CN116194493B - 茂金属配合物及由其制备的催化剂 - Google Patents

茂金属配合物及由其制备的催化剂 Download PDF

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Publication number
CN116194493B
CN116194493B CN202180065420.6A CN202180065420A CN116194493B CN 116194493 B CN116194493 B CN 116194493B CN 202180065420 A CN202180065420 A CN 202180065420A CN 116194493 B CN116194493 B CN 116194493B
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group
alkyl
metallocene complex
different
racemic
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Chinese (zh)
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CN116194493A (zh
Inventor
G·基皮阿尼
M·穆斯托宁
P·卡斯特罗
K·卡利奥
I·赛义德
J·考哈宁
T·哈迈来宁
E·赛科宁
J·哈西宁
J·E·克特纳
M·霍夫
A·Z·沃斯科博尼克弗
V·V·伊兹迈尔
D·S·克诺诺维奇
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Borealis GmbH
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Borealis GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN202180065420.6A 2020-07-23 2021-07-23 茂金属配合物及由其制备的催化剂 Active CN116194493B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20187383.3 2020-07-23
EP20187383 2020-07-23
PCT/EP2021/070763 WO2022018293A1 (en) 2020-07-23 2021-07-23 Metallocene complexes and catalysts made therefrom

Publications (2)

Publication Number Publication Date
CN116194493A CN116194493A (zh) 2023-05-30
CN116194493B true CN116194493B (zh) 2025-04-22

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CN202180065420.6A Active CN116194493B (zh) 2020-07-23 2021-07-23 茂金属配合物及由其制备的催化剂
CN202180065417.4A Pending CN116323687A (zh) 2020-07-23 2021-07-23 多峰聚乙烯的制备方法

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CN202180065417.4A Pending CN116323687A (zh) 2020-07-23 2021-07-23 多峰聚乙烯的制备方法

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US (2) US12595325B2 (https=)
EP (2) EP4185622A1 (https=)
JP (2) JP2023535704A (https=)
KR (2) KR20230043168A (https=)
CN (2) CN116194493B (https=)
WO (2) WO2022018293A1 (https=)

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EP4185622A1 (en) * 2020-07-23 2023-05-31 Borealis AG Metallocene complexes and catalysts made therefrom
US20250230307A1 (en) * 2022-04-06 2025-07-17 Borealis Ag Multilayered film
US20250229471A1 (en) * 2022-04-06 2025-07-17 Borealis Ag Multilayered film
WO2023198600A1 (en) 2022-04-11 2023-10-19 Borealis Ag Copolymer
PL4418434T3 (pl) 2022-12-26 2026-02-16 Lg Energy Solution, Ltd. Moduł akumulatorowy oraz pakiet akumulatorowy i pojazd zawierające taki moduł
EP4703426A1 (en) 2024-08-27 2026-03-04 Borealis GmbH Method for controlling polymer material formation

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CN103582669A (zh) * 2011-03-30 2014-02-12 日本聚乙烯株式会社 乙烯类聚合物、聚乙烯类树脂组合物及其用途、烯烃聚合用催化剂成分、包含所述成分的烯烃聚合用催化剂以及使用所述催化剂生产乙烯类聚合物的方法

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CN103582669A (zh) * 2011-03-30 2014-02-12 日本聚乙烯株式会社 乙烯类聚合物、聚乙烯类树脂组合物及其用途、烯烃聚合用催化剂成分、包含所述成分的烯烃聚合用催化剂以及使用所述催化剂生产乙烯类聚合物的方法

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Publication number Publication date
WO2022018290A1 (en) 2022-01-27
KR20230043168A (ko) 2023-03-30
CN116323687A (zh) 2023-06-23
EP4185622A1 (en) 2023-05-31
EP4185621A1 (en) 2023-05-31
KR20230043173A (ko) 2023-03-30
JP2023535705A (ja) 2023-08-21
US20240002560A1 (en) 2024-01-04
CN116194493A (zh) 2023-05-30
JP2023535704A (ja) 2023-08-21
US20250171481A1 (en) 2025-05-29
US12583955B2 (en) 2026-03-24
US12595325B2 (en) 2026-04-07
WO2022018293A1 (en) 2022-01-27

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