CN113174144B - 树脂添加剂组合物及使用其的合成树脂组合物 - Google Patents

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Publication number

CN113174144B

CN113174144B CN202110403719.XA CN202110403719A CN113174144B CN 113174144 B CN113174144 B CN 113174144B CN 202110403719 A CN202110403719 A CN 202110403719A CN 113174144 B CN113174144 B CN 113174144B

Authority

CN

China

Prior art keywords

mass

parts

resin

tert

synthetic resin

Prior art date

2015-08-20

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• 239000000203 mixture Substances 0.000 title claims abstract description 95
• 239000000057 synthetic resin Substances 0.000 title claims abstract description 48
• 229920003002 synthetic resin Polymers 0.000 title claims abstract description 48
• 229920005989 resin Polymers 0.000 title abstract description 86
• 239000011347 resin Substances 0.000 title abstract description 86
• 239000000654 additive Substances 0.000 title abstract description 65
• 230000000996 additive effect Effects 0.000 title abstract description 61
• -1 phosphate ester Chemical class 0.000 claims abstract description 76
• 229910052751 metal Inorganic materials 0.000 claims abstract description 35
• 239000002184 metal Substances 0.000 claims abstract description 35
• 150000003839 salts Chemical class 0.000 claims abstract description 24
• ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 claims abstract description 20
• 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 19
• 239000000194 fatty acid Substances 0.000 claims abstract description 19
• 229930195729 fatty acid Natural products 0.000 claims abstract description 19
• 150000004665 fatty acids Chemical class 0.000 claims abstract description 14
• 150000001875 compounds Chemical class 0.000 claims description 17
• 238000000465 moulding Methods 0.000 claims description 17
• 125000004432 carbon atom Chemical group C* 0.000 claims description 13
• 229910052783 alkali metal Inorganic materials 0.000 claims description 7
• 125000000217 alkyl group Chemical group 0.000 claims description 7
• 125000004429 atom Chemical group 0.000 claims description 7
• 239000000835 fiber Substances 0.000 claims description 6
• 239000011777 magnesium Substances 0.000 claims description 6
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
• 125000001931 aliphatic group Chemical class 0.000 claims description 5
• 150000001340 alkali metals Chemical class 0.000 claims description 5
• 229910052749 magnesium Inorganic materials 0.000 claims description 5
• 229920005672 polyolefin resin Polymers 0.000 claims description 5
• 239000011701 zinc Substances 0.000 claims description 5
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
• HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
• 125000001118 alkylidene group Chemical group 0.000 claims description 4
• 229910052725 zinc Inorganic materials 0.000 claims description 4
• 229910052788 barium Inorganic materials 0.000 claims description 3
• DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
• 239000000463 material Substances 0.000 claims description 3
• 229920005992 thermoplastic resin Polymers 0.000 claims description 3
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
• 229910052735 hafnium Inorganic materials 0.000 claims description 2
• VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
• 229910052742 iron Inorganic materials 0.000 claims description 2
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
• 238000004321 preservation Methods 0.000 claims description 2
• 229910052710 silicon Inorganic materials 0.000 claims description 2
• 239000010703 silicon Substances 0.000 claims description 2
• 229910052712 strontium Inorganic materials 0.000 claims description 2
• CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
• 229910052719 titanium Inorganic materials 0.000 claims description 2
• 239000010936 titanium Substances 0.000 claims description 2
• 229910052727 yttrium Inorganic materials 0.000 claims description 2
• VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
• 229910052726 zirconium Inorganic materials 0.000 claims description 2
• 230000000694 effects Effects 0.000 abstract description 22
• 229910019142 PO4 Inorganic materials 0.000 abstract description 10
• 230000000704 physical effect Effects 0.000 abstract description 10
• 239000002245 particle Substances 0.000 abstract description 9
• 239000010452 phosphate Substances 0.000 abstract description 9
• 239000008188 pellet Substances 0.000 description 35
• 238000004519 manufacturing process Methods 0.000 description 23
• 230000003078 antioxidant effect Effects 0.000 description 18
• 239000003963 antioxidant agent Substances 0.000 description 17
• 230000000052 comparative effect Effects 0.000 description 15
• VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
• 239000002530 phenolic antioxidant Substances 0.000 description 13
• 239000000843 powder Substances 0.000 description 11
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 10
• 239000000975 dye Substances 0.000 description 10
• 239000007983 Tris buffer Substances 0.000 description 9
• 239000002216 antistatic agent Substances 0.000 description 9
• 239000013078 crystal Substances 0.000 description 9
• 239000003484 crystal nucleating agent Substances 0.000 description 9
• 238000001746 injection moulding Methods 0.000 description 9
• NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 9
• 235000021317 phosphate Nutrition 0.000 description 9
• 229910052698 phosphorus Inorganic materials 0.000 description 9
• 239000011574 phosphorus Substances 0.000 description 9
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
• 238000002425 crystallisation Methods 0.000 description 8
• 230000008025 crystallization Effects 0.000 description 8
• GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 8
• 229960001545 hydrotalcite Drugs 0.000 description 8
• 229910001701 hydrotalcite Inorganic materials 0.000 description 8
• 238000000034 method Methods 0.000 description 8
• 239000000049 pigment Substances 0.000 description 8
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
• JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 7
• CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 7
• 239000008116 calcium stearate Substances 0.000 description 7
• 235000013539 calcium stearate Nutrition 0.000 description 7
• 229920001577 copolymer Polymers 0.000 description 7
• 238000001125 extrusion Methods 0.000 description 7
• 239000003063 flame retardant Substances 0.000 description 7
• 239000000047 product Substances 0.000 description 7
• WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
• UADIOTAIECKQLQ-UHFFFAOYSA-M lithium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Li+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C UADIOTAIECKQLQ-UHFFFAOYSA-M 0.000 description 6
• 238000002156 mixing Methods 0.000 description 6
• NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
• 235000021355 Stearic acid Nutrition 0.000 description 5
• 229920001971 elastomer Polymers 0.000 description 5
• 239000000945 filler Substances 0.000 description 5
• KJSPVJJOPONRTK-UHFFFAOYSA-M lithium;tetradecanoate Chemical compound [Li+].CCCCCCCCCCCCCC([O-])=O KJSPVJJOPONRTK-UHFFFAOYSA-M 0.000 description 5
• 238000002844 melting Methods 0.000 description 5
• 230000008018 melting Effects 0.000 description 5
• QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
• OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
• 239000008117 stearic acid Substances 0.000 description 5
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
• FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
• CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
• 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 4
• 229910052782 aluminium Inorganic materials 0.000 description 4
• IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
• 239000003795 chemical substances by application Substances 0.000 description 4
• SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 4
• UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
• POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
• 238000009472 formulation Methods 0.000 description 4
• IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
• 238000002347 injection Methods 0.000 description 4
• 239000007924 injection Substances 0.000 description 4
• 239000000314 lubricant Substances 0.000 description 4
• 239000002667 nucleating agent Substances 0.000 description 4
• 229920005862 polyol Polymers 0.000 description 4
• 150000004671 saturated fatty acids Chemical class 0.000 description 4
• XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 3
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
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