CN112654599A - 共价有机框架材料的制备方法和缺陷修复方法 - Google Patents
共价有机框架材料的制备方法和缺陷修复方法 Download PDFInfo
- Publication number
- CN112654599A CN112654599A CN201880096737.4A CN201880096737A CN112654599A CN 112654599 A CN112654599 A CN 112654599A CN 201880096737 A CN201880096737 A CN 201880096737A CN 112654599 A CN112654599 A CN 112654599A
- Authority
- CN
- China
- Prior art keywords
- derivatives
- acid
- control agent
- tert
- cof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/06—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/06—Amines
- C08G12/08—Amines aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
本发明涉及一种制备共价有机框架(COF)材料的方法—可逆缩聚/终止聚合方法，通过该方法制备的COF材料具有高结晶性、高比表面积、规整且可控的形貌。本发明还涉及一种修复COF材料的缺陷的方法—可逆解聚重组，该方法可消除已有COF材料的缺陷，从而提高COF材料的结晶性和比表面积以及改善其形貌特征。
Description
PCT国内申请，说明书已公开。
Claims (20)
- PCT国内申请，权利要求书已公开。
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2018/116174 WO2020102936A1 (zh) | 2018-11-19 | 2018-11-19 | 共价有机框架材料的制备方法和缺陷修复方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112654599A true CN112654599A (zh) | 2021-04-13 |
| CN112654599B CN112654599B (zh) | 2023-04-28 |
Family
ID=70773206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880096737.4A Active CN112654599B (zh) | 2018-11-19 | 2018-11-19 | 共价有机框架材料的制备方法和缺陷修复方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20220153904A1 (zh) |
| EP (1) | EP3862341A4 (zh) |
| CN (1) | CN112654599B (zh) |
| WO (1) | WO2020102936A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115487866A (zh) * | 2021-06-18 | 2022-12-20 | 浙江大学 | 一种共价有机框架材料耦合纳米金属催化剂及其制备方法 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113214446B (zh) * | 2021-03-25 | 2022-03-18 | 南昌大学 | 一种sp2碳共价有机框架的合成方法及在有机污染物的光催化降解中的应用 |
| CN113368077B (zh) * | 2021-04-27 | 2022-06-21 | 山东师范大学 | 一种聚多巴胺修饰的纳米共价有机框架及其制备方法与应用 |
| CN113512162B (zh) * | 2021-04-30 | 2022-04-15 | 华中科技大学 | 一种硫醚基共价有机框架材料及其制备方法和应用 |
| CN113336961B (zh) * | 2021-06-30 | 2023-03-10 | 山西大同大学 | 噻唑基的富硫共价有机框架及其制备方法与应用 |
| CN113617388B (zh) * | 2021-08-10 | 2023-06-23 | 河北大学 | 基于多孔吡啶基共价有机框架的银纳米催化剂及其制备方法和应用 |
| CN113600137B (zh) * | 2021-08-19 | 2023-04-07 | 东北师范大学 | 一种共价有机骨架纳米线材料的制备方法及其应用 |
| CN114106276B (zh) * | 2021-12-07 | 2023-05-23 | 中国科学院兰州化学物理研究所 | 一种形貌可控的共价有机框架材料的制备方法 |
| CN115124675B (zh) * | 2022-07-15 | 2024-04-12 | 江南大学 | 二维菱形异孔共价有机框架材料及制备方法 |
| CN115286757B (zh) * | 2022-08-04 | 2023-03-10 | 中原工学院 | 基于多氮烯烃连接的共价有机框架材料及其制备方法和应用 |
| CN115521426B (zh) * | 2022-09-26 | 2024-02-09 | 通化师范学院 | 一种亚胺连接微孔共价有机骨架材料、制备方法及其应用 |
| CN116178646B (zh) * | 2022-12-11 | 2024-01-16 | 三峡大学 | 一种高熵共价有机框架化合物的制备方法 |
| CN117659325B (zh) * | 2024-01-31 | 2024-04-12 | 德州学院 | 一种具有电化学活性的共价有机框架材料的制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103209763A (zh) * | 2010-09-13 | 2013-07-17 | 康奈尔大学 | 共价有机框架膜及其制备方法和用途 |
| CN105214340A (zh) * | 2015-09-14 | 2016-01-06 | 武汉长林医药科技有限公司 | 一种固定共价有机骨架材料的方法及其应用 |
| CN105440058A (zh) * | 2015-11-04 | 2016-03-30 | 兰州大学 | 一种基于苯并噻唑单元的共价有机框架材料的合成方法 |
| CN106083909A (zh) * | 2016-06-24 | 2016-11-09 | 兰州大学 | 一种共价有机框架材料单晶的制备方法 |
| CN107325113A (zh) * | 2017-07-06 | 2017-11-07 | 福州大学 | 一种包含Salen单元的笼型共价有机框架化合物的制备方法 |
| CN108794756A (zh) * | 2018-06-28 | 2018-11-13 | 福州大学 | 一种镍离子修饰的共价有机框架材料的制备方法及其应用 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2832767A1 (en) | 2013-07-31 | 2015-02-04 | Fundación Imdea Nanociencia | Method for the Synthesis of Covalent Organic Frameworks |
-
2018
- 2018-11-19 US US17/292,485 patent/US20220153904A1/en active Pending
- 2018-11-19 CN CN201880096737.4A patent/CN112654599B/zh active Active
- 2018-11-19 EP EP18940484.1A patent/EP3862341A4/en active Pending
- 2018-11-19 WO PCT/CN2018/116174 patent/WO2020102936A1/zh unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103209763A (zh) * | 2010-09-13 | 2013-07-17 | 康奈尔大学 | 共价有机框架膜及其制备方法和用途 |
| CN105214340A (zh) * | 2015-09-14 | 2016-01-06 | 武汉长林医药科技有限公司 | 一种固定共价有机骨架材料的方法及其应用 |
| CN105440058A (zh) * | 2015-11-04 | 2016-03-30 | 兰州大学 | 一种基于苯并噻唑单元的共价有机框架材料的合成方法 |
| CN106083909A (zh) * | 2016-06-24 | 2016-11-09 | 兰州大学 | 一种共价有机框架材料单晶的制备方法 |
| CN107325113A (zh) * | 2017-07-06 | 2017-11-07 | 福州大学 | 一种包含Salen单元的笼型共价有机框架化合物的制备方法 |
| CN108794756A (zh) * | 2018-06-28 | 2018-11-13 | 福州大学 | 一种镍离子修饰的共价有机框架材料的制备方法及其应用 |
Non-Patent Citations (4)
| Title |
|---|
| AUSTIN M. EVANS等: "Seeded growth of single-crystal two-dimensional covalent organic frameworks", 《SCIENCE》 * |
| MICHIO MATSUMOTO等: "Rapid, Low Temperature Formation of Imine-Linked Covalent Organic Frameworks Catalyzed by Metal Triflates", 《J.AM.CHEM.SOC.》 * |
| TIANQIONG MA等: "Single-crystal x-ray diffraction structures of covalent organic frameworks", 《SCIENCE》 * |
| YUE-BIAO ZHANG等: "Single-Crystal Structure of a Covalent Organic Framework", 《J.AM.CHEM.SOC.》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115487866A (zh) * | 2021-06-18 | 2022-12-20 | 浙江大学 | 一种共价有机框架材料耦合纳米金属催化剂及其制备方法 |
| CN115487866B (zh) * | 2021-06-18 | 2024-05-14 | 浙江大学 | 一种共价有机框架材料耦合纳米金属催化剂及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3862341A1 (en) | 2021-08-11 |
| WO2020102936A1 (zh) | 2020-05-28 |
| US20220153904A1 (en) | 2022-05-19 |
| EP3862341A4 (en) | 2022-08-10 |
| CN112654599B (zh) | 2023-04-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112654599A (zh) | 共价有机框架材料的制备方法和缺陷修复方法 | |
| CN114761452B (zh) | 一种制备中空共价有机框架材料的方法 | |
| CN110523354B (zh) | 一种含固载催化剂的微反应器的制备方法 | |
| CN101225227A (zh) | 超支化聚酰胺胺与金属纳米复合物及制备方法和应用 | |
| CN103657545A (zh) | 具有核壳结构的磁性高分子/碳基微球材料及其制备方法 | |
| CN108689786B (zh) | 一种借氢还原偶联合成亚胺和胺类化合物的方法 | |
| CN110560170B (zh) | 一种Pd@MOF材料及其制备方法和其在联苯制备中的应用 | |
| CN115487866B (zh) | 一种共价有机框架材料耦合纳米金属催化剂及其制备方法 | |
| CN111285986B (zh) | 含杂原子、亚胺和三嗪环结构富氮多孔聚合物及制备方法 | |
| CN113480774B (zh) | 一种超弹性的太阳能界面蒸发纤维素气凝胶及其制备方法 | |
| CN114632430B (zh) | 一种用于气体分离的共价有机聚合物材料纳米片复合基质膜及其制备方法 | |
| CN102553647A (zh) | 一种磁性纳米固体酸催化剂及其制备方法 | |
| CN109762080B (zh) | 一种超分子手性多孔聚合物分离介质及其制备方法及应用 | |
| Zha et al. | Sculpting Mesoscopic Helical Chirality into Covalent Organic Framework Nanotubes from Entirely Achiral Building Blocks | |
| Hu | Novel fluorescent porous hyperbranched aromatic polyamide containing 1, 3, 5‐triphenylbenzene moieties: Synthesis and characterization | |
| CN110746612B (zh) | 一种自组装有机分子笼及其制备方法 | |
| CN107555413B (zh) | 一种含氮量可调控的掺氮有序中孔炭的制备方法 | |
| CN108117471B (zh) | 一种提高有机框架多孔材料化学稳定性的方法 | |
| CN106046363B (zh) | 一类含四甲氧基芴结构高可溶性聚芳酰胺及其制备方法 | |
| US20240182624A1 (en) | A method for preparing hollow covalent organic framework materials | |
| CN111019145B (zh) | 一种有机共价聚合物材料及其制备方法与应用 | |
| CN107163249B (zh) | 一种花状结构聚酰亚胺的合成方法 | |
| TWI647260B (zh) | 用於有機溶液脫水之高透過和高選擇性之PVA/GA/CS-M<sup>+</sup>滲透蒸發薄膜 | |
| Nabae et al. | Synthesis of TEMPO Functionalized Polyimides by A2+ B3 polymerization | |
| CN116284629B (zh) | 一种廉价多孔有机聚合物材料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |