CN110352195B - 催化剂 - Google Patents

催化剂 Download PDF

Info

Publication number
CN110352195B
CN110352195B CN201780087557.5A CN201780087557A CN110352195B CN 110352195 B CN110352195 B CN 110352195B CN 201780087557 A CN201780087557 A CN 201780087557A CN 110352195 B CN110352195 B CN 110352195B
Authority
CN
China
Prior art keywords
tert
alkyl
catalyst
phenyl
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780087557.5A
Other languages
English (en)
Chinese (zh)
Other versions
CN110352195A (zh
Inventor
W·托尔茨
S·施瓦曾伯格
I·莱赫蒂涅米
L·雷科尼
V·维尔肯恩
N·阿杰拉尔
V·V·伊泽尔
D·S·科诺诺维奇
A·Z·沃斯科博尼科夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis GmbH
Original Assignee
Borealis GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis GmbH filed Critical Borealis GmbH
Publication of CN110352195A publication Critical patent/CN110352195A/zh
Application granted granted Critical
Publication of CN110352195B publication Critical patent/CN110352195B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/02—Polymerisation in bulk
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
CN201780087557.5A 2016-12-29 2017-12-21 催化剂 Active CN110352195B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16207302.7 2016-12-29
EP16207302 2016-12-29
PCT/EP2017/084273 WO2018122134A1 (en) 2016-12-29 2017-12-21 Catalysts

Publications (2)

Publication Number Publication Date
CN110352195A CN110352195A (zh) 2019-10-18
CN110352195B true CN110352195B (zh) 2022-11-11

Family

ID=57680151

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780087557.5A Active CN110352195B (zh) 2016-12-29 2017-12-21 催化剂

Country Status (6)

Country Link
US (1) US11807655B2 (https=)
EP (1) EP3562831B1 (https=)
JP (1) JP7130649B2 (https=)
KR (1) KR102618904B1 (https=)
CN (1) CN110352195B (https=)
WO (1) WO2018122134A1 (https=)

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
EP3768735B1 (en) 2018-03-19 2021-12-29 Borealis AG Catalysts for olefin polymerization
EP3567060A1 (en) * 2018-05-09 2019-11-13 Borealis AG Process for preparing heterophasic propylene copolymers
CN112424241B (zh) * 2018-06-28 2023-06-06 博里利斯股份公司 催化剂
US20210253836A1 (en) 2018-07-13 2021-08-19 Borealis Ag Heterophasic polypropylene composition with improved balance of properties
EP3647356B8 (en) 2018-10-31 2022-03-30 Borealis AG Polyolefin composition with improved balance of properties
KR102568458B1 (ko) 2019-02-08 2023-08-18 보레알리스 아게 높은 강성을 갖는 핵화된 프로필렌 중합체 조성물
JP7555972B2 (ja) 2019-05-29 2024-09-25 ボレアリス エージー 触媒系
WO2020239561A1 (en) 2019-05-29 2020-12-03 Borealis Ag C2c3 random copolymer composition
EP3976676B1 (en) 2019-05-29 2023-05-10 Borealis AG C2c3 random copolymer
CN113874407B (zh) 2019-05-29 2023-11-24 博里利斯股份公司 C2c3无规共聚物
JP7134370B2 (ja) 2019-07-04 2022-09-09 ボレアリス エージー 長鎖分岐プロピレンポリマー組成物
US12415875B2 (en) 2019-07-04 2025-09-16 Borealis Ag Long-chain branched propylene polymer composition
CN114127171B (zh) * 2019-07-19 2023-08-04 博里利斯股份公司 具有改善的滑动性能的聚丙烯薄膜
US12606657B2 (en) 2019-08-22 2026-04-21 Exxonmobil Chemical Patents Inc. Isotactic propylene homopolymers and copolymers produced with C1 symmetric metallocene catalysts
ES3037772T3 (en) 2019-09-25 2025-10-07 Borealis Gmbh Catalysts
ES2952233T3 (es) 2019-10-01 2023-10-30 Borealis Ag Composición polimérica apropiada para la fabricación de películas sopladas
WO2021063975A1 (en) 2019-10-02 2021-04-08 Borealis Ag Polymer composition suitable for making blown films
CN114729482B (zh) 2019-12-04 2024-01-02 博里利斯股份公司 由具有改善的过滤性能的熔喷纤维制成的过滤介质
US12571144B2 (en) 2019-12-04 2026-03-10 Borealis Ag Light weight melt blown webs with improved barrier properties
EP3896101B1 (en) 2020-04-17 2024-08-07 Borealis AG Hms polypropylene for foams
ES2925719T3 (es) 2020-05-18 2022-10-19 Borealis Ag Películas sopladas con perfil de propiedades mejorado
EP3912794B1 (en) 2020-05-18 2022-09-07 Borealis AG Multilayer film with improved properties
EP3912810B1 (en) 2020-05-18 2022-08-10 Borealis AG Polypropylene composition
MX2022014306A (es) 2020-05-22 2022-12-07 Borealis Ag Material compuesto de fibra de vidrio.
EP3913005A1 (en) 2020-05-22 2021-11-24 Borealis AG Glass fiber reinforced composite with narrow mwd polypropylene
EP3916022A1 (en) 2020-05-27 2021-12-01 Borealis AG Polypropylene coating composition
KR20230017262A (ko) 2020-05-27 2023-02-03 보레알리스 아게 폴리프로필렌 섬유를 함유하는 부직포
EP3916023A1 (en) 2020-05-27 2021-12-01 Borealis AG Polypropylene coating composition
US20230257934A1 (en) 2020-06-26 2023-08-17 Borealis Ag Nonwoven composite structure with excellent water vapour permeability
KR20230029678A (ko) * 2020-06-29 2023-03-03 더블유.알. 그레이스 앤드 캄파니-콘. 높은 강성 특성을 갖는 프탈레이트-무함유 폴리프로필렌 단일중합체
EP4442428A3 (en) 2020-06-29 2025-01-01 Borealis AG Recyclable polymer films and compositions
KR102736434B1 (ko) * 2020-07-16 2024-11-29 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
EP3950739B1 (en) 2020-08-05 2023-11-08 Borealis AG Polypropylene sheet
CN116134087B (zh) 2020-08-13 2024-10-15 博里利斯股份公司 汽车组合物
ES2984829T3 (es) 2020-08-13 2024-10-31 Borealis Ag Composición automotriz
EP3967716B1 (en) 2020-09-11 2024-03-13 Borealis AG Polypropylene-based article having an increased surface tension retention
CN116547313B (zh) 2020-11-23 2026-03-27 博里利斯股份公司 齐格勒-纳塔催化的成核聚丙烯和茂金属催化的聚丙烯的原位反应器共混物
KR102932322B1 (ko) 2021-01-22 2026-02-27 보레알리스 게엠베하 섬유 강화 폴리프로필렌 조성물
PT4036129T (pt) 2021-02-02 2023-09-11 Borealis Ag Película feita a partir de mistura de terpolímero c2c3c4 - copolímero c3c4 e mistura de terpolímero c2c3c4 - copolímero c3c4
JP7840342B2 (ja) 2021-02-15 2026-04-03 ボレアリス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング コーティングされた物品
US20240191015A1 (en) 2021-03-24 2024-06-13 Borealis Ag Copolymer
KR20230159581A (ko) 2021-03-24 2023-11-21 보레알리스 아게 헤테로상 폴리프로필렌 수지의 제조 방법
CN117098659B (zh) * 2021-04-01 2024-09-20 北欧化工公司 双轴取向聚丙烯系多层膜
EP4359448A1 (en) 2021-06-25 2024-05-01 Braskem, S.A. Propylene preliminary polymerization
CN117897272A (zh) 2021-08-04 2024-04-16 博里利斯股份公司 多层非织造结构
ES2982603T3 (es) 2021-08-31 2024-10-17 Borealis Ag Una mezcla de homopolímero y copolímero aleatorio con un equilibrio beneficioso de propiedades ópticas y mecánicas
EP4405403B8 (en) 2021-09-23 2025-08-06 Borealis GmbH Monophasic bimodal propylene/ethylene/1-butene random terpolymer compositions with improved optical and sealing properties
KR20240060696A (ko) 2021-09-23 2024-05-08 보레알리스 아게 프로필렌 공중합체의 제조방법
US20240409734A1 (en) 2021-10-14 2024-12-12 Borealis Ag A propylene-ethylene random copolymer with highly randomized ethylene distribution
KR20240107369A (ko) 2021-12-01 2024-07-09 보레알리스 아게 패키징 적용에 적합한 폴리프로필렌 조성물
MX2024006394A (es) 2021-12-01 2024-06-04 Borealis Ag Composicion de polipropileno de flujo de fusion elevado.
JP7825067B2 (ja) 2022-03-21 2026-03-05 ボレアリス ゲーエムベーハー 繊維強化組成物および繊維強化組成物を含む物品
CN119032124A (zh) 2022-04-26 2024-11-26 北欧化工公司 回收聚丙烯膜的方法
ES3015219T3 (en) 2022-05-31 2025-04-30 Borealis Ag Glass fiber composite
CN119497725A (zh) 2022-07-11 2025-02-21 北欧化工公司 用于管道应用的丙烯-乙烯无规共聚物
KR20250028474A (ko) 2022-07-11 2025-02-28 보레알리스 아게 파이프 적용 분야용의 프로필렌-에틸렌 랜덤 공중합체의 제조방법
CN119744282A (zh) 2022-08-23 2025-04-01 博里利斯股份公司 用于吹塑膜和流延膜的α-成核的丙烯/乙烯/1-丁烯三元共聚物组合物
EP4577583A1 (en) 2022-08-24 2025-07-02 Borealis AG Polymer composition suitable for film manufacturing
EP4590728A1 (en) 2022-09-21 2025-07-30 Borealis GmbH Propylene/ethylene/1-butene terpolymer compositions with multimodal base polymer
WO2024094676A1 (en) 2022-10-31 2024-05-10 Borealis Ag Compositon for automotive exterior parts
TW202438541A (zh) 2022-10-31 2024-10-01 奧地利商柏列利斯股份公司 高流動性異相丙烯共聚物組成物的製造方法及以該方法獲得的組成物
EP4427926A1 (en) 2023-03-07 2024-09-11 Borealis AG Biaxially oriented polypropylene-based multilayer film
EP4427923A1 (en) 2023-03-07 2024-09-11 Borealis AG Biaxially oriented polypropylene-based multilayer film
WO2025016568A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016565A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016569A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016564A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016570A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
CN121605112A (zh) 2023-07-14 2026-03-03 北欧化工有限责任公司 负载型催化剂体系的制备
WO2025061926A1 (en) 2023-09-21 2025-03-27 Borealis Ag Polypropylene compositions suitable for automotive applications
WO2025252807A1 (en) 2024-06-06 2025-12-11 Borealis Gmbh Polypropylene composition for automotive applications
EP4703395A1 (en) * 2024-08-26 2026-03-04 Borealis GmbH Cast film consisting of a polypropylene composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102666605A (zh) * 2009-12-22 2012-09-12 博里利斯股份公司 催化剂
CN102947354A (zh) * 2010-04-28 2013-02-27 博瑞立斯有限公司 包含桥连的茂金属的固体颗粒催化剂
TW201605913A (zh) * 2014-04-17 2016-02-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之改良催化劑系統
TW201609841A (zh) * 2014-04-17 2016-03-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之新穎催化劑系統

Family Cites Families (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
WO1997014727A1 (en) 1995-10-19 1997-04-24 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
AU6401098A (en) 1997-03-07 1998-09-29 Targor Gmbh Preparation of preparing substituted indanones
US6252019B1 (en) 1997-05-13 2001-06-26 Montell Technology Company Bv Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes
US6214760B1 (en) 1998-08-11 2001-04-10 The Dow Chemical Company Catalyst activator composition
US6528670B1 (en) 1998-10-23 2003-03-04 Exxonmobil Chemical Patents Inc. Bridged metallocenes for olefin copolymerization
AU761531B2 (en) 1998-10-23 2003-06-05 Exxonmobil Chemical Patents Inc Olefin copolymerization process with bridged hafnocenes
WO2002002576A1 (en) 2000-06-30 2002-01-10 Exxonmobil Chemical Patents Inc. Bridged bis (indenyl) metallocene compounds
AU2002362036A1 (en) 2001-12-05 2003-06-23 Exxonmobil Chemical Patents Inc. Bulky borate activations
AU2002230934A1 (en) 2001-12-10 2003-06-23 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
EP2465879B1 (en) 2002-09-27 2019-04-24 Mitsui Chemicals, Inc. Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same
DE602004026627D1 (de) * 2003-12-10 2010-05-27 Basell Polyolefine Gmbh Organometallische übergangsmetallverbindung, biscyd herstellung von polyolefinen
DE10358082A1 (de) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US20050288461A1 (en) 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
EA012018B1 (ru) 2004-12-31 2009-06-30 Бореалис Текнолоджи Ой Способ получения катализатора полимеризации олефинов
FR2882480B1 (fr) 2005-02-18 2007-07-13 France Telecom Procede et dispositif de synchronisation trame
KR101293405B1 (ko) 2005-03-18 2013-08-05 바젤 폴리올레핀 게엠베하 메탈로센 화합물
WO2006100258A1 (en) 2005-03-23 2006-09-28 Basell Polyolefine Gmbh Process for the polymerization of olefins
WO2007116034A1 (en) 2006-04-12 2007-10-18 Basell Polyolefine Gmbh Metallocene compounds
EP2010580B1 (en) 2006-04-21 2016-07-13 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers
US7429635B2 (en) 2006-09-28 2008-09-30 Equistar Chemicals, Lp Preparation of ultra high molecular weight linear low density polyethylene
KR101278336B1 (ko) 2007-10-25 2013-06-25 루머스 노보렌 테크놀로지 게엠베하 안사-메탈로센 화합물의 라세모선택적 합성, 안사-메탈로센 화합물, 이를 포함하는 촉매, 그 촉매를 이용한 올레핀 폴리머 제조 공정, 그리고 올레핀 호모- 및 코폴리머
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
EP2361267B1 (en) 2008-11-07 2015-03-04 Borealis AG Process to prepare a solid catalyst composition
WO2010052263A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
KR101154507B1 (ko) 2009-07-31 2012-06-13 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체
WO2011076443A1 (en) 2009-12-22 2011-06-30 Borealis Ag Preparation of polypropylene in the presence of a single-site catalyst
EP2563821B1 (en) 2010-04-28 2019-08-07 Borealis AG Catalysts
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
EP2402354B1 (en) 2010-07-01 2016-03-02 Borealis AG Process for olefin polymerisation using group 4 metallocene as catalysts
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
US9079985B2 (en) 2010-12-22 2015-07-14 Borealis Ag Bridged metallocene catalysts
EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
KR101918175B1 (ko) 2011-07-08 2019-01-29 보레알리스 아게 헤테로상 공중합체
EP2657285B1 (en) 2012-04-25 2015-07-22 Borealis AG moulded polypropylene with high content of beta form
ES2622627T3 (es) 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
EP2746301B1 (en) 2012-12-21 2018-05-30 Borealis AG Catalyst
JP6193398B2 (ja) 2012-12-21 2017-09-06 ボレアリス エージー 触媒
EP2746289B1 (en) 2012-12-21 2017-09-27 Borealis AG Catalysts
ES2589053T3 (es) 2013-06-10 2016-11-08 Borealis Ag Procedimiento para la preparación de un polímero de propileno
EP2829558B1 (en) 2013-07-24 2016-12-14 Borealis AG Process
CH709492A2 (de) 2014-04-15 2015-10-15 Kringlan Composites Ag Fahrzeugrad aus faserverstärktem Kunststoff.
EP2933275A1 (en) 2014-04-17 2015-10-21 Borealis AG New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP2995629B1 (en) 2014-09-12 2018-03-07 Borealis AG Process for producing propylene copolymers in gas phase
KR20170068474A (ko) 2014-09-12 2017-06-19 보레알리스 아게 프로필렌의 코폴리머의 제조 공정
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
US11530280B2 (en) 2016-12-15 2022-12-20 Borealis Ag Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
KR102534541B1 (ko) 2016-12-15 2023-05-18 보레알리스 아게 고온 용액 중합 공정으로 폴리에틸렌 공중합체를 제조하기 위한 촉매 시스템
EA201992705A1 (ru) 2017-06-29 2020-06-03 Бореалис Аг Способ получения полипропиленовой композиции
PT3456776T (pt) 2017-09-13 2020-03-09 Borealis Ag Composição de polipropileno
EP3768735B1 (en) 2018-03-19 2021-12-29 Borealis AG Catalysts for olefin polymerization

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102666605A (zh) * 2009-12-22 2012-09-12 博里利斯股份公司 催化剂
CN102947354A (zh) * 2010-04-28 2013-02-27 博瑞立斯有限公司 包含桥连的茂金属的固体颗粒催化剂
TW201605913A (zh) * 2014-04-17 2016-02-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之改良催化劑系統
TW201609841A (zh) * 2014-04-17 2016-03-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之新穎催化劑系統

Also Published As

Publication number Publication date
KR102618904B1 (ko) 2023-12-27
JP7130649B2 (ja) 2022-09-05
US20220363703A1 (en) 2022-11-17
WO2018122134A1 (en) 2018-07-05
EP3562831A1 (en) 2019-11-06
US11807655B2 (en) 2023-11-07
EP3562831B1 (en) 2021-10-20
KR20190095956A (ko) 2019-08-16
JP2020511423A (ja) 2020-04-16
CN110352195A (zh) 2019-10-18

Similar Documents

Publication Publication Date Title
CN110352195B (zh) 催化剂
JP7555972B2 (ja) 触媒系
JP7297782B2 (ja) オレフィン重合用触媒
KR102505086B1 (ko) 촉매
CN104870462B (zh) 催化剂
CN103649209B (zh) 多相共聚物
KR101810913B1 (ko) 촉매로서 4족 메탈로센을 사용한 올레핀 중합방법
KR102106661B1 (ko) 촉매
US11078304B2 (en) Process for preparing heterophasic propylene copolymers
CN111902436B (zh) 用于制备丙烯聚合物的方法
CN111936528A (zh) 用于制备包括C4至C12-α烯烃共聚单体单元的丙烯共聚物的方法
CN112424241B (zh) 催化剂
EP3567060A1 (en) Process for preparing heterophasic propylene copolymers

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant