CN1150809A - 由乙烯、α-烯烃和任选的二烯烃制备弹性体聚合物的方法 - Google Patents

由乙烯、α-烯烃和任选的二烯烃制备弹性体聚合物的方法 Download PDF

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Publication number
CN1150809A
CN1150809A CN95193633.6A CN95193633A CN1150809A CN 1150809 A CN1150809 A CN 1150809A CN 95193633 A CN95193633 A CN 95193633A CN 1150809 A CN1150809 A CN 1150809A
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CN
China
Prior art keywords
polymer
group
elastomeric
molecular weight
ethylene
Prior art date
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Pending
Application number
CN95193633.6A
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English (en)
Chinese (zh)
Inventor
B·J·穆斯肯斯
J·伦吉马
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
DSM NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM NV filed Critical DSM NV
Publication of CN1150809A publication Critical patent/CN1150809A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN95193633.6A 1994-05-06 1995-04-18 由乙烯、α-烯烃和任选的二烯烃制备弹性体聚合物的方法 Pending CN1150809A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9400758A NL9400758A (nl) 1994-05-06 1994-05-06 Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
NL9400758 1994-05-06

Publications (1)

Publication Number Publication Date
CN1150809A true CN1150809A (zh) 1997-05-28

Family

ID=19864171

Family Applications (1)

Application Number Title Priority Date Filing Date
CN95193633.6A Pending CN1150809A (zh) 1994-05-06 1995-04-18 由乙烯、α-烯烃和任选的二烯烃制备弹性体聚合物的方法

Country Status (12)

Country Link
US (1) US5902867A (enExample)
EP (1) EP0758346B1 (enExample)
JP (1) JPH09512848A (enExample)
CN (1) CN1150809A (enExample)
AU (1) AU2149895A (enExample)
BR (1) BR9507707A (enExample)
CA (1) CA2189570A1 (enExample)
DE (1) DE69503778T2 (enExample)
MX (1) MX9605423A (enExample)
NL (1) NL9400758A (enExample)
TW (1) TW294681B (enExample)
WO (1) WO1995030698A1 (enExample)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1930193B (zh) * 2003-06-05 2011-03-23 尤尼威蒂恩技术有限责任公司 金属茂类和生产聚乙烯的方法
US9428600B2 (en) 2013-06-28 2016-08-30 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
US9493593B2 (en) 2013-06-28 2016-11-15 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
US9637579B2 (en) 2013-06-28 2017-05-02 Lg Chem, Ltd. Elastic terpolymer including diene group and preparation method thereof
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
CN109563326A (zh) * 2016-06-30 2019-04-02 陶氏环球技术有限责任公司 基于乙烯/α-烯烃/多烯的组合物

Families Citing this family (21)

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BR9406903A (pt) * 1993-06-21 1996-04-02 Dsm Nv Processo para a preparação de copolimeros de etileno de baixo peso molecular com pelo menos um outro 1-alqueno
ES2116188B1 (es) * 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
WO1997001586A1 (en) * 1995-06-29 1997-01-16 Dsm N.V. Elastomeric copolymer
US5814714A (en) * 1995-11-30 1998-09-29 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
NL1006346C2 (nl) * 1997-06-18 1998-12-21 Dsm Nv Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen.
JP4958130B2 (ja) * 1997-06-27 2012-06-20 ランクセス エラストマーズ ビー．ブイ． 弾性共重合体及びその製造方法
NL1006421C2 (nl) * 1997-06-27 1998-12-29 Dsm Nv Elastomeer copolymeer.
DE69943133D1 (de) 1998-11-02 2011-02-24 Dow Global Technologies Inc Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung
MY137183A (en) 2001-03-16 2009-01-30 Dow Global Technologies Inc Method of making interpolymers and products made therefrom
KR101446685B1 (ko) * 2014-04-04 2014-10-06 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585206B1 (ko) 2013-07-22 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
WO2015142547A1 (en) 2014-03-21 2015-09-24 Exxonmobil Chemical Patents Inc. Process to produce ethylene propylene copolymers
KR101655392B1 (ko) 2014-04-21 2016-09-07 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101973191B1 (ko) 2015-06-05 2019-04-26 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
KR101926833B1 (ko) 2015-06-05 2019-03-07 주식회사 엘지화학 메탈로센 화합물
JP2019059895A (ja) * 2017-09-28 2019-04-18 三井化学株式会社 防振ゴム用組成物および防振ゴム製品
JP2019059893A (ja) * 2017-09-28 2019-04-18 三井化学株式会社 防振ゴム用組成物および防振ゴム製品
JP2019059894A (ja) * 2017-09-28 2019-04-18 三井化学株式会社 防振ゴム用組成物および防振ゴム製品
CN111868166A (zh) 2018-02-14 2020-10-30 陶氏环球技术有限责任公司 具有改进的长期热老化性能的乙烯/α-烯烃互聚物组合物
WO2020220244A1 (en) 2019-04-30 2020-11-05 Dow Global Technologies Llc Ethylene/propylene/nonconjugated diene interpolymer composition
US11866530B2 (en) 2019-04-30 2024-01-09 Dow Global Technologies Llc Ethylene/propylene/nonconjugated diene interpolymer composition

Family Cites Families (14)

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Publication number Priority date Publication date Assignee Title
FR2322883A1 (fr) * 1975-09-02 1977-04-01 Michelin & Cie Elastomeres du type e p t, et articles comportant de tels elastomeres
JPH0618942B2 (ja) * 1985-05-17 1994-03-16 日本合成ゴム株式会社 押し出し加工性に優れたゴム組成物
US5001205A (en) * 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
JPH05500080A (ja) * 1989-09-06 1993-01-14 エクソン・ケミカル・パテンツ・インク 狭いｍｗｄと広い組成分布を有するアルファーオレフィンコポリマー
ES2087339T3 (es) * 1991-05-27 1996-07-16 Hoechst Ag Procedimiento para la preparacion de poliolefinas con amplia distribucion de masas moleculares.
DE4139261A1 (de) * 1991-11-29 1993-06-03 Basf Ag Ethylen-copolymerisate niederer dichte
DE59305691D1 (de) * 1992-05-26 1997-04-17 Hoechst Ag Verfahren zur Herstellung von Polyolefinwachsen
ES2114978T3 (es) * 1992-08-03 1998-06-16 Targor Gmbh Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos con ligandos indenilo de substitucion especial.
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1930193B (zh) * 2003-06-05 2011-03-23 尤尼威蒂恩技术有限责任公司 金属茂类和生产聚乙烯的方法
US9428600B2 (en) 2013-06-28 2016-08-30 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
US9493593B2 (en) 2013-06-28 2016-11-15 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
US9637579B2 (en) 2013-06-28 2017-05-02 Lg Chem, Ltd. Elastic terpolymer including diene group and preparation method thereof
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
CN109563326A (zh) * 2016-06-30 2019-04-02 陶氏环球技术有限责任公司 基于乙烯/α-烯烃/多烯的组合物

Also Published As

Publication number Publication date
JPH09512848A (ja) 1997-12-22
MX9605423A (es) 1997-12-31
US5902867A (en) 1999-05-11
BR9507707A (pt) 1997-08-19
DE69503778T2 (de) 1999-04-15
AU2149895A (en) 1995-11-29
DE69503778D1 (de) 1998-09-03
CA2189570A1 (en) 1995-11-16
TW294681B (enExample) 1997-01-01
EP0758346A1 (en) 1997-02-19
WO1995030698A1 (en) 1995-11-16
EP0758346B1 (en) 1998-07-29
NL9400758A (nl) 1995-12-01

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