DE69503778D1 - Verfahren zur herstellung eines elastomeren aus ethylen, alfa-olefin und gegebenfalls dien - Google Patents

Verfahren zur herstellung eines elastomeren aus ethylen, alfa-olefin und gegebenfalls dien

Info

Publication number
DE69503778D1
DE69503778D1 DE69503778T DE69503778T DE69503778D1 DE 69503778 D1 DE69503778 D1 DE 69503778D1 DE 69503778 T DE69503778 T DE 69503778T DE 69503778 T DE69503778 T DE 69503778T DE 69503778 D1 DE69503778 D1 DE 69503778D1
Authority
DE
Germany
Prior art keywords
alfa
olefin
elastomer
ethylene
serve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69503778T
Other languages
English (en)
Other versions
DE69503778T2 (de
Inventor
Jacob Renkema
Bernardus Muskens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
DSM NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM NV filed Critical DSM NV
Publication of DE69503778D1 publication Critical patent/DE69503778D1/de
Application granted granted Critical
Publication of DE69503778T2 publication Critical patent/DE69503778T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69503778T 1994-05-06 1995-04-18 Verfahren zur herstellung eines elastomeren aus ethylen, alfa-olefin und gegebenfalls dien Expired - Fee Related DE69503778T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9400758A NL9400758A (nl) 1994-05-06 1994-05-06 Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
PCT/NL1995/000140 WO1995030698A1 (en) 1994-05-06 1995-04-18 Process for the preparation of an elastomeric polymer from ethylene, alpha-olefin and optionally diene

Publications (2)

Publication Number Publication Date
DE69503778D1 true DE69503778D1 (de) 1998-09-03
DE69503778T2 DE69503778T2 (de) 1999-04-15

Family

ID=19864171

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69503778T Expired - Fee Related DE69503778T2 (de) 1994-05-06 1995-04-18 Verfahren zur herstellung eines elastomeren aus ethylen, alfa-olefin und gegebenfalls dien

Country Status (12)

Country Link
US (1) US5902867A (de)
EP (1) EP0758346B1 (de)
JP (1) JPH09512848A (de)
CN (1) CN1150809A (de)
AU (1) AU2149895A (de)
BR (1) BR9507707A (de)
CA (1) CA2189570A1 (de)
DE (1) DE69503778T2 (de)
MX (1) MX9605423A (de)
NL (1) NL9400758A (de)
TW (1) TW294681B (de)
WO (1) WO1995030698A1 (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1042639C (zh) * 1993-06-21 1999-03-24 Dsm有限公司 乙烯与至少一种其它1－烯烃的低分子量共聚物的制备方法
ES2116188B1 (es) * 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
EP0835271A1 (de) * 1995-06-29 1998-04-15 Dsm N.V. Elastomeres copolymer
US5814714A (en) * 1995-11-30 1998-09-29 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
NL1006346C2 (nl) * 1997-06-18 1998-12-21 Dsm Nv Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen.
WO1999000434A1 (en) * 1997-06-27 1999-01-07 Dsm N.V. Elastomeric copolymer and process for the preparation thereof
NL1006421C2 (nl) * 1997-06-27 1998-12-29 Dsm Nv Elastomeer copolymeer.
JP5276757B2 (ja) 1998-11-02 2013-08-28 ダウ グローバル テクノロジーズ エルエルシー 剪断減粘性エチレン／α−オレフィンインターポリマーおよびそれらの製造法
MY137183A (en) * 2001-03-16 2009-01-30 Dow Global Technologies Inc Method of making interpolymers and products made therefrom
US6911508B2 (en) * 2003-06-05 2005-06-28 Univation Technologies, Llc Class of metallocenes and method of producing polyethylene
KR101585206B1 (ko) 2013-07-22 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
US9493593B2 (en) 2013-06-28 2016-11-15 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
CN104736579A (zh) 2013-06-28 2015-06-24 株式会社Lg化学 弹性二烯三元共聚物及其制备方法
EP2883889A4 (de) 2013-06-28 2016-06-01 Lg Chemical Ltd Ternäres elastisches copolymer mit einem dien und verfahren zur herstellung davon
KR101446685B1 (ko) * 2014-04-04 2014-10-06 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
JP6355815B2 (ja) 2014-03-21 2018-07-11 エクソンモービル・ケミカル・パテンツ・インク エチレンプロピレンコポリマーを製造する方法
KR101655392B1 (ko) 2014-04-21 2016-09-07 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101926833B1 (ko) 2015-06-05 2019-03-07 주식회사 엘지화학 메탈로센 화합물
KR101973191B1 (ko) 2015-06-05 2019-04-26 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
EP3478762A1 (de) * 2016-06-30 2019-05-08 Dow Global Technologies, LLC Auf ethylen/alpha-olefin/polyen basierende zusammensetzungen
JP2019059893A (ja) * 2017-09-28 2019-04-18 三井化学株式会社 防振ゴム用組成物および防振ゴム製品
JP2019059894A (ja) * 2017-09-28 2019-04-18 三井化学株式会社 防振ゴム用組成物および防振ゴム製品
JP2019059895A (ja) * 2017-09-28 2019-04-18 三井化学株式会社 防振ゴム用組成物および防振ゴム製品
WO2019157687A1 (en) 2018-02-14 2019-08-22 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
US20220213305A1 (en) 2019-04-30 2022-07-07 Dow Global Technologies Llc Ethylene/Propylene/Nonconjugated Diene Interpolymer Composition
US11866530B2 (en) * 2019-04-30 2024-01-09 Dow Global Technologies Llc Ethylene/propylene/nonconjugated diene interpolymer composition

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2322883A1 (fr) * 1975-09-02 1977-04-01 Michelin & Cie Elastomeres du type e p t, et articles comportant de tels elastomeres
JPH0618942B2 (ja) * 1985-05-17 1994-03-16 日本合成ゴム株式会社 押し出し加工性に優れたゴム組成物
US5001205A (en) * 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
CA2065302A1 (en) * 1989-09-06 1991-03-07 Charles Cozewith Alpha olefin copolmers having a narrow mwd and broad compositional distribution
EP0702030B1 (de) * 1991-05-27 2001-03-21 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
DE4139261A1 (de) * 1991-11-29 1993-06-03 Basf Ag Ethylen-copolymerisate niederer dichte
EP0571882B1 (de) * 1992-05-26 1997-03-12 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinwachsen
EP0582194B1 (de) * 1992-08-03 1998-05-06 TARGOR GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung

Also Published As

Publication number Publication date
NL9400758A (nl) 1995-12-01
US5902867A (en) 1999-05-11
JPH09512848A (ja) 1997-12-22
MX9605423A (es) 1997-12-31
WO1995030698A1 (en) 1995-11-16
TW294681B (de) 1997-01-01
EP0758346A1 (de) 1997-02-19
EP0758346B1 (de) 1998-07-29
DE69503778T2 (de) 1999-04-15
CA2189570A1 (en) 1995-11-16
BR9507707A (pt) 1997-08-19
CN1150809A (zh) 1997-05-28
AU2149895A (en) 1995-11-29

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Legal Events

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8339 Ceased/non-payment of the annual fee