CN1127374C - 载体催化剂及其在烃类气相氧化作用中的用途 - Google Patents
载体催化剂及其在烃类气相氧化作用中的用途 Download PDFInfo
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- CN1127374C CN1127374C CN00132140A CN00132140A CN1127374C CN 1127374 C CN1127374 C CN 1127374C CN 00132140 A CN00132140 A CN 00132140A CN 00132140 A CN00132140 A CN 00132140A CN 1127374 C CN1127374 C CN 1127374C
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/55—Cylinders or rings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S261/00—Gas and liquid contact apparatus
- Y10S261/72—Packing elements
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
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- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
压力(巴)流量为3立方米(标准状态)/小时 | 压力(巴)流量为4立方米(标准状态)/小时 | ||
A | 未经涂敷,有凹口的环状体7×7×4毫米 | 0.069 | 0.106 |
B | 未经涂敷,无凹口的环状体7×7×4毫米 | 0.082 | 0.128 |
C | 经涂敷,有凹口的环状体7×7×4毫米 | 0.064 | 0.099 |
D | 经涂敷,无凹口的环状体7×7×4毫米 | 0.079 | 0.120 |
E | 未经涂敷,有凹口的环状体7×7×4毫米 | 0.026 | 0.039 |
F | 未经涂敷,无凹口的环状体7×7×4毫米 | 0.038 | 0.059 |
压力降(巴)流量为3立方米(标准状态)/小时 | 压力降(%)流量为3立方米(标准状态)/小时 | 压力降(巴)流量为4立方米(标准状态)/小时 | 压力降(%)流量为4立方米(标准状态)小时 | |
压力(B-A) | 0.012 | 18.8 | 0.022 | 20.8 |
压力(D-C) | 0.015 | 23.4 | 0.021 | 21.2 |
压力(F-E) | 0.012 | 32 | 0.02 | 34 |
在流量4立方米(标准状况)/小时的情况下的压力降 | 邻苯二甲酸酐产率(重量%) | 催化剂床体内的最高温度(℃)(=热点) | |
本发明催化剂 | 0.33巴 | -113 | 434 |
比较性催化剂 | 0.40巴 | -111 | 449 |
Claims (12)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19959413.9 | 1999-12-09 | ||
DE19959413A DE19959413A1 (de) | 1999-12-09 | 1999-12-09 | Trägerkatalysatoren und deren Verwendung bei der Gasphasenoxidation von Kohlenwasserstoffen |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1298763A CN1298763A (zh) | 2001-06-13 |
CN1127374C true CN1127374C (zh) | 2003-11-12 |
Family
ID=7932024
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN00132140A Expired - Fee Related CN1127374C (zh) | 1999-12-09 | 2000-12-08 | 载体催化剂及其在烃类气相氧化作用中的用途 |
Country Status (10)
Country | Link |
---|---|
US (1) | US6624114B1 (zh) |
EP (1) | EP1108470B1 (zh) |
JP (1) | JP3757111B2 (zh) |
CN (1) | CN1127374C (zh) |
AT (1) | ATE220572T1 (zh) |
BR (1) | BR0005810B1 (zh) |
DE (2) | DE19959413A1 (zh) |
ES (1) | ES2179804T3 (zh) |
NO (1) | NO321987B1 (zh) |
TW (1) | TWI258390B (zh) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10159834A1 (de) | 2001-12-06 | 2003-06-26 | Consortium Elektrochem Ind | Verfahren zur Herstellung von gesättigten Carbonsäuren mit ein bis vier C-Atomen durch Gasphasenoxidation von 2-Butanon |
DE102004005863A1 (de) * | 2004-02-05 | 2005-09-08 | Stockhausen Gmbh | Reaktor mit einem einen Einsatz aufweisenden Wärmetauscherbereich |
US7297402B2 (en) * | 2004-04-15 | 2007-11-20 | Shell Oil Company | Shaped particle having an asymmetrical cross sectional geometry |
DE102005019596A1 (de) * | 2005-04-27 | 2006-11-02 | Süd-Chemie AG | Katalysatorträger |
DK1965911T3 (da) * | 2005-11-23 | 2013-09-16 | Sued Chemie Ip Gmbh & Co Kg | Skal-katalysator, især til oxidation af methanol til formaldehyd, og fremgangsmåde til produktion deraf |
EP1792651A1 (de) * | 2005-11-23 | 2007-06-06 | Süd-Chemie Ag | Schalenkatalysator, insbesondere zur Oxidation von Methanol zu Formaldehyd sowie Verfahren zu dessen Herstellung |
JP5300738B2 (ja) * | 2006-12-21 | 2013-09-25 | ビーエーエスエフ ソシエタス・ヨーロピア | 前方層を使用して気相酸化するための触媒系及び方法 |
DE102007011847A1 (de) | 2007-03-12 | 2008-09-18 | Wacker Chemie Ag | Verfahren zur Herstellung von Essig- und Ameisensäure durch Gasphasenoxidation von Ethanol |
WO2009068510A2 (en) | 2007-11-27 | 2009-06-04 | Shell Internationale Research Maatschappij B.V. | Catalyst support |
US7998899B2 (en) * | 2007-11-27 | 2011-08-16 | Shell Oil Company | Catalyst with support structure |
US7910518B2 (en) * | 2008-03-10 | 2011-03-22 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Geometrically sized solid shaped carrier for olefin epoxidation catalyst |
CN102137751B (zh) * | 2008-07-02 | 2014-12-31 | 巴斯夫欧洲公司 | 制备氧化的几何成型体的方法 |
US8673245B2 (en) * | 2008-09-22 | 2014-03-18 | Nippon Shokubai Co., Ltd. | Fixed-bed reactor and process for producing acrylic acid using the reactor |
JP2011140210A (ja) * | 2009-06-24 | 2011-07-21 | Sumitomo Chemical Co Ltd | 成形体およびその製造方法、並びに触媒およびその製造方法 |
DE102010052126A1 (de) | 2010-11-22 | 2012-05-24 | Süd-Chemie AG | Katalysatorformkörper für durchströmte Festbettreaktoren |
FR2980721B1 (fr) * | 2011-10-04 | 2015-03-13 | IFP Energies Nouvelles | Mise en forme de masses de captation pour la purification d'une charge gaz ou liquide contenant du mercure |
US11786924B2 (en) | 2018-09-20 | 2023-10-17 | Glaxosmithkline Consumer Healthcare Holdings (Us) Llc | Variable dose container |
CN112642454A (zh) * | 2019-10-12 | 2021-04-13 | 中国石油化工股份有限公司 | 一种邻二甲苯氧化制苯酐的催化剂及其制备方法 |
CN113617396A (zh) * | 2021-07-20 | 2021-11-09 | 安徽力天环保科技股份有限公司 | 一种苯酐催化剂及其制备方法 |
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US2408164A (en) | 1942-04-25 | 1946-09-24 | Phillips Petroleum Co | Catalyst preparation |
US3284762A (en) * | 1965-03-26 | 1966-11-08 | Harry W Kompanek | Mechanical-to-electrical transducer |
GB1373351A (en) | 1972-02-16 | 1974-11-13 | Monsanto Ltd | Catalyst tablets |
US3966644A (en) | 1973-08-03 | 1976-06-29 | American Cyanamid Company | Shaped catalyst particles |
DE2811115A1 (de) | 1978-03-15 | 1979-09-27 | Hoechst Ag | Traeger-katalysator fuer die herstellung von vinylacetat aus ethylen, essigsaeure und sauerstoff in der gasphase |
US4328130A (en) | 1980-10-22 | 1982-05-04 | Chevron Research Company | Shaped channeled catalyst |
BE886363A (fr) * | 1980-11-26 | 1981-03-16 | Catalysts & Chem Europ | Catalyseurs de reformage et leur utilisation |
JPS60216844A (ja) | 1984-04-13 | 1985-10-30 | Nippon Shokubai Kagaku Kogyo Co Ltd | エチレンオキシド製造用銀触媒 |
DE3445289A1 (de) | 1984-12-12 | 1986-06-19 | Basf Ag, 6700 Ludwigshafen | Geformter katalysator fuer heterogen katalysierte reaktionen |
NZ217874A (en) | 1985-10-25 | 1989-01-27 | Mobil Oil Corp | Quadrulobe catalysts |
GB2193907A (en) | 1986-06-24 | 1988-02-24 | Dyson Refractories | Ribbed catalyst bodies |
GB2197597B (en) | 1986-06-24 | 1990-05-09 | Dyson Refractories | Catalyst bodies |
EP0464633B1 (en) | 1990-07-03 | 1994-01-19 | Kuraray Co., Ltd. | Catalyst and process for producing unsaturated ester |
ES2046157T1 (es) | 1990-10-04 | 1994-02-01 | Monsanto Company | Estructuras conformadas de catalizadores de oxidacion para la produccion de anhidrido maleico. |
DE4442346A1 (de) | 1994-11-29 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung eines Katalysators, bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse |
DE19721368A1 (de) | 1997-05-22 | 1998-11-26 | Hoechst Ag | Verfahren zur Herstellung von Vinylacetat |
US6117812A (en) * | 1998-10-06 | 2000-09-12 | China Petro-Chemical Corporation | Dual functional catalyst of packing type and the catalytic distillation equipment |
-
1999
- 1999-12-09 DE DE19959413A patent/DE19959413A1/de not_active Withdrawn
-
2000
- 2000-11-10 US US09/709,832 patent/US6624114B1/en not_active Expired - Lifetime
- 2000-11-16 AT AT00124327T patent/ATE220572T1/de active
- 2000-11-16 ES ES00124327T patent/ES2179804T3/es not_active Expired - Lifetime
- 2000-11-16 EP EP00124327A patent/EP1108470B1/de not_active Expired - Lifetime
- 2000-11-16 DE DE50000281T patent/DE50000281D1/de not_active Expired - Lifetime
- 2000-12-07 JP JP2000372601A patent/JP3757111B2/ja not_active Expired - Fee Related
- 2000-12-07 NO NO20006216A patent/NO321987B1/no not_active IP Right Cessation
- 2000-12-07 TW TW089126123A patent/TWI258390B/zh not_active IP Right Cessation
- 2000-12-08 CN CN00132140A patent/CN1127374C/zh not_active Expired - Fee Related
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JP3757111B2 (ja) | 2006-03-22 |
DE19959413A1 (de) | 2001-06-21 |
CN1298763A (zh) | 2001-06-13 |
BR0005810A (pt) | 2002-01-02 |
DE50000281D1 (de) | 2002-08-22 |
NO321987B1 (no) | 2006-07-31 |
ATE220572T1 (de) | 2002-08-15 |
US6624114B1 (en) | 2003-09-23 |
NO20006216L (no) | 2001-06-11 |
EP1108470A1 (de) | 2001-06-20 |
ES2179804T3 (es) | 2003-02-01 |
NO20006216D0 (no) | 2000-12-07 |
BR0005810B1 (pt) | 2010-11-30 |
JP2001205107A (ja) | 2001-07-31 |
EP1108470B1 (de) | 2002-07-17 |
TWI258390B (en) | 2006-07-21 |
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