CN110355382A - 一种含有空心结构的微晶银粉的制备方法 - Google Patents
一种含有空心结构的微晶银粉的制备方法 Download PDFInfo
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- CN110355382A CN110355382A CN201910785034.9A CN201910785034A CN110355382A CN 110355382 A CN110355382 A CN 110355382A CN 201910785034 A CN201910785034 A CN 201910785034A CN 110355382 A CN110355382 A CN 110355382A
- Authority
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- Prior art keywords
- silver
- hollow structure
- crystallite
- silver powder
- silver salt
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 25
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 23
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 10
- 230000002194 synthesizing effect Effects 0.000 claims abstract 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 108
- 239000000243 solution Substances 0.000 claims description 95
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 70
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 54
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 45
- 239000011668 ascorbic acid Substances 0.000 claims description 35
- 229960005070 ascorbic acid Drugs 0.000 claims description 35
- 235000010323 ascorbic acid Nutrition 0.000 claims description 35
- 239000012266 salt solution Substances 0.000 claims description 28
- 239000002270 dispersing agent Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000003638 chemical reducing agent Substances 0.000 claims description 21
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 15
- 229910017604 nitric acid Inorganic materials 0.000 claims description 15
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 14
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 14
- 229910052709 silver Inorganic materials 0.000 claims description 12
- 239000004332 silver Substances 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 8
- 230000009467 reduction Effects 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000005639 Lauric acid Substances 0.000 claims description 3
- -1 sorbitan carboxylic esters Chemical class 0.000 claims description 3
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000011017 operating method Methods 0.000 claims description 2
- 229940083466 soybean lecithin Drugs 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
- 239000008367 deionised water Substances 0.000 description 19
- 229910021641 deionized water Inorganic materials 0.000 description 19
- 239000002002 slurry Substances 0.000 description 10
- 238000001035 drying Methods 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 9
- 239000006228 supernatant Substances 0.000 description 9
- 238000006722 reduction reaction Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 230000002572 peristaltic effect Effects 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- GDSOZVZXVXTJMI-SNAWJCMRSA-N (e)-1-methylbut-1-ene-1,2,4-tricarboxylic acid Chemical compound OC(=O)C(/C)=C(C(O)=O)\CCC(O)=O GDSOZVZXVXTJMI-SNAWJCMRSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910001923 silver oxide Inorganic materials 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 239000002101 nanobubble Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 241000194020 Streptococcus thermophilus Species 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/06—Metallic powder characterised by the shape of the particles
- B22F1/065—Spherical particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/06—Metallic powder characterised by the shape of the particles
- B22F1/065—Spherical particles
- B22F1/0655—Hollow particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
Claims (10)
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CN201910785034.9A CN110355382B (zh) | 2019-08-23 | 2019-08-23 | 一种含有空心结构的微晶银粉的制备方法 |
Publications (2)
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CN110355382A true CN110355382A (zh) | 2019-10-22 |
CN110355382B CN110355382B (zh) | 2022-06-14 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110947980A (zh) * | 2019-12-24 | 2020-04-03 | 长沙新材料产业研究院有限公司 | 一种微米/亚微米级银粉的制备方法 |
CN111804905A (zh) * | 2020-09-02 | 2020-10-23 | 西安宏星电子浆料科技股份有限公司 | 一种微米级球形空心金粉及其制备方法 |
CN114210991A (zh) * | 2021-11-30 | 2022-03-22 | 达高工业技术研究院(广州)有限公司 | 一种空穴结构的球形银粉及其制备方法 |
CN115121804A (zh) * | 2022-07-14 | 2022-09-30 | 江西理工大学南昌校区 | 太阳能电池电极气溶胶喷涂微米级空心球银颗粒的合成方法 |
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CN101905330A (zh) * | 2010-08-20 | 2010-12-08 | 上海交通大学 | 空心银微球及其制备和在拉曼检测方面应用方法 |
CN102179527A (zh) * | 2011-05-10 | 2011-09-14 | 湖南省娄底维亚科技有限公司 | 一种纳米镍粉的制备方法 |
CN103231069A (zh) * | 2013-03-22 | 2013-08-07 | 常州大学 | 空心纳米金属的制备方法 |
CN104084598A (zh) * | 2014-08-01 | 2014-10-08 | 天津市职业大学 | 一种太阳能电池高密度单分散银粉的生产方法 |
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JP6385705B2 (ja) * | 2014-01-10 | 2018-09-05 | 丸祥電器株式会社 | 極細炭素繊維を含有する球状複合銀微粒子の製造方法 |
CN110102778A (zh) * | 2019-06-14 | 2019-08-09 | 上海镭立激光科技有限公司 | 一种低温烧结高结晶度银粉的制备方法 |
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2019
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CN102179527A (zh) * | 2011-05-10 | 2011-09-14 | 湖南省娄底维亚科技有限公司 | 一种纳米镍粉的制备方法 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110947980A (zh) * | 2019-12-24 | 2020-04-03 | 长沙新材料产业研究院有限公司 | 一种微米/亚微米级银粉的制备方法 |
CN111804905A (zh) * | 2020-09-02 | 2020-10-23 | 西安宏星电子浆料科技股份有限公司 | 一种微米级球形空心金粉及其制备方法 |
CN114210991A (zh) * | 2021-11-30 | 2022-03-22 | 达高工业技术研究院(广州)有限公司 | 一种空穴结构的球形银粉及其制备方法 |
CN114210991B (zh) * | 2021-11-30 | 2022-08-19 | 达高工业技术研究院(广州)有限公司 | 一种空穴结构的球形银粉及其制备方法 |
CN115121804A (zh) * | 2022-07-14 | 2022-09-30 | 江西理工大学南昌校区 | 太阳能电池电极气溶胶喷涂微米级空心球银颗粒的合成方法 |
CN115121804B (zh) * | 2022-07-14 | 2023-09-29 | 江西理工大学南昌校区 | 太阳能电池电极气溶胶喷涂微米级空心球银颗粒的合成方法 |
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Denomination of invention: A preparation method of microcrystalline silver powder containing hollow structure Effective date of registration: 20230327 Granted publication date: 20220614 Pledgee: Jinan Branch of Qingdao Bank Co.,Ltd. Pledgor: SHANDONG JIANBANG COLLOID MATERIAL CO.,LTD. Registration number: Y2023980036193 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20220614 Pledgee: Jinan Branch of Qingdao Bank Co.,Ltd. Pledgor: SHANDONG JIANBANG COLLOID MATERIAL CO.,LTD. Registration number: Y2023980036193 |