CN1105148C - 具有改善的滑动性和防粘性的聚酰胺母料及其应用 - Google Patents
具有改善的滑动性和防粘性的聚酰胺母料及其应用 Download PDFInfo
- Publication number
- CN1105148C CN1105148C CN97122705A CN97122705A CN1105148C CN 1105148 C CN1105148 C CN 1105148C CN 97122705 A CN97122705 A CN 97122705A CN 97122705 A CN97122705 A CN 97122705A CN 1105148 C CN1105148 C CN 1105148C
- Authority
- CN
- China
- Prior art keywords
- masterbatch
- polyamide
- masterbatch according
- weight
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 70
- 229920002647 polyamide Polymers 0.000 title claims abstract description 16
- 239000004952 Polyamide Substances 0.000 title claims abstract description 14
- 239000000314 lubricant Substances 0.000 title abstract 2
- 239000000654 additive Substances 0.000 claims abstract description 21
- 239000000194 fatty acid Substances 0.000 claims abstract description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 3
- 229930195729 fatty acid Natural products 0.000 claims abstract 3
- 230000000996 additive effect Effects 0.000 claims description 15
- 229920002292 Nylon 6 Polymers 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 4
- 229910052623 talc Inorganic materials 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 claims description 2
- 239000012876 carrier material Substances 0.000 claims 3
- 229920006020 amorphous polyamide Polymers 0.000 claims 2
- 150000004665 fatty acids Chemical class 0.000 claims 2
- 239000002667 nucleating agent Substances 0.000 claims 2
- 229920000299 Nylon 12 Polymers 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 239000002356 single layer Substances 0.000 claims 1
- 230000018984 mastication Effects 0.000 abstract description 2
- 238000010077 mastication Methods 0.000 abstract description 2
- -1 N,N'-ethylene bis fatty acid Chemical class 0.000 abstract 1
- 239000006057 Non-nutritive feed additive Substances 0.000 abstract 1
- 230000003064 anti-oxidating effect Effects 0.000 abstract 1
- 230000006911 nucleation Effects 0.000 abstract 1
- 238000010899 nucleation Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 35
- 150000001408 amides Chemical class 0.000 description 16
- 239000000463 material Substances 0.000 description 15
- 239000007787 solid Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 7
- 238000004659 sterilization and disinfection Methods 0.000 description 6
- 229920000572 Nylon 6/12 Polymers 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000012785 packaging film Substances 0.000 description 3
- 229920006280 packaging film Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- 235000014676 Phragmites communis Nutrition 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- 229920003620 Grilon® Polymers 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000002650 habitual effect Effects 0.000 description 1
- 229920006017 homo-polyamide Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19641659.0 | 1996-10-09 | ||
| DE19641659A DE19641659C2 (de) | 1996-10-09 | 1996-10-09 | Polyamid-Masterbatch mit verbesserten Gleit- und Antiblock-Eigenschaften und dessen Verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1180717A CN1180717A (zh) | 1998-05-06 |
| CN1105148C true CN1105148C (zh) | 2003-04-09 |
Family
ID=7808293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97122705A Expired - Fee Related CN1105148C (zh) | 1996-10-09 | 1997-10-09 | 具有改善的滑动性和防粘性的聚酰胺母料及其应用 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6515056B2 (enExample) |
| EP (1) | EP0835903B1 (enExample) |
| JP (1) | JP4709983B2 (enExample) |
| KR (1) | KR100530173B1 (enExample) |
| CN (1) | CN1105148C (enExample) |
| BR (1) | BR9705003A (enExample) |
| DE (2) | DE19641659C2 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4511137B2 (ja) * | 2003-07-25 | 2010-07-28 | オカモト株式会社 | カレンダー成型用共重合ポリアミド樹脂組成物 |
| CN101600763B (zh) * | 2006-11-01 | 2012-05-09 | 三菱工程塑料株式会社 | 聚酰胺树脂组合物粒料共混物、成形品及粒料共混物的制备方法 |
| JP5451970B2 (ja) * | 2006-11-01 | 2014-03-26 | 三菱エンジニアリングプラスチックス株式会社 | ポリアミド樹脂組成物ペレットブレンド物、成形品およびペレットブレンド物の製造方法 |
| EP2062718B1 (de) * | 2007-11-14 | 2015-10-07 | Ems-Patent Ag | Herstellung und Verwendung eines Polyamid-Antiblock-Masterbatches |
| WO2009095440A1 (de) * | 2008-01-31 | 2009-08-06 | Basf Se | Transparente polyamid[5,10] formmassen |
| US9312047B2 (en) | 2012-06-22 | 2016-04-12 | Honeywell International Inc. | Method and compositions for producing polymer blends |
| CN102896849B (zh) * | 2012-07-19 | 2016-01-20 | 厦门长塑实业有限公司 | 高阻隔尼龙薄膜及其制备方法 |
| CN103264563B (zh) * | 2013-06-04 | 2015-04-29 | 河南省银丰塑料有限公司 | 三层共挤eva长寿消雾环保型多功能大棚膜 |
| WO2018015099A1 (en) | 2016-07-18 | 2018-01-25 | Unilever N.V. | A method of modifying the dispensing properties of a container |
| CN107915987B (zh) * | 2016-10-11 | 2021-01-05 | 中国石油化工股份有限公司 | 一种用于制备聚酰胺薄膜的组合原料及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6155146A (ja) * | 1984-08-24 | 1986-03-19 | Dainichi Seika Kogyo Kk | ポリアミド着色成形用組成物 |
| US5109049A (en) * | 1987-08-24 | 1992-04-28 | American National Can Company | Nylon carrier for polymer concentrate, and films and packages made with the concentrate |
| JPH06240134A (ja) * | 1993-02-16 | 1994-08-30 | Toray Ind Inc | ポリアミドフィルム |
| EP0705877A1 (en) * | 1993-06-25 | 1996-04-10 | Tonen Chemical Corporation | Whisker-reinforced thermoplastic resin composition |
| JPH08113639A (ja) * | 1994-10-14 | 1996-05-07 | Mitsubishi Gas Chem Co Inc | 共重合ポリアミド |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2948698A (en) * | 1957-04-11 | 1960-08-09 | Du Pont | Polyamide molding compositions |
| US3342762A (en) * | 1964-10-09 | 1967-09-19 | Monsanto Co | Polyamide fibers containing lubricant |
| GB1327341A (en) * | 1971-01-18 | 1973-08-22 | Imp Chemical Ind Ld | Moulding compositions |
| IE39220B1 (en) * | 1973-05-14 | 1978-08-30 | Ici Ltd | Improved polyamide compositions |
| US4187212A (en) * | 1975-02-20 | 1980-02-05 | Ciba-Geigy Corporation | Stabilization systems from triarylphosphites and phenols |
| DE2643204C3 (de) * | 1976-09-25 | 1985-03-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Stabilisieren von Polyamiden |
| US4278576A (en) * | 1978-12-05 | 1981-07-14 | Rohm And Haas Company | Isolation and improvement of impact modifier polymer powders |
| JPS58101008A (ja) * | 1981-12-09 | 1983-06-16 | Mitsuboshi Belting Ltd | ポリアミド樹脂製ペレツトの製造方法 |
| JPS6044345B2 (ja) * | 1982-06-21 | 1985-10-03 | 旭化成株式会社 | 透明性及び表面光沢の良好なポリアミドフイラメント製造用ペレツト及びその製造方法 |
| CA1202759A (en) * | 1982-06-29 | 1986-04-08 | Du Pont Canada Inc. | Nylon film with improved slip characteristics and process therefor |
| US4749736A (en) * | 1986-10-20 | 1988-06-07 | Allied Corporation | Nucleating system for polyamides |
| US4786678A (en) * | 1986-12-29 | 1988-11-22 | Mobil Oil Corporation | Method of producing films from polyethylene resin, an additive and a second polymeric resin |
| DE3726125A1 (de) * | 1987-08-06 | 1989-02-16 | Basf Ag | Feststoffmischung aus nukleierten und nicht nukleierten polyamiden |
| FR2619385B1 (fr) * | 1987-08-11 | 1992-01-17 | Atochem | Poudre de polyamide constituee de particules a structure " rose des sables ". procede d'obtention de la poudre de polyamide |
| US4877684A (en) * | 1987-08-24 | 1989-10-31 | American National Can Company | Nylon carrier for polymer concentrate, and films and packages made with the concentrate |
| DE3901969A1 (de) * | 1989-01-24 | 1990-07-26 | Hoechst Ag | Biaxial orientierte kunststoffolie |
| JPH0747653B2 (ja) * | 1989-08-22 | 1995-05-24 | ユニチカ株式会社 | 易滑性ポリアミドフィルムの製造方法 |
| DE3931772A1 (de) * | 1989-09-23 | 1991-04-04 | Bayer Ag | Thermoplastische formmassen aus polyalkylenterephthalat, speziellem bariumsulfat, teilchenfoermigen pfropfpolymerisaten und gegebenenfalls verstaerkungsmitteln |
| WO1992015638A1 (en) * | 1991-02-28 | 1992-09-17 | Dsm N.V. | Process for preparing intrinsically foamed thermoplastic polymer |
| US5176751A (en) * | 1991-03-01 | 1993-01-05 | Thermocolor Corporation | Pellets useful in production of plastic resin materials |
| JP3265714B2 (ja) * | 1993-05-28 | 2002-03-18 | 東レ株式会社 | 高タフネス黒原着ポリアミド繊維 |
| DE4400248A1 (de) * | 1994-01-06 | 1995-07-13 | Hoechst Ag | Verfahren zur Herstellung von massegefärbten geformten Gebilden auf der Basis von aromatischen Polyamiden, massegefärbte Fasern, sowie Vermischung zur Herstellung von massegefärbten geformten Gebilden |
| DE4424775A1 (de) * | 1994-07-05 | 1996-01-11 | Grace Gmbh | Antiblockingmittel und Verfahren zu dessen Herstellung |
-
1996
- 1996-10-09 DE DE19641659A patent/DE19641659C2/de not_active Revoked
-
1997
- 1997-10-02 DE DE59707210T patent/DE59707210D1/de not_active Expired - Lifetime
- 1997-10-02 EP EP97117111A patent/EP0835903B1/de not_active Expired - Lifetime
- 1997-10-09 KR KR1019970051710A patent/KR100530173B1/ko not_active Expired - Lifetime
- 1997-10-09 JP JP27679297A patent/JP4709983B2/ja not_active Expired - Lifetime
- 1997-10-09 CN CN97122705A patent/CN1105148C/zh not_active Expired - Fee Related
- 1997-10-09 BR BR9705003A patent/BR9705003A/pt not_active IP Right Cessation
-
2001
- 2001-04-19 US US09/839,192 patent/US6515056B2/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6155146A (ja) * | 1984-08-24 | 1986-03-19 | Dainichi Seika Kogyo Kk | ポリアミド着色成形用組成物 |
| US5109049A (en) * | 1987-08-24 | 1992-04-28 | American National Can Company | Nylon carrier for polymer concentrate, and films and packages made with the concentrate |
| JPH06240134A (ja) * | 1993-02-16 | 1994-08-30 | Toray Ind Inc | ポリアミドフィルム |
| EP0705877A1 (en) * | 1993-06-25 | 1996-04-10 | Tonen Chemical Corporation | Whisker-reinforced thermoplastic resin composition |
| JPH08113639A (ja) * | 1994-10-14 | 1996-05-07 | Mitsubishi Gas Chem Co Inc | 共重合ポリアミド |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100530173B1 (ko) | 2006-01-27 |
| US6515056B2 (en) | 2003-02-04 |
| DE19641659C2 (de) | 1999-03-11 |
| KR19980032676A (ko) | 1998-07-25 |
| US20010031810A1 (en) | 2001-10-18 |
| EP0835903B1 (de) | 2002-05-08 |
| CN1180717A (zh) | 1998-05-06 |
| DE59707210D1 (de) | 2002-06-13 |
| JPH10182846A (ja) | 1998-07-07 |
| BR9705003A (pt) | 1998-12-29 |
| EP0835903A1 (de) | 1998-04-15 |
| JP4709983B2 (ja) | 2011-06-29 |
| DE19641659A1 (de) | 1998-04-16 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: AMES PATENT CO., LTD. Free format text: FORMER OWNER: WOODINVITA-FISCHER AG Effective date: 20070803 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| C56 | Change in the name or address of the patentee |
Owner name: WOODINVITA-FISCHER AG Free format text: FORMER NAME OR ADDRESS: EMS-INVENTA AG |
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| CP03 | Change of name, title or address |
Address after: Swiss Manny Dov Patentee after: Wood Invita-Fisher Co.,Ltd. Address before: Zurich Patentee before: Ems-Inventa AG |
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Effective date of registration: 20070803 Address after: Swiss Matt Patentee after: EMS-PATENT AG Address before: Swiss Manny Dov Patentee before: Wood Invita-Fisher Co.,Ltd. |
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Granted publication date: 20030409 Termination date: 20161009 |