CN110352195B - 催化剂 - Google Patents

催化剂 Download PDF

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Publication number
CN110352195B
CN110352195B CN201780087557.5A CN201780087557A CN110352195B CN 110352195 B CN110352195 B CN 110352195B CN 201780087557 A CN201780087557 A CN 201780087557A CN 110352195 B CN110352195 B CN 110352195B
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tert
alkyl
catalyst
phenyl
methyl
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Chinese (zh)
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CN110352195A (zh
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W·托尔茨
S·施瓦曾伯格
I·莱赫蒂涅米
L·雷科尼
V·维尔肯恩
N·阿杰拉尔
V·V·伊泽尔
D·S·科诺诺维奇
A·Z·沃斯科博尼科夫
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Borealis GmbH
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Borealis GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/02—Polymerisation in bulk
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
CN201780087557.5A 2016-12-29 2017-12-21 催化剂 Active CN110352195B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16207302 2016-12-29
EP16207302.7 2016-12-29
PCT/EP2017/084273 WO2018122134A1 (en) 2016-12-29 2017-12-21 Catalysts

Publications (2)

Publication Number Publication Date
CN110352195A CN110352195A (zh) 2019-10-18
CN110352195B true CN110352195B (zh) 2022-11-11

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US (1) US11807655B2 (https=)
EP (1) EP3562831B1 (https=)
JP (1) JP7130649B2 (https=)
KR (1) KR102618904B1 (https=)
CN (1) CN110352195B (https=)
WO (1) WO2018122134A1 (https=)

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
EP3768735B1 (en) 2018-03-19 2021-12-29 Borealis AG Catalysts for olefin polymerization
EP3567060A1 (en) * 2018-05-09 2019-11-13 Borealis AG Process for preparing heterophasic propylene copolymers
KR20210027401A (ko) 2018-06-28 2021-03-10 보레알리스 아게 촉매
RU2754224C1 (ru) 2018-07-13 2021-08-30 Бореалис Аг Композиция гетерофазного полипропилена с улучшенным балансом свойств
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CN113474406B (zh) 2019-02-08 2023-09-15 博里利斯股份公司 具有高韧性的成核丙烯聚合物组合物
US11485845B2 (en) 2019-05-29 2022-11-01 Borealis Ag C2C3 random copolymer
US12312368B2 (en) 2019-05-29 2025-05-27 Borealis Ag Preparation of catalyst system
US12258429B2 (en) 2019-05-29 2025-03-25 Borealis Ag C2C3 random copolymer composition
EP3976677A1 (en) 2019-05-29 2022-04-06 Borealis AG C2c3 random copolymer
EP3994188B1 (en) 2019-07-04 2023-11-08 Borealis AG Long chain branched propylene polymer composition
WO2021001174A1 (en) 2019-07-04 2021-01-07 Borealis Ag Long-chain branched propylene polymer composition
US12600807B2 (en) 2019-07-19 2026-04-14 Borealis Ag Polypropylene film with improved slip performance
EP4017887A4 (en) 2019-08-22 2023-01-18 ExxonMobil Chemical Patents Inc. ISOTACTIC PROPYLENE HOMOPOLYMERS AND COPOLYMERS MADE WITH C1-SYMMETRIC METALLOCENE CATALYSTS
EP4034579B8 (en) * 2019-09-25 2025-08-27 Borealis GmbH Catalysts
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WO2021063975A1 (en) 2019-10-02 2021-04-08 Borealis Ag Polymer composition suitable for making blown films
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US20230312782A1 (en) * 2020-06-29 2023-10-05 W.R. Grace & Co.-Conn. Phthalate-free polypropylene homopolymer having high stiffness properties
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CN119731217A (zh) 2022-08-24 2025-03-28 北欧化工公司 适用于薄膜制造的聚合物组合物
EP4590728A1 (en) 2022-09-21 2025-07-30 Borealis GmbH Propylene/ethylene/1-butene terpolymer compositions with multimodal base polymer
EP4612194A1 (en) 2022-10-31 2025-09-10 Borealis GmbH Process for producing high-flow heterophasic propylene copolymer compositions
WO2024094676A1 (en) 2022-10-31 2024-05-10 Borealis Ag Compositon for automotive exterior parts
EP4427923B1 (en) 2023-03-07 2026-05-06 Borealis GmbH Biaxially oriented polypropylene-based multilayer film
EP4427926A1 (en) 2023-03-07 2024-09-11 Borealis AG Biaxially oriented polypropylene-based multilayer film
WO2025016570A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016565A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016564A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016569A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016568A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
CN121605112A (zh) 2023-07-14 2026-03-03 北欧化工有限责任公司 负载型催化剂体系的制备
WO2025061926A1 (en) 2023-09-21 2025-03-27 Borealis Ag Polypropylene compositions suitable for automotive applications
WO2025252807A1 (en) 2024-06-06 2025-12-11 Borealis Gmbh Polypropylene composition for automotive applications
EP4703395A1 (en) * 2024-08-26 2026-03-04 Borealis GmbH Cast film consisting of a polypropylene composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102666605A (zh) * 2009-12-22 2012-09-12 博里利斯股份公司 催化剂
CN102947354A (zh) * 2010-04-28 2013-02-27 博瑞立斯有限公司 包含桥连的茂金属的固体颗粒催化剂
TW201605913A (zh) * 2014-04-17 2016-02-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之改良催化劑系統
TW201609841A (zh) * 2014-04-17 2016-03-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之新穎催化劑系統

Family Cites Families (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
US5756609A (en) 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
KR100624632B1 (ko) 1997-03-07 2006-09-15 타고르 게엠베하 메탈로센 및 그의 제조 방법
US6252019B1 (en) 1997-05-13 2001-06-26 Montell Technology Company Bv Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes
DE69902548T2 (de) 1998-08-11 2003-04-10 The Dow Chemical Co., Midland Katalysatoraktivatorverbindung
ES2233109T3 (es) 1998-10-23 2005-06-01 Exxonmobil Chemical Patents Inc. Metalocenos puenteados para la copolimerizacion de olefinas.
KR100621299B1 (ko) 1998-10-23 2006-09-13 엑손모빌 케미칼 패턴츠 인코포레이티드 브릿지된 하프노센에 의한 올레핀 공중합 방법
JP2004502699A (ja) 2000-06-30 2004-01-29 エクソンモービル・ケミカル・パテンツ・インク 架橋ビス（インデニル）メタロセン化合物
AU2002362036A1 (en) 2001-12-05 2003-06-23 Exxonmobil Chemical Patents Inc. Bulky borate activations
DE60132827D1 (de) 2001-12-10 2008-03-27 Exxon Chemical Patents Inc Metallocene und von ihnen abgeleitete katalysatorzusammensetzungen
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
WO2004029062A1 (ja) 2002-09-27 2004-04-08 Mitsui Chemicals, Inc. オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法
DE602004026627D1 (de) * 2003-12-10 2010-05-27 Basell Polyolefine Gmbh Organometallische übergangsmetallverbindung, biscyd herstellung von polyolefinen
DE10358082A1 (de) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US20050288461A1 (en) 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
KR101286307B1 (ko) 2004-12-31 2013-07-15 보레알리스 테크놀로지 오와이. 공정
FR2882480B1 (fr) 2005-02-18 2007-07-13 France Telecom Procede et dispositif de synchronisation trame
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7799880B2 (en) 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
US7834205B2 (en) 2006-04-12 2010-11-16 Basell Polyolifine GmbH Metallocene compounds
EP2010580B1 (en) 2006-04-21 2016-07-13 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers
US7429635B2 (en) 2006-09-28 2008-09-30 Equistar Chemicals, Lp Preparation of ultra high molecular weight linear low density polyethylene
ATE547439T1 (de) 2007-10-25 2012-03-15 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere
WO2010052264A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
ES2619729T3 (es) 2008-11-07 2017-06-26 Borealis Ag Composición de catalizador sólida
EP2361267B1 (en) 2008-11-07 2015-03-04 Borealis AG Process to prepare a solid catalyst composition
KR101154507B1 (ko) 2009-07-31 2012-06-13 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체
EP2516484A1 (en) 2009-12-22 2012-10-31 Borealis AG Preparation of polypropylene in the presence of a single-site catalyst
US8729206B2 (en) 2010-04-28 2014-05-20 Borealis Ag Solid particulate catalysts comprising bridged metallocenes
ES2565438T3 (es) 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
EP2655431A1 (en) 2010-12-22 2013-10-30 Borealis AG Bridged metallocene catalysts
EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
CN103649101A (zh) 2011-07-08 2014-03-19 博瑞立斯有限公司 催化剂
ES2550044T3 (es) 2012-04-25 2015-11-04 Borealis Ag Polipropileno moldeado con alto contenido de forma beta
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
EP2722344B1 (en) 2012-10-18 2017-03-22 Borealis AG Polymerisation process
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
WO2014096282A1 (en) 2012-12-21 2014-06-26 Borealis Ag Catalyst
EP2746301B1 (en) 2012-12-21 2018-05-30 Borealis AG Catalyst
ES2589053T3 (es) 2013-06-10 2016-11-08 Borealis Ag Procedimiento para la preparación de un polímero de propileno
EP2829558B1 (en) 2013-07-24 2016-12-14 Borealis AG Process
CH709492A2 (de) 2014-04-15 2015-10-15 Kringlan Composites Ag Fahrzeugrad aus faserverstärktem Kunststoff.
EP2933275A1 (en) 2014-04-17 2015-10-21 Borealis AG New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP2995629B1 (en) 2014-09-12 2018-03-07 Borealis AG Process for producing propylene copolymers in gas phase
WO2016038211A1 (en) 2014-09-12 2016-03-17 Borealis Ag Process for the preparation of copolymers of propylene
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
EP3555149B1 (en) 2016-12-15 2025-11-12 Borealis GmbH New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
JP7130644B2 (ja) 2016-12-15 2022-09-05 ボレアリス エージー 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系
US11370904B2 (en) 2017-06-29 2022-06-28 Borealis Ag Process for preparing a polypropylene composition
EP3456776B1 (en) 2017-09-13 2019-12-11 Borealis AG Polypropylene composition
EP3768735B1 (en) 2018-03-19 2021-12-29 Borealis AG Catalysts for olefin polymerization

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102666605A (zh) * 2009-12-22 2012-09-12 博里利斯股份公司 催化剂
CN102947354A (zh) * 2010-04-28 2013-02-27 博瑞立斯有限公司 包含桥连的茂金属的固体颗粒催化剂
TW201605913A (zh) * 2014-04-17 2016-02-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之改良催化劑系統
TW201609841A (zh) * 2014-04-17 2016-03-16 波瑞利斯公司 用於在高溫溶液聚合方法中製造聚乙烯共聚物之新穎催化劑系統

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