CN110982056B - 一种炔二醇嵌段聚醚的合成方法 - Google Patents

一种炔二醇嵌段聚醚的合成方法 Download PDF

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Publication number
CN110982056B
CN110982056B CN201911256920.9A CN201911256920A CN110982056B CN 110982056 B CN110982056 B CN 110982056B CN 201911256920 A CN201911256920 A CN 201911256920A CN 110982056 B CN110982056 B CN 110982056B
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alkynediol
block polyether
diol
composite catalyst
initiator
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Chinese (zh)
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CN110982056A (zh
Inventor
殷其文
郏超伟
糜泽峰
高洪军
裘碧菡
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Zhejiang Huangma Technology Co Ltd
Zhejiang Lvkean Chemical Co Ltd
Zhejiang Huangma Shangyi New Material Co Ltd
Zhejiang Huangma Surfactant Research Institute Co Ltd
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Zhejiang Huangma Technology Co Ltd
Zhejiang Lvkean Chemical Co Ltd
Zhejiang Huangma Shangyi New Material Co Ltd
Zhejiang Huangma Surfactant Research Institute Co Ltd
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Priority to CN201911256920.9A priority Critical patent/CN110982056B/zh
Publication of CN110982056A publication Critical patent/CN110982056A/zh
Priority to PCT/CN2020/099059 priority patent/WO2021114619A1/zh
Priority to KR1020227023420A priority patent/KR20220114004A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/22—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the initiator used in polymerisation
    • C08G2650/24—Polymeric initiators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/58—Ethylene oxide or propylene oxide copolymers, e.g. pluronics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/60—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing acetylenic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/62—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the nature of monomer used
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)
CN201911256920.9A 2019-12-10 2019-12-10 一种炔二醇嵌段聚醚的合成方法 Active CN110982056B (zh)

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Application Number Priority Date Filing Date Title
CN201911256920.9A CN110982056B (zh) 2019-12-10 2019-12-10 一种炔二醇嵌段聚醚的合成方法
PCT/CN2020/099059 WO2021114619A1 (zh) 2019-12-10 2020-06-30 一种炔二醇嵌段聚醚及其合成方法
KR1020227023420A KR20220114004A (ko) 2019-12-10 2020-06-30 알킨디올 블록 폴리에테르 및 이의 합성 방법

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CN110982056B true CN110982056B (zh) 2022-09-27

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Publication number Priority date Publication date Assignee Title
CN110982056B (zh) * 2019-12-10 2022-09-27 浙江皇马科技股份有限公司 一种炔二醇嵌段聚醚的合成方法
CN111471180A (zh) * 2020-05-07 2020-07-31 上海麦豪新材料科技有限公司 一种有机硅表面活性剂及其在制备慢回弹聚氨酯泡沫体中的应用
CN111533916A (zh) * 2020-05-11 2020-08-14 江西麦豪化工科技有限公司 一种有机硅表面活性剂及其在制备聚氨酯软质泡沫体中的应用
CN112898556B (zh) * 2021-03-23 2023-08-01 浙江皇马科技股份有限公司 一种炔二醇聚醚及制备方法
CN115109246B (zh) * 2022-07-01 2023-07-14 佳化化学科技发展（上海）有限公司 一种炔基醇醚及其制备方法与应用
CN117487153B (zh) * 2023-12-29 2024-05-10 山东一诺威新材料有限公司 用于工业消泡的炔醇聚醚及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03163038A (ja) * 1989-08-15 1991-07-15 Nisshin Kagaku Kogyo Kk アセチレングリコールのプロピレンオキサイド付加物及びその製造方法
CN107935826A (zh) * 2017-11-21 2018-04-20 浙江皇马科技股份有限公司 一种低温稳定性好的脂肪醇嵌段聚醚及其制备方法和应用
CN109970964A (zh) * 2019-03-29 2019-07-05 浙江皇马科技股份有限公司 一种叔炔醇聚醚的制备方法

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US6864395B2 (en) * 1999-05-04 2005-03-08 Air Products And Chemicals, Inc. Acetylenic diol ethylene oxide/propylene oxide adducts and processes for their manufacture
US6455234B1 (en) * 1999-05-04 2002-09-24 Air Products And Chemicals, Inc. Acetylenic diol ethylene oxide/propylene oxide adducts and their use in photoresist developers
CN103242143A (zh) * 2013-04-18 2013-08-14 岳阳市英泰合成材料有限公司 一种炔醇烷氧基化的生产工艺
CN103965462B (zh) * 2014-05-19 2016-07-06 上海多纶化工有限公司 用于炔二醇聚氧乙烯醚合成的催化剂
CN105384926B (zh) * 2015-12-17 2017-05-17 上海多纶化工有限公司 炔二醇聚醚粗产物的精制方法
CN110982056B (zh) * 2019-12-10 2022-09-27 浙江皇马科技股份有限公司 一种炔二醇嵌段聚醚的合成方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03163038A (ja) * 1989-08-15 1991-07-15 Nisshin Kagaku Kogyo Kk アセチレングリコールのプロピレンオキサイド付加物及びその製造方法
CN107935826A (zh) * 2017-11-21 2018-04-20 浙江皇马科技股份有限公司 一种低温稳定性好的脂肪醇嵌段聚醚及其制备方法和应用
CN109970964A (zh) * 2019-03-29 2019-07-05 浙江皇马科技股份有限公司 一种叔炔醇聚醚的制备方法

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WO2021114619A1 (zh) 2021-06-17
KR20220114004A (ko) 2022-08-17

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