CN1153077A - 经碱处理的氧化铝在压力回转吸附中的应用 - Google Patents

经碱处理的氧化铝在压力回转吸附中的应用 Download PDF

Info

Publication number
CN1153077A
CN1153077A CN96120134A CN96120134A CN1153077A CN 1153077 A CN1153077 A CN 1153077A CN 96120134 A CN96120134 A CN 96120134A CN 96120134 A CN96120134 A CN 96120134A CN 1153077 A CN1153077 A CN 1153077A
Authority
CN
China
Prior art keywords
aluminium oxide
adsorbent
pressure
zpc
carbon dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN96120134A
Other languages
English (en)
Other versions
CN1076978C (zh
Inventor
T·C·戈登
F·W·泰勒
A·W·王
M·A·卡尔巴西
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Publication of CN1153077A publication Critical patent/CN1153077A/zh
Application granted granted Critical
Publication of CN1076978C publication Critical patent/CN1076978C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/22—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043—Purging
    • B01D2259/4005—Nature of purge gas
    • B01D2259/40052—Recycled product or process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043—Purging
    • B01D2259/4005—Nature of purge gas
    • B01D2259/40056—Gases other than recycled product or process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/402—Further details for adsorption processes and devices using two beds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent

Abstract

本发明涉及使用通过用一种pH至少为9的碱溶液例如碱性化合物如KHCO3的溶液浸渍原料氧化铝，并在足以避免将所述碱化合物分解成吸附CO2后在减压清洗下不能再生的化合物形式的低温下干燥而获得的改良的氧化铝以便从气流中去除CO2的压力回转吸附。

Description

经碱处理的氧化铝在压力回转吸附中的应用
本发明涉及压力回转吸附(PSA)领域，提供使用改良的氧化铝吸附剂从一气体中去除二氧二碳的PSA的方法。
在空气导入到将氮气和氧气相互分离的低温空气分离过程中之前，需要去除空气中存在的低水平如400ppm的二氧化碳。如果不进行该步骤，则二氧化碳会在空气分离装置中固化。一般用于去除这种二氧化碳的两种方法是温度回转吸附(PSA)的压力回转吸附。
在这两种技术中，吸附床暴露于原料空气流中一段时间以从空气中吸附二氧化碳。此后，关闭原料空气流进入吸附床，并通入清洗气流将吸附剂上所吸附的二氧化带走而将吸附剂再生以备继续使用。在TSA中，通过在再生相中加热吸附剂而将二氧化碳从吸附剂解吸，在PSA中，清洗气的压力低于原料气的压力，压力上的变化被利用来从吸附剂中去除二氧化碳。
通过这些方法还可从原料空气去除其它组分，包括烃类和水。这些吸附方法也可应用于非空气的原料气体上或应用到为用于空气分离设备以外的目的而纯化的空气上。
利用PSA在低温空气分离前从空气中除去二氧化碳的文献有很多，例如US-A-4249915和US-A-4477264。最初的方法是采用二张氧化铝床去除水接着一张沸石如13X床去除二氧化碳。此后，已有建议使用全氧化铝PSA系统，如US-A-5232474中的所述。全氧化铝系统的优点包括较低的吸附剂费用、不需要筛来分离两种不同的吸附剂的容器设计和在泄料和再加压时在吸附容器中更好的热稳定性。但是需要开发改良的二氧化碳吸附量的吸附剂。从而可以达到具较低的基本投资的较小的床尺寸和在解压时较少的损失掉的空隙气体，即可获得较高的空气回收率。
氧化铝在TSA中也作为吸附剂作用，为此已建议将氧化铝进行处理以在其上面形成碱金属氧化物而提高所述氧化铝的吸附能力。作为例子，美国专利4493715提出了通过将原料气体和一基本包含在氧化铝上有1-6％(重量)选自钠、钾和锂的碱金属氧化物的可再生的煅烧吸附剂接触来从烯烃流去除CO2的方法。所述吸附剂是通过将氧化铝和在煅烧时可转变成金属氧化物的碱金属化合物接触而制备的。
美国专利4433981描述了一种从气流中去除CO2的方法，包括所述气流在高达约300℃的温度下与通过含钠或钾氧化物的多孔氧化铝的浸渍制备的吸附剂接触。相应的氧化物可通过用一种可分解的盐浸渍并在350-850℃的温度下煅烧来制备。所述盐包括碱金属碳酸氢盐。
美国专利3557025描述了通过选择性地煅烧氧化铝并和一种碱或碳酸氢铵盐接触而形成至少30％(重量)具MAl(OH)2CO3经验式的碱化氧化铝的制备能吸附SO2的碱化氧化铝的方法。
US-A-3865924描述了细粉状碳酸钾和氧化铝的混合物作为二氧化碳的吸附剂的用途，它和碳酸盐及水反应形成碳酸氢盐。所述吸附剂混合物通过适度地加热如压93℃(200°F)再生。化学计量量的水的存在是必要的，所述氧化铝看来好象基本上只是作为碳酸钾的载体。其它碳酸盐也可使用。
US-A-5232474描述了使用占70-100％床体积的氧化铝从至气除去水和二氧化碳的PSA方法。与大多数一般只含约1％硅石的氧化铝相反的含高达10％(重量)硅石的氧化铝被认为是优选的。硅石是酸性材料。因此本文所提出的使用碱性化合物提高二氧化碳吸附量的观点与该文献正好相反。
我们已发现用没有煅烧成碱金属氧化物的碱处理氧化铝可极大地提高在PSA条件下可再生的氧化铝的二氧化碳吸附量。
因此，本发明提供了从气体中吸附二氧化碳的压力回转吸附方法，包括在第一种压力下将气体暴露到吸附剂上以从气体中除去二氧化碳，并通过减压使吸附剂暴露于低于所述第一种压力的压力下而将所述吸附剂周期性再生，其中所述吸附剂通过用pH至少为9的碱溶液浸渍氧化铝并将其干燥后形成。
所述氧化铝用碱溶液处理的有益效果可能是由于二化碳和在所述氧化铝表面的碱性环境中的氢氧根离子反应形成碳酸氢根离子，但本申请人并不希望受该理论束缚。
浸渍溶液的pH优选至少10，更优选10至12，已经用pH约11的浸渍溶液获得了最佳效果。
浸渍溶液的pH与所述氧化铝的零点的零点负荷(ZPC)以下式相关联也是优选的：
PH≥ZPC-1.4
以下式相关联则更优选：
ZPC＋2≤pH≥ZPC-1.4
浸渍溶液的pH最优选以下式的形式与氧化铝的零点负荷相关联：
ZPC＋2≤pH≥ZPC-1
适合的所述碱溶液是碱金属或铵化合物，例如碱金属或铵的氢氧化物、碳酸盐、碳酸氢盐、磷酸盐和有机酸盐。可用的适合的碱化合物包括钠、钾或铵的碳酸盐、氢氧化物、碳酸氢盐、硝酸盐、甲酸盐、乙酸盐、苯甲酸盐或柠檬酸盐。
用于本发明的最优选的碱性化合物是碳酸钾。
本发明的PSA方法优选应用于在吸附过程前，从含低水平如含不高于1000ppm的二氧化碳的气流中去除二氧化碳。
用于本发明的改性氧化铝可这样制备：先配制具上述适当pH的所选碱性化合物溶液。然后将体积正好足够填满氧化铝的孔而不产生表面润湿的所配溶液加到氧化铝中。可选择溶液的浓度和量使氧化铝上化合物的负载为1-10％(以干重计)。
所处理的氧化铝应在一定温度下干燥，所述温度下高到引起所加入化合物的分解而产生通过降低气压不能逆转而只能象在TSA中通过高温才能逆转的和二氧化碳结合的氧化物。这样，US-A-4433981公开了用碳酸钠或其它化合物的溶液处理氧化铝、在100℃下干燥、然后在575℃下进一步热处理。这里的第二加热步骤产生了不适合于本发明的PSA方法的物质。
用于浸渍用于本发明的氧化铝的化合物最好不会引起水和这种吸附剂反应而使它在所用的压力回转条件下不被解吸。水的不可逆吸附会逐渐妨碍二氧化碳的吸附。如果首先通管一吸附剂将水除去(可逆吸附)，那么这种类型的材料的使用是可接受的。我们已发现如果浸渍氧化铝的化合物是一种磷酸盐如磷酸钾那么就可能遇到水的不可逆吸附。
因此干燥优选在200℃以下进行，更优选在150℃以下进行。
本发明将通过下列实施例进一步说明。在下列实施例中，通过将20g氧化铝置于水中并在24小时后测定pH来测量氧化铝的零点负荷。单位为毫摩尔/克/大气压(mmole/g/atm)的作为初始等温线斜率的亨利定律常数(K1)在250℃50微米压力下脱气16小时并接着在30℃重复地定量供给CO2和随后在50微米压力下抽真空16小时后测定。初始的亨利定律常数(K1)在第一次定量供给CO2时同样地测定。高的K1值表示通过压力回转不可逆而只是通过高温处理才可能可逆的较大的吸附二氧化碳的吸附能力。高的K2值指示本发明所需的高的可再生的(通过压力回转)吸附能力。
                      实施例1
将一种活性氧化铝用各种不同pH的溶液浸渍。在每种情况下，加入正好填满氧化铝的孔体积的足量溶液，所述溶液的浓度是能在120℃干燥后的氧化铝上产生5％(重量比，溶质/固体物总重量)的溶质负荷的浓度。然后测定亨利定律常数，其结果列于下面的表1中。
                                                表1
    吸附剂 浸渍溶液的pH (mmole/g/atm)K1   (mmole/g/atm)K2
 Alcan AA-300      -*     14.8     5.6
 5％Fe(NO3)3     1.2*     1.3     1.2
 5％柠檬酸     1.7*     0.92     0.88
 5％Csl     5.8*     2.0     1.6
 5％NH4HCO3     7.8*     6.3     4.9
 5％(NH4)2CO3     8.9*     6.6     5.8
 5％K2CO3     11.4     81.0     22.8
 5％Na3PO4     12.7     12.4     12.2
 5％NaOH     13.1     340     15.1
                                     *没有按照本发明
表1的结果清楚地表明用酸性溶液浸渍氧化铝降低了这种材料的CO2吸附量。此外，pH9以上的碱性溶液显著提高了对CO2的K2值，指明使氧化铝的表面增加碱性增大了CO2吸附量。
                  实施例2
该实施例证明所获得的吸队附能力的增加取决于pH而不只是所用溶质的本性。为表明这点，将K2CO3浸渍溶液缓冲到13.8、10.4(AlcanAA-300的ZPC)和4的pH值。这些溶液被用来通过水的早期润湿技术进行5％(重量)的浸渍。然后在30℃下如上所述的那样测定CO2等温线。再用亨利定律常数比较低压数据。结果列于表2中。
                            表2
    溶液pH (mmole/g/atm)
 K2CO3调到13.8     6.3
 K2CO3调到10.41     10.8
 K2CO3调到4.0     0.6*
*没有按照本发明
明显酸浸渍的样品性能下降，但强的碱性溶液和弱碱性溶液(pH＝10.41)相比地损失了一些性能。这种出乎意料的结果表明通过使用等于或稍碱于吸附剂氧化铝的自然零点负荷的浸渍获得最高的可再生CO2吸附量。
                  实施例3
制备用各种盐的混合物制备的水溶液而在Alcan AA-300氧化铝上达到5％(重量)浸渍。然后按如上所述在所述样品上测量CO2等温线。测定结果显示于表3中。
                                                表3
样品(均5重量％)     pH (mmole/g/atm)K1 (mmole/g/atm)K2
碳酸氢铵/甲酸铵   7.78*     2.7     2.1
碳酸氢铵/甲酸钠   7.81*     16.2     6.0
碳酸氢铵/碳酸钾   9.0     49.2     13.2
NaOH/碳酸氢铵   11.19     223.5     27.3
碳酸钠   11.4     188     12.4
NaOH/碳酸氢钠   13.34     55.4     14.5
NaOH/甲酸钠   13.58     349.3     11.1
NaOH/苯甲酸钠   13.97     232.7     19.0
                          *发有按照本发明
表3的结果表明当浸渍溶液的pH＞9时增强了可再生的CO2吸附。在所述氧化铝的自然ZPC附近这种增强效果达到最高，随着pH再增高这种效果开始下降，在pH＞13.4时则出现明显下降。在浸渍溶液的这些高pH下，初始亨利定律常数是相当高的。但是真空再生后测得的亨利定律常数的大的降低表明在第一次操作时吸附的大量CO2被化学吸附而在PSA应用中不可去除。
                    实施例4
用碱盐浸渍的氧化铝的效用也通过测量CO2穿透曲线来测定。用含400ppm(V)CO2的原料空气流在100磅/平方英寸(表压)(689.5KPa)的进口压力和22℃的吸附温度下在6英尺×1英寸柱中测量穿透曲线。原料流速是271bmol/t2/hr(131Kgmol/m2/hr)。通过在柱上简间的质量平衡，测定不同吸附剂的CO2的吸附量和CO2传质区长度。穿透测定的结果列于表4中。
                                             表4
吸附剂 (mmole/g)CO2吸附量   英寸(cm)传统区
    AA-300*     0.11     14(35.6)
含5％K2CO3的AA-300     0.25     16(40.6)
含5％Na3PO34的AA-300     0.17     14(35.6)
                         *没有按照本发明
表4的结果表明用碱盐浸渍的氧化铝对空气中CO2的吸附量大于未处理的氧化铝。此外，这种吸附能力的提高是在没有增加吸附CO2所需的传质区长度的情况下获得的。
               实施例5
将实施例4的碱盐浸渍的氧化铝在单柱PSA单元中测定。所述单元由一个6英寸长1英寸直径的单柱构成。
所述吸附剂在PSA循环中如下测定：
(1)以每分钟28标准升的流速在22℃100磅/平方英寸(表压)
(685.5KPa)下将含400ppm CO2的空气导入，
(2)逆流减压到10磅/平方英寸(表压)(60KPa)。
(3)以每分钟15标准升的流速在10磅/平方英寸(表压)(69KPa)
下用N2清洗和
(4)用N2再加压到进料压力。
总循环时间为20分钟，9.8分钟用于进料，9.8分钟用于清洗。
表5列出了在上述的相同循环下三种表4所列的吸附剂的吸附
量。
                                   表5
吸附剂 (kg处理的空气吸附剂)吸附量
    AA-330*     3.54
含5％K2CO3的AA-300     3.87
含5％Na3PO34的AA-300     3.99
              *没有按照本发明
表5所示的结果表明用碱盐浸渍AA-300氧化铝(分别对K2CO3和Na3PO4浸渍的吸附剂来说)提高了所述材料9％和13％的原料空气处理量。
               实施例6
一种5％K2CO3浸渍的氧化铝AA-300样品在一大规模PSA中试验。所述单元含一直径为0.21米、长2半的柱。PSA循环仍按上述的循环步骤进行。但是进料时间为14分钟，再加压时间为2分钟。该测定结果列于表6中。
                                           表6
    进料压力   清洗气/空气摩尔比 (kg空气/kg/hr)AA-300 (kg空气/kg/hr)K2CO3
    10     0.30     3.1     3.5
    6     0.45     2.8     3.3
表6的结果表明在上述试验的处理条件下用K2CO3浸渍的氧化铝可比未处理的氧化铝处理更大量的空气。这意味着和未处理的氧化铝相比，在进料空气流速一定时，可使用较小体积的含经浸渍的氧化铝的床。在实施例5和该实施例的条件下，采用经浸渍的氧化铝比未处理的氧化铝需要量减少10-15％。这种较小的吸附剂物料量和因此导致的较低的床体积然后就转换成在泄料时较少的开关损失，这提高了回收率和降低PSA的操作费用。
尽管已用优选的实施例描述了本发明的情况，但可以理解在本发明的范围内还可进行许多修改和变化。

Claims (10)

1.从气体中吸附二氧化碳的压力回转吸附方法，包括在第一种压力下将气体暴露到通过用至少pH9的碱溶液浸渍氧化铝而形成的吸附剂上而从所述气体中除去二氧化碳，并通过减压使吸附剂暴露于低于所述第一种压力的压力下而将所述吸附剂周期性再生。
2.权利要求1的方法，其中所述浸渍溶液的pH至少为10。
3.权利要求1的方法，其中所述浸渍溶液的pH为10至12。
4.权利要求1的方法，其中所述浸渍溶液的pH是约11。
5.权利要求1的方法，其中所述浸渍溶液的pH与氧化铝的零点负荷的关系如下：
         pH≥zpc-1.4
6.权利要求5的方法，其中所述浸渍溶液的pH与氧化铝的零点负荷的关系如下：
         zpc＋2≤pH≥zpc-1.4
7.权利要求1的方法，其中所述浸渍溶液的pH与氧化铝的零点负荷的关系如下：
         zpc＋1≤pH≥zpc-1
8.权利要求1的方法，其中所述碱性溶液是碱金属或铵化合物的溶液。
9.权利要求1的方法，其中所述化合物选自氢氧化物、碳酸盐、碳酸氢盐、磷酸盐和有机酸盐。
10.权利要求1的方法，其中在吸附处理前，所述气体含至多1000ppm的二氧化碳。
CN96120134A 1995-10-04 1996-09-27 经碱处理的氧化铝在变压吸附中的应用 Expired - Lifetime CN1076978C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/538,876 US5656064A (en) 1995-10-04 1995-10-04 Base treated alumina in pressure swing adsorption
US538,876 1995-10-04

Publications (2)

Publication Number Publication Date
CN1153077A true CN1153077A (zh) 1997-07-02
CN1076978C CN1076978C (zh) 2002-01-02

Family

ID=24148800

Family Applications (1)

Application Number Title Priority Date Filing Date
CN96120134A Expired - Lifetime CN1076978C (zh) 1995-10-04 1996-09-27 经碱处理的氧化铝在变压吸附中的应用

Country Status (10)

Country Link
US (2) US5656064A (zh)
EP (1) EP0766991B1 (zh)
JP (1) JP2785870B2 (zh)
KR (1) KR100192691B1 (zh)
CN (1) CN1076978C (zh)
CA (1) CA2186681C (zh)
DE (1) DE69626913T2 (zh)
ES (1) ES2194959T3 (zh)
NO (1) NO316950B1 (zh)
TW (1) TW306884B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844076B (zh) * 2009-03-26 2012-02-29 宝山钢铁股份有限公司 一种氧化铝球内部聚合污的清理方法
WO2019223111A1 (zh) * 2018-05-21 2019-11-28 成都威能士医疗科技有限公司 利用活性材料或改性活性材料捕获及富集空气中二氧化碳的方法及在捕捉昆虫中的应用

Families Citing this family (135)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE38493E1 (en) 1996-04-24 2004-04-13 Questair Technologies Inc. Flow regulated pressure swing adsorption system
SE509580C2 (sv) * 1996-11-18 1999-02-08 Gibeck Ab Louis Regenererbar absorbatoranordningsapparat, jämte ett förfarande för avlägsnande av koldioxid från utandningsgaser under anestesi samt ett recirkulerande recirkulerande system för anestesi.
US5846295A (en) * 1997-03-07 1998-12-08 Air Products And Chemicals, Inc. Temperature swing adsorption
US5779767A (en) * 1997-03-07 1998-07-14 Air Products And Chemicals, Inc. Use of zeolites and alumina in adsorption processes
US5855650A (en) * 1997-09-09 1999-01-05 Air Products And Chemicals, Inc. Purification of gases using solid adsorbents
US5840099A (en) * 1997-09-16 1998-11-24 Air Products And Chemicals, Inc. Process for the removal of water, CO2, ethane and C3 + hydrocarbons from a gas stream
US5980611A (en) * 1997-09-25 1999-11-09 The Boc Group, Inc. Air purification process
FR2771944B1 (fr) * 1997-12-08 2000-01-14 Air Liquide Procede de purification d'air par adsorption sur alumine calcinee des impuretes co2 et h2o
US6033460A (en) * 1998-04-29 2000-03-07 Millipore Corporation Reactive matrix for removing moisture from a fluorine containing gas and process
US6921597B2 (en) * 1998-09-14 2005-07-26 Questair Technologies Inc. Electrical current generation system
US6106593A (en) * 1998-10-08 2000-08-22 Air Products And Chemicals, Inc. Purification of air
US6423881B1 (en) 1998-10-22 2002-07-23 The Regents Of The University Of Michigan Selective adsorption of alkenes using supported metal compounds
US6215037B1 (en) 1998-10-27 2001-04-10 The Regents Of The University Of Michigan Method for selective adsorption of dienes
US6406523B1 (en) 1999-06-09 2002-06-18 Questair Technologies, Inc. Rotary pressure swing adsorption apparatus
US6280503B1 (en) * 1999-08-06 2001-08-28 Air Products And Chemicals, Inc. Carbon dioxide adsorbents containing magnesium oxide suitable for use at high temperatures
US6370911B1 (en) * 1999-08-13 2002-04-16 Air Liquide America Corporation Nitrous oxide purification system and process
US6284021B1 (en) * 1999-09-02 2001-09-04 The Boc Group, Inc. Composite adsorbent beads for adsorption process
FR2798304B1 (fr) * 1999-09-13 2001-11-09 Air Liquide Utilisation d'une alumine activee pour eliminer le co2 d'un gaz
US7250073B2 (en) * 1999-12-09 2007-07-31 Questair Technologies, Inc. Life support oxygen concentrator
US6514319B2 (en) * 1999-12-09 2003-02-04 Questair Technologies Inc. Life support oxygen concentrator
US6322612B1 (en) * 1999-12-23 2001-11-27 Air Products And Chemicals, Inc. PSA process for removal of bulk carbon dioxide from a wet high-temperature gas
CA2306311C (en) 2000-04-20 2007-04-10 Quest Air Gases Inc. Absorbent laminate structures
US6911569B1 (en) 2000-08-07 2005-06-28 The Regents Of The University Of Michigan Sulfur resistant adsorbents
US6416569B1 (en) 2000-08-28 2002-07-09 The Boc Group, Inc. Temperature swing adsorption process
US6432171B1 (en) 2000-08-28 2002-08-13 The Boc Group, Inc. Thermal swing adsorption process
US6596256B1 (en) 2000-08-28 2003-07-22 The Boc Group, Inc. Synthesis of low silicon sodium X zeolite
US6409800B1 (en) 2000-08-28 2002-06-25 The Boc Group, Inc. Temperature swing adsorption process
EP1344270B1 (en) * 2000-10-27 2017-06-21 Air Products and Chemicals, Inc. Systems and processes for providing hydrogen to fuel cells
US7097925B2 (en) * 2000-10-30 2006-08-29 Questair Technologies Inc. High temperature fuel cell power plant
CA2325072A1 (en) 2000-10-30 2002-04-30 Questair Technologies Inc. Gas separation for molten carbonate fuel cell
US6461411B1 (en) * 2000-12-04 2002-10-08 Matheson Tri-Gas Method and materials for purifying hydride gases, inert gases, and non-reactive gases
AU2002215752A1 (en) * 2000-12-08 2002-06-18 Denis Connor Methods and apparatuses for gas separation by pressure swing adsorption with partial gas product feed to fuel cell power source
CA2329475A1 (en) * 2000-12-11 2002-06-11 Andrea Gibbs Fast cycle psa with adsorbents sensitive to atmospheric humidity
US20020112479A1 (en) * 2001-01-09 2002-08-22 Keefer Bowie G. Power plant with energy recovery from fuel storage
FR2823131B1 (fr) * 2001-04-04 2004-10-22 Pro Catalyse Procede d'elimination des molecules oxygenees organiques presentes dans un effluent organique, utilisant des agglomeres d'alumine
EP1249264A1 (en) * 2001-04-11 2002-10-16 Ammonia Casale S.A. Process for the separation and recovery of carbon dioxide from waste gas or fumes produced by combustible oxidation
EP1483035B1 (en) * 2002-03-14 2011-09-14 QuestAir Technologies Inc. Gas separation by combined pressure swing and displacement purge
US7387849B2 (en) * 2002-03-14 2008-06-17 Questair Technologies Inc. Hydrogen recycle for solid oxide fuel cell
US20030221555A1 (en) * 2002-05-31 2003-12-04 Golden Timothy Christopher Purification of gas streams using composite adsorbent
US7446078B2 (en) * 2002-07-09 2008-11-04 Air Products And Chemicals, Inc. Adsorbent for water removal from ammonia
US7285350B2 (en) * 2002-09-27 2007-10-23 Questair Technologies Inc. Enhanced solid oxide fuel cell systems
US6866702B2 (en) * 2003-01-29 2005-03-15 International Environmental Conservative Association, Inc. Device for absorbing carbon dioxide, and a method for absorbing carbon dioxide
WO2004076017A2 (en) * 2003-02-26 2004-09-10 Questair Technologies Inc. Hydrogen recycle for high temperature fuel cells
US7189280B2 (en) * 2004-06-29 2007-03-13 Questair Technologies Inc. Adsorptive separation of gas streams
WO2006023743A2 (en) * 2004-08-20 2006-03-02 The Trustees Of Columbia University In The City Of New York Laminar scrubber apparatus for capturing carbon dioxide from air and methods of use
US20060051274A1 (en) * 2004-08-23 2006-03-09 Wright Allen B Removal of carbon dioxide from air
US7314847B1 (en) 2004-10-21 2008-01-01 The United States Of America As Represented By The United States Department Of Energy Regenerable sorbents for CO2 capture from moderate and high temperature gas streams
US7828877B2 (en) * 2004-11-05 2010-11-09 Xebec Adsorption, Inc. Separation of carbon dioxide from other gases
EP1855784A1 (en) * 2005-02-02 2007-11-21 Global Research Technologies, LLC Removal of carbon dioxide from air
US7759288B2 (en) 2005-07-27 2010-07-20 Air Products And Chemicals, Inc. Co-formed base-treated aluminas for water and CO2 removal
AU2006275799B8 (en) * 2005-07-28 2011-07-14 Carbon Sink, Inc. Removal of carbon dioxide from air
US9266051B2 (en) 2005-07-28 2016-02-23 Carbon Sink, Inc. Removal of carbon dioxide from air
EP2668992A3 (en) * 2006-03-08 2014-04-02 Kilimanjaro Energy, Inc. Air collector with functionalized ion exchange membrane for capturing ambient CO2
CN101998876B (zh) * 2006-10-02 2015-03-25 环球研究技术有限公司 从空气中提取co2的方法和装置
US7927568B2 (en) * 2006-10-26 2011-04-19 Foster Wheeler Energy Corporation Method of and apparatus for CO2 capture in oxy-combustion
CA2684280C (en) 2007-04-17 2015-02-10 Global Research Technologies, Llc Capture of carbon dioxide (co2) from air
US20090007779A1 (en) * 2007-05-17 2009-01-08 Coignet Philippe A Method and system of providing carbon dioxide-enriched gas for greenhouses
US8529663B2 (en) * 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Process for removing a target gas from a mixture of gases by swing adsorption
US8444750B2 (en) * 2007-05-18 2013-05-21 Exxonmobil Research And Engineering Company Removal of CO2, N2, or H2S from gas mixtures by swing adsorption with low mesoporosity adsorbent contactors
AU2008254512B2 (en) * 2007-05-18 2012-03-01 Exxonmobil Upstream Research Company Process for removing a target gas from a mixture of gases by thermal swing adsorption
EP2164603B1 (en) * 2007-05-18 2016-10-05 ExxonMobil Research and Engineering Company Temperature swing adsorption of co2 from flue gas using a parallel channel contactor
US7959720B2 (en) 2007-05-18 2011-06-14 Exxonmobil Research And Engineering Company Low mesopore adsorbent contactors for use in swing adsorption processes
US8529662B2 (en) 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Removal of heavy hydrocarbons from gas mixtures containing heavy hydrocarbons and methane
US8545602B2 (en) 2007-05-18 2013-10-01 Exxonmobil Research And Engineering Company Removal of CO2, N2, and H2S from gas mixtures containing same
TWI422739B (zh) * 2007-06-13 2014-01-11 Wormser Energy Solutions Inc 適度氣化複合循環發電設備
US8133305B2 (en) * 2007-11-05 2012-03-13 Kilimanjaro Energy, Inc. Removal of carbon dioxide from air
US8377173B2 (en) * 2007-11-08 2013-02-19 The University Of Akron Amine absorber for carbon dioxide capture and processes for making and using the same
US8262774B2 (en) * 2007-11-20 2012-09-11 Kilimanjaro Energy, Inc. Air collector with functionalized ion exchange membrane for capturing ambient CO2
US20090232861A1 (en) * 2008-02-19 2009-09-17 Wright Allen B Extraction and sequestration of carbon dioxide
WO2009149292A1 (en) * 2008-06-04 2009-12-10 Global Research Technologies, Llc Laminar flow air collector with solid sorbent materials for capturing ambient co2
WO2010099626A1 (en) * 2009-03-05 2010-09-10 G4 Insights Inc. Process and system for thermochemical conversion of biomass
WO2010109477A2 (en) 2009-03-27 2010-09-30 Council Of Scientific & Industrial Research A process for the preparation of molecular sieve adsorbent for the size/shape selective adsorption of carbon dioxide from its gaseous mixture with nitrogen
WO2010113169A1 (en) 2009-03-31 2010-10-07 Council Of Scientific & Industrial Research A process for the preparation and use of pentasil type zeolite for the selective adsorption of carbon dioxide from flue gas
US8137435B2 (en) * 2009-03-31 2012-03-20 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Carbon dioxide recovery from low concentration sources
EP2478074A4 (en) * 2009-09-18 2013-11-20 Wormser Energy Solutions Inc SYSTEMS, DEVICES AND METHODS FOR CALCIUM BONDING
US9873840B2 (en) 2009-09-18 2018-01-23 Wormser Energy Solutions, Inc. Integrated gasification combined cycle plant with char preparation system
WO2011060539A1 (en) 2009-11-18 2011-05-26 G4 Insights Inc. Method and system for biomass hydrogasification
EP2501788A4 (en) 2009-11-18 2013-12-04 G4 Insights Inc BY SORPTION REINFORCED METHANIZATION OF BIOMASS
MY170412A (en) * 2010-03-09 2019-07-27 Univ Sains Malaysia Method for capturing and fixing carbon dioxide and apparatus for carrying out said method
BR112012030016B8 (pt) 2010-05-24 2021-05-18 Siluria Technologies Inc processo para preparar etileno a partir de metano e método para preparar um produto a jusante de etileno
US8383871B1 (en) 2010-09-03 2013-02-26 Brian G. Sellars Method of hydrogasification of biomass to methane with low depositable tars
KR101267986B1 (ko) * 2010-11-22 2013-05-27 한국철도기술연구원 이산화탄소 흡착제의 제조방법 및 상기 흡착제를 이용한 다단 흡착필터
EA029867B1 (ru) * 2011-05-24 2018-05-31 Силурия Текнолоджиз, Инк. Катализаторы для нефтехимического катализа
US20130158322A1 (en) 2011-11-29 2013-06-20 Siluria Technologies, Inc. Polymer templated nanowire catalysts
US9133079B2 (en) 2012-01-13 2015-09-15 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
US9446397B2 (en) 2012-02-03 2016-09-20 Siluria Technologies, Inc. Method for isolation of nanomaterials
CA3125016C (en) 2012-05-24 2024-04-30 Lummus Technology Llc Catalytic forms and formulations
CA2874526C (en) 2012-05-24 2022-01-18 Siluria Technologies, Inc. Oxidative coupling of methane systems and methods
US8734571B2 (en) 2012-05-31 2014-05-27 Air Products And Chemicals, Inc. Purification of air
SG11201406800UA (en) 2012-05-31 2014-11-27 Air Prod & Chem Purification of air
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
US20140175336A1 (en) * 2012-12-20 2014-06-26 Exxonmobil Research And Engineering Company Co2 capture processes using rotary wheel configurations
EP2969184A4 (en) 2013-03-15 2016-12-21 Siluria Technologies Inc CATALYSTS FOR PETROCHEMICAL CATALYSIS
CN103223288B (zh) * 2013-04-08 2015-01-21 河南心连心化肥有限公司 变压吸附脱碳装置及工艺
US9333485B1 (en) * 2013-04-22 2016-05-10 U.S. Department Of Energy Preparation of sorbent pellets with high integrity for sorption of CO2 from gas streams
US9079160B2 (en) * 2013-04-22 2015-07-14 U.S. Department Of Energy Method of preparation of a CO2 removal sorbent with high chemical stability during multiple cycles
US9108145B2 (en) 2013-05-16 2015-08-18 Air Products And Chemicals, Inc. Purification of air
WO2015006268A2 (en) * 2013-07-08 2015-01-15 Exxonmobil Research And Engineering Company Rotary moving bed for co2 separation and use of same
WO2015006285A2 (en) * 2013-07-08 2015-01-15 Exxonmobil Research And Engineering Company Compositions for carbon dioxide separation using steam regeneration, and method for preparing same
WO2015052726A1 (en) 2013-10-09 2015-04-16 Reliance Industries Limited A single compression system and process for capturing carbon dioxide
US9931593B2 (en) 2013-10-09 2018-04-03 Reliance Industries Limited Multi-compression system and process for capturing carbon dioxide
WO2015081122A2 (en) 2013-11-27 2015-06-04 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CN106068323B (zh) 2014-01-08 2019-09-06 希路瑞亚技术公司 乙烯成液体的系统和方法
WO2015106023A1 (en) 2014-01-09 2015-07-16 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
US10988379B2 (en) * 2014-03-27 2021-04-27 Georgia Tech Research Corporation Reactor for steam reforming and methods of use thereof
WO2015168601A2 (en) 2014-05-02 2015-11-05 Siluria Technologies, Inc. Heterogeneous catalysts
HUE054014T2 (hu) 2014-09-17 2021-08-30 Lummus Technology Inc Katalizátorok metán oxidatív csatolására és etán oxidatív dehidrogenálására
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
EP3362425B1 (en) 2015-10-16 2020-10-28 Lummus Technology LLC Separation methods and systems for oxidative coupling of methane
CA3019396A1 (en) 2016-04-13 2017-10-19 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
US20180169561A1 (en) 2016-12-19 2018-06-21 Siluria Technologies, Inc. Methods and systems for performing chemical separations
WO2018160956A1 (en) * 2017-03-03 2018-09-07 Exxonmobil Research And Engineering Company Calcination of co2/h2o displacement desorption sorbents
US20180264433A1 (en) 2017-03-17 2018-09-20 Air Products And Chemicals, Inc. Alkali-Promoted Activated Alumina Adsorbent
US10252242B2 (en) 2017-03-17 2019-04-09 Air Products And Chemicals, Inc. Alkali-promoted activated alumina adsorbent
PL3375517T3 (pl) 2017-03-17 2023-10-02 Air Products And Chemicals, Inc. Adsorbent z aktywowanego tlenku glinu promowanego alkalami
US11001542B2 (en) 2017-05-23 2021-05-11 Lummus Technology Llc Integration of oxidative coupling of methane processes
WO2019010498A1 (en) 2017-07-07 2019-01-10 Siluria Technologies, Inc. SYSTEMS AND METHODS FOR OXIDIZING METHANE COUPLING
US10765991B2 (en) 2017-08-10 2020-09-08 Air Products And Chemicals, Inc. Rapid cycle pressure swing adsorption process and adsorbent laminates for use therein
WO2019161114A1 (en) 2018-02-16 2019-08-22 Carbon Sink, Inc. Fluidized bed extractors for capture of co2 from ambient air
US11148092B2 (en) 2018-06-27 2021-10-19 University Of South Carolina Temperature-vacuum swing adsorption process for capture of CO2
US11007473B2 (en) 2018-07-09 2021-05-18 University Of South Carolina Removal of water vapor from streams containing carbon dioxide and/or carbon monoxide
CN109718630A (zh) * 2019-03-01 2019-05-07 西安鸿钧睿泽新材料科技有限公司 一种耦合联产制合成气的系统及方法
WO2021108395A1 (en) 2019-11-25 2021-06-03 Wormser Energy Solutions, Inc. Char preparation system and gasifier for all-steam gasification with carbon capture
US11596895B2 (en) 2020-07-17 2023-03-07 Air Products And Chemicals, Inc. Radial adsorber, adsorption system, and adsorption methods
US11731075B2 (en) 2020-08-10 2023-08-22 Praxair Technology, Inc. High recovery process for purification of multicomponent gases
RU2760325C1 (ru) * 2020-11-27 2021-11-24 Федеральное государственное бюджетное учреждение науки «Федеральный исследовательский центр «Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук» (Институт катализа СО РАН, ИК СО РАН) Поглотитель диоксида углерода, способ его приготовления и способ очистки газовых смесей
RU2768831C1 (ru) * 2021-07-05 2022-03-24 Николай Конкордиевич Зайцев Способ очистки газовой смеси от углекислого газа
US20230027070A1 (en) 2021-07-21 2023-01-26 Air Products And Chemicals, Inc. Air separation apparatus, adsorber, and method
US20230087673A1 (en) 2021-09-23 2023-03-23 Air Products And Chemicals, Inc. Pre-purification arrangement for air separation and method of hybrid air purification
WO2024080190A1 (ja) * 2022-10-13 2024-04-18 国立大学法人広島大学 二酸化炭素吸着剤、二酸化炭素吸着剤の使用、二酸化炭素分離方法、二酸化炭素回収・貯留プラント、及び二酸化炭素回収・貯留方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3141729A (en) * 1960-07-11 1964-07-21 United Aircraft Corp Gels and method of making
US3232028A (en) * 1962-07-02 1966-02-01 Isomet Corp Composition and method for absorption and regeneration of carbon dioxide
US3557025A (en) * 1968-05-13 1971-01-19 Kaiser Aluminium Chem Corp Method of producing alkalized alumina and products produced thereby
US3627478A (en) * 1969-08-12 1971-12-14 Mine Safety Appliances Co Method for separating carbon dioxide from other gases
US3865924A (en) * 1972-03-03 1975-02-11 Inst Gas Technology Process for regenerative sorption of CO{HD 2
NL7307675A (zh) * 1972-06-16 1973-12-18
US4264340A (en) * 1979-02-28 1981-04-28 Air Products And Chemicals, Inc. Vacuum swing adsorption for air fractionation
US4249915A (en) * 1979-05-30 1981-02-10 Air Products And Chemicals, Inc. Removal of water and carbon dioxide from air
US4233038A (en) * 1979-08-06 1980-11-11 Air Products And Chemicals, Inc. Reactivation system for water-carbon dioxide adsorbers
US4433981A (en) * 1981-02-18 1984-02-28 Shell Oil Company CO2 Removal from gaseous streams
DE3143993A1 (de) * 1981-11-05 1983-05-11 Bayer Ag, 5090 Leverkusen Molekularsieb-zeolith fuer die gewinnung von wasserstoff mit der druckwechsel-adsorptions-technik
US4493715A (en) * 1982-12-20 1985-01-15 Phillips Petroleum Company Removal of carbon dioxide from olefin containing streams
CA1208141A (en) * 1982-12-20 1986-07-22 John P. Hogan Removal of carbon dioxide from olefin containing streams
US4477264A (en) * 1983-03-30 1984-10-16 Air Products And Chemicals, Inc. Pressure swing adsorption process for a medical oxygen generator for home use
JPS61157322A (ja) * 1984-12-28 1986-07-17 Kogyo Kaihatsu Kenkyusho Ｃｏ↓２含有ガスからｃｏ↓２を分離濃縮する方法
JPS6277531A (ja) * 1985-09-27 1987-04-09 Mitsubishi Electric Corp 加湿器
US4711645A (en) * 1986-02-10 1987-12-08 Air Products And Chemicals, Inc. Removal of water and carbon dioxide from atmospheric air
US4795735A (en) * 1986-09-25 1989-01-03 Aluminum Company Of America Activated carbon/alumina composite
JPS63107720A (ja) * 1986-10-23 1988-05-12 Taiyo N P S Kk 空気中の水分および炭酸ガスの分離除去方法
GB8714232D0 (en) * 1987-06-17 1987-07-22 Ici Plc Sulphur compounds removal
US4855276A (en) * 1987-09-02 1989-08-08 Purafil, Inc. Solid filtration medium incorporating alumina and carbon
JP2651605B2 (ja) * 1988-09-09 1997-09-10 日本パイオニクス株式会社 二酸化炭素の除去方法
US4937059A (en) * 1988-09-26 1990-06-26 Phillips Petroleum Company Absorption and desorption of carbon dioxide
FR2641711B1 (fr) * 1989-01-18 1993-10-22 Rhone Poulenc Chimie Adsorbant pour purification de polyolefines et procede de fabrication de celui-ci
CA2014500C (en) * 1989-04-17 1996-09-24 Yoshitsugu Sakata Acidic gas absorbent and process for production thereof
US5232474A (en) * 1990-04-20 1993-08-03 The Boc Group, Inc. Pre-purification of air for separation
JPH04200742A (ja) * 1990-11-30 1992-07-21 Kuraray Chem Corp 炭酸ガス吸着剤
US5186727A (en) * 1991-06-07 1993-02-16 Allied-Signal Inc. Mixed-metal oxide absorbent for carbon dioxide and water removal
JPH0549918A (ja) * 1991-08-10 1993-03-02 Kuraray Chem Corp 炭酸ガス吸着剤
US5214019A (en) * 1992-02-24 1993-05-25 United Technologies Corporation Enhancing carbon dioxide sorption rates using hygroscopic additives

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844076B (zh) * 2009-03-26 2012-02-29 宝山钢铁股份有限公司 一种氧化铝球内部聚合污的清理方法
WO2019223111A1 (zh) * 2018-05-21 2019-11-28 成都威能士医疗科技有限公司 利用活性材料或改性活性材料捕获及富集空气中二氧化碳的方法及在捕捉昆虫中的应用

Also Published As

Publication number Publication date
TW306884B (zh) 1997-06-01
CN1076978C (zh) 2002-01-02
DE69626913D1 (de) 2003-04-30
EP0766991A1 (en) 1997-04-09
JPH09103631A (ja) 1997-04-22
JP2785870B2 (ja) 1998-08-13
NO316950B1 (no) 2004-07-05
EP0766991B1 (en) 2003-03-26
US5917136A (en) 1999-06-29
CA2186681C (en) 2002-04-23
KR100192691B1 (ko) 1999-06-15
NO964167L (no) 1997-04-07
CA2186681A1 (en) 1997-04-05
KR970020157A (ko) 1997-05-28
DE69626913T2 (de) 2003-11-13
ES2194959T3 (es) 2003-12-01
NO964167D0 (no) 1996-10-02
US5656064A (en) 1997-08-12

Similar Documents

Publication Publication Date Title
CN1076978C (zh) 经碱处理的氧化铝在变压吸附中的应用
AU768949B2 (en) Zeolite adsorbents, method for obtaining them and their use for removing carbonates from a gas stream
EP0862936B9 (en) The use of zeolites and alumina in adsorption processes
Hao et al. Activated carbons prepared from hydrothermally carbonized waste biomass used as adsorbents for CO2
US5074892A (en) Air separation pressure swing adsorption process
EP3706898B1 (en) Materials for the direct capture of carbon dioxide from atmospheric air
CN1111442C (zh) 采用煅烧氧化铝吸附杂质二氧化碳和水净化空气的方法
CN1198358A (zh) 变温吸附
EP2420551A1 (en) Use of a microporous crystalline material of zeolitic nature with rho structure in natural gas processing
CN1031358A (zh) 由空气生产高纯氧气的方法
AU702778B1 (en) Process for the removal of water, CO2, ethane and CO3+ hydrocarbons from gas stream
AU2004305251A1 (en) Method of purifying a gas stream contaminated by CO2 and one or more hydrocarbons and/or nitrogen oxides by adsorption on an aggregated zeolitic adsorbent
JP2002177773A (ja) モノリス吸着剤の活性化方法
EP1574246A1 (en) Periodic high temperature regeneration of thermal swing adsorption systems
CN114835142B (zh) 一种从工业窑炉尾气中回收二氧化碳并生产碳酸锂的方法
CN1019475B (zh) 变压吸附法从混合气中提取二氧化碳
CN112755961B (zh) 一种负载有MgO的活性炭及其制备方法和应用
RU2244586C1 (ru) Поглотитель диоксида углерода и способ удаления диоксида углерода из газовых смесей
EP1188478B1 (en) Process for producing an adsorbent for gas separation processes
CN116440855B (zh) 一种净化材料及其制备方法和应用
JP4438145B2 (ja) 一酸化炭素の吸着分離方法
JPH05184850A (ja) 窒素濃縮方法
WO1996015842A1 (en) Air separation process
JPS6139089B2 (zh)

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term

Granted publication date: 20020102

EXPY Termination of patent right or utility model