KR20230043168A - 메탈로센 착물 및 이로부터 제조된 촉매 - Google Patents

메탈로센 착물 및 이로부터 제조된 촉매 Download PDF

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Publication number
KR20230043168A
KR20230043168A KR1020237006292A KR20237006292A KR20230043168A KR 20230043168 A KR20230043168 A KR 20230043168A KR 1020237006292 A KR1020237006292 A KR 1020237006292A KR 20237006292 A KR20237006292 A KR 20237006292A KR 20230043168 A KR20230043168 A KR 20230043168A
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South Korea
Prior art keywords
group
alkyl
different
same
metallocene complex
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Pending
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KR1020237006292A
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English (en)
Korean (ko)
Inventor
게오르기 키피아니
마르자 무스토넨
파스칼 카스트로
칼레 칼리오
이르판 사이드
지르키 카우하넨
티이나 해맬래이넨
에스코 사이코넨
자르코 하씨넨
조아나 엘비라 케트너
마티아스 호프
알렉산더 제트 보스코보이니코프
뱌체슬라프 브이 이즈머
드미트리 에스 코노노비치
Original Assignee
보레알리스 아게
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Application filed by 보레알리스 아게 filed Critical 보레알리스 아게
Publication of KR20230043168A publication Critical patent/KR20230043168A/ko
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020237006292A 2020-07-23 2021-07-23 메탈로센 착물 및 이로부터 제조된 촉매 Pending KR20230043168A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20187383 2020-07-23
EP20187383.3 2020-07-23
PCT/EP2021/070763 WO2022018293A1 (en) 2020-07-23 2021-07-23 Metallocene complexes and catalysts made therefrom

Publications (1)

Publication Number Publication Date
KR20230043168A true KR20230043168A (ko) 2023-03-30

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KR1020237006292A Pending KR20230043168A (ko) 2020-07-23 2021-07-23 메탈로센 착물 및 이로부터 제조된 촉매
KR1020237006342A Pending KR20230043173A (ko) 2020-07-23 2021-07-23 다봉-분포 폴리에틸렌의 제조 방법

Family Applications After (1)

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Country Status (6)

Country Link
US (2) US12583955B2 (https=)
EP (2) EP4185622A1 (https=)
JP (2) JP2023535705A (https=)
KR (2) KR20230043168A (https=)
CN (2) CN116194493B (https=)
WO (2) WO2022018293A1 (https=)

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CN116194493B (zh) * 2020-07-23 2025-04-22 博里利斯股份公司 茂金属配合物及由其制备的催化剂
EP4504515A1 (en) * 2022-04-06 2025-02-12 Borealis AG Multilayered film
EP4504514A1 (en) * 2022-04-06 2025-02-12 Borealis AG Multilayered film
WO2023198600A1 (en) 2022-04-11 2023-10-19 Borealis Ag Copolymer
EP4418434B1 (en) 2022-12-26 2025-11-19 Lg Energy Solution, Ltd. Battery module, and battery pack and vehicle including same
EP4703426A1 (en) 2024-08-27 2026-03-04 Borealis GmbH Method for controlling polymer material formation

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Publication number Publication date
JP2023535705A (ja) 2023-08-21
WO2022018293A1 (en) 2022-01-27
CN116323687A (zh) 2023-06-23
US20240002560A1 (en) 2024-01-04
EP4185622A1 (en) 2023-05-31
JP2023535704A (ja) 2023-08-21
US12595325B2 (en) 2026-04-07
CN116194493A (zh) 2023-05-30
US20250171481A1 (en) 2025-05-29
KR20230043173A (ko) 2023-03-30
WO2022018290A1 (en) 2022-01-27
EP4185621A1 (en) 2023-05-31
US12583955B2 (en) 2026-03-24
CN116194493B (zh) 2025-04-22

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