CN112080147A - 一种巯基有机硅纳米球及其巯基-烯聚合物阻燃体系的制备方法 - Google Patents
一种巯基有机硅纳米球及其巯基-烯聚合物阻燃体系的制备方法 Download PDFInfo
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- CN112080147A CN112080147A CN202010986519.7A CN202010986519A CN112080147A CN 112080147 A CN112080147 A CN 112080147A CN 202010986519 A CN202010986519 A CN 202010986519A CN 112080147 A CN112080147 A CN 112080147A
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- mercapto
- organosilicon
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 58
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 239000002077 nanosphere Substances 0.000 title claims abstract description 48
- 229920000642 polymer Polymers 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title abstract description 11
- 229910052710 silicon Inorganic materials 0.000 title abstract description 11
- 239000010703 silicon Substances 0.000 title abstract description 11
- 125000003396 thiol group Chemical group [H]S* 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims description 22
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 16
- 238000009210 therapy by ultrasound Methods 0.000 claims description 16
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 14
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 claims description 12
- -1 sulfhydryl compound Chemical class 0.000 claims description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 10
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 238000006068 polycondensation reaction Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000004132 cross linking Methods 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 8
- 238000001723 curing Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 230000035484 reaction time Effects 0.000 claims description 4
- 101000623895 Bos taurus Mucin-15 Proteins 0.000 claims description 3
- 238000005189 flocculation Methods 0.000 claims description 2
- 230000016615 flocculation Effects 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 abstract description 11
- 230000009257 reactivity Effects 0.000 abstract description 6
- 230000005012 migration Effects 0.000 abstract description 5
- 238000013508 migration Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 3
- 238000003786 synthesis reaction Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 230000003311 flocculating effect Effects 0.000 description 6
- 239000002041 carbon nanotube Substances 0.000 description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/02—Polythioethers; Polythioether-ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
- C08G75/045—Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Silicon Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
Claims (9)
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CN202010986519.7A CN112080147B (zh) | 2020-09-18 | 2020-09-18 | 一种巯基有机硅纳米球及其巯基-烯聚合物阻燃体系的制备方法 |
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CN202010986519.7A CN112080147B (zh) | 2020-09-18 | 2020-09-18 | 一种巯基有机硅纳米球及其巯基-烯聚合物阻燃体系的制备方法 |
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Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06279586A (ja) * | 1993-03-25 | 1994-10-04 | Showa Denko Kk | ポリメチルシルセスキオキサン系重合体およびポリメチルシルセスキオキサン構造を有するポリマー |
US20080108737A1 (en) * | 2006-06-06 | 2008-05-08 | Shin-Etsu Chemical Co., Ltd. | Additive for imparting flame retardance with an organic resin, flame retardant resin composition, and article molded therefrom |
KR20080085383A (ko) * | 2007-03-19 | 2008-09-24 | (주)석경에이.티 | 다관능기를 함유하는 유기 실리카 미세입자 및 이의제조방법 |
KR20090055966A (ko) * | 2007-11-29 | 2009-06-03 | (주)석경에이.티 | 유기 실리카 미세입자 및 정전하상 현상용 토너 외첨제 |
CN104861165A (zh) * | 2015-06-03 | 2015-08-26 | 宁波工程学院 | 一种巯基-烯聚合物阻燃体系的制备方法 |
CN105860083A (zh) * | 2016-04-14 | 2016-08-17 | 顺德职业技术学院 | 改性乙烯基硅树脂及含改性乙烯基硅树脂的有机硅封胶的制备方法 |
CN106317409A (zh) * | 2016-08-20 | 2017-01-11 | 浙江新安化工集团股份有限公司 | 一种聚硅氧烷微球的制备方法 |
CN106521970A (zh) * | 2016-10-28 | 2017-03-22 | 南昌航空大学 | 一种基于巯基‑烯光聚合的聚硫醚聚合物接枝碳纤维的制备方法 |
CN111100298A (zh) * | 2019-04-25 | 2020-05-05 | 杭州师范大学 | 一种光学透明有机硅材料及其制备方法 |
-
2020
- 2020-09-18 CN CN202010986519.7A patent/CN112080147B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06279586A (ja) * | 1993-03-25 | 1994-10-04 | Showa Denko Kk | ポリメチルシルセスキオキサン系重合体およびポリメチルシルセスキオキサン構造を有するポリマー |
US20080108737A1 (en) * | 2006-06-06 | 2008-05-08 | Shin-Etsu Chemical Co., Ltd. | Additive for imparting flame retardance with an organic resin, flame retardant resin composition, and article molded therefrom |
KR20080085383A (ko) * | 2007-03-19 | 2008-09-24 | (주)석경에이.티 | 다관능기를 함유하는 유기 실리카 미세입자 및 이의제조방법 |
KR20090055966A (ko) * | 2007-11-29 | 2009-06-03 | (주)석경에이.티 | 유기 실리카 미세입자 및 정전하상 현상용 토너 외첨제 |
CN104861165A (zh) * | 2015-06-03 | 2015-08-26 | 宁波工程学院 | 一种巯基-烯聚合物阻燃体系的制备方法 |
CN105860083A (zh) * | 2016-04-14 | 2016-08-17 | 顺德职业技术学院 | 改性乙烯基硅树脂及含改性乙烯基硅树脂的有机硅封胶的制备方法 |
CN106317409A (zh) * | 2016-08-20 | 2017-01-11 | 浙江新安化工集团股份有限公司 | 一种聚硅氧烷微球的制备方法 |
CN106521970A (zh) * | 2016-10-28 | 2017-03-22 | 南昌航空大学 | 一种基于巯基‑烯光聚合的聚硫醚聚合物接枝碳纤维的制备方法 |
CN111100298A (zh) * | 2019-04-25 | 2020-05-05 | 杭州师范大学 | 一种光学透明有机硅材料及其制备方法 |
Non-Patent Citations (2)
Title |
---|
RUI-CHAO CHEN ET AL.: "Chemically bonding BaTiO3 nanoparticles in highly filled polymer nanocomposites for greatly enhanced dielectric properties", 《JOURNAL OF MATERIALS CHEMISTRY C》 * |
袁刚等: "巯基-苯基聚倍半硅氧烷的合成", 《材料开发与应用》 * |
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