CN110783567B - 硫代磷酸锂复合材料的微波合成 - Google Patents
硫代磷酸锂复合材料的微波合成 Download PDFInfo
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- CN110783567B CN110783567B CN201910672318.7A CN201910672318A CN110783567B CN 110783567 B CN110783567 B CN 110783567B CN 201910672318 A CN201910672318 A CN 201910672318A CN 110783567 B CN110783567 B CN 110783567B
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- Prior art keywords
- composite
- thiophosphate
- lithium thiophosphate
- component
- microwave
- Prior art date
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- WAWVSIXKQGJDBE-UHFFFAOYSA-K trilithium thiophosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=S WAWVSIXKQGJDBE-UHFFFAOYSA-K 0.000 title claims abstract description 54
- 239000002131 composite material Substances 0.000 title claims abstract description 50
- 238000003786 synthesis reaction Methods 0.000 title abstract description 21
- 230000015572 biosynthetic process Effects 0.000 title abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 25
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 75
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 72
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 36
- 238000006243 chemical reaction Methods 0.000 claims description 34
- 229910018091 Li 2 S Inorganic materials 0.000 claims description 31
- 239000002904 solvent Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 29
- 239000002798 polar solvent Substances 0.000 claims description 18
- 229910001216 Li2S Inorganic materials 0.000 claims description 11
- 229910005842 GeS2 Inorganic materials 0.000 claims description 8
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 8
- GUWHRJQTTVADPB-UHFFFAOYSA-N lithium azide Chemical compound [Li+].[N-]=[N+]=[N-] GUWHRJQTTVADPB-UHFFFAOYSA-N 0.000 claims description 8
- 230000035484 reaction time Effects 0.000 claims description 8
- 230000007704 transition Effects 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- 230000002194 synthesizing effect Effects 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000306 component Substances 0.000 claims 1
- 238000004729 solvothermal method Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 36
- 239000000843 powder Substances 0.000 description 20
- 239000007787 solid Substances 0.000 description 18
- 229910001416 lithium ion Inorganic materials 0.000 description 13
- 238000001069 Raman spectroscopy Methods 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 11
- 239000002243 precursor Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 238000002411 thermogravimetry Methods 0.000 description 10
- 238000001237 Raman spectrum Methods 0.000 description 9
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 9
- 229910052744 lithium Inorganic materials 0.000 description 9
- 239000008188 pellet Substances 0.000 description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
- 239000007784 solid electrolyte Substances 0.000 description 7
- 230000004580 weight loss Effects 0.000 description 7
- 238000000498 ball milling Methods 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000001757 thermogravimetry curve Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000011244 liquid electrolyte Substances 0.000 description 4
- 238000003801 milling Methods 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 3
- 229910011201 Li7P3S11 Inorganic materials 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 239000010416 ion conductor Substances 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 3
- 101100317222 Borrelia hermsii vsp3 gene Proteins 0.000 description 2
- 239000006091 Macor Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- -1 lithium hexafluorophosphate salt Chemical compound 0.000 description 2
- 229910000921 lithium phosphorous sulfides (LPS) Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011255 nonaqueous electrolyte Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910009160 xLi2S Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000002227 LISICON Substances 0.000 description 1
- 229910018869 La0.5Li0.5TiO3 Inorganic materials 0.000 description 1
- 229910009178 Li1.3Al0.3Ti1.7(PO4)3 Inorganic materials 0.000 description 1
- 229910005313 Li14ZnGe4O16 Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000002228 NASICON Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000007578 melt-quenching technique Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000007144 microwave assisted synthesis reaction Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 238000010671 solid-state reaction Methods 0.000 description 1
- 238000006561 solvent free reaction Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/126—Microwaves
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/14—Sulfur, selenium, or tellurium compounds of phosphorus
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/06—Sulfates; Sulfites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Electromagnetism (AREA)
- Crystallography & Structural Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/043,944 US11325096B2 (en) | 2018-07-24 | 2018-07-24 | Microwave synthesis of lithium thiophosphate composite materials |
| US16/043,944 | 2018-07-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110783567A CN110783567A (zh) | 2020-02-11 |
| CN110783567B true CN110783567B (zh) | 2024-06-11 |
Family
ID=67438733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910672318.7A Active CN110783567B (zh) | 2018-07-24 | 2019-07-24 | 硫代磷酸锂复合材料的微波合成 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US11325096B2 (https=) |
| EP (1) | EP3599659B1 (https=) |
| JP (1) | JP7362332B2 (https=) |
| CN (1) | CN110783567B (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102938244B1 (ko) * | 2019-11-20 | 2026-03-12 | 사이언스코 | 리튬 티오포스페이트의 제조 방법 |
| JP2021122866A (ja) | 2020-01-31 | 2021-08-30 | セイコーエプソン株式会社 | ロボット、ロボット搭載用移動体および移動ロボット |
| US20210336291A1 (en) * | 2020-04-22 | 2021-10-28 | Ut-Battelle, Llc | Solid thiophosphate electrolyte composition for lithium-based batteries |
| CN113991167A (zh) * | 2021-10-26 | 2022-01-28 | 西安交通大学 | 一种卤化物固态电解质材料及其制备方法和应用 |
| WO2023140178A1 (ja) * | 2022-01-18 | 2023-07-27 | 出光興産株式会社 | 硫化物固体電解質の製造方法 |
| CN115588734B (zh) * | 2022-09-08 | 2025-06-20 | 中国科学院化学研究所 | 一种复合补锂剂及其制备方法 |
| JPWO2024075618A1 (https=) * | 2022-10-07 | 2024-04-11 | ||
| CN115838287B (zh) * | 2023-02-10 | 2023-06-27 | 中国科学院宁波材料技术与工程研究所 | 多步烧结制备硫化物电解质的方法及制备的硫化物电解质 |
| WO2024204581A1 (ja) * | 2023-03-28 | 2024-10-03 | 公立大学法人大阪 | 固体電解質材料、固体電解質複合体、電極及び固体電解質材料の製造方法 |
| FR3157375A1 (fr) | 2023-12-21 | 2025-06-27 | IFP Energies Nouvelles | Méthode de synthèse en solution de particules thiophosphate de sodium ou lithium |
| FR3164317A1 (fr) | 2024-07-02 | 2026-01-09 | IFP Energies Nouvelles | Procédé de synthèse de particules de thiophosphate Li3PS4 |
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| CN102787146A (zh) * | 2012-07-28 | 2012-11-21 | 江南大学 | 一种用微波辅助脂肪酶催化合成酯化改性egcg的方法 |
| CN103349917A (zh) * | 2013-07-26 | 2013-10-16 | 北京工业大学 | 一种微波强化层层组装聚电解质多层薄膜的方法 |
| EP2778177A1 (en) * | 2011-11-07 | 2014-09-17 | Shenyang Kesi High-technology Co. Ltd. | Method for extracting polysaccharides from higher plants and fungi through microwave chemical treatment |
| JP2016518016A (ja) * | 2013-05-16 | 2016-06-20 | ロックウッド リチウム ゲゼルシャフト ミット ベシュレンクテル ハフツングＲｏｃｋｗｏｏｄ Ｌｉｔｈｉｕｍ ＧｍｂＨ | リチウムイオン電池のための活性リチウムリザーバー |
| CN107394262A (zh) * | 2017-07-25 | 2017-11-24 | 深圳市沃特玛电池有限公司 | 一种复合固态电解质的制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090117020A1 (en) * | 2007-11-05 | 2009-05-07 | Board Of Regents, The University Of Texas System | Rapid microwave-solvothermal synthesis and surface modification of nanostructured phospho-olivine cathodes for lithium ion batteries |
| JP5510036B2 (ja) | 2009-05-28 | 2014-06-04 | Ｔｄｋ株式会社 | 活物質、活物質の製造方法及びリチウムイオン二次電池 |
| KR101748406B1 (ko) * | 2009-08-07 | 2017-06-16 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질의 제작 방법 |
| WO2011096532A1 (ja) | 2010-02-05 | 2011-08-11 | 国立大学法人秋田大学 | 固体電解質及び電気化学素子 |
| WO2011100487A2 (en) | 2010-02-12 | 2011-08-18 | Applied Materials, Inc. | HYDROTHERMAL SYNTHESIS OF LiFePO4 NANOPARTICLES |
| WO2011118801A1 (ja) | 2010-03-26 | 2011-09-29 | 国立大学法人東京工業大学 | 硫化物固体電解質材料、電池および硫化物固体電解質材料の製造方法 |
| WO2013069083A1 (ja) | 2011-11-07 | 2013-05-16 | トヨタ自動車株式会社 | 全固体電池 |
| US20140377664A1 (en) | 2012-01-10 | 2014-12-25 | The Regents Of The University Of Colorado, A Body Corporate | Lithium all-solid-state battery |
| JP5851251B2 (ja) * | 2012-01-16 | 2016-02-03 | ネットエージェント株式会社 | 通信パケット保存装置 |
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| Publication number | Publication date |
|---|---|
| EP3599659B1 (en) | 2021-06-23 |
| EP3599659A1 (en) | 2020-01-29 |
| US20200030768A1 (en) | 2020-01-30 |
| CN110783567A (zh) | 2020-02-11 |
| JP7362332B2 (ja) | 2023-10-17 |
| JP2020015661A (ja) | 2020-01-30 |
| US11325096B2 (en) | 2022-05-10 |
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