CN1114005C - 含有氧化钛的天然纤维及其制造方法 - Google Patents
含有氧化钛的天然纤维及其制造方法 Download PDFInfo
- Publication number
- CN1114005C CN1114005C CN98805379A CN98805379A CN1114005C CN 1114005 C CN1114005 C CN 1114005C CN 98805379 A CN98805379 A CN 98805379A CN 98805379 A CN98805379 A CN 98805379A CN 1114005 C CN1114005 C CN 1114005C
- Authority
- CN
- China
- Prior art keywords
- titanium oxide
- organic fiber
- natural organic
- wool
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 162
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 title claims abstract description 154
- 239000000835 fiber Substances 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims description 31
- 230000008569 process Effects 0.000 title description 3
- 210000002268 wool Anatomy 0.000 claims abstract description 95
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims abstract description 30
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 27
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004327 boric acid Substances 0.000 claims abstract description 8
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 claims abstract description 8
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000010931 gold Substances 0.000 claims description 18
- 229910000510 noble metal Inorganic materials 0.000 claims description 16
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 15
- 238000007747 plating Methods 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 238000012545 processing Methods 0.000 claims description 14
- 229910052737 gold Inorganic materials 0.000 claims description 13
- 108090000623 proteins and genes Proteins 0.000 claims description 11
- 102000004169 proteins and genes Human genes 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 10
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- 150000003609 titanium compounds Chemical class 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 5
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims description 4
- 229940018557 citraconic acid Drugs 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 230000006866 deterioration Effects 0.000 claims description 4
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003125 aqueous solvent Substances 0.000 claims description 2
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 2
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid group Chemical group S(N)(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 20
- 229910052719 titanium Inorganic materials 0.000 abstract description 14
- 239000010936 titanium Substances 0.000 abstract description 14
- 239000000203 mixture Substances 0.000 abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- -1 titanium alkoxide Chemical class 0.000 abstract description 6
- 239000007864 aqueous solution Substances 0.000 abstract description 4
- 125000000129 anionic group Chemical group 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 60
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 21
- 238000007146 photocatalysis Methods 0.000 description 16
- 230000001699 photocatalysis Effects 0.000 description 16
- 230000003115 biocidal effect Effects 0.000 description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052709 silver Inorganic materials 0.000 description 8
- 239000004332 silver Substances 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 238000005286 illumination Methods 0.000 description 6
- 229940116298 l- malic acid Drugs 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 230000003373 anti-fouling effect Effects 0.000 description 5
- 238000006555 catalytic reaction Methods 0.000 description 5
- 238000004299 exfoliation Methods 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 229910001258 titanium gold Inorganic materials 0.000 description 5
- 241000191967 Staphylococcus aureus Species 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 4
- 238000005108 dry cleaning Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 230000008676 import Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 241000208125 Nicotiana Species 0.000 description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007772 electroless plating Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910001423 beryllium ion Inorganic materials 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- DUFCMRCMPHIFTR-UHFFFAOYSA-N 5-(dimethylsulfamoyl)-2-methylfuran-3-carboxylic acid Chemical compound CN(C)S(=O)(=O)C1=CC(C(O)=O)=C(C)O1 DUFCMRCMPHIFTR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 241000588748 Klebsiella Species 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000021539 instant coffee Nutrition 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- KELHQGOVULCJSG-UHFFFAOYSA-N n,n-dimethyl-1-(5-methylfuran-2-yl)ethane-1,2-diamine Chemical compound CN(C)C(CN)C1=CC=C(C)O1 KELHQGOVULCJSG-UHFFFAOYSA-N 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- GQUJEMVIKWQAEH-UHFFFAOYSA-N titanium(III) oxide Chemical compound O=[Ti]O[Ti]=O GQUJEMVIKWQAEH-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- GBNDTYKAOXLLID-UHFFFAOYSA-N zirconium(4+) ion Chemical compound [Zr+4] GBNDTYKAOXLLID-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2927—Rod, strand, filament or fiber including structurally defined particulate matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Catalysts (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Inorganic Fibers (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
试样名 | 制备后立即 | 1小时 | 灭菌率(%) |
未处理羊毛 | 1.72×104 | 1.61×104 | 6.4 |
处理羊毛 | 1.72×104 | 1.83×102 | 89.4 |
试样名 | 制备后立即 | 1小时 | 灭菌率(%) |
未处理羊毛 | 1.22×104 | 1.24×104 | -1.6 |
处理羊毛 | 1.22×104 | 500 | 95.9 |
初期(ppm) | 5分钟后(ppm) | 30分钟后(ppm) | 60分钟后(ppm) | ||
氨 | 未处理羊毛 | 300 | 280 | 240 | 200 |
处理羊毛 | 300 | 250 | 120 | 30 | |
硫化氢 | 未处理羊毛 | 30 | 30 | 29 | 29 |
处理羊毛 | 30 | 25 | 10 | 5 | |
乙酸 | 未处理羊毛 | 100 | 70 | 55 | 40 |
处理羊毛 | 100 | 70 | 40 | 10 |
初期(ppm) | 5分钟后(ppm) | 30分钟后(ppm) | 60分钟后(ppm) | ||
氨 | 未处理羊毛 | 300 | 280 | 240 | 200 |
处理羊毛 | 300 | 270 | 240 | 200 | |
硫化氢 | 未处理羊毛 | 30 | 30 | 29 | 29 |
处理羊毛 | 30 | 30 | 29 | 29 | |
乙酸 | 未处理羊毛 | 100 | 70 | 55 | 40 |
处理羊毛 | 100 | 70 | 50 | 40 |
光照射(30W荧光灯10cm下) | 曝光20小时后 | |
初期着色 | 20小时后着色 | |
未处理羊毛(对照) | 100 | 85 |
处理羊毛 | 100 | 52 |
氧化钛粘附量(%) | 脱落度(%) | |
初期 | 0.34 | - |
干洗10次 | 0.33 | 2.9 |
干洗20次 | 0.32 | 5.9 |
实施例1 | 实施例1-b | |
变黄度(Δb) | 0.18 | 6.3 |
试样名 | 制备后立即 | 1小时 | 灭菌率(%) |
未处理羊毛 | 1.90×104 | 1.97×104 | -6.4 |
处理羊毛 | 1.90×104 | 50 | 99.7 |
试样名 | 制备后立即 | 1小时 | 灭菌率(%) |
未处理羊毛 | 1.64×104 | 1.75×104 | -6.7 |
处理羊毛 | 1.64×104 | 20 | 99.9 |
初期(ppm) | 5分钟后(ppm) | 30分钟后(ppm) | 60分钟后(ppm) | |
(氨) | ||||
未处理羊毛 | 300 | 280 | 240 | 200 |
处理羊毛 | 300 | 150 | 20 | 0 |
(硫化氢) | ||||
未处理羊毛 | 30 | 30 | 29 | 29 |
处理羊毛 | 30 | 20 | 10 | 5 |
(乙酸) | ||||
未处理羊毛 | 100 | 70 | 55 | 40 |
处理羊毛 | 100 | 20 | 10 | 0 |
初期(ppm) | 5分钟后(ppm) | 30分钟后(ppm) | 60分钟后(ppm) | |
(氨) | ||||
未处理羊毛 | 300 | 280 | 240 | 200 |
处理羊毛 | 300 | 170 | 40 | 0 |
(硫化氢) | ||||
未处理羊毛 | 30 | 30 | 29 | 29 |
处理羊毛 | 30 | 20 | 9 | 0 |
(乙酸) | ||||
未处理羊毛 | 100 | 70 | 55 | 40 |
处理羊毛 | 100 | 20 | 0 | 0 |
光照射(30W荧光灯10cm下) | 曝光20小时后 | |
初期着色 | 20小时后着色 | |
未处理羊毛 | 100 | 85 |
处理羊毛 | 100 | 22 |
氧化钛粘附量(%) | 脱落度(%) | |
初期 | 0.52 | - |
洗涤10次 | 0.51 | 1.9 |
洗涤20次 | 0.48 | 7.7 |
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP133923/1997 | 1997-05-23 | ||
JP13392397 | 1997-05-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1257560A CN1257560A (zh) | 2000-06-21 |
CN1114005C true CN1114005C (zh) | 2003-07-09 |
Family
ID=15116256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN98805379A Expired - Fee Related CN1114005C (zh) | 1997-05-23 | 1998-05-18 | 含有氧化钛的天然纤维及其制造方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US6265064B1 (zh) |
EP (1) | EP0997575B1 (zh) |
KR (1) | KR100483935B1 (zh) |
CN (1) | CN1114005C (zh) |
AT (1) | ATE247187T1 (zh) |
DE (1) | DE69817185T2 (zh) |
TW (1) | TW473575B (zh) |
WO (1) | WO1998053132A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101084342B (zh) * | 2004-11-02 | 2010-09-29 | 有限会社高·饭研究所 | 具有杀菌作用的过滤器、口罩等用片材 |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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US6479141B1 (en) * | 1999-09-30 | 2002-11-12 | Showa Denko K.K. | Photocatalytic coating composition and product having photocatalytic thin film |
KR20020065139A (ko) * | 2001-02-05 | 2002-08-13 | 안정오 | 항균양모의 처리제법 |
TWI301164B (zh) | 2001-10-12 | 2008-09-21 | Phild Co Ltd | |
US6916261B2 (en) * | 2003-10-03 | 2005-07-12 | Stephen M. Cullen | Composite bamboo sporting implement |
JP2008519289A (ja) * | 2004-09-14 | 2008-06-05 | シーディーエム オプティックス, インコーポレイテッド | 低い高さのイメージングシステムおよび関連方法 |
US7560142B1 (en) * | 2005-09-08 | 2009-07-14 | Graver Technologies Llc | Fibers with bound metal oxides and method thereof |
DE102006011848A1 (de) * | 2006-03-15 | 2007-09-20 | Bayerische Motoren Werke Ag | Selbstreinigende Oberfläche |
US8679588B2 (en) * | 2007-04-02 | 2014-03-25 | The Hong Kong Polytechnic University | Formulation coated self-cleaning wool |
JP5760305B2 (ja) * | 2009-10-09 | 2015-08-05 | 富士通株式会社 | 保護袋 |
WO2016013484A1 (ja) * | 2014-07-22 | 2016-01-28 | 株式会社シルクウェーブ産業 | 表面改質繊維材料の製造方法および表面改質繊維材料 |
EP3705622B1 (en) * | 2017-10-31 | 2022-06-08 | Nippon Paper Industries Co., Ltd. | Titanium oxide composite fibers and method for producing same |
CN109898215A (zh) * | 2019-02-28 | 2019-06-18 | 上海恋轩实业有限公司 | 具有抗寒保暖功能的复合羊毛面料及其制作工艺 |
WO2020243889A1 (en) * | 2019-06-04 | 2020-12-10 | Lora & Festa Limited | Functional cashmere fiber and fabrication method thereof |
Citations (2)
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JPS6386205A (ja) * | 1986-09-29 | 1988-04-16 | 大塚化学株式会社 | 導電性組成物 |
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JPH03221146A (ja) * | 1990-01-29 | 1991-09-30 | Mitsubishi Heavy Ind Ltd | 燃焼排ガス処理用触媒フィルタ基材 |
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JP3273269B2 (ja) * | 1993-02-17 | 2002-04-08 | 株式会社サトーセン | 繊維品に抗菌性および抗かび性を付与する方法 |
JPH0866635A (ja) | 1993-12-14 | 1996-03-12 | Toto Ltd | 光触媒薄膜及びその形成方法 |
JP3390278B2 (ja) * | 1994-12-05 | 2003-03-24 | ダイセル化学工業株式会社 | セルロースエステル組成物および成形品 |
US5919422A (en) * | 1995-07-28 | 1999-07-06 | Toyoda Gosei Co., Ltd. | Titanium dioxide photo-catalyzer |
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- 1998-05-16 TW TW087107614A patent/TW473575B/zh not_active IP Right Cessation
- 1998-05-18 DE DE69817185T patent/DE69817185T2/de not_active Expired - Fee Related
- 1998-05-18 AT AT98919648T patent/ATE247187T1/de not_active IP Right Cessation
- 1998-05-18 KR KR10-1999-7010821A patent/KR100483935B1/ko not_active IP Right Cessation
- 1998-05-18 EP EP98919648A patent/EP0997575B1/en not_active Expired - Lifetime
- 1998-05-18 WO PCT/JP1998/002188 patent/WO1998053132A1/ja active IP Right Grant
- 1998-05-18 CN CN98805379A patent/CN1114005C/zh not_active Expired - Fee Related
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JPS6065179A (ja) * | 1983-09-14 | 1985-04-13 | 凸版印刷株式会社 | 金属被覆繊維 |
JPS6386205A (ja) * | 1986-09-29 | 1988-04-16 | 大塚化学株式会社 | 導電性組成物 |
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CN101084342B (zh) * | 2004-11-02 | 2010-09-29 | 有限会社高·饭研究所 | 具有杀菌作用的过滤器、口罩等用片材 |
Also Published As
Publication number | Publication date |
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EP0997575A4 (en) | 2000-07-26 |
WO1998053132A1 (fr) | 1998-11-26 |
DE69817185D1 (de) | 2003-09-18 |
EP0997575B1 (en) | 2003-08-13 |
KR20010012855A (ko) | 2001-02-26 |
US6265064B1 (en) | 2001-07-24 |
KR100483935B1 (ko) | 2005-04-15 |
EP0997575A1 (en) | 2000-05-03 |
DE69817185T2 (de) | 2004-06-09 |
CN1257560A (zh) | 2000-06-21 |
ATE247187T1 (de) | 2003-08-15 |
TW473575B (en) | 2002-01-21 |
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