CN1161979A - 用于阴离子型内酰胺聚合的液相多组份体系 - Google Patents
用于阴离子型内酰胺聚合的液相多组份体系 Download PDFInfo
- Publication number
- CN1161979A CN1161979A CN97100400A CN97100400A CN1161979A CN 1161979 A CN1161979 A CN 1161979A CN 97100400 A CN97100400 A CN 97100400A CN 97100400 A CN97100400 A CN 97100400A CN 1161979 A CN1161979 A CN 1161979A
- Authority
- CN
- China
- Prior art keywords
- component system
- lactan
- ester
- lactam
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
- C08G69/18—Anionic polymerisation
- C08G69/20—Anionic polymerisation characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
- C08G69/18—Anionic polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
Description
序号 | 组份a) | 份a) | 组份b) | 份b) | 组份c) | 份c) | 备 注 |
1 | N-甲基-己内酰胺 | 50 | Na-CL | 25 | CD | 25 | 黄色,透明液体 |
2 | Irganox1135CL | 6010 | Na-CL | 15 | CL-MDI | 15 | 黄色,透明液体,粘稠的 |
3 | TNPP | 62 | Na-CL | 19 | CD | 19 | 黄色,透明液体,粘稠的 |
4 | BBSADMPU | 1050 | Na-CL | 20 | CD | 20 | 黄色,透明液体 |
5 | TPM | 50 | Na-CL | 25 | Bis-Ox | 25 | 黄色,透明液体 |
6 | TPM | 50 | Na-CL | 25 | CL-IDI | 25 | 黄色,透明液体 |
7 | TPM | 50 | Na-CL | 25 | PCD | 25 | 黄色,透明液体 |
8 | DMSO | 50 | Na-CL | 25 | CD | 25 | 黄色,透明液体 |
9 | 聚乙二醇二甲醚MG250 | 50 | Na-CL | 25 | CD | 25 | 黄色,透明液体 |
10 | 邻苯二羧酸二乙酯 | 50 | Na-CL | 25 | CD | 25 | |
11 | 氨丙基聚四氢呋喃750CL | 6010 | Na-CL | 15 | CL-MDI | 15 | 黄色,透明液体达20℃下呈液状 |
序号 | 内酰胺 | 份 | 体系按照 | 份 | 熔体温度 | 对比时间t | DSC熔点聚合物 | 备注 |
1 | 月桂内酰胺 | 100 | 实施例1 | 3 | 175℃ | 200秒 | 171℃ | |
2 | 月桂内酰胺 | 100 | 实施例2 | 4 | 175℃ | 100秒 | 170℃ | |
3 | 月桂内酰胺 | 100 | 实施例3 | 5 | 162℃ | 270秒 | 172℃ | |
4 | 月桂内酰胺 | 100 | 实施例4 | 3 | 162℃ | 210秒 | 170℃ | BBSA的链调节 |
5 | 月桂内酰胺 | 100 | 实施例5 | 3 | 162℃ | 30秒 | 173℃ | |
6 | 月桂内酰胺 | 100 | 实施例6 | 3 | 175℃ | 70秒 | 170℃ | |
7 | 月桂内酰胺 | 100 | 实施例7 | 3 | 175℃ | 200秒 | 170℃ | |
8 | 月桂内酰胺 | 100 | 实施例8 | 4 | 175℃ | 190秒 | 170℃ | |
9 | 己内酰胺 | 100 | 实施例9 | 5 | 150℃ | 240秒 | 211℃ | |
10 | 月桂内酰胺 | 100 | 实施例10 | 4 | 175℃ | 200秒 | 171℃ | |
11 | 月桂内酰胺 | 100 | 实施例11 | 4 | 175℃ | 70秒 | 172℃ |
Claims (23)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19603305A DE19603305C2 (de) | 1996-01-25 | 1996-01-25 | Flüssiges Mehrkomponentensystem zur Durchführung der anionischen Lactampolymerisation |
DE19603305.5 | 1996-01-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1161979A true CN1161979A (zh) | 1997-10-15 |
CN1104454C CN1104454C (zh) | 2003-04-02 |
Family
ID=7784055
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97100400A Expired - Fee Related CN1104454C (zh) | 1996-01-25 | 1997-01-27 | 用于阴离子型内酰胺聚合的液相多组份体系 |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0786486B1 (zh) |
JP (1) | JP3441908B2 (zh) |
KR (1) | KR100513025B1 (zh) |
CN (1) | CN1104454C (zh) |
AR (1) | AR005517A1 (zh) |
AU (1) | AU722606B2 (zh) |
BR (1) | BR9700770A (zh) |
DE (2) | DE19603305C2 (zh) |
IN (1) | IN190934B (zh) |
PL (1) | PL318123A1 (zh) |
TW (1) | TW459002B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101336261B (zh) * | 2005-11-24 | 2011-06-08 | 原子能委员会 | 己内酰胺组合物、制备不可渗透的元件的方法,及贮罐 |
CN103237832A (zh) * | 2010-10-07 | 2013-08-07 | 巴斯夫欧洲公司 | 制备单体组合物的方法及其在制备聚酰胺模制品中的用途 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19715679C2 (de) * | 1997-04-15 | 1999-06-02 | Inventa Ag | Verfahren zur Herstellung eines katalytisch wirkenden Flüssigsystems zur Auslösung der anionischen Lactam-Polymerisation |
DE19961818C2 (de) | 1999-12-21 | 2002-12-05 | Ems Chemie Ag | Flüssiginitiator zur beschleunigten Durchführung der anionischen Lactampolymerisation, Verfahren zu dessen Herstellung und Verwendung |
DE19961819C2 (de) | 1999-12-21 | 2002-11-14 | Ems Chemie Ag | Flüssiginitiator zur beschleunigten Durchführung der anionischen Lactampolymerisation, Verfahren zu dessen Herstellung und Verwendung |
DE10129049A1 (de) * | 2001-06-15 | 2003-06-26 | Ems Chemie Ag | Flüssigkatalysator |
CN1615215A (zh) * | 2001-12-20 | 2005-05-11 | 埃姆斯化学品有限公司 | 用于生产具有热塑性基质的复合体的方法 |
DE10341811B4 (de) * | 2003-09-10 | 2006-09-28 | Ems-Chemie Ag | Katalysatorlösung zur Durchführung der anionischen Lactampolymerisation, Verfahren zu deren Herstellung und Polyamidformmasse |
CN101007869B (zh) * | 2006-01-27 | 2010-09-08 | 中国石油化工股份有限公司 | 制备己内酰胺均聚物和共聚物的阴离子淤浆聚合方法 |
KR100816068B1 (ko) | 2007-04-10 | 2008-03-24 | 주식회사 에스앤엠 | 난연 mc나일론의 제조방법 및 상기 방법으로 제조된 난연mc나일론 |
US10538624B2 (en) | 2010-10-07 | 2020-01-21 | Basf Se | Process for producing monomer compositions and use of these for producing a polyamide molding |
EP3130622B1 (de) * | 2015-08-11 | 2020-04-08 | LANXESS Deutschland GmbH | Polymerisierbare zusammensetzung |
CN108350169A (zh) * | 2015-09-16 | 2018-07-31 | 巴斯夫欧洲公司 | 内酰胺的阴离子聚合 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU45885A1 (zh) * | 1963-04-23 | 1964-07-03 | ||
DE1495132A1 (de) | 1963-07-17 | 1969-01-30 | Basf Ag | Alkalilactamatloesungen fuer Polymerisationszwecke |
DE1495848C3 (de) * | 1964-12-10 | 1979-01-11 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Poly-e-caprolactam |
US3575938A (en) * | 1969-01-08 | 1971-04-20 | Monsanto Co | Anionic lactam catalyst system |
DE2035733C3 (de) * | 1970-07-18 | 1982-03-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur anionischen Polymerisation von Lactamen und Katalysatorlösungen hierfür |
DE2230732C3 (de) * | 1972-06-23 | 1982-03-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Polyamiden durch die Polymerisation von Lactamen und Katalysatorlösungen hierfür |
DE4002260A1 (de) * | 1990-01-26 | 1991-08-01 | Basf Ag | Katalysatorloesung fuer die anionische polymerisation von lactamen und deren verwendung fuer die anionische polymerisation von caprolactam |
-
1996
- 1996-01-25 DE DE19603305A patent/DE19603305C2/de not_active Expired - Fee Related
-
1997
- 1997-01-17 TW TW086100456A patent/TW459002B/zh not_active IP Right Cessation
- 1997-01-22 AR ARP970100257A patent/AR005517A1/es unknown
- 1997-01-24 PL PL97318123A patent/PL318123A1/xx unknown
- 1997-01-24 DE DE59701456T patent/DE59701456D1/de not_active Expired - Fee Related
- 1997-01-24 EP EP97101102A patent/EP0786486B1/de not_active Expired - Lifetime
- 1997-01-24 KR KR1019970002012A patent/KR100513025B1/ko not_active IP Right Cessation
- 1997-01-24 BR BR9700770A patent/BR9700770A/pt not_active IP Right Cessation
- 1997-01-24 IN IN140CA1997 patent/IN190934B/en unknown
- 1997-01-24 JP JP01105897A patent/JP3441908B2/ja not_active Expired - Fee Related
- 1997-01-24 AU AU12314/97A patent/AU722606B2/en not_active Ceased
- 1997-01-27 CN CN97100400A patent/CN1104454C/zh not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101336261B (zh) * | 2005-11-24 | 2011-06-08 | 原子能委员会 | 己内酰胺组合物、制备不可渗透的元件的方法,及贮罐 |
CN103237832A (zh) * | 2010-10-07 | 2013-08-07 | 巴斯夫欧洲公司 | 制备单体组合物的方法及其在制备聚酰胺模制品中的用途 |
CN103237832B (zh) * | 2010-10-07 | 2016-02-03 | 巴斯夫欧洲公司 | 制备单体组合物的方法及其在制备聚酰胺模制品中的用途 |
CN105601911A (zh) * | 2010-10-07 | 2016-05-25 | 巴斯夫欧洲公司 | 制备单体组合物的方法及其在制备聚酰胺模制品中的用途 |
CN105601911B (zh) * | 2010-10-07 | 2018-07-10 | 巴斯夫欧洲公司 | 制备单体组合物的方法及其在制备聚酰胺模制品中的用途 |
Also Published As
Publication number | Publication date |
---|---|
DE19603305C2 (de) | 1999-07-22 |
BR9700770A (pt) | 1998-10-06 |
AU722606B2 (en) | 2000-08-10 |
PL318123A1 (en) | 1997-08-04 |
EP0786486A3 (de) | 1998-07-29 |
AR005517A1 (es) | 1999-06-23 |
CN1104454C (zh) | 2003-04-02 |
IN190934B (zh) | 2003-09-06 |
TW459002B (en) | 2001-10-11 |
DE19603305A1 (de) | 1997-08-07 |
KR970059201A (ko) | 1997-08-12 |
JPH09208692A (ja) | 1997-08-12 |
KR100513025B1 (ko) | 2005-12-29 |
DE59701456D1 (de) | 2000-05-25 |
EP0786486B1 (de) | 2000-04-19 |
AU1231497A (en) | 1997-07-31 |
JP3441908B2 (ja) | 2003-09-02 |
EP0786486A2 (de) | 1997-07-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: AIMUSI·PATEENTE CO., LTD. Free format text: FORMER OWNER: UHDE INVENTA-FISCHER CO., LTD. Effective date: 20070907 |
|
C41 | Transfer of patent application or patent right or utility model | ||
C56 | Change in the name or address of the patentee |
Owner name: UHDE INVENTA-FISCHER CO., LTD. Free format text: FORMER NAME OR ADDRESS: EMS-INVENTA AG |
|
CP03 | Change of name, title or address |
Address after: Menedorf of Switzerland (8708) koogal Road No. 22 Patentee after: Wood Ivanda-Fischer Co.,Ltd. Address before: Zurich Patentee before: EMS-Inventa AG |
|
TR01 | Transfer of patent right |
Effective date of registration: 20070907 Address after: Swiss Matt / Ames (7013) reichenauer Street Patentee after: EMS-PATENT AG Address before: Menedorf of Switzerland (8708) koogal Road No. 22 Patentee before: Wood Ivanda-Fischer Co.,Ltd. |
|
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |