CN119456024A - 用于丙烯环氧化的钛沸石催化剂的再生方法 - Google Patents
用于丙烯环氧化的钛沸石催化剂的再生方法 Download PDFInfo
- Publication number
- CN119456024A CN119456024A CN202311377139.3A CN202311377139A CN119456024A CN 119456024 A CN119456024 A CN 119456024A CN 202311377139 A CN202311377139 A CN 202311377139A CN 119456024 A CN119456024 A CN 119456024A
- Authority
- CN
- China
- Prior art keywords
- catalyst
- reactor
- stream
- hydrogen peroxide
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/02—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
- C01B39/085—Group IVB- metallosilicates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562115658P | 2015-02-13 | 2015-02-13 | |
| US62/115,658 | 2015-02-13 | ||
| EP15154998 | 2015-02-13 | ||
| EP15154998.7 | 2015-02-13 | ||
| PCT/EP2016/052983 WO2016128538A1 (en) | 2015-02-13 | 2016-02-12 | Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation |
| CN201680020837.XA CN107530693A (zh) | 2015-02-13 | 2016-02-12 | 用于丙烯环氧化的钛沸石催化剂的再生方法 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680020837.XA Division CN107530693A (zh) | 2015-02-13 | 2016-02-12 | 用于丙烯环氧化的钛沸石催化剂的再生方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN119456024A true CN119456024A (zh) | 2025-02-18 |
Family
ID=52472215
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202311377139.3A Pending CN119456024A (zh) | 2015-02-13 | 2016-02-12 | 用于丙烯环氧化的钛沸石催化剂的再生方法 |
| CN201680020837.XA Pending CN107530693A (zh) | 2015-02-13 | 2016-02-12 | 用于丙烯环氧化的钛沸石催化剂的再生方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680020837.XA Pending CN107530693A (zh) | 2015-02-13 | 2016-02-12 | 用于丙烯环氧化的钛沸石催化剂的再生方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10195598B2 (https=) |
| EP (1) | EP3256252B1 (https=) |
| JP (1) | JP6685315B2 (https=) |
| KR (1) | KR102512661B1 (https=) |
| CN (2) | CN119456024A (https=) |
| BR (1) | BR112017017269B1 (https=) |
| MX (1) | MX2017010402A (https=) |
| MY (1) | MY189272A (https=) |
| PL (1) | PL3256252T3 (https=) |
| SG (1) | SG11201706530RA (https=) |
| WO (1) | WO2016128538A1 (https=) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016177814A1 (en) | 2015-05-04 | 2016-11-10 | Basf Se | Process for the preparation of melonal |
| MX2018000609A (es) | 2015-07-15 | 2018-05-07 | Basf Se | Proceso para preparar un arilpropeno. |
| RU2732326C2 (ru) | 2015-07-22 | 2020-09-15 | Басф Се | Способ получения фуран-2,5-дикарбоновой кислоты |
| EP3170828A1 (de) | 2015-11-23 | 2017-05-24 | Basf Se | Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten |
| US10737239B2 (en) | 2015-11-27 | 2020-08-11 | Basf Se | Ultrafast high space-time-yield synthesis of metal-organic frameworks |
| EP3178788A1 (en) | 2015-12-08 | 2017-06-14 | Basf Se | A tin-containing zeolitic material having a bea framework structure |
| US10737944B2 (en) | 2015-12-08 | 2020-08-11 | Basf Se | Tin-containing zeolitic material having a BEA framework structure |
| EP3411357A1 (de) | 2016-02-01 | 2018-12-12 | Basf Se | Verfahren zur herstellung von c4-c15-lactamen |
| JP7039498B2 (ja) | 2016-06-29 | 2022-03-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 液相の存在下でのアルコールの酸化によるアルファ,ベータ不飽和アルデヒドの製造方法 |
| CN109415311B (zh) | 2016-07-08 | 2021-07-23 | 巴斯夫欧洲公司 | 制备有机砜的方法 |
| SG11201811020XA (en) | 2016-07-20 | 2019-02-27 | Basf Se | A process for purifying propylene oxide |
| BR112019001675A2 (pt) | 2016-07-29 | 2019-05-14 | Basf Corporation | processos para a preparação de um material zeolítico, para a preparação de um substrato revestido e para a preparação de um corpo moldado, material zeolítico, método para a redução e utilização de um material zeolítico |
| WO2018096171A1 (en) | 2016-11-28 | 2018-05-31 | Basf Se | Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins |
| EP3568387B1 (en) | 2016-11-30 | 2021-05-05 | Basf Se | Process for the conversion of ethylene glycol to ethylenediamine employing a zeolite catalyst |
| JP2019536774A (ja) | 2016-11-30 | 2019-12-19 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Mor骨格構造の銅変性ゼオライトを用いて、モノエタノールアミンをエチレンジアミンに変換する方法 |
| KR102530741B1 (ko) | 2016-12-13 | 2023-05-09 | 바스프 에스이 | 티탄-함유 제올라이트의 제조 방법 |
| MX2020006560A (es) * | 2017-12-21 | 2020-09-24 | Basf Se | Proceso para la preparacion de aldehidos alfa-beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida. |
| EP3604222A1 (en) * | 2018-07-30 | 2020-02-05 | Evonik Operations GmbH | Process for the purification of hydrogen cyanide |
| AU2018449272B2 (en) * | 2018-11-15 | 2022-09-01 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Method for preparing hierarchical porous titanosilicate TS-1 molecular sieve |
| TW202045484A (zh) * | 2019-02-08 | 2020-12-16 | 德商贏創運營有限公司 | 有機化合物的氧化 |
| CN110252393A (zh) * | 2019-05-21 | 2019-09-20 | 江西农业大学 | 一种用于合成环氧大豆油的钛硅沸石负载镉催化剂、制备方法及应用 |
| CN110075914A (zh) * | 2019-05-28 | 2019-08-02 | 江苏扬农化工集团有限公司 | 一种hppo工艺失活钛硅分子筛催化剂器内再生的方法 |
| EP3812375A1 (en) * | 2019-10-21 | 2021-04-28 | Evonik Operations GmbH | Process for the epoxidation of propene |
| CN112354557B (zh) * | 2020-11-16 | 2023-03-24 | 华东师范大学 | 一种整体式钛沸石催化剂制备方法及其应用 |
| CN112678866B (zh) * | 2020-12-24 | 2023-07-04 | 中国石油化工股份有限公司 | 一种烯烃聚合工业废酸渣资源化处理方法 |
| CN112844468A (zh) * | 2021-01-19 | 2021-05-28 | 中国科学院大连化学物理研究所 | 一种用于丙烯气相环氧化制环氧丙烷的催化剂及其制备方法 |
| WO2022263437A1 (en) | 2021-06-15 | 2022-12-22 | Basf Se | Shutdown method for a process for preparing an olefin oxide |
| CN113368895B (zh) * | 2021-07-13 | 2023-09-29 | 福州大学 | 一种具有高转化率的丙烯气相环氧化催化剂的制备方法 |
| US20250050322A1 (en) * | 2021-09-30 | 2025-02-13 | Basf Corporation | Pretreatment of porous metal oxide catalysts for use in dehydrogenation and other reactions |
| CN118022856B (zh) * | 2022-11-04 | 2026-04-07 | 万华化学集团股份有限公司 | 一种双氧水法环氧氯丙烷环氧化用催化剂的再生工艺 |
| EP4626620A1 (en) | 2022-12-02 | 2025-10-08 | Basf Se | Process for regeneration of an epoxidation reactor |
| CN117504927B (zh) * | 2023-11-10 | 2025-04-29 | 江西师范大学 | 一种负载型Ti-MWW分子筛与金属氧化物的复合催化剂及其制备与应用 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19723751A1 (de) | 1997-06-06 | 1998-12-10 | Basf Ag | Formkörper und Verfahren zu dessen Herstellung |
| US6114551A (en) | 1999-10-04 | 2000-09-05 | Mobil Oil Corporation | Olefin epoxidation catalysts |
| DE10044798A1 (de) * | 2000-09-11 | 2002-04-04 | Basf Ag | Verfahren zur Regenerierung eines Zeolith-Katalysators |
| DE50115570D1 (de) | 2001-01-08 | 2010-09-09 | Evonik Degussa Gmbh | Verfahren zur Epoxidierung von Olefinen |
| DE10320635A1 (de) * | 2003-05-08 | 2004-11-18 | Basf Ag | Verfahren zur Herstellung von Propylenoxid |
| EP1489074A1 (en) | 2003-06-18 | 2004-12-22 | Degussa AG | Process for the epoxidation of propene |
| US20050277542A1 (en) * | 2004-06-14 | 2005-12-15 | Kaminsky Mark P | Catalyst regeneration process |
| KR101166932B1 (ko) | 2005-07-27 | 2012-07-19 | 에스케이이노베이션 주식회사 | 티타늄 함유 분자체 촉매의 재생방법 |
| JP2009233656A (ja) * | 2008-03-05 | 2009-10-15 | Sumitomo Chemical Co Ltd | チタノシリケート触媒の再生方法 |
| CN101480623B (zh) * | 2009-02-24 | 2011-06-08 | 江苏扬农化工集团有限公司 | 一种钛硅分子筛催化剂的再生方法 |
| CN102791376A (zh) * | 2010-03-18 | 2012-11-21 | 住友化学株式会社 | 钛硅酸盐催化剂的再生方法 |
| CN106925344B (zh) | 2012-02-07 | 2020-08-14 | 巴斯夫欧洲公司 | 包括含Ti和Zn的沸石材料的模制品 |
| CN104014365B (zh) * | 2013-02-28 | 2016-08-24 | 中国石油化工股份有限公司 | 一种钛硅分子筛的再生方法 |
| HUE065342T2 (hu) | 2013-07-24 | 2024-05-28 | Basf Se | Titántartalmú zeolit regenerálása |
-
2016
- 2016-02-12 KR KR1020177025695A patent/KR102512661B1/ko active Active
- 2016-02-12 BR BR112017017269-0A patent/BR112017017269B1/pt active IP Right Grant
- 2016-02-12 MY MYPI2017001194A patent/MY189272A/en unknown
- 2016-02-12 CN CN202311377139.3A patent/CN119456024A/zh active Pending
- 2016-02-12 PL PL16704206T patent/PL3256252T3/pl unknown
- 2016-02-12 EP EP16704206.8A patent/EP3256252B1/en active Active
- 2016-02-12 CN CN201680020837.XA patent/CN107530693A/zh active Pending
- 2016-02-12 WO PCT/EP2016/052983 patent/WO2016128538A1/en not_active Ceased
- 2016-02-12 US US15/550,581 patent/US10195598B2/en active Active
- 2016-02-12 JP JP2017542404A patent/JP6685315B2/ja active Active
- 2016-02-12 MX MX2017010402A patent/MX2017010402A/es unknown
- 2016-02-12 SG SG11201706530RA patent/SG11201706530RA/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN107530693A (zh) | 2018-01-02 |
| JP6685315B2 (ja) | 2020-04-22 |
| EP3256252B1 (en) | 2021-04-07 |
| US10195598B2 (en) | 2019-02-05 |
| SG11201706530RA (en) | 2017-09-28 |
| BR112017017269A2 (pt) | 2018-04-17 |
| US20180036723A1 (en) | 2018-02-08 |
| BR112017017269B1 (pt) | 2022-05-24 |
| KR20170117509A (ko) | 2017-10-23 |
| JP2018511459A (ja) | 2018-04-26 |
| MX2017010402A (es) | 2018-05-28 |
| MY189272A (en) | 2022-01-31 |
| KR102512661B1 (ko) | 2023-03-21 |
| WO2016128538A1 (en) | 2016-08-18 |
| PL3256252T3 (pl) | 2021-10-25 |
| EP3256252A1 (en) | 2017-12-20 |
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