烯烃组合物,例如聚丙烯纤维的需求。
美国专利5,096,995公开了具芳香族骨架的聚醚酯酰胺。
美国专利3,487,453公开了通过添加芳香族聚醚酯而改善聚丙烯纤维的染料接收能力。
美国专利5,140,065公开了与颜料相容的热塑性模塑组合物,它包含嵌段聚醚聚酰胺、嵌段聚醚酯聚酰胺、非晶态共聚酰胺和改性共聚烯烃。
美国专利5,604,284;5,652,326和5,886,098公开了包含某种聚醚酯酰胺添加剂的抗静电树脂组合物。
美国专利5,985,999公开了可染色的聚烯烃组合物,它包含功能化聚丙烯与聚醚胺的反应产物,其中聚醚胺是接枝在功能化聚丙烯上的。
GB-A-2 112 789公开了含聚醚酯酰胺的聚烯烃组合物,该组合物具有改善的低温耐冲击性能、改善的染色亲和力和抗静电性能。
GB-A-2 112 795公开了含聚醚酯酰胺的聚烯烃织物组合物,该组合物具有改善的染色性能和改善的抗静电性能。
WO-A-97/47684公开了对分散染料有亲和力的聚丙烯组合物,该组合物包含等规聚丙烯、共聚酰胺和EVA共聚物。
令人惊奇地发现,某一类特定的聚醚酯酰胺如果以熔体添加剂的形式引入时,在赋予聚烯烃纤维和织物染色能力方面特别有效。
本发明涉及包含熔体共混物的可染色纤维或丝,该共混物包含
(A) 聚烯烃;和
(B) 至少一种聚醚酯酰胺,它含有衍生自芳香族二醇的部分,其中芳香族二醇选自
其中
R1和R2独立地是环氧乙烷或环氧丙烷,
Y是共价键、1~6个碳原子的烷撑、2~6个碳原子的烷叉(RCH=)、5~12个碳原子的亚环烷基、7~15个碳原子的芳基亚烷基、O、SO、SO2、CO、S、CF2、C(CF3)2、或NH,
X是1~6个碳原子的烷基、卤素、磺酸或磺酸盐;
X1和X2独立地是氢、1~6个碳原子的直链或支化烷基、6~10个碳原子的芳烷基、芳基、卤素、磺酸或磺酸盐,
j是0~4,并且
m和n独立地是1~32。
1~6个碳原子的亚烷基是支化或非支化基团,比如亚甲基、亚乙基、亚丙基、三亚甲基、四亚甲基、五亚甲基或六亚甲基。
2~6个碳原子的亚烷基(RCH=)是支化或非支化基团,比如亚乙基、亚丙基、亚丁基、亚戊基、4-甲基亚戊基或亚己基。
5~12个碳原子的亚环烷基比如是,亚环戊基、亚环己基、亚环庚基、亚环辛基、亚环壬基、亚环癸基、亚环十一烷基或亚环十二烷基。
7~15个碳原子的芳基亚烷基比如是,亚苄基或2-苯基亚乙基。
1~6个碳原子的直链或支化烷基比如是,甲基、乙基、丙基、正丁基、异丁基、叔丁基、戊基或己基。
6~10个碳原子的芳烷基比如是,噻吩基甲基、苄基、α-甲基苄基、α,α-二甲基苄基或2-苯基乙基。
芳基比如是,噻吩基、苯基、吡啶基或咪唑基。
卤素比如是,氯、溴或碘。优选氯和溴。
磺酸盐比如是,磺酸的钠或钾盐。
组分(B)聚醚酯酰胺添加剂包括美国专利5,096,995;5,604,284;5,652,326和5,886,098所述的那些,均在此将其引入作为参考。本发明的聚醚酯酰胺可通过这些文献中所公开的方法进行制备。
在美国专利5,096,995中,含芳香族聚醚部分的聚醚酯酰胺是通过共聚以下组分而制备的:(a)氨基羧酸、内酰胺或二胺与二羧酸通过合成而得到的盐;(b)至少一种选自前述结构式(I)、(II)和(III)的二醇;(c)至少一种选自聚醚二醇和HO-R3-OH二醇的二醇化合物,其中R3是2~16个碳原子的亚烷基、亚烷基(RCH=)、亚环烷基或芳基亚烷基;和(d)4~20个碳原子的二羧酸;其中聚醚酯单元的含量为10~90重量%。
化合物(c)聚醚二醇比如是聚乙二醇或聚丙二醇。
美国专利5,604,284、5,652,326和5,886,098的聚醚酯酰胺基本上由两个组分构成,一是带有羧基链端的聚酰胺低聚物,其数均分子量为200~5,000,二是含氧化烯单元的双酚化合物,其数均分子量为300~3,000。
美国专利5,604,284、5,652,326和5,886,098中的术语“含氧化烯单元的双酚化合物”和“烷氧化双酚”在本发明中相当于结构式(II)的“芳香族二醇”。
本文提到术语“基本上”的目的是使人明白,虽然本发明聚醚酯酰胺在实施时可由两个前述组分构成,但是向该聚合物中添加第三组分也是允许的,只要其范围不损害本发明的目的和有利效果即可。
形成前述聚酰胺低聚物所用的化合物是氨基羧酸、内酰胺和二胺与二羧酸的盐。氨基羧酸的实例是ω-氨基己酸、ω-氨基庚酸、ω-氨基辛酸、ω-氨基壬酸、ω-氨基癸酸、11-氨基癸酸和12-氨基癸酸。内酰胺的实例是己内酰胺、庚内酰胺、辛内酰胺和十二内酰胺。前述盐的二胺组分是六亚甲基二胺、七亚甲基二胺、八亚甲基二胺和十亚甲基二胺,而二羧酸是己二酸、壬二酸、癸二酸、十一烷二甲酸、十二烷二甲酸和间苯二甲酸。在这些化合物中,实例是己内酰胺、12-氨基十二烷酸和己二酸与六亚甲基二胺的盐。
数均分子量200~5,000且带羧基链端的聚酰胺低聚物是成聚酰胺组分在分子量改良剂的存在下通过开环聚合反应或缩聚反应而制备的。作为分子量改良剂,常用的是4~20个碳原子的二羧酸,更具体的是脂肪族二羧酸比如琥珀酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、十一烷基二甲酸和十二烷二甲酸;芳香族二羧酸比如对苯二甲酸、间苯二甲酸、邻苯二甲酸、萘二甲酸和3-磺基间苯二甲酸碱金属盐;以及脂环族二羧酸比如1,4-环己烷二甲酸、二环己基-4,4′-二甲酸。也可以采用这些羧酸的卤代或亚硫酰衍生物。在这些化合物中,实例是脂肪族二羧酸和芳香族二羧酸,更优选己二酸、癸二酸、对苯二甲酸、间苯二甲酸和3-磺基间苯二甲酸碱金属盐。
双酚化合物的实例是二羟基二苯基、C-烷基取代的双酚;卤代双酚;亚烷基双酚比如双酚F;亚烷基(RCH=)双酚比如双酚A、亚环己基双酚和双三氟甲基亚甲基双酚;芳基亚烷基(RCH=)双酚;双酚S和羟基二苯酮。在这些化合物中,具体的实例是亚烷基(RCH=)双酚,比如双酚A。
美国专利5,604,284、5,652,326和5,886,098双酚化合物中所包括的氧化烯单元是氧化乙烯单元、氧化丙烯单元、1-或2-氧化丁烯单元和氧化四亚甲基单元。这些氧化烯单元中的实例是氧化乙烯单元或氧化乙烯与氧化丙烯单元的组合。
含氧化烯单元的双酚化合物即烷氧化双酚化合物,其数均分子量为300~3,000,比如1,600~3,000。比如,适宜采用含32~60个氧化乙烯单元的双酚化合物。
本文所着重的纤维或丝是烷氧化双酚化合物包含烷氧化亚烷基双酚比如烷氧化双酚A的那些。
美国专利5,604,284、5,652,326和5,886,098的聚醚酯酰胺是前述聚酰胺低聚物和双酚化合物在已知催化剂存在下通过缩聚反应而制备的,根据需要,催化剂比如是三氧化锑、一丁基氧化锡、钛酸四丁酯、锆酸四丁酯和乙酸锌。含氧化烯单元的双酚链的适宜含量为占聚醚酯酰胺的20~80重量%。聚醚酯酰胺的相对粘度比如是0.5~4.0,比如0.6~3.0。相对粘度是在25℃下以聚醚酯酰胺的0.5重量%间甲酚溶液测定的。
本发明的聚醚酯酰胺比如可以是双酚A-环氧乙烷加成物与含羧基链端的低聚物的反应产物,该低聚物是由ε-己内酰胺和己二酸制备的。
本发明聚醚酯酰胺可为聚烯烃纤维、丝和织物提供优异的染色性,该聚醚酯酰胺含有双酚化合物,就是说从芳香族二醇衍生的那些类型。
本发明的组合物可包含由两种或多种不同组分(B)聚醚酯酰胺构成的添加剂混合物。
本文所用术语“纤维”或“丝”是指长宽比大且横截面小、柔软且宏观上均匀的合成体。纤维可通过现有技术已知的任何方法进行制造,包括但不限于直接型材挤出法以及薄膜切割成布法或纤化带法。因此,本发明组合物可用来制备可染色纤维,包括可染色织造和非织造聚烯烃纤维。
本发明组合物是通过熔体挤出法制备而成型为纤维或丝的。根据已知的技术,比如针对纱线或短纤维的连续纺丝法,以及非织造法比如纺粘制造法和熔体喷射制造法,纤维或丝是使熔融聚合物挤出通过小喷丝孔而成型的。一般而言,然后牵引或拉伸由此成型的纤维或丝,诱导分子取向并影响结晶性能,使其直径减小并改善物理性能。在非织造方法比如纺粘法和熔体喷射法中,纤维或丝是直接沉积在多孔表面上的,比如移动的平型运输机,然后采用任何一种措施使其至少部分固结,这些措施包括但不限于,热、机械或化学粘合法。本领域熟练人员都知道,通过组合使用多个方法或者由不同方法获得的纤维,可制造出具有某些所需特性的复合纤维。实例是组合使用纺粘法和熔体喷射法来制造层合纤维,就是经常说的SMS,它代表的是两个纺粘织物外层和一个熔体喷射织物内层。另外,两种方法之一或二者均可以与短纤维粗梳法或由非织造短纤维粗梳法获得的粘合织物按任何排列顺序进行组合。在这类层合纤维中,一般都通过前述措施之一使各层至少部分固结。
本发明也适用于熔体挤出的双组分纤维,其中一个组分是本发明的聚烯烃。
聚烯烃非织造织物可具有粗梳纤维结构或者包含毡片,纤维或丝在该毡片中按无规方式分布。可通过任何一种已知方法来成型织物,包括水力缠结或射流喷网成布技术,或者气流成网或熔体喷射丝、毛絮牵引、缝编法等,取决于由织物制造的制品的最终用途。
纺粘丝的尺寸为约1.0~约3.2旦。熔体喷射纤维的纤维直径一般小于15μm,而且一般低于5μm,其下限可直至亚微米大小。复合构造的织物可加工成多种的织物单位重量。纤维的尺寸将取决于最终用途。比如,地毯背衬经常采用较重的纤维,而制造服装时则采用的是较为轻便的纤维,等等。本发明的纤维比如可以是约1~约1500旦。
热塑性聚丙烯纤维一般是在约210~约240℃的温度下挤出的,它们在本质上是疏水的,因为它们基本上不含孔隙,而且是由无法吸引或结合染料的连续分子链构成的。因此,未经处理的聚丙烯纤维即使是具有开孔结构也很难施用染料。
根据本发明,将聚醚酯酰胺添加剂引入到熔体形式的热塑性聚烯烃比如聚丙烯中,并且与聚烯烃一起挤出成型为纤维和丝,然后进行骤冷、减薄并成型为织物,这些操作可在先后或并行的加工步骤中进行。
聚醚酯酰胺可以与待熔体挤出的聚合物粒料进行共混。为了改善加工过程,可将聚醚酯酰胺预先调配或共混到低MFR聚丙烯中,该聚丙烯也可含有少量无机粉末,比如滑石,和其它常规稳定剂。
聚醚酯酰胺在聚烯烃中的混合是通过采用常用技术将其混入熔融聚合物中实现的,比如辊研磨法、在Banbury型混合机中混合或者在挤出机机筒中混合,等等。将聚醚酯酰胺与未经加热的聚合物颗粒混合,这可缩短热史(高温保留时间),从而使该试剂在聚合物本体中达到基本均匀的分布,由此降低在熔融温度下充分混合所需的时间量。
为了方便起见,聚醚酯酰胺添加剂还可以与某些情况下所需的任何其它添加剂基本上同时或先后添加。聚醚酯酰胺也可以事先与其它添加剂混合,然后将该共混物添加到聚合物中。在某些情况下,希望聚醚酯酰胺有某些附加的有益性能,该性能可使其它添加剂更容易或均匀地分散或溶解在聚烯烃中。为了方便批与批之间的质量控制,优选采用浓缩的聚合物/添加剂共混物母炼胶,然后取其一部分与附加量的聚合物共混,由此获得所需的最终配方。可将母炼胶或纯添加剂注射到新制备的聚合物中,此时聚合物仍呈熔融状态并且已离开聚合反应容器或反应装置,然后与其进行混合,接着将熔融聚合物骤冷成固体或者进行进一步的加工处理。
本发明组合物中组分(B)聚醚酯酰胺与组分(A)聚烯烃的重量比(B):(A)为0.1∶99.9~40∶60。在许多应用中,聚醚酯酰胺的含量为0.1重量%~15重量%,基于组分(A)的重量,比如其量为1重量%~7重量%,基于组分(A)的重量。
将组分(B)聚醚酯酰胺引入到本发明聚烯烃纤维或丝中,可明显改善这些本性疏水的材料的染色性。该改善效果也能持久,因此这类纤维或丝以及由其制造的织物在熟化或操作过程中不会丧失其染色性。该染色性改善效果在重复洗涤的情况下也很稳定,而不损失效力,即使是在长期使用之后也是如此。
因此,本发明也涉及为聚烯烃纤维、丝和由其制造的织造或非织造织物赋予永久染色性的方法,该方法包括熔体挤出包含热塑性聚烯烃和至少一种组分(B)聚醚酯酰胺的混合物。
本发明针对的是非织造织物,比如聚丙烯织物。本发明也针对常规织造方法中编织或针织所用的丝线或纱线。
本发明添加剂的效果不受左右非织造织物性能的其它因素的影响,比如织物单位重量、纤维直径、纤维的粘合程度和粘合类型,以及复合结构的协同效应和影响,比如之前所述的SMS结构。
本发明不限于单组分纤维。聚烯烃双组分纤维,特别是聚丙烯和聚乙烯并列型或皮芯型纤维,预期具有与相应类型的单组分纤维相同的实用效果。
由本发明纤维和丝制备的可染色织物包括,织造服(外衣和内衣);地毯;家具和汽车套、织造工业织物;尿布、卫生巾、失禁垫、干湿拭具、伤口绷带、阻渗漏材料、医用吸收垫所用的非织造吸收材料;非织造服,包括一次性医护服;毡片;压制片材;土工布;滤器(双极性);包装材料,包括信封,以及合成纸。
本发明织物可通过曝露于约0.5~约10Mrad的γ射线进行消毒。γ射线消毒常用于医院服等等。
组分(A)聚烯烃的实例是:
1.单烯烃和二烯烃的聚合物,比如聚丙烯、聚异丁烯、聚丁-1-烯、聚-4-甲基戊-1-烯、聚异戊二烯或聚丁二烯,以及环烯烃的聚合物,比如环戊烯或降冰片烯,聚乙烯(任选交联),比如高密度聚乙烯(HDPE)、高密度和高分子量聚乙烯(HDPE-HMW)、高密度和超高分子量聚乙烯(HDPE-UHMW)、中密度聚乙烯(MDPE)、低密度聚乙烯(LDPE)、线性低密度聚乙烯(LLDPE)、(VLDPE)和(ULDPE)。
聚烯烃即前述段落中例示的单烯烃聚合物,比如聚乙烯和聚丙烯,其可通过多种方法进行制备,特别是以下方法:
i)自由基聚合反应(一般在高压和高温下)。
ii)催化剂聚合反应,所采用的催化剂一般含有一种或多种元素周期表IVb、Vb、VIb或VIII族金属。这些金属一般有一个或多个配体,一般是氧化物、卤化物、醇化物、酯、醚、胺、烷基、链烯基和/或芳基,它们可以是p或s配位的。这些金属配合物可以是游离形式或者固定在基底上,一般是固定在活化的氯化镁、氯化钛(III)、氧化铝或氧化硅上。这些催化剂可溶于或不可溶于聚合反应介质中。催化剂可直接在聚合反应中使用,或者可使用其进一步的活化物,一般是烷基金属、氢化金属、金属烷基卤、金属烷基醚或金属alkyloxane,所述金属可以是元素周期表Ia、IIa和/或IIIa族元素。该活化物很容易经由其它酯、醚、胺或甲硅烷基醚基团进行改性。这些催化剂体系一般被称为Philips、Standard Oil Indiana、Ziegler(-Natta)、TNZ(DuPont)、金属茂或单位点催化剂(SSC)。
2.1.)中所述聚合物的混合物,比如聚丙烯与聚异丁烯的混合物、聚丙烯与聚乙烯的混合物(比如PP/HDPE、PP/LDPE)以及不同类型聚乙烯的混合物(比如LDPE/HDPE)。
3.单烯烃和二烯烃与彼此或其它乙烯基单体的共聚物,比如乙烯/丙烯共聚物、线性低密度聚乙烯(LLDPE)及其与低密度聚乙烯(LDPE)的混合物、丙烯/丁-1-烯共聚物、丙烯/异丁烯共聚物、乙烯/丁-1-烯共聚物、乙烯/己烯共聚物、乙烯/甲基戊烯共聚物、乙烯/庚烯共聚物、乙烯/辛烯共聚物、丙烯/丁二烯共聚物、异丁烯/异戊二烯共聚物、乙烯/丙烯酸烷基酯共聚物、乙烯/甲基丙烯酸烷基酯共聚物、乙烯/醋酸乙烯酯共聚物及其与一氧化碳的共聚物,或者乙烯/丙烯酸共聚物及其盐(离聚物),还有乙烯与丙烯和二烯比如己二烯、二环戊二烯或亚乙基降冰片烯的三元共聚物;以及这些共聚物与彼此及之前1)所述聚合物的混合物,比如聚丙烯/乙烯-丙烯共聚物、LDPE/乙烯-醋酸乙烯酯共聚物(EVA)、LDPE/乙烯-丙烯酸共聚物(EAA)、LLDPE/EVA、LLDPE/EAA,以及交替或无规聚烯/一氧化碳共聚物及其与其它聚合物比如聚酰胺的混合物。
本发明的聚烯烃比如是聚丙烯或聚乙烯。特别重要的是聚丙烯均和共聚物以及聚乙烯均和共聚物。比如,聚丙烯、高密度聚乙烯(HDPE)、线性低密度聚乙烯(LLDPE)和聚丙烯无规和耐冲击共聚物。
采用烯烃聚合物的共混物或合金也是包括本发明范围之内的。
也可以向本发明聚烯烃纤维、丝和织物中引入或施用适宜的添加剂,比如紫外光吸收剂、位阻胺光稳定剂、抗氧化剂、加工助剂和其它添加剂。
比如,本发明组合物也任选含有约0.01~约10%,优选约0.025~约5%,特别是约0.1~约3重量%的各种常规稳定剂辅助添加剂,比如以下所示的物质,或其混合物。
1.抗氧化剂
1.1.烷基化一元酚,比如2,6-二-叔丁基-4-甲基苯酚、2-叔丁基-4,6-二甲基苯酚、2,6-二叔丁基-4-乙基苯酚、2,6-二叔丁基-4-正丁基苯酚、2,6-二叔丁基-4-异丁基苯酚、2,6-二环戊基-4-甲基苯酚、2-(α-甲基环己基)-4,6-二甲基苯酚、2,6-双十八烷基-4-甲基苯酚、2,4,6-三环己基苯酚、2,6-二叔丁基-4-甲氧基甲基苯酚、带线性或支化侧链的壬基酚,比如2,6-二壬基-4-甲基苯酚、2,4-二甲基-6-(1′-甲基十一烷-1′-基)苯酚、2,4-二甲基-6-(1′-甲基十七烷-1′-基)苯酚、2,4-二甲基-6-(1′-甲基十三烷-1′-基)苯酚和其混合物。
1.2.烷基硫甲基苯酚,比如2,4-二辛基硫甲基-6-叔丁基苯酚、2,4-二辛基硫甲基-6-甲基苯酚、2,4-二辛基硫甲基-6-乙基苯酚、2,6-双十二烷基硫甲基-4-壬基苯酚。
1.3.氢醌和烷基化氢醌,比如2,6-二叔丁基-4-甲氧基苯酚、2,5-二叔丁基氢醌、2,5-二叔戊基氢醌、2,6-二苯基-4-十八烷氧基苯酚、2,6-二叔丁基氢醌、2,5-二叔丁基-4-羟基苯甲醚、3,5-二叔丁基-4-羟基苯甲醚、3,5-二叔丁基-4-羟基苯基硬脂酸酯、双(3,5-二叔丁基-4-羟基苯基)己二酸酯。
1.4.生育酚,比如α-生育酚、β-生育酚、γ-生育酚、δ-生育酚和其混合物(维生素E)。
1.5.羟基化硫代二苯醚,比如2.2′-硫代双(6-叔丁基-4-甲基苯酚)、2,2′-硫代双(4-辛基苯酚)、4,4′-硫代双(6-叔丁基-3-甲基苯酚)、4,4′-硫代双(6-叔丁基-2-甲基苯酚)、4,4′-硫代双(3,6-二仲戊基苯酚)、4,4′-双(2,6-二甲基-4-羟基苯基)-二硫化物。
1.6.亚烷基双酚,比如2,2′-亚甲基双(6-叔丁基-4-甲基苯酚)、2,2′-亚甲基双(6-叔丁基-4-乙基苯酚)、2,2′-亚甲基双[4-甲基-6-(α-甲基环己基)-苯酚]、2,2′-亚甲基双(4-甲基-6-环己基苯酚)、2,2′-亚甲基双(6-壬基-4-甲基苯酚)、2,2′-亚甲基双(4,6-二叔丁基苯酚)、2,2′-亚乙基双(4,6-二叔丁基苯酚)、2,2′-亚乙基双(6-叔丁基-4-异丁基苯酚)、2,2′-亚甲基双[6-(α-甲基苄基)-4-壬基苯酚]、2,2′-亚甲基双[6-(α,α-二甲基苄基)-4-壬基苯酚]、4,4′-亚甲基双(2,6-二叔丁基苯酚)、4,4′-亚甲基双(6-叔丁基-2-甲基苯酚)、1,1-双(5-叔丁基-4-羟基-2-甲基苯基)丁烷、2,6-双(3-叔丁基-5-甲基-2-羟基苄基)-4-甲基苯酚、1,1,3-三(5-叔丁基-4-羟基-2-甲基苯基)丁烷、1,1-双(5-叔丁基-4-羟基-2-甲基苯基)-3-正十二烷基巯基丁烷、乙二醇双[3,3-双(3′-叔丁基-4′-羟基苯基)丁酸酯]、双(3-叔丁基-4-羟基-5-甲基苯基)二环戊二烯、双[2-(3′-叔丁基-2′-羟基-5′-甲基苄基)-6-叔丁基-4-甲基苯基]对苯二甲酸酯、1,1-双(3,5-二甲基-2-羟基苯基)丁烷、2,2-双(3,5-二叔丁基-4-羟基苯基)丙烷、2,2-双(5-叔丁基-4-羟基-2-甲基苯基)-4-正十二烷基巯基丁烷、1,1,5,5-四(5-叔丁基-4-羟基-2-甲基苯基)戊烷。
1.7.0-、N-和S-苄基化合物,比如3,5,3′,5′-四叔丁基-4,4′-二羟基二苄基醚、十八烷基-4-羟基-3,5-二甲基苄基巯基乙酸酯、十三烷基-4-羟基-3,5-二叔丁基苄基巯基乙酸酯、三(3,5-二叔丁基-4-羟基苄基)胺、双(4-叔丁基-3-羟基-2,6-二甲基苄基)二硫代对苯二甲酸酯、双(3,5-二叔丁基-4-羟基苄基)硫化物、异辛基-3,5-二叔丁基-4-羟基苄基巯基乙酸酯。
1.8.羟基苄基化丙二酸酯,比如双十八烷基-2,2-双(3,5-二叔丁基-2-羟基苄基)丙二酸酯、双十八烷基-2-(3-叔丁基-4-羟基-5-甲基苄基)丙二酸酯、双十二烷基巯基乙基-2,2-双(3,5-二叔丁基-4-羟基苄基)丙二酸酯、双[4-(1,1,3,3-四甲基丁基)苯基]-2,2-双(3,5-二叔丁基-4-羟基苄基)丙二酸酯。
1.9.芳香族羟基苄基化合物,比如1,3,5-三(3,5-二叔丁基-4-羟基苄基)-2,4,6-三甲基苯、1,4-双(3,5-二叔丁基-4-羟基苄基)-2,3,5,6-四甲基苯、2,4,6-三(3,5-二叔丁基-4-羟基苄基)苯酚。
1.10.三嗪化合物,比如2,4-双(辛基巯基)-6-(3,5-二叔丁基-4-羟基苯胺基)-1,3,5-三嗪、2-辛基巯基-4,6-双(3,5-二叔丁基-4-羟基苯胺基)-1,3,5-三嗪、2-辛基巯基-4,6-双(3,5-二叔丁基-4-羟基苯氧基)-1,3,5-三嗪、2,4,6-三(3,5-二叔丁基-4-羟基苯氧基)-1,2,3-三嗪、1,3,5-三(3,5-二叔丁基-4-羟基苄基)异氰脲酸酯、1,3,5-三(4-叔丁基-3-羟基-2,6-二甲基苄基)异氰脲酸酯、2,4,6-三(3,5-二叔丁基-4-羟基苯基乙基)-1,3,5-三嗪、1,3,5-三(3,5-二叔丁基-4-羟基苯基丙酰)-六氢-1,3,5-三嗪、1,3,5-三(3,5-二环己基-4-羟基苄基)异氰脲酸酯。
1.11.苄基膦酸酯,比如二甲基-2,5-二叔丁基-4-羟基苄基膦酸酯、二乙基-3,5-二叔丁基-4-羟基苄基膦酸酯、双十八烷基-3,5-二叔丁基-4-羟基苄基膦酸酯、双十八烷基-5-叔丁基-4-羟基-3-甲基苄基膦酸酯、3,5-二叔丁基-4-羟基苄基膦酸单乙酯的钙盐。
1.12.酰氨基酚,比如4-羟基N-月桂酰苯胺、4-羟基N-硬脂酰苯胺、辛基N-(3,5-二叔丁基-4-羟基苯基)氨基甲酸酯。
1.13.β-(3,5-二叔丁基-4-羟基苯基)丙酸与一元或多元醇的 酯,醇比如甲醇、乙醇、正辛醇、异辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟基乙基)异氰脲酸酯、N,N′-双(羟基乙基)草酰胺、3-硫代十一烷醇、3-硫代十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷。
1.14.β-(5-叔丁基-4-羟基-3-甲基苯基)丙酸与一元或多元醇 的酯,醇比如甲醇、乙醇、正辛醇、异辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟基乙基)异氰脲酸酯、N,N′-双(羟基乙基)草酰胺、3-硫代十一烷醇、3-硫代十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧代双环[2.2.2]辛烷;3,9-双[2-{3-(3-叔丁基-4-羟基-5-甲基苯基)丙酰氧基)-1,1-二甲基乙基]-2,4,8,10-四氧杂螺[5.5]-十一烷。
1.15.β-(3,5-二环己基-4-羟基苯基)丙酸与一元或多元醇的 酯,醇比如甲醇、乙醇、辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟基乙基)异氰脲酸酯、N,N′-双(羟基乙基)草酰胺、3-硫代十一烷醇、3-硫代十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧代双环[2.2.2]辛烷。
1.16.3,5-二叔丁基-4-羟基苯基乙酸与一元或多元醇的酯,醇比如甲醇、乙醇、辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟基乙基)异氰脲酸酯、N,N′-双(羟基乙基)草酰胺、3-硫代十一烷醇、3-硫代十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧代双环[2.2.2]辛烷。
1.17.β-(3,5-二叔丁基-4-羟基苯基)丙酸的酰胺,比如N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰)六亚甲基二酰胺、N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰)三亚甲基二酰胺、N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰)酰肼、N,N′-双[2-(3-[3,5-二叔丁基-4-羟基苯基]丙酰氧基)乙基]草酰胺(Uniroyal提供的Naugard XL-1)。
1.18.抗坏血酸(维生素C)
1.19.胺属抗氧化剂,比如N,N′-二异丙基对苯二胺、N,N′-二仲丁基对苯二胺、N,N′-双(1,4-二甲基戊基)对苯二胺、N,N′-双(1-乙基-3-甲基戊基)对苯二胺、N,N′-双(1-甲基庚基)对苯二胺、N,N′-二环己基对苯二胺、N,N′-二苯基对苯二胺、N,N′-双(2-萘基)对苯二胺、N-异丙基-N′-苯基对苯二胺、N-(1,3-二甲基丁基)-N′-苯基对苯二胺、N-(1-甲基庚基)-N′-苯基对苯二胺、N-环己基-N′-苯基对苯二胺、4-(对甲苯磺酰)二苯基胺、N,N′-二甲基-N,N′-二仲丁基对苯二胺、二苯基胺、N-烯丙基二苯基胺、4-异丙氧基二苯基胺、N-苯基-1-萘基胺、N-(4-叔辛基苯基)-1-萘基胺、N-苯基-2-萘基胺、辛基化二苯基胺,比如p,p′-二叔辛基二苯基胺、4-正丁基氨基苯酚、4-丁酰基氨基苯酚、4-壬酰基氨基苯酚、4-十二烷酰基氨基苯酚、4-十八烷酰基氨基苯酚、双(4-甲氧基苯基)胺、2,6-二叔丁基-4-二甲基氨基甲基苯酚、2,4′-二氨基二苯基甲烷、4,4′-二氨基二苯基甲烷、N,N,N′,N′-四甲基-4,4′-二氨基二苯基甲烷、1,2-双[(2-甲基苯基)氨基]乙烷、1,2-双(苯基氨基)丙烷、(邻甲苯基)双胍、双[4-(1′,3′-二甲基丁基)苯基]胺、叔辛基化N-苯基-1-萘基胺、单和二烷基化叔丁基/叔辛基二苯基胺的混合物、单和二烷基化壬基二苯基胺的混合物、单和二烷基化十二烷基二苯基胺的混合物、单和二烷基化异丙基/异己基二苯基胺的混合物、单和二烷基化叔丁基二苯基胺的混合物、2,3-二氢-3,3-二甲基-4H-1,4-苯并噻嗪、吩噻嗪、单和二烷基化叔丁基/叔辛基吩噻嗪的混合物、单和二烷基化叔辛基吩噻嗪的混合物、N-烯丙基吩噻嗪、N,N,N′,N′-四苯基-1,4-二氨基丁-2-烯。
2.UV吸收剂和光稳定剂
2.1.2-(2′-羟基苯基)苯并三唑,比如2-(2′-羟基-5′-甲基苯基)苯并三唑、2-(3′,5′-二叔丁基-2′-羟基苯基)苯并三唑、2-(5′-叔丁基-2′-羟基苯基)苯并三唑、2-(2′-羟基-5′-(1,1,3,3-四甲基丁基)苯基)苯并三唑、2-(3′,5′-二叔丁基-2′-羟基苯基)-5-氯代苯并三唑、2-(3′-叔丁基-2′-羟基-5′-甲基苯基)-5-氯代苯并三唑、2-(3′-仲丁基-5′-叔丁基-2′-羟基苯基)苯并三唑、2-(2′-羟基-4′-辛氧基苯基)苯并三唑、2-(3′,5′-二叔戊基-2′-羟基苯基)苯并三唑、2-(3′,5′-双(α,α-二甲基苄基)-2′-羟基苯基)苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-辛氧基羰基乙基)苯基)-5-氯代苯并三唑、2-(3′-叔丁基-5′-[2-(2-乙基己氧基)羰基乙基]-2′-羟基苯基)-5-氯代苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-甲氧基羰基乙基)苯基)-5-氯代苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-甲氧基羰基乙基)苯基)苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-辛氧基羰基乙基)苯基)苯并三唑、2-(3′-叔丁基-5′-[2-(2-乙基己氧基)羰基乙基]-2′-羟基苯基)苯并三唑、2-(3′-十二烷基-2′-羟基-5′-甲基苯基)苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-异辛氧基羰基乙基)苯基苯并三唑、2,2′-亚甲基双[4-(1,1,3,3-四甲基丁基)-6-苯并三唑-2-基苯酚];2-[3′-叔丁基-5′-(2-甲氧基羰基乙基)-2′-羟基苯基]-2H-苯并三唑与聚乙二醇300的酯交换反应产物;[R-CH2CH2-COO-CH2CH2]2,其中R=3′-叔丁基-4′-羟基-5′-2H-苯并三唑-2-基苯基、2-[2′-羟基-3′-(α,α-二甲基苄基)-5′-(1,1,3,3-四甲基丁基)苯基]苯并三唑;2-[2′-羟基-3′-(1,1,3,3-四甲基丁基)-5′-(α,α-二甲基苄基)-苯基]苯并三唑。
2.2.2-羟基二苯酮,比如4-羟基、4-甲氧基、4-辛氧基、4-癸氧基、4-十二烷氧基、4-苄氧基、4,2′,4′-三羟基和2′-羟基-4,4′-二甲氧基衍生物。
2.3.取代和未取代苯甲酸的酯,比如4-叔丁基苯基水杨酸酯、苯基水杨酸酯、辛基苯基水杨酸酯、二苯甲酰间苯二酚、双(4-叔丁基苯甲酰)间苯二酚、苯甲酰间苯二酚、3,5-二叔丁基-4-羟基苯甲酸2,4-二叔丁基苯基酯、3,5-二叔丁基-4-羟基苯甲酸十六烷基酯、3,5-二叔丁基-4-羟基苯甲酸十八烷基酯、3,5-二叔丁基-4-羟基苯甲酸2-甲基-4,6-二叔丁基苯基酯。
2.4.丙烯酸酯,比如α-氰基-β,β-二苯基丙烯酸乙酯、α-氰基-β,β-二苯基丙烯酸异辛酯、α-甲氧甲酰肉桂酸甲酯、α-氰基-β-甲基-对甲氧基肉桂酸甲酯、α-氰基-β-甲基-对甲氧基肉桂酸丁酯、α-甲氧甲酰-对甲氧基肉桂酸甲酯和N-(β-甲氧甲酰-β-氰基乙烯基)-2-甲基二氢吲哚。
2.5.镍化合物,比如2,2′-硫代双[4-(1,1,3,3-四甲基丁基)苯酚]的镍配合物,比如1∶1或1∶2配合物,该配合物可带或不带其它配体,比如正丁基胺、三乙醇胺或N-环己基二乙醇胺,二丁基二硫代氨基甲酸镍、4-羟基-3,5-二叔丁基苄基膦酸单烷基酯比如甲酯或乙酯的镍盐、酮肟比如2-羟基-4-甲基苯基十-烷基酮肟的镍配合物、1-苯基-4-月桂酰-5-羟基吡唑的镍配合物,这些配合物可带或不带其它配体。
2.6.位阻胺,比如双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯、双(2,2,6,6-四甲基-4-哌啶基)丁二酸酯、双(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯、双(1-辛氧基-2,2,6,6-四甲基-4-哌啶基)癸二酸酯、双(1,2,2,6,6-五甲基-4-哌啶基)正丁基-3,5-二叔丁基-4-羟基苄基丙二酸酯、1-(2-羟基乙基)-2,2,6,6-四甲基-4-羟基哌啶与琥珀酸的缩合物、N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺与4-叔辛基氨基-2,6-二氯-1,3,5-三嗪的线性或环状缩合物、三(2,2,6,6-四甲基-4-哌啶基)次氮基三乙酸酯、四(2,2,6,6-四甲基-4-哌啶基)-1,2,3,4-丁四甲酸酯、1,1′-(1,2-乙二基)-双(3,3,5,5-四甲基哌嗪酮)、4-苯甲酰基-2,2,6,6-四甲基哌啶、4-硬脂酰氧基-2,2,6,6-四甲基哌啶、双(1,2,2,6,6-五甲基哌啶基)-2-正丁基-2-(2-羟基-3,5-二叔丁基苄基)丙二酸酯、3-正辛基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸烷-2,4-二酮、双(1-辛氧基-2,2,6,6-四甲基哌啶基)癸二酸酯、双(1-辛氧基-2,2,6,6-四甲基哌啶基)琥珀酸酯、N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺与4-吗啉代-2,6-二氯-1,3,5-三嗪的线性或环状缩合物、2-氯-4,6-双(4-正丁基氨基-2,2,6,6-四甲基哌啶基)-1,3,5-三嗪与1,2-双(3-氨基丙基氨基)乙烷的缩合物、2-氯-4,6-二(4-正丁基氨基-1,2,2,6,6-五甲基哌啶基)-1,3,5-三嗪与1,2-双(3-氨基丙基氨基)乙烷的缩合物、8-乙酰基-3-十二烷基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸烷-2,4-二酮、3-十二烷基-1-(2,2,6,6-四甲基-4-哌啶基)吡咯烷-2,5-二酮、3-十二烷基-1-(1,2,2,6,6-五甲基-4-哌啶基)吡咯烷-2,5-二酮、4-十六烷氧基和4-十八烷氧基-2,2,6,6-四甲基哌啶的混合物、N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺与4-环己基氨基-2,6-二氯-1,3,5-三嗪的缩合物、1,2-双(3-氨基丙基氨基)乙烷与2,4,6-三氯-1,3,5-三嗪和4-丁基氨基-2,2,6,6-四甲基哌啶的缩合物(CAS注册号[136504-96-6]);1,6-己二胺与2,4,6-三氯-1,3,5-三嗪、N,N-二丁基胺以及4-丁基氨基-2,2,6,6-四甲基哌啶的缩合物(CAS注册号[192268-64-7]);N-(2,2,6,6-四甲基-4-哌啶基)-正十二烷基琥珀酰亚胺、N-(1,2,2,6,6-五甲基-4-哌啶基)-正十二烷基琥珀酰亚胺、2-十一烷基-7,7,9,9-四甲基-1-氧杂-3,8-二氮杂-4-氧代螺[4.5]癸烷、7,7,9,9-四甲基-2-环十一烷基-1-氧杂-3,8-二氮杂-4-氧代螺[4.5]癸烷与表氯醇的反应产物、1,1-双(1,2,2,6,6-五甲基-4-哌啶氧基羰基)-2-(4-甲氧基苯基)乙烯、N,N′-双甲酰基-N,N′-(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺、4-甲氧基亚甲基丙二酸与1,2,2,6,6-五甲基-4-羟基哌啶的二酯、聚[甲基丙基-3-氧-4-(2,2,6,6-四甲基-4-哌啶基)硅氧烷、马来酸酐-α-烯烃共聚物与2,2,6,6-四甲基-4-氨基哌啶或1,2,2,6,6-五甲基-4-氨基哌啶的反应产物。
位阻胺也可以选自GB-A-2 301 106所述的化合物组分I-a)、I-b)、I-c)、I-d)、I-e)、I-f)、I-g)、I-h)、I-i)、I-j)、I-k)或I-1)之一,特别是所述GB-A-2 301 106第68~73页上所列的光稳定剂1-a-1、1-a-2、1-b-1、1-c-1、1-c-2、1-d-1、1-d-2、1-d-3、1-e-1、1-f-1、1-g-1、1-g-2或1-k-1。
位阻胺也可以选自EP-A-0 782 994所述的化合物之一,比如其中权利要求10或38或者实施例1~12或D-1~D-5所述的化合物。
2.7.N原子处被羟基取代的烷氧基所取代的位阻胺,该类化合物比如1-(2-羟基-2-甲基丙氧基)-4-十八烷酰氧基-2,2,6,6-四甲基哌啶、1-(2-羟基-2-甲基丙氧基)-4-十六烷酰氧基-2,2,6,6-四甲基哌啶、1-氧-4-羟基-2,2,6,6-四甲基哌啶与来自叔戊醇的碳自由基的反应产物、1-(2-羟基-2-甲基丙氧基)-4-羟基-2,2,6,6-四甲基哌啶、1-(2-羟基-2-甲基丙氧基)-4-氧代-2,2,6,6-四甲基哌啶、双(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)癸二酸酯、双(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)己二酸酯、双(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)丁二酸酯、双(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)戊二酸酯和2,4-双{N-[1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基]-N-丁基氨基}-6-(2-羟基乙基氨基)-s-三嗪。
2.8.草酰胺,比如4,4′-二辛氧基N,N′-草酰二苯胺、2,2′-二乙氧基N,N’-草酰二苯胺、2,2′-二辛氧基-5,5′-二叔丁基N,N’-草酰二苯胺、2,2′-双十二烷氧基-5,5′-二叔丁基N,N’-草酰二苯胺、2-乙氧基-2′-乙基草酰苯二胺、N,N′-双(3-二甲基氨基丙基)草酰胺、2-乙氧基-5-叔丁基-2′-乙基草酰苯二胺以及它与2-乙氧基-2′-乙基-5,4′-二叔丁基草酰苯二胺的混合物、邻和对甲氧基二取代草酰苯二胺的混合物以及邻和对乙氧基二取代草酰苯二胺的混合物。
2.9.2-(2-羟基苯基)-1,3,5-三嗪,比如2,4,6-三(2-羟基-4-辛氧基苯基)-1,3,5-三嗪、2-(2-羟基-4-辛氧基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-(2,4-二羟基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2,4-双(2-羟基-4-丙氧基苯基)-6-(2,4-二甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-辛氧基苯基)-4,6-双(4-甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-十二烷氧基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-十三烷氧基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-[2-羟基-4-(2-羟基-3-丁氧基丙氧基)苯基]-4,6-双(2,4-二甲基)-1,3,5-三嗪、2-[2-羟基-4-(2-羟基-3-辛氧基丙氧基)苯基]-4,6-双(2,4-二甲基)-1,3,5-三嗪、2-[4-(十二烷氧基/十三烷氧基-2-羟基丙氧基)-2-羟基苯基]-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-[2-羟基-4-(2-羟基-3-十二烷氧基丙氧基)苯基]-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-己氧基)苯基-4,6-二苯基-1,3,5-三嗪、2-(2-羟基-4-甲氧基苯基)-4,6-二苯基-1,3,5-三嗪、2,4,6-三[2-羟基-4-(3-丁氧基-2-羟基丙氧基)苯基]-1,3,5-三嗪、2-(2-羟基苯基)-4-(4-甲氧基苯基)-6-苯基-1,3,5-三嗪、2-{2-羟基-4-[3-(2-乙基己基-1-氧)-2-羟基丙氧基]苯基}-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪。
3.金属钝化剂,比如N,N′-二苯基草酰胺、N-水杨醛-N′-水杨酰肼、N,N′-双(水杨酰)肼、N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰)肼、3-水杨酰氨基-1,2,4-三唑、双(亚苄基)草酰二酰肼、草酰苯二胺、间苯二甲酰二酰肼、癸二酰二苯基酰肼、N,N′-二乙酰基己二酰二酰肼、N,N′-双(水杨酰)草酰二酰肼、N,N′-双(水杨酰)硫代丙酰二酰肼。
4.亚磷酸酯和亚膦酸酯,比如亚磷酸三苯酯、亚磷酸二苯基烷基酯、亚磷酸苯基二烷基酯、亚磷酸三(壬基苯基)酯、亚磷酸三月桂基酯、亚磷酸三(十八烷基)酯、双十八烷基季戊四醇二亚磷酸酯、三(2,4-二叔丁基苯基)亚磷酸酯、二异癸基季戊四醇二亚磷酸酯、双(2,4-二叔丁基苯基)季戊四醇二亚磷酸酯、双(2,4-二枯基苯基)季戊四醇二亚磷酸酯、双(2,6-二叔丁基-4-甲基苯基)季戊四醇二亚磷酸酯、二异癸氧基季戊四醇二亚磷酸酯、双(2,4-二叔丁基-6-甲基苯基)季戊四醇二亚磷酸酯、双(2,4,6-三(叔丁基苯基))季戊四醇二亚磷酸酯、三硬脂基山梨糖醇三亚磷酸酯、四(2,4-二叔丁基苯基)4,4′-亚联苯基二亚膦酸酯、6-异辛氧基-2,4,8,10-四叔丁基-12H-二苯并[d,g]-1,3,2-二氧杂phosphocin、双(2,4-二叔丁基-6-甲基苯基)甲基亚磷酸酯、双(2,4-二叔丁基-6-甲基苯基)乙基亚磷酸酯、6-氟-2,4,8,10-四叔丁基-12-甲基-二苯并[d,g]-1,3,2-二氧杂phosphocin、2,2′,2′′-次氮基-[三乙基三(3,3′,5,5′-四叔丁基-1,1′-联苯-2,2′-二基)亚磷酸酯]、2-乙基己基(3,3′,5,5′-四叔丁基-1,1′-联苯-2,2′-二基)亚磷酸酯、5-丁基-5-乙基-2-(2,4,6-三叔丁基苯氧基)-1,3,2-二氧杂phosphirane。
特别优选以下亚磷酸酯:
三(2,4-二叔丁基苯基)亚磷酸酯(Irgafos168,Ciba SpecialtyChemicals Inc.)、三(壬基苯基)亚磷酸酯、
5.羟胺,比如N,N-二苄基羟胺、N,N-二乙基羟胺、N,N-二辛基羟胺、N,N-二月桂基羟胺、N,N-双十四烷基羟胺、N,N-双十六烷基羟胺、N,N-双十八烷基羟胺、N-十六烷基-N-十八烷基羟胺、N-十七烷基-N-十八烷基羟胺、来自氢化牛油胺的N,N-二烷基羟胺。
6.硝酮,比如N-苄基-α-苯基硝酮、N-乙基-α-甲基硝酮、N-辛基-α-庚基硝酮、N-月桂基-α-十-烷基硝酮、N-十四烷基-α-十三烷基硝酮、N-十六烷基-α-十五烷基硝酮、N-十八烷基-α-十七烷基硝酮、N-十六烷基-α-十七烷基硝酮、N-十八烷基-α-十五烷基硝酮、N-十七烷基-α-十七烷基硝酮、N-十八烷基-α-十六烷基硝酮、由来自氢化牛油胺的N,N-二烷基羟胺获得的硝酮。
7.氧化胺,比如美国专利5,844,029和5,880,191所公开的氧化胺衍生物、二癸基甲基氧化胺、三癸基氧化胺、三(十二烷基)氧化胺和三(十六烷基)氧化胺。
8.苯并呋喃酮和吲哚满酮,比如参见美国专利4,325,863;4,338,244;5,175,312;5,216,052;5,252,643;DE-A-4316611;DE-A-4316622;DE-A-4316876;EP-A-0589839或EP-A-0591102,或者3-[4-(2-乙酰氧基乙氧基)苯基]-5,7-二叔丁基苯并呋喃-2-酮、5,7-二叔丁基-3-[4-(2-硬脂酰氧基乙氧基)苯基]-苯并呋喃-2-酮、3,3′-双[5,7-二叔丁基-3-(4-[2-羟基乙氧基]苯基)-苯并呋喃-2-酮]、5,7-二叔丁基-3-(4-乙氧基苯基)苯并呋喃-2-酮、3-(4-乙酰氧基-3,5-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(3,5-二甲基-4-新戊酰氧基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(3,4-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(2,3-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮。
9.硫代增效剂,比如二月桂基硫代二丙酸酯或二硬脂基硫代二丙酸酯。
10.过氧化物清除剂,比如β-硫代二丙酸酯,比如月桂基酯、硬脂基酯、肉豆蔻基酯或十三烷基酯,巯基苯并咪唑或2-巯基苯并咪唑锌盐、二丁基二硫代氨基甲酸锌、双十八烷基二硫化物、季戊四醇四(β-十二烷基巯基)丙酸酯。
11.聚酰胺稳定剂,比如铜盐与碘化物和/或磷化合物组合使用,以及二价锰盐。
12.碱性助稳定剂,比如蜜胺、聚乙烯基吡咯烷酮、双氰胺、三烯丙基异氰脲酸酯、脲衍生物、肼衍生物、胺、聚酰胺、聚氨酯、高级脂肪酸的碱金属盐和碱土金属盐,比如硬脂酸钙、硬脂酸锌、山萮酸镁、硬脂酸镁、蓖麻酸钠和棕榈酸钾、焦儿茶酸锑或焦儿茶酸锌。
13.成核剂,比如无机物质,比如滑石、金属氧化物如二氧化钛或氧化镁,磷酸盐、碳酸盐或硫酸盐,均优选碱土金属的盐;有机化合物,比如一元或聚羧酸和其盐,比如4-叔丁基苯甲酸、己二酸、二苯基乙酸、琥珀酸钠或苯甲酸钠;高分子化合物,比如离子共聚物(离聚物)。特别优选1,3∶2,4-双(3′,4′-二甲基亚苄基)山梨糖醇、1,3∶2,4-二(对甲基二亚苄基)山梨糖醇和1,3∶2,4-二(亚苄基)山梨糖醇。
14.填料和增强剂,比如碳酸钙、硅酸盐、玻璃纤维、玻璃球、石棉、滑石、高岭土、云母、硫酸钡、金属氧化物和氢氧化物、碳黑、石墨、木粉以及其他天然产品的粉或纤维、合成纤维。
15.分散剂,比如聚氧化乙烯蜡或矿物油。
16.其它添加剂,比如增塑剂、润滑剂、乳化剂、颜料、染料、流变添加剂、催化剂、流动控制剂、光学增白剂、滑爽剂、交联剂、交联助促进剂、卤素清除剂、烟雾抑制剂、防燃剂、抗静电剂、澄清剂比如取代和未取代双亚苄基山梨糖醇、苯并噁嗪酮UV吸收剂比如2,2′-对亚苯基-双(3,1-苯并噁嗪-4-酮),Cyasorb 3638(CAS号18600-59-4),以及发泡剂。
比如,本领域中常用的添加剂也可以任选引入到本发明的可染色纤维中。这类物质的代表性实例包括亲水改性剂,比如单甘油酯如甘油单硬脂酸酯,带有亲水侧基的长链烃比如线性烷基磷酸酯的钾盐或钠盐,或者其组合。亲水基团可以是羧酸盐、硫酸盐、磺酸盐、磷酸盐、膦酸盐,以及季铵盐和聚醚基团。除此之外,染色过程中可采用溶胀剂,还有润湿剂、染料相容剂和增稠剂如各种胶。因为聚烯烃纤维常用于室外用途,比如室外地毯,因此适宜添加UV稳定剂。而且,组合物中还可添加抗氧化剂。
除此之外,本发明组合物预期会改善聚烯烃基织造织物或非织造毡片的洗涤性。非极性聚烯烃容易沾灰尘,因为二者在本性上均属疏水。组分(B)聚醚酯酰胺预期会有助于洗涤剂渗入织物或基体内,从而使洗涤剂能够松脱灰尘和油污并将之洗去。
向聚烯烃中引入组分(B)聚醚酯酰胺也预期会提高聚烯烃织造织物和非织造物的吸收和芯吸性能。一个实例是婴儿尿布中的熔体喷射非织造吸收材料。向聚烯烃中引入极性聚醚酯酰胺可使得非织造丝的表面更为亲水,这预期会大大增强尿布的潮气吸收特性。
引入组分(B)聚醚酯酰胺还预期会提高纤维、织物和其它制品的耐磨性。耐磨性在牵引已成型纤维时是很重要的。一般都施用浆料来减少纤维与牵引系统金属表面之间的摩擦。
本发明所制备的聚烯烃织造和非织造纤维和织物也表现出优异的可印染性。由于生性疏水,聚烯烃纤维和织物在印染性方面可能会存在问题,这指的是那些标准印染技术。本发明组合物同样解决了这些问题。
可采用常规方法来染色本发明的纤维。比如,可在采用了常规染料和分散染料技术的染色浴中对纤维进行染色。染料一般以染料溶液的形式施用,由此很容易通过使纤维浸渍通过比如含有染料溶液的染色槽的方式来施用染料,也可将染料溶液喷施在纤维上,或者采用阶式辊技术。染料溶液一般是印染浆的形式,而染色过程则一般是通过辊印染法或筛网印染法进行的。可采用一种或多种染色技术使纤维染色多次。
含水染色浴的pH值一般为约2~约11,酸性染料一般是约2~约6。根据需要,可采用多种化合物来调整pH值,比如甲酸、乙酸、氨基磺酸、柠檬酸、磷酸、硝酸、硫酸、磷酸一钠、磷酸四钠、磷酸三钠、氢氧化铵、氢氧化钠和其组合。使用表面活性剂可有助于水溶性不佳的分散染料在染色浴中的分散。针对此目的,一般采用的是非离子表面活性剂。在染色过程中,搅拌染色浴可促进染色比。染色步骤可在各种温度下进行,高温一般会促进染色率。
现有技术中已知的另一种技术是喷射染色法,它利用了文丘里喷射系统,可实现高温染色并且将染料喷射到移动的织物上。通过使用载体,可在常压和温度低于100℃下加快染色。载体一般是有机化合物,它们可在水中乳化并且对纤维有亲和力。这类载体的代表性实例包括芳香烃类,比如联苯和甲基萘、酚类比如苯基苯酚、氯代烃类比如二氯和三氯苯,以及芳香族酯比如水杨酸甲酯、苯甲酸丁酯、邻苯二甲酸二乙酯和苯甲醛。载体在染色之后一般被除去。
染色结束后,采用含前述添加剂的染料混合物,可在很宽的高温范围内对纤维施加干燥热,使染料渗入纤维并固定在其中。染料固定步骤涉及使纤维曝露于干燥热,比如在烘箱中。温度最高可达复合纤维的熔点或玻璃化转变温度。一般而言,温度越高,干燥时间就越短。加热时间一般为约1min~约10min。然后将残留的染料从纤维上除去。
由此可按各种方式将分散染料混合物施用到聚丙烯纤维上。染料混合物可沿着纤维所形成的纱线的长度方向间歇施用,可采用各种已知技术来产生所需效果。一种适宜的纤维染色方法被称为“编-拆”染色技术。根据该方法,先将纤维成型为纱线,然后编织该纱线,一般使之成为管状构造。然后向该编织管上间歇地施用染料混合物。染色结束后,拆开该管状构造,此时纱线就带有间隔染色图案了。根据另一种染色方法,将纤维首先成型为纱线,然后使纱线纺织或编织成织物,或者打成地毯。可采用常规平板筛网染色机将染料混合物施用到织物或地毯上。
连续染色在染色机组上进行,使织物或地毯在此处连续输送通过染料溶液,其长度应足以实现初始染料渗透效果。某些分散染料在加热和部分真空下可因升华而进入聚合物纤维中,这些方法是现有技术已知的。本发明所制备的聚烯烃组合物,其印染过程可采用分散染料通过加压热转印印染法进行,所施加的热量要足以使染料扩散或分散到聚烯烃中。可以采用木板、平板筛网和热转印批量法,以及花辊和旋转筛网印染连续法。当织物在喷嘴底下通过时,不同的染料溶液可按规定的顺序喷射到由本发明组合物制成的织物或地毯上,形成图案。可将染料溶液计量并分解或分割成液滴图案,然后滴落在从其下通过的已染色地毯上,于是在地毯上形成扩散的套染图案。在染色由几种不同的纤维比如尼龙、聚酯等,以及聚烯烃构成的风格化地毯时,可采用聚烯烃的竞争染色法。通过控制所存在的每种类型纤维上的色调深度,可产生不同的风格化效果。根据所存在的纤维的不同,可采用酸性、分散和金属络合染料,或其组合,从而获得风格化效果。通过控制可染色组合物中反应产物和/或聚醚酯酰胺的量,可制造出粗呢效果。印染染色法、空间染色法和连续染色法均适用于由这类纱线制造的织物。
市售的分散染料有许多种。染料是基于施用方法分类的,同时也稍微参照了the Society of Dyers and Colorists的化学构造。各种分散染料均可以在Textile Chemist and Colorist,1992年7月,第24卷,第7号给出的“Dyes and Pigments by Color Index andGeneric Names”中找到,这是the American Association of TextileChemists and Colorists的出版物。
染料是用来着色各种基材比如纸、塑料或织物材料的强有色物质。据信染料是通过物理吸附、形成盐或金属配合物或者形成共价化学键的方式保留在这些基材中的。向基材上施用染料所用的方法有很多种,取决于基材和染料类型。染料与颜料的区别之处在于施用方法,而非化学构造。在施用过程中,染料因溶解或蒸发而失去其晶体结构。在某些情况下,这些晶体结构在染色过程的后续阶段中还能得以恢复。另一方面,颜料在整个施用程序过程中均保持其晶体或颗粒形式。
因为有各种各样的材料需要染色,所以拥有数目庞大且性能千差万别的染料是很必要的。在整个世界范围内,据信已有几千种不同的染料实现了商业应用价值。一般按两种方式将染料分类。一种分类方法是化学构造,其中将染料按照分子的生色或供色单元进行分类。第二种分类方法基于染料最终用途的应用分类。染料索引(CI)中所用的双重分类系统已被国际上全体染料制造和染料应用工业所接受。在该系统中,将染料按照化学类别进行归组,每种化合物有一个CI编号,也按照用途或应用类别进行归组,每种染料有一个CI名称。分散染料一般是非水溶性的非离子染料,一般用于由含水分散体来染色亲水性纤维。分散染料已应用于聚酯、尼龙和乙酸酯纤维。
在进行牵引之前,可对纤维施用多种纺丝整理剂。这类整理剂可以是水基的。这些纺丝整理剂可以是阴离子或非离子型的,这是现有技术已知的。也可以在染色之前对纤维进行整理,比如通过机械卷曲或成型而结构化,这是现有技术已知的。
本发明也涉及为聚烯烃纤维或丝或者由其制造的织造或非织造织物赋予永久染色性的方法,包括将包含聚烯烃和至少一种聚醚酯酰胺的混合物熔体挤出成多个纤维,然后冷却这些纤维,该聚醚酯酰胺含有衍生自芳香族二醇的部分,其中该芳香族二醇选自
其中
R1和R2独立地是环氧乙烷或环氧丙烷,
Y是共价键、1~6个碳原子的烷撑、2~6个碳原子的烷叉(RCH=)、5~12个碳原子的亚环烷基、7~15个碳原子的芳基亚烷基、O、SO、SO2、CO、S、CF2、C(CF3)2、或NH,
X是1~6个碳原子的烷基、卤素、磺酸或磺酸盐;
X1和X2独立地是氢、1~6个碳原子的直链或支化烷基、6~10个碳原子的芳烷基、芳基、卤素、磺酸或磺酸盐,
j是0~4,并且
m和n独立地是1~32。
该方法优选进一步包括使纤维、丝或织物在使纤维有效染色的条件下与染料接触。
本发明也涉及包含织造或非织造织物的制品,选自织造服、地毯、家具套、汽车套、织造工业织物、一次性尿布、卫生巾、失禁垫、干湿拭具、伤口绷带、阻渗漏材料、医用吸收垫、非织造服、一次性医护服、毡片、压制片材、土工布、双极性滤器、包装材料、信封和合成纸。
因此,本发明的优选实施方案是组分(B)为聚烯烃纤维、丝或者织造或非织造织物赋予永久染色性的用途。
以下实施例对本发明进行了更为详尽的说明。它们对本发明不构成任何形式的限制。
以下实施例中所用的添加剂是:
PEBAX 1074(注册商标,Elf Atochem)是由PA 12和聚乙二醇制造的聚醚酯酰胺,其熔点为158℃。
PELESTAT 1250(注册商标,Sanyo Chemical Industries),本发明的聚醚酯酰胺,含有烷氧基化双酚并且熔点约为150℃。
PELESTAT 6321(注册商标,Sanyo Chemical Industries),本发明的聚醚酯酰胺,含有烷氧基化双酚并且熔点约为203℃。
IRGASTAB FS 410(注册商标,Ciba SC)是irgastab FS-042[注册商标,Ciba SC,由N,N-二(氢化牛油)胺经直接氧化而获得的N,N-二(烷基)羟胺]与CHIMASSORB 944(注册商标,Ciba SC)的1∶1混合物。
IRGANOX B 1411(注册商标,Ciba SC)是IRGAFOS 168(注册商标,Ciba SC)与IRGANOX 3114(注册商标,Ciba SC)的1∶1增效混合物。IRGAFOS 168(注册商标)是三(2,4-二叔丁基苯基)亚磷酸酯,IRGANOX 3114(注册商标)是三(3,5-二叔丁基-4-羟基苄基)异氰脲酸酯。
IRGANOX XP 620(注册商标,Ciba SC)是33%IRGAFOS 126[注册商标,Ciba SC,双(2,4-二叔丁基苯基)季戊四醇二亚磷酸酯]、17%IRGANOX HP-136[注册商标,Ciba SC,3-(3,4-二甲基苯基)-5,7-二叔丁基苯并呋喃-3-酮]与50% IRGANOX 1010[注册商标,Ciba SC,季戊四醇四[3-(3,5-二叔丁基-4-羟基苯基)丙酸酯]的混合物。
TINUVIN 234(注册商标,Ciba SC)是2-(3,5-双-α-枯基-2-羟基苯基)-2H-苯并三唑。
TINUVIN 1577(注册商标,Ciba SC)是4,6-二苯基-2-(4-己氧基-2-羟基苯基)-s-三嗪。
CHIMASSORB 81(注册商标,Ciba SC)是2-羟基-4-辛氧基二苯酮。
TINUVIN 111(注册商标,Ciba SC)是CHIMASSORB 119(注册商标,Ciba SC)与TINUVIN 622(注册商标,Ciba SC)的增效混合物。
TINUVIN 783(注册商标,Ciba SC)是CHIMASSORB 944(注册商标,Ciba SC)与TINUVIN 622(注册商标,Ciba SC)的增效混合物。
其中m是2~200的整数。
其中R′是
以下实施例仅是说明性的,并不视为对本发明构成任何形式的限制。添加剂水平以重量百分数计。
实施例1:聚丙烯纤维的染色性
使纤维级聚丙烯profax 6301(注册商标,Montell)和适量聚醚酯酰胺添加剂在湍动混合机中混合15min。将共混物添加到温度为218、232、246和246℃的超级MPM单螺杆实验室型挤出机中,螺杆速度是80rpm。使含有添加剂的熔融聚丙烯离开圆形模具,在水槽中冷却,然后加料到conair jetro造粒机中。将混合粒料加料到带有41孔δ喷丝板的Hills实验室型挤出机中,其温度为232、246、260和274℃。通过反馈回路在恒压750psi下控制螺杆速度。加料、牵引和松弛辊的温度为79和100℃,其转速为120、400和383m/min。使纤维与6%含水纤维整理溶液接触,该溶液紧邻加料辊并在其之前。该溶液是来自Goulston Industries的LUROL PP-4521(注册商标)。处于生产线末端的Leesona(注册商标)绕线器将纤维收集在线轴上。最终的单丝纤度为15。将收集的纤维从线轴上取下,然后用LawsonHemphill FAK(注册商标)样品编织机编织成袜子。
在另一容器中制备染料在蒸馏水中的1.0g/L溶液。为了分散染料,可首先将水加热至63-85℃,然后向染料中添加水即可。酸性染料溶液是通过将水加热至85-100℃而制备的。均染剂、润滑剂和pH值控制化学品的溶液是在室温下制备的,浓度为10%重量/重量。
将ROACHES(注册商标)程控染色浴设置为以下条件:
PP用分散染料:温升3.5℃/min,升高至98℃,在98℃下的保留时间为60min,然后进行冷却,最大冷却速率为5.5℃/min。
PP用酸性染料:温升3.5℃/min,升高至98℃,在98℃下的保留时间为30min,然后进行冷却,最大冷却速率为5.5℃/min。
基于5.0g重袜子,向500ml钢质圆桶中添加适量的溶液(见表1)。袜子贴上洗衣签以示区分,然后将其放入圆桶中。把圆桶充满蒸馏水。检查pH值,分散染色应为4-5,而酸性染色应为6-6.5。最后将圆桶密封,并放入染色浴中开始循环。染色循环结束后,从圆桶中取出袜子,然后用自来水进行漂洗。借助离心机从袜子中排出过量的水,然后在强制空气烘箱中在100℃下干燥15min。
在Datacolor Spect rophotometer SF 600上测定袜子的亮度和暗度(L)。L是0(暗)~100(亮)标度内亮与暗的度量。仪器条件是CIE实验室状态、D65、10°、SCI、SAV、UV400-700。结果见表2。L值越低,表明染色性越好。
表1
染料溶液 | |
酸性染料 | 基于纤维的重量% |
IRGALAN黄2GL | 1.0 |
IRGALAN枣红EL | 0.2 |
ERIONYL黑MR | 0.3 |
磷酸钠 | 3.0 |
焦磷酸四钠 | 1.0 |
IRGASOL SW | 1.0 |
分散染料 | |
黄K-GL | 0.5 |
红K-BB | 0.5 |
蓝K-RB | 1.0 |
UNIVADINE DIF | 2.0 |
CIBAFLUID UA | 1.0 |
乙酸 | 0.5 |
表2
染色性 | |||
配方 | 添加剂 | L值 | |
酸性染料 | A | 无 | 78.9 |
B | 5%PELESTAT 1250 | 65.8 | |
C | 5%PEBAX 1074 | 68.2 | |
D | 10%PELESTAT 1250 | 52.6 | |
E | 10%PEBAX 1074 | 53.6 | |
分散染料 | A | 无 | 54.2 |
B | 5%PELESTAT 1250 | 23.4 | |
C | 5%PEBAX 1074 | 29.9 | |
D | 10%PELESTAT 1250 | 19.2 | |
E | 10%PEBAX 1074 | 21.1 |
添加剂以基于聚丙烯的重量百分数计。
配方B和D含有本发明的聚醚酯酰胺添加剂,它与不含添加剂以及含有非本发明聚醚酯酰胺添加剂(配方C和E)的袜子相比,改善了聚丙烯袜子的染色性。
也测试了组合物的干湿摩擦掉色值。摩擦掉色测试方法测定的是色彩因摩擦而从染色制品表面向其它表面迁移的程度。这种染色迁移现象是所不希望的。该测试需要借助摩擦掉色测定仪,用干湿两块白色测试布沿着染色制品进行特定的摩擦操作。然后通过灰度色标来评价这些布。灰度色标是一种5单位制色标(1-5,0.5分度),5表示染料迁移不明显。
为了成为合格的增强聚烯烃染色性的有效添加剂,含添加剂的袜子在进行摩擦掉色测试评价时,其染料迁移现象必须不明显,而且其物理性能也不应有任何损失。
含有本发明聚醚酯酰胺的袜子也显示出优异的染色性,以适宜的干湿摩擦掉色值为证。
也测试了染色组合物的拉伸强度。含有本发明聚醚酯酰胺的袜子与不含添加剂的袜子相比,其拉伸强度没有发生任何降低。
实施例2:聚烯烃染色性
按照实施例1的步骤制备了如下的配方(所有的量均为重量百分数),并且测试其染色性:
聚丙烯 | 聚醚酯酰胺 | 抗氧化剂 | UVA | HAS |
97 | 3 | 0.1 | — | 0.2 |
95 | 5 | 0.1 | 0.1 | 0.2 |
90 | 10 | 0.2 | 0.2 | 0.1 |
85 | 15 | 0.2 | 0.2 | 0.3 |
80 | 20 | 0.2 | 0.3 | 0.2 |
70 | 30 | 0.3 | 0.3 | 0.3 |
聚乙烯 | 聚醚酯酰胺 | 抗氧化剂 | UVA | HAS |
95 | 5 | 0.1 | 0.15 | 0.25 |
90 | 10 | 0.1 | 0.2 | 0.25 |
85 | 15 | 0.2 | 0.2 | 0.3 |
75 | 25 | 0.2 | 0.3 | 0.3 |
65 | 35 | 0.3 | 0.4 | 0.2 |
聚醚酯酰胺添加剂选自PELESTAT 1250和PELESTAT 6321(注册商标,Sanyo Chemical Industries)。抗氧化剂选自IRGASTAB FS410、IRGANOX B 1411 和 IRGANOX XP 620(注册商标,Ciba SC)。紫外线吸收剂(UVA)选自TINUVIN 234、TINUVIN 1577和CHIMASSORB81(注册商标,Ciba SC)。位阻胺稳定剂(HAS)选自TINUVIN 111、TINUVIN 622、TINUVIN 783、CHIMASSORB 944和FLAMSTAB FR 116(注册商标,Ciba SC)。
本发明的组合物可进一步含有UV吸收剂、位阻胺、羟胺、亚磷酸酯和酚抗氧化剂等添加剂,它们具有优异的染色性,以低L值和适宜的干湿摩擦掉色值为证。
Claims (14)
1.一种包含熔体共混物的可染色纤维或丝,该共混物包含:
(A)聚烯烃;和
(B)至少一种聚醚酯酰胺,它含有衍生自芳香族二醇的部分,其中芳香族二醇选自
和
其中
R1和R2独立地是环氧乙烷或环氧丙烷,
Y是共价键、1~6个碳原子的烷撑、2~6个碳原子的烷叉、5~12个碳原子的亚环烷基、7~15个碳原子的芳基亚烷基、O、SO、SO2、CO、S、CF2、C(CF3)2、或NH,
X是1~6个碳原子的烷基、卤素、磺酸或磺酸盐;
X1和X2独立地是氢、1~6个碳原子的直链或支化烷基、6~10个碳原子的芳烷基、芳基、卤素、磺酸或磺酸盐,
j是0~4,并且
m和n独立地是1~32。
2.权利要求1的纤维或丝,其中聚醚酯酰胺基本上由衍生自(1)末端单元含有羧基而且数均分子量为200~5,000的聚酰胺低聚物和(2)数均分子量为300~3,000的结构式(II)烷氧基化双酚化合物的残基构成。
3.权利要求1的纤维或丝,其中聚烯烃是聚丙烯或聚乙烯。
4.权利要求2的纤维或丝,其中羧基衍生自己二酸、癸二酸、对苯二甲酸或间苯二甲酸,或者3-磺基间苯二甲酸碱金属盐。
5.权利要求2的纤维或丝,其中所述烷氧基化双酚化合物包含烷氧基化亚烷基双酚。
6.权利要求5的纤维或丝,其中所述烷氧基化亚烷基双酚是烷氧基化双酚A。
7.权利要求2的纤维或丝,其中所述烷氧基化双酚化合物是20重量%~80重量%的聚醚酯酰胺。
8.权利要求1的纤维或丝,其中组分(B)聚醚酯酰胺与组分(A)聚烯烃的重量比(B)∶(A)为0.1∶99.9~40∶60。
9.权利要求1的纤维或丝,它进一步包含染料。
10.一种包含聚烯烃组分的双组分纤维,其中聚烯烃组分包含熔体共混物,该共混物包含权利要求1的(A)和(B)。
11.一种织造或非织造织物,其包含编织或粘合的权利要求1的聚烯烃纤维或丝。
12.一种为聚烯烃纤维或丝或者由其制造的织造或非织造织物赋予永久染色性的方法,包括将包含聚烯烃和至少一种聚醚酯酰胺的混合物熔体挤出成多个纤维,然后冷却这些纤维,该聚醚酯酰胺含有衍生自芳香族二醇的部分,其中该芳香族二醇选自
其中
R1和R2独立地是环氧乙烷或环氧丙烷,
Y是共价键、1~6个碳原子的烷撑、2~6个碳原子的烷叉、5~12个碳原子的亚环烷基、7~15个碳原子的芳基亚烷基、O、SO、SO2、CO、S、CF2、C(CF3)2、或NH,
X是1~6个碳原子的烷基、卤素、磺酸或磺酸盐;
X1和X2独立地是氢、1~6个碳原子的直链或支化烷基、6~10个碳原子的芳烷基、芳基、卤素、磺酸或磺酸盐,
j是0~4,并且
m和n独立地是1~32。
13.权利要求12的方法,其进一步包括使纤维、丝或织物在使纤维有效染色的条件下与染料接触。
14.一种包含权利要求11的织造或非织造织物的制品,其选自织造服、地毯、家具套、汽车套、织造工业织物、一次性尿布、卫生巾、失禁垫、干湿拭具、伤口绷带、阻渗漏材料、医用吸收垫、非织造服、一次性医护服、毡片、压制片材、土工布、双极性滤器、包装材料、信封和合成纸。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US25163800P | 2000-12-06 | 2000-12-06 | |
US60/251,638 | 2000-12-06 | ||
US27782301P | 2001-03-22 | 2001-03-22 | |
US60/277,823 | 2001-03-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1479812A CN1479812A (zh) | 2004-03-03 |
CN1239762C true CN1239762C (zh) | 2006-02-01 |
Family
ID=26941731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB018202306A Expired - Fee Related CN1239762C (zh) | 2000-12-06 | 2001-11-27 | 可染色的聚烯烃纤维和织物 |
Country Status (16)
Country | Link |
---|---|
US (1) | US6679754B2 (zh) |
EP (1) | EP1354083B1 (zh) |
JP (1) | JP3959688B2 (zh) |
KR (1) | KR100764071B1 (zh) |
CN (1) | CN1239762C (zh) |
AT (1) | ATE317922T1 (zh) |
AU (2) | AU2189902A (zh) |
BR (1) | BR0115962B1 (zh) |
CZ (1) | CZ20031835A3 (zh) |
DE (1) | DE60117301T2 (zh) |
DK (1) | DK1354083T3 (zh) |
ES (1) | ES2257472T3 (zh) |
MX (1) | MXPA03004827A (zh) |
SK (1) | SK8632003A3 (zh) |
TW (1) | TWI297367B (zh) |
WO (1) | WO2002046503A1 (zh) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004141613A (ja) * | 2002-08-30 | 2004-05-20 | Japan Vilene Co Ltd | 医療衛生用基材 |
US7247658B2 (en) * | 2003-07-08 | 2007-07-24 | Milliken & Company | Reduction of discoloration in white polyurethane foams |
US20090104426A1 (en) * | 2003-07-22 | 2009-04-23 | E.I. Du Pont De Nemours And Company | Fibers, Tapes and Films Prepared from Olefinic and Segmented Elastomers |
US20060191493A1 (en) * | 2003-12-29 | 2006-08-31 | Better Gear Inc. | Whale safe groundline and yarn and fiber therefor |
US20050150152A1 (en) * | 2003-12-29 | 2005-07-14 | Holy Norman L. | Whale safe groundline |
US7094127B2 (en) * | 2004-03-01 | 2006-08-22 | Milliken & Company | Apparel articles including white polyurethane foams that exhibit a reduction in propensity for discoloring |
JP2007533867A (ja) * | 2004-04-23 | 2007-11-22 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 可染性ポリオレフィン繊維及び布 |
TWI358481B (en) * | 2004-06-03 | 2012-02-21 | Takemoto Oil & Fat Co Ltd | Processing agents and methods for synthetic fibers |
JP4691415B2 (ja) * | 2004-11-02 | 2011-06-01 | 竹本油脂株式会社 | 合成繊維用処理剤及び合成繊維の処理方法 |
US7074483B2 (en) * | 2004-11-05 | 2006-07-11 | Innegrity, Llc | Melt-spun multifilament polyolefin yarn formation processes and yarns formed therefrom |
US7364672B2 (en) * | 2004-12-06 | 2008-04-29 | Arlon, Inc. | Low loss prepregs, compositions useful for the preparation thereof and uses therefor |
JP4902113B2 (ja) * | 2004-12-13 | 2012-03-21 | 株式会社プライムポリマー | 可染性ポリプロピレン樹脂組成物及びこれを用いた繊維・不織布 |
BRPI0610488A2 (pt) * | 2005-05-30 | 2016-11-16 | Basf Ag | composição polimérica, e, processo para produzir a mesma |
US8057887B2 (en) * | 2005-08-17 | 2011-11-15 | Rampart Fibers, LLC | Composite materials including high modulus polyolefin fibers |
US7648607B2 (en) * | 2005-08-17 | 2010-01-19 | Innegrity, Llc | Methods of forming composite materials including high modulus polyolefin fibers |
US7892633B2 (en) * | 2005-08-17 | 2011-02-22 | Innegrity, Llc | Low dielectric composite materials including high modulus polyolefin fibers |
US20080009211A1 (en) * | 2006-07-07 | 2008-01-10 | Matthew Raymond Himes | Assemblies useful for the preparation of electronic components and methods for making same |
WO2008077156A2 (en) * | 2006-12-20 | 2008-06-26 | Imerys Pigments, Inc. | Spunlaid fibers comprising coated calcium carbonate, processes for their production, and nonwoven products |
TWI388624B (zh) * | 2007-03-29 | 2013-03-11 | Invista Tech Sarl | 包含活性化合物之耐洗的合成聚合物組合物 |
KR20110053960A (ko) | 2008-07-30 | 2011-05-24 | 바스프 에스이 | 살충제 함침된 망 및 이의 방충 용도 |
MX2012000258A (es) | 2009-07-09 | 2012-01-25 | Basf Se | Sustrato recubrimiento con insecticida para proteger seres humanos y animales domesticos. |
JP2012532841A (ja) | 2009-07-09 | 2012-12-20 | ビーエーエスエフ ソシエタス・ヨーロピア | ヒトおよびペットを保護するための殺虫性のシート状成形体 |
US8292863B2 (en) * | 2009-10-21 | 2012-10-23 | Donoho Christopher D | Disposable diaper with pouches |
CN102918124B (zh) * | 2010-06-02 | 2015-11-25 | 路博润高级材料公司 | 油墨/染料接受性薄膜、纸和织物 |
US8759430B1 (en) | 2010-06-02 | 2014-06-24 | Aquadye Fibers, Inc. | Acid dyed polyester (PET) or olefin yarns and textile fabrics using such yarns |
WO2012038460A2 (de) | 2010-09-23 | 2012-03-29 | Basf Se | Verfahren zum schutz von lebenden pflanzen vor schadinsekten mit einem flächengebilde |
JP5370390B2 (ja) * | 2011-02-14 | 2013-12-18 | Jnc株式会社 | ポリオレフィン系帯電防止繊維およびそれからなる不織布 |
PT2723156E (pt) | 2011-06-27 | 2015-08-03 | Basf Se | Sistema de proteção de produtos armazenados |
AR086771A1 (es) | 2011-06-27 | 2014-01-22 | Basf Se | Sistema para proteger mercaderia durante el transporte |
EP2849937A4 (en) | 2012-05-15 | 2016-03-23 | 3M Innovative Properties Co | POLYURETHANE BASED COATINGS FOR ROTOR BLADES |
GB2510550B (en) | 2012-09-06 | 2017-05-17 | Devan Chemicals Nv | Methods and compositions for modifying polypropylene-based fibres |
US10266986B2 (en) | 2014-02-21 | 2019-04-23 | Cocona, Inc. | Incorporation of active particles into substrates |
EP3131396B1 (en) | 2014-04-17 | 2021-09-15 | Basf Se | Pesticidal tape for controlling crawling pests |
CN105707988A (zh) * | 2014-12-05 | 2016-06-29 | 东营市半球纺织有限公司 | 一种防脱丝丝袜 |
BR112017022938A2 (pt) | 2015-04-24 | 2018-07-17 | 3M Innovative Properties Co | revestimentos de poliuretano de duas partes resistentes à erosão |
MX2018014917A (es) * | 2016-05-31 | 2019-08-29 | Basf Se | Telas no tejidas elaboradas de fibras bicomponentes. |
MX2019003759A (es) * | 2016-11-09 | 2019-07-04 | Borealis Ag | Composicion de polipropileno. |
US11931973B2 (en) | 2018-03-02 | 2024-03-19 | Ticona Llc | Weatherable fiber-reinforced propylene composition |
CN111088549B (zh) * | 2019-12-24 | 2022-05-20 | 温州大学 | 一种用于制备飞织鞋面的低熔点锦纶热熔丝 |
WO2022132462A1 (en) | 2020-12-16 | 2022-06-23 | Ticona Llc | Uv stable fiber-reinforced polymer composition |
WO2023218248A1 (en) * | 2022-05-11 | 2023-11-16 | Braskem S.A. | Bio-based hdpe for non-woven application |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL136115C (zh) | 1968-03-25 | |||
GB1414778A (en) | 1972-01-13 | 1975-11-19 | Herbert C W | Rotational drive shaft arrangements |
FR2519012B1 (fr) * | 1981-12-29 | 1987-04-10 | Ato Chimie | Composition nouvelle formee d'un melange intime de polyolefines et de polyetheresteramides |
FR2519034A1 (fr) * | 1981-12-29 | 1983-07-01 | Ato Chimie | Matieres textiles a base de polyolefines |
US5096995A (en) | 1987-08-13 | 1992-03-17 | Toray Industries, Inc. | Polyether-ester amide and permanently antistatic resin composition |
CH677674A5 (zh) | 1989-03-30 | 1991-06-14 | Inventa Ag | |
US5652326A (en) * | 1993-03-03 | 1997-07-29 | Sanyo Chemical Industries, Ltd. | Polyetheresteramide and antistatic resin composition |
US5985999A (en) | 1993-07-13 | 1999-11-16 | Huntsman, Petrochemical Corporation | Dyeable polyolefin containing polyetheramine modified functionalized polyolefin |
BE1010347A4 (nl) | 1996-06-12 | 1998-06-02 | Wetenschappelijk En Tech Ct Va | Verfbare en bedrukbare polypropyleensamenstelling en daaruit vervaardigde producten. |
US5965206A (en) | 1996-09-16 | 1999-10-12 | Ciba Specialty Chemicals Corporation | Antistatic composition |
-
2001
- 2001-11-27 EP EP01999691A patent/EP1354083B1/en not_active Expired - Lifetime
- 2001-11-27 CZ CZ20031835A patent/CZ20031835A3/cs unknown
- 2001-11-27 CN CNB018202306A patent/CN1239762C/zh not_active Expired - Fee Related
- 2001-11-27 DK DK01999691T patent/DK1354083T3/da active
- 2001-11-27 JP JP2002548215A patent/JP3959688B2/ja not_active Expired - Fee Related
- 2001-11-27 AT AT01999691T patent/ATE317922T1/de active
- 2001-11-27 AU AU2189902A patent/AU2189902A/xx active Pending
- 2001-11-27 MX MXPA03004827A patent/MXPA03004827A/es active IP Right Grant
- 2001-11-27 BR BR0115962A patent/BR0115962B1/pt not_active IP Right Cessation
- 2001-11-27 AU AU2002221899A patent/AU2002221899B2/en not_active Ceased
- 2001-11-27 WO PCT/EP2001/013790 patent/WO2002046503A1/en active IP Right Grant
- 2001-11-27 KR KR1020037007325A patent/KR100764071B1/ko not_active IP Right Cessation
- 2001-11-27 DE DE2001617301 patent/DE60117301T2/de not_active Expired - Lifetime
- 2001-11-27 ES ES01999691T patent/ES2257472T3/es not_active Expired - Lifetime
- 2001-11-27 SK SK863-2003A patent/SK8632003A3/sk unknown
- 2001-12-04 TW TW90129925A patent/TWI297367B/zh not_active IP Right Cessation
- 2001-12-06 US US10/013,106 patent/US6679754B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1354083A1 (en) | 2003-10-22 |
BR0115962B1 (pt) | 2010-06-01 |
ES2257472T3 (es) | 2006-08-01 |
TWI297367B (en) | 2008-06-01 |
DE60117301T2 (de) | 2006-07-27 |
KR100764071B1 (ko) | 2007-10-08 |
JP3959688B2 (ja) | 2007-08-15 |
DE60117301D1 (de) | 2006-04-20 |
JP2004515658A (ja) | 2004-05-27 |
US20020161123A1 (en) | 2002-10-31 |
KR20030064800A (ko) | 2003-08-02 |
ATE317922T1 (de) | 2006-03-15 |
CZ20031835A3 (cs) | 2003-10-15 |
WO2002046503A1 (en) | 2002-06-13 |
EP1354083B1 (en) | 2006-02-15 |
AU2189902A (en) | 2002-06-18 |
US6679754B2 (en) | 2004-01-20 |
DK1354083T3 (da) | 2006-06-06 |
BR0115962A (pt) | 2003-10-28 |
SK8632003A3 (en) | 2003-11-04 |
AU2002221899B2 (en) | 2006-12-07 |
MXPA03004827A (es) | 2003-08-19 |
CN1479812A (zh) | 2004-03-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1239762C (zh) | 可染色的聚烯烃纤维和织物 | |
CN1243858C (zh) | 可湿聚烯烃纤维和织物 | |
CN1942613A (zh) | 可染色的聚烯烃纤维和织物 | |
KR101718565B1 (ko) | 방적가능하고 염색가능한 폴리에스테르 섬유의 제조 방법 | |
AU2002221899A1 (en) | Dyeable polyolefin fibers and fabrics | |
MXPA96006194A (en) | Compositions of dyeed polyolephine and met | |
CN1157015A (zh) | 可染色的聚烯烃组合物和染色方法 | |
CN1989279A (zh) | 可湿性聚酯纤维和织物 | |
US11359310B2 (en) | False twist yarn comprising dyeable polyolefin fibers | |
US10793976B2 (en) | Dyeable polyolefin fiber and fibrous structure comprising same | |
KR20080015442A (ko) | 폴리올레핀 및 양친매성 블록 공중합체 및 임의로 다른공중합체 및/또는 충전제를 포함하는 중합체 조성물 및이러한 조성물의 염색 또는 날염 | |
BE1018358A3 (nl) | Procede voor de bereiding van synthetische vezels voor garen met verhoogde verfbaarheid. | |
CN1820054B (zh) | 作为疏水聚合物物品的染色促进剂的缩聚物 | |
JP2019127679A (ja) | 可染性ポリオレフィン芯鞘型複合繊維およびそれからなる繊維構造体 | |
JPH01239172A (ja) | ポリエステルユニフォーム | |
RU2278187C2 (ru) | Улучшенные синтетические волокна на основе полиолефинов и способ их получения | |
CN1011511B (zh) | 可染色的聚-α-烯烃组合物 | |
ZA200303766B (en) | Dyeable polyolefin fibers and fabrics. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060201 Termination date: 20111127 |