CN1123558C - 多元醇的制备方法 - Google Patents

多元醇的制备方法 Download PDF

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Publication number
CN1123558C
CN1123558C CN97180072A CN97180072A CN1123558C CN 1123558 C CN1123558 C CN 1123558C CN 97180072 A CN97180072 A CN 97180072A CN 97180072 A CN97180072 A CN 97180072A CN 1123558 C CN1123558 C CN 1123558C
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China
Prior art keywords
formula
reaction
compound
formaldehyde
described method
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Expired - Fee Related
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CN97180072A
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English (en)
Chinese (zh)
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CN1238753A (zh
Inventor
D·克拉茨
A·斯塔默
G·舒尔茨
G·沃伊特
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/75—Reactions with formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN97180072A 1996-12-20 1997-12-04 多元醇的制备方法 Expired - Fee Related CN1123558C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE1996153093 DE19653093A1 (de) 1996-12-20 1996-12-20 Verfahren zur Herstellung von Polyalkoholen
DE19653093.8 1996-12-20

Publications (2)

Publication Number Publication Date
CN1238753A CN1238753A (zh) 1999-12-15
CN1123558C true CN1123558C (zh) 2003-10-08

Family

ID=7815413

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97180072A Expired - Fee Related CN1123558C (zh) 1996-12-20 1997-12-04 多元醇的制备方法

Country Status (10)

Country Link
US (1) US6187971B1 (enExample)
EP (1) EP0946483B1 (enExample)
JP (1) JP3983302B2 (enExample)
KR (1) KR100499599B1 (enExample)
CN (1) CN1123558C (enExample)
CA (1) CA2274083A1 (enExample)
DE (2) DE19653093A1 (enExample)
ES (1) ES2184146T3 (enExample)
TW (1) TW462961B (enExample)
WO (1) WO1998028253A1 (enExample)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5994592A (en) * 1997-02-19 1999-11-30 Nippon Kasei Chemical Company Limited Process for producing 2,2'-bis(hydroxymethyl)alkanal and 2,2'-bis(hydroxymethyl)alkanoic acid
DE19963442A1 (de) * 1999-12-28 2001-07-05 Basf Ag Farbzahlverbesserung von mehrwertigen Alkoholen durch Hydrierung
DE19963437A1 (de) 1999-12-28 2001-07-05 Basf Ag Verfahren zur Zersetzung von bei der Synthese mehrwertiger Alkohole gebildeter hochsiedender Nebenprodukte
DE19963435A1 (de) 1999-12-28 2001-07-05 Basf Ag Verfahren zur Reinigung von durch Hydrierung hergestelltem Trimethylolpropan durch kontinuierliche Destillation
DE19963438A1 (de) * 1999-12-28 2001-10-31 Basf Ag Verfahren zur Herstellung von Polyalkoholen mit Methanolarmem Formaldehyd
DE10001257A1 (de) * 2000-01-14 2001-07-19 Bayer Ag Verfahren zur Herstellung von Trimethylolalkanen
DE10041197A1 (de) * 2000-08-23 2002-03-07 Bayer Ag TMP/Dampfdruckfiltration
DE10050645A1 (de) * 2000-10-13 2002-04-18 Basf Ag Farbzahlverbesserung von mehrwertigen Alkoholen durch Hydrierung
DE10055180A1 (de) 2000-11-08 2002-05-29 Basf Ag Verfahren zur Hydrierung von Poly- oder Monomethylolalkanalen
DE10152525A1 (de) * 2001-10-24 2003-05-08 Basf Ag Verfahren zur Zersetzung von Ammoniumformiaten in polyolhaltigen Reaktionsgemischen
MXPA04004210A (es) * 2001-11-15 2004-07-08 Basf Ag Procedimiento para la eliminacion de acetales que contienen formaldehido de alcoholes polivalentes por templado.
DE10160180A1 (de) 2001-12-07 2003-06-18 Basf Ag Verfahren zur Isolierung von Trimethylolpropan aus einem Reaktionsgemisch
DE10223055A1 (de) * 2002-05-24 2003-12-11 Basf Ag Verfahren zur Herstellung von Polyesterpolyolen mehrwertiger Alkohole
DE10234016A1 (de) 2002-07-26 2004-02-05 Basf Ag Verfahren zur Ausbeuteerhöhung bei der Herstellung von mehrwertigen Alkoholen durch Spaltung acetalhaltiger Nebenprodukte
SE0301102D0 (sv) 2003-04-14 2003-04-14 Tetra Laval Holdings & Finance Method in connection with the production of a apckaging laminate thus produced and a packaging container manufactures from the packaging laminate
DE10317543A1 (de) 2003-04-16 2004-11-04 Basf Ag Verfahren zur Hydrierung von Methylolalkanalen
DE102006009838A1 (de) * 2006-03-01 2007-09-06 Basf Ag Verfahren zur Hydrierung von Methylolalkanalen
US7388116B2 (en) 2006-06-06 2008-06-17 Basf Aktiengesellschaft Hydrogenation of methylolalkanals
US20080004475A1 (en) * 2006-06-28 2008-01-03 Basf Aktiengesellschaft Process for the production of neopentylglycol using formaldehyde with a low methanol content
US7462747B2 (en) * 2007-01-05 2008-12-09 Basf Aktiengesellschaft Process for preparing polyalcohols from formaldehyde having a low formic acid content
EP2134669B1 (de) 2007-03-02 2013-01-09 Basf Se Verfahren zur herstellung von hydroxypivalinaldehyd und neopentylglykol
WO2010066674A2 (de) * 2008-12-09 2010-06-17 Basf Se Verfahren zur herstellung von polymethylolen
US8575401B2 (en) 2008-12-09 2013-11-05 Basf Se Method for purifying crude polymethylols
EP2385933B1 (de) * 2009-01-12 2014-06-25 Basf Se Verfahren zur herstellung von polymethylolen
EP2607341B1 (en) * 2009-12-24 2015-11-18 Oxea Bishop LLC Trimethylolpropane color improvement
US8853465B2 (en) 2010-05-12 2014-10-07 Basf Se Process for preparing neopentyl glycol
SG185512A1 (en) 2010-05-12 2012-12-28 Basf Se Process for preparing neopentyl glycol
DE102010033844B4 (de) 2010-08-11 2013-01-03 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
WO2012143309A1 (de) 2011-04-19 2012-10-26 Basf Se Verfahren zur herstellung von neopentylglykol
CN102304022A (zh) * 2011-07-05 2012-01-04 上海华谊（集团）公司 一种缩合加氢法制备三羟甲基丙烷反应过程中副产物2-乙基丙烯醛的回收利用方法
CN102391070B (zh) * 2011-10-19 2014-09-03 上海华谊（集团）公司 利用甲醛生产三羟甲基丙烷的方法
DE102011118956A1 (de) 2011-11-19 2013-05-23 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
DE102011118953B4 (de) 2011-11-19 2014-06-05 Oxea Gmbh Destillatives Verfahren zur Gewinnung von Di-Trimethylolpropan
DE102011118993A1 (de) 2011-11-19 2013-05-23 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylpropan und mit Trimethylpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
DE102011122356A1 (de) 2011-12-23 2013-06-27 Oxea Gmbh Verfahren zur Gewinnung von mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
US8710278B1 (en) 2013-01-31 2014-04-29 Eastman Chemical Company Process for producing polyols
US9056824B2 (en) 2013-01-31 2015-06-16 Eastman Chemical Company Preparation of hydroxy aldehydes
KR101529828B1 (ko) * 2013-07-26 2015-06-17 주식회사 엘지화학 메틸올알칸알의 제조방법
CN105431402B (zh) * 2013-08-06 2018-01-02 欧季亚毕夏普有限责任公司 羟甲基烷烃的改良制法
TW201536734A (zh) 2014-03-12 2015-10-01 Basf Se 甲酸鹽的分解
KR102224267B1 (ko) * 2016-10-31 2021-03-08 주식회사 엘지화학 트리메틸올프로판의 제조장치 및 이를 이용한 제조방법
KR102224243B1 (ko) * 2016-10-31 2021-03-08 주식회사 엘지화학 트리메틸올프로판의 제조장치 및 이를 이용한 제조방법
KR102224268B1 (ko) * 2016-10-31 2021-03-08 주식회사 엘지화학 트리메틸올프로판의 제조장치 및 이를 이용한 제조방법
KR102245932B1 (ko) * 2017-10-23 2021-04-28 주식회사 엘지화학 트리메틸올프로판의 제조방법
KR102522282B1 (ko) * 2018-04-24 2023-04-14 주식회사 엘지화학 포름알데히드의 회수방법
CN113845403B (zh) * 2021-11-30 2023-08-11 万华化学集团股份有限公司 一种联产2-甲基-1,3-丙二醇和季戊四醇的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4594461A (en) * 1983-11-11 1986-06-10 Basf Aktiengesellschaft Preparation of trimethylolalkanes from alkanals and formaldehyde

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1952738A1 (de) * 1968-12-17 1970-07-09 Leuna Werke Veb Verfahren zur Herstellung von Trimethylolpropan
BE758910A (fr) * 1969-11-15 1971-05-13 Basf Ag Preparation de dimethyl-2, 2-propanediol-1, 3
DE2507461C3 (de) * 1975-02-21 1986-05-07 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von 2,2- Dimethylolalkanalen
US4740639A (en) * 1987-06-12 1988-04-26 Eastman Kodak Company Process for preparation of 2,4-disubstituted-1,5-pentanediols
US4851592A (en) * 1987-10-27 1989-07-25 Eastman Kodak Company Triethylamine catalyzed neopentyl glycol production utilizing a gas sparged reactor
DE3942792A1 (de) * 1989-12-23 1991-06-27 Hoechst Ag Verfahren zur herstellung von 2,2-dimethylpropandiol-(1,3)
US5532417A (en) * 1991-04-26 1996-07-02 Aristech Chemical Corporation Manufacture of neopentyl glycol (IV)
US5185478A (en) * 1991-06-17 1993-02-09 Aristech Chemical Corporation Manufacture of neopentyl glycol (IIA)
US5763690A (en) * 1992-09-25 1998-06-09 Aristech Chemical Corporation Manufacture of trimethylolpropane

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4594461A (en) * 1983-11-11 1986-06-10 Basf Aktiengesellschaft Preparation of trimethylolalkanes from alkanals and formaldehyde

Also Published As

Publication number Publication date
JP2001506658A (ja) 2001-05-22
CA2274083A1 (en) 1998-07-02
US6187971B1 (en) 2001-02-13
WO1998028253A1 (de) 1998-07-02
KR100499599B1 (ko) 2005-07-07
ES2184146T3 (es) 2003-04-01
TW462961B (en) 2001-11-11
DE59708146D1 (de) 2002-10-10
EP0946483B1 (de) 2002-09-04
JP3983302B2 (ja) 2007-09-26
EP0946483A1 (de) 1999-10-06
KR20000062250A (ko) 2000-10-25
DE19653093A1 (de) 1998-06-25
CN1238753A (zh) 1999-12-15

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Granted publication date: 20031008

Termination date: 20101204