CN1109709C - 高弹性泡沫材料 - Google Patents
高弹性泡沫材料 Download PDFInfo
- Publication number
- CN1109709C CN1109709C CN98107469A CN98107469A CN1109709C CN 1109709 C CN1109709 C CN 1109709C CN 98107469 A CN98107469 A CN 98107469A CN 98107469 A CN98107469 A CN 98107469A CN 1109709 C CN1109709 C CN 1109709C
- Authority
- CN
- China
- Prior art keywords
- rubber
- weight
- thermoplastic polymers
- repeating unit
- thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000006260 foam Substances 0.000 title claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 70
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 70
- 229920006342 thermoplastic vulcanizate Polymers 0.000 claims abstract description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 238000011084 recovery Methods 0.000 claims abstract description 15
- 229920001971 elastomer Polymers 0.000 claims description 70
- 239000005060 rubber Substances 0.000 claims description 66
- 238000005187 foaming Methods 0.000 claims description 42
- 239000000126 substance Substances 0.000 claims description 41
- 229920001577 copolymer Polymers 0.000 claims description 19
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 9
- 229920001195 polyisoprene Polymers 0.000 claims description 9
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 238000004132 cross linking Methods 0.000 claims description 7
- 238000002474 experimental method Methods 0.000 claims description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- JBAUPCNQUQGXJT-UHFFFAOYSA-N 1-ethenyl-4-methylbenzene;2-methylprop-1-ene Chemical compound CC(C)=C.CC1=CC=C(C=C)C=C1 JBAUPCNQUQGXJT-UHFFFAOYSA-N 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 229920006285 olefinic elastomer Polymers 0.000 claims description 4
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000006069 physical mixture Substances 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 23
- 239000000178 monomer Substances 0.000 description 17
- -1 for example Polymers 0.000 description 13
- 229920000098 polyolefin Polymers 0.000 description 13
- 238000012360 testing method Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- 150000001721 carbon Chemical group 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 229920003051 synthetic elastomer Polymers 0.000 description 8
- 229920002943 EPDM rubber Polymers 0.000 description 7
- 238000007664 blowing Methods 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000000945 filler Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 7
- 239000005061 synthetic rubber Substances 0.000 description 7
- 229920002725 thermoplastic elastomer Polymers 0.000 description 7
- 239000005038 ethylene vinyl acetate Substances 0.000 description 6
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 6
- 239000006261 foam material Substances 0.000 description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 6
- 229920003031 santoprene Polymers 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000004902 Softening Agent Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 229920000428 triblock copolymer Polymers 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229920003052 natural elastomer Polymers 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000031709 bromination Effects 0.000 description 3
- 238000005893 bromination reaction Methods 0.000 description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000004636 vulcanized rubber Substances 0.000 description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 2
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 2
- 229920006245 ethylene-butyl acrylate Polymers 0.000 description 2
- 239000005043 ethylene-methyl acrylate Substances 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229920005555 halobutyl Polymers 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 230000026030 halogenation Effects 0.000 description 2
- 238000005658 halogenation reaction Methods 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000012958 reprocessing Methods 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- VXPSQDAMFATNNG-UHFFFAOYSA-N 3-[2-(2,5-dioxopyrrol-3-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C(=CC=CC=2)C=2C(NC(=O)C=2)=O)=C1 VXPSQDAMFATNNG-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 206010012442 Dermatitis contact Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 244000228957 Ferula foetida Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 208000010247 contact dermatitis Diseases 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000011243 crosslinked material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000008380 degradant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 150000007520 diprotic acids Chemical class 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- DPUXQWOMYBMHRN-UHFFFAOYSA-N hexa-2,3-diene Chemical compound CCC=C=CC DPUXQWOMYBMHRN-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/125—Water, e.g. hydrated salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US848,992 | 1997-05-02 | ||
| US848992 | 1997-05-02 | ||
| US08/848,992 US5939464A (en) | 1997-05-02 | 1997-05-02 | High elasticity foams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1199063A CN1199063A (zh) | 1998-11-18 |
| CN1109709C true CN1109709C (zh) | 2003-05-28 |
Family
ID=25304806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98107469A Expired - Lifetime CN1109709C (zh) | 1997-05-02 | 1998-04-29 | 高弹性泡沫材料 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5939464A (enExample) |
| EP (1) | EP0875526B1 (enExample) |
| JP (1) | JPH10306177A (enExample) |
| KR (1) | KR19980086726A (enExample) |
| CN (1) | CN1109709C (enExample) |
| AU (1) | AU732088B2 (enExample) |
| BR (1) | BR9801493A (enExample) |
| CA (1) | CA2232851A1 (enExample) |
| DE (1) | DE69823091T2 (enExample) |
| ES (1) | ES2215251T3 (enExample) |
| IL (1) | IL124270A (enExample) |
| MY (1) | MY114815A (enExample) |
| TW (1) | TW460517B (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002523585A (ja) * | 1998-09-01 | 2002-07-30 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 高分子成形材料、泡生成工程におけるその成形材料の使用、発泡方法、発泡した成形材料および発泡した成形材料を含有する製品 |
| US6855424B1 (en) * | 1998-12-28 | 2005-02-15 | Kinberly-Clark Worldwide, Inc. | Breathable composite elastic material having a cellular elastomeric film layer and method of making same |
| US6258868B1 (en) * | 1999-03-15 | 2001-07-10 | Gerro Plast Gmbh | Foam material |
| US6323251B1 (en) * | 1999-09-24 | 2001-11-27 | 3M Innovative Properties Co | Thermoplastic/thermoset hybrid foams and methods for making same |
| JP4799793B2 (ja) * | 2000-01-31 | 2011-10-26 | アドバンスド エラストマー システムズ，エル．ピー． | 改良された接着特性を有する熱可塑性エラストマー |
| ATE274026T1 (de) | 2000-03-01 | 2004-09-15 | Jsr Corp | Thermoplastische elastomerzusammensetzung, daraus hergestellter schaum und verfahren zur schaumherstellung |
| FR2807965A1 (fr) * | 2000-04-25 | 2001-10-26 | Michelin Soc Tech | Procede de fabrication d'un appui de securite pour pneumatique et appui obtenu par ce procede |
| US6530231B1 (en) | 2000-09-22 | 2003-03-11 | Te Technology, Inc. | Thermoelectric assembly sealing member and thermoelectric assembly incorporating same |
| US6653360B2 (en) | 2001-05-23 | 2003-11-25 | Chakra V. Gupta | Flexible foamed polyethylene |
| WO2002100940A1 (en) * | 2001-06-08 | 2002-12-19 | Thermoplastic Rubber Systems, Inc. | Thermoplastic vulcanizates |
| AU2002366330A1 (en) * | 2001-12-13 | 2003-06-30 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcaninates for run-flat tires |
| US6864195B2 (en) * | 2002-08-15 | 2005-03-08 | Bfs Diversified Products, Llc | Heat weldable roofing membrane |
| JP5091388B2 (ja) * | 2002-08-15 | 2012-12-05 | アドバンスド エラストマー システムズ，エル．ピー． | 強化された発泡特性および物理的性質を有する熱可塑性エラストマー |
| WO2005082996A1 (fr) * | 2004-02-24 | 2005-09-09 | Arkema France | Composition reticulee comprenant un copolymere sequence triblocs, son procede d'obtention et ses utilisations |
| JP4291374B2 (ja) | 2004-09-03 | 2009-07-08 | クレイトン・ポリマーズ・リサーチ・ベー・ベー | 発泡性ポリマー組成物および発泡組成物を含む物品 |
| DE102005049911A1 (de) | 2005-10-17 | 2007-04-19 | Woco Industrietechnik Gmbh | Verwendung eines flächigen Mehrschichtverbundsystems als Bauteil im Motorinnenraum eines Kraftfahrzeugs |
| DE102006014235A1 (de) * | 2006-03-28 | 2007-10-04 | Brugg Rohr Ag, Holding | Mantel für wärmeisolierte Leitungsrohre |
| KR100856166B1 (ko) | 2006-04-24 | 2008-09-03 | 크레이튼 폴리머즈 리서치 비.브이. | 발포성 중합체 조성물 및 발포된 조성물을 함유하는 물품 |
| DE102007026805B4 (de) | 2007-06-06 | 2009-08-20 | Woco Industrietechnik Gmbh | Mediendichtes Bauteil, insbesondere Entlüftungsrohr, umfassend mindestens ein Metallteil und mindestens ein Kunststoffteil |
| US7847658B2 (en) * | 2008-06-04 | 2010-12-07 | Alcatel-Lucent Usa Inc. | Light-weight low-thermal-expansion polymer foam for radiofrequency filtering applications |
| JP6032636B2 (ja) * | 2012-05-14 | 2016-11-30 | 国立大学法人東京農工大学 | ゴム−ポリオレフィン複合体の製造方法 |
| US20160177159A1 (en) * | 2013-09-11 | 2016-06-23 | Dow Global Technologies Llc | Multi-phase elastomeric thermally conductive materials |
| US20150073064A1 (en) * | 2013-09-12 | 2015-03-12 | Kimberly-Clark Worldwide, Inc. | Highly crystalline and frothed polyolefin foam |
| US20170253709A1 (en) * | 2014-09-08 | 2017-09-07 | Mitsui Chemicals, Inc. | Thermoplastic elastomer composition and molded product obtained therefrom |
| CN105504427A (zh) * | 2015-12-30 | 2016-04-20 | 芜湖馨源海绵有限公司 | 一种具有高密封性的汽车水箱海绵密封条及其制备方法 |
| US10808971B2 (en) | 2016-08-12 | 2020-10-20 | Te Technology, Inc. | Thermoelectric assembly sealing member with metal vapor barrier |
| US11768017B2 (en) | 2016-08-12 | 2023-09-26 | Te Technology, Inc. | Thermoelectric assembly sealing member with vapor barrier |
| WO2020056243A1 (en) * | 2018-09-13 | 2020-03-19 | 3M Innovative Properties Company | Polymeric membrane useful as a commercial roofing membrane |
| CN112266544A (zh) * | 2020-10-31 | 2021-01-26 | 三益(玉田)新材料科技有限公司 | 一种高尺寸稳定性的聚苯乙烯挤塑板及其制备工艺 |
| CN115266412B (zh) * | 2022-08-23 | 2025-11-28 | 中国石油天然气集团有限公司 | 油气井固井用水泥石的抗套管变形能力评价方法和系统 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4130535A (en) * | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
| EP0503220A1 (en) * | 1991-03-13 | 1992-09-16 | Advanced Elastomer Systems, L.P. | Foaming thermoplastic elastomers |
| WO1995004775A1 (en) * | 1993-08-05 | 1995-02-16 | Dsm N.V. | Plastic article and process for the preparation thereof |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4020025A (en) * | 1973-05-08 | 1977-04-26 | Basf Aktiengesellschaft | Extrudable foamable composition comprising an olefin polymer, a styrene polymer and a hydrogenated styrene butadiene block copolymer |
| US4130534A (en) * | 1976-12-27 | 1978-12-19 | Monsanto Company | Elastoplastic compositions of butyl rubber and polyolefin resin |
| DE2822815C2 (de) * | 1977-05-26 | 1994-02-17 | Mitsui Petrochemical Ind | Verfahren zur Herstellung einer teilweise vulkanisierten thermoplastischen Masse |
| US4311628A (en) * | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4677133A (en) * | 1984-08-06 | 1987-06-30 | Q'so, Inc. | Thermally applied sealants and process |
| DE3532357A1 (de) * | 1985-09-11 | 1987-03-19 | Bayer Ag | Thermoplastische elastomere |
| JPS62201950A (ja) * | 1986-03-03 | 1987-09-05 | Toa Nenryo Kogyo Kk | 熱可塑性エラストマ−組成物 |
| US4898760A (en) * | 1987-11-17 | 1990-02-06 | Amesbury Industries, Inc. | Process and apparatus for extruding a low density elastomeric thermoplastic foam |
| IT1223262B (it) * | 1987-12-11 | 1990-09-19 | Himont Inc | Composizioni elasto plastiche e procedimento per la loro preparazione |
| US5073597A (en) * | 1989-05-26 | 1991-12-17 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
| US5114987A (en) * | 1990-10-15 | 1992-05-19 | Edison Polymer Innovation Corp. | Foamed polymer blends |
| US5176953A (en) * | 1990-12-21 | 1993-01-05 | Amoco Corporation | Oriented polymeric microporous films |
-
1997
- 1997-05-02 US US08/848,992 patent/US5939464A/en not_active Expired - Lifetime
-
1998
- 1998-03-19 CA CA002232851A patent/CA2232851A1/en not_active Abandoned
- 1998-03-25 TW TW087104462A patent/TW460517B/zh not_active IP Right Cessation
- 1998-04-22 JP JP10128271A patent/JPH10306177A/ja active Pending
- 1998-04-28 BR BR9801493-5A patent/BR9801493A/pt not_active Application Discontinuation
- 1998-04-28 IL IL12427098A patent/IL124270A/en not_active IP Right Cessation
- 1998-04-29 DE DE69823091T patent/DE69823091T2/de not_active Expired - Lifetime
- 1998-04-29 EP EP98107817A patent/EP0875526B1/en not_active Expired - Lifetime
- 1998-04-29 ES ES98107817T patent/ES2215251T3/es not_active Expired - Lifetime
- 1998-04-29 CN CN98107469A patent/CN1109709C/zh not_active Expired - Lifetime
- 1998-04-30 MY MYPI98001944A patent/MY114815A/en unknown
- 1998-05-02 KR KR1019980015849A patent/KR19980086726A/ko not_active Ceased
- 1998-05-22 AU AU68067/98A patent/AU732088B2/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4130535A (en) * | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
| EP0503220A1 (en) * | 1991-03-13 | 1992-09-16 | Advanced Elastomer Systems, L.P. | Foaming thermoplastic elastomers |
| WO1995004775A1 (en) * | 1993-08-05 | 1995-02-16 | Dsm N.V. | Plastic article and process for the preparation thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| US5939464A (en) | 1999-08-17 |
| CA2232851A1 (en) | 1998-11-02 |
| ES2215251T3 (es) | 2004-10-01 |
| CN1199063A (zh) | 1998-11-18 |
| DE69823091D1 (de) | 2004-05-19 |
| TW460517B (en) | 2001-10-21 |
| EP0875526A3 (en) | 1999-04-07 |
| MY114815A (en) | 2003-01-31 |
| AU6806798A (en) | 1998-11-26 |
| EP0875526A2 (en) | 1998-11-04 |
| EP0875526B1 (en) | 2004-04-14 |
| JPH10306177A (ja) | 1998-11-17 |
| KR19980086726A (ko) | 1998-12-05 |
| DE69823091T2 (de) | 2005-03-24 |
| BR9801493A (pt) | 1999-12-21 |
| AU732088B2 (en) | 2001-04-12 |
| IL124270A (en) | 2001-07-24 |
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