CN110256682A - 有机发光材料及其制备方法 - Google Patents
有机发光材料及其制备方法 Download PDFInfo
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- CN110256682A CN110256682A CN201910152993.7A CN201910152993A CN110256682A CN 110256682 A CN110256682 A CN 110256682A CN 201910152993 A CN201910152993 A CN 201910152993A CN 110256682 A CN110256682 A CN 110256682A
- Authority
- CN
- China
- Prior art keywords
- organic material
- preparation
- luminous organic
- oxide
- rare earth
- Prior art date
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Links
- 239000011368 organic material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 97
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 63
- 238000006243 chemical reaction Methods 0.000 claims abstract description 33
- 239000011259 mixed solution Substances 0.000 claims abstract description 29
- 239000007787 solid Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007864 aqueous solution Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000001632 sodium acetate Substances 0.000 claims abstract description 13
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 13
- 229910052796 boron Inorganic materials 0.000 claims abstract description 12
- QMKYBPDZANOJGF-UHFFFAOYSA-N trimesic acid Natural products OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 238000005119 centrifugation Methods 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims abstract description 4
- 229910016644 EuCl3 Inorganic materials 0.000 claims description 18
- NNMXSTWQJRPBJZ-UHFFFAOYSA-K europium(iii) chloride Chemical compound Cl[Eu](Cl)Cl NNMXSTWQJRPBJZ-UHFFFAOYSA-K 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 14
- 238000001291 vacuum drying Methods 0.000 claims description 14
- 229910001940 europium oxide Inorganic materials 0.000 claims description 11
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- AEDROEGYZIARPU-UHFFFAOYSA-K lutetium(iii) chloride Chemical compound Cl[Lu](Cl)Cl AEDROEGYZIARPU-UHFFFAOYSA-K 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 3
- 229910001938 gadolinium oxide Inorganic materials 0.000 claims description 3
- 229940075613 gadolinium oxide Drugs 0.000 claims description 3
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 claims description 3
- -1 luteium oxide Chemical compound 0.000 claims description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 3
- 229910003451 terbium oxide Inorganic materials 0.000 claims description 3
- SCRZPWWVSXWCMC-UHFFFAOYSA-N terbium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Tb+3].[Tb+3] SCRZPWWVSXWCMC-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 claims 1
- 150000002910 rare earth metals Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 description 10
- 230000005284 excitation Effects 0.000 description 6
- 239000012621 metal-organic framework Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000000295 emission spectrum Methods 0.000 description 4
- 230000003760 hair shine Effects 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 238000002242 deionisation method Methods 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000002428 photodynamic therapy Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/182—Metal complexes of the rare earth metals, i.e. Sc, Y or lanthanide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Luminescent Compositions (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201910152993.7A CN110256682B (zh) | 2019-02-28 | 2019-02-28 | 有机发光材料及其制备方法 |
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CN201910152993.7A CN110256682B (zh) | 2019-02-28 | 2019-02-28 | 有机发光材料及其制备方法 |
Publications (2)
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CN110256682A true CN110256682A (zh) | 2019-09-20 |
CN110256682B CN110256682B (zh) | 2021-09-21 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112457499A (zh) * | 2020-11-30 | 2021-03-09 | 华南理工大学 | 一种稀土基金属有机框架荧光纳米材料及其制备方法与应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101711265A (zh) * | 2007-06-06 | 2010-05-19 | 雷恩国家应用科学学院 | 基于热塑性或热固性高分子有机基质的材料的标记方法 |
CN102671553A (zh) * | 2012-05-02 | 2012-09-19 | 珠海市吉林大学无机合成与制备化学重点实验室 | 应用静电纺丝技术生长无机微孔分离膜的方法 |
CN105949226A (zh) * | 2016-06-23 | 2016-09-21 | 哈尔滨工业大学 | 铕铈共掺杂配合物荧光传感材料的制备方法及应用其检测有机小分子化合物 |
CN106497547A (zh) * | 2016-10-21 | 2017-03-15 | 中国科学院长春光学精密机械与物理研究所 | 一种稀土发光材料及其制备方法、应用 |
CN106822926A (zh) * | 2017-02-20 | 2017-06-13 | 武汉科技大学 | 一种用于磁共振成像的纳米Gd‑MOFs的制备方法 |
-
2019
- 2019-02-28 CN CN201910152993.7A patent/CN110256682B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101711265A (zh) * | 2007-06-06 | 2010-05-19 | 雷恩国家应用科学学院 | 基于热塑性或热固性高分子有机基质的材料的标记方法 |
CN102671553A (zh) * | 2012-05-02 | 2012-09-19 | 珠海市吉林大学无机合成与制备化学重点实验室 | 应用静电纺丝技术生长无机微孔分离膜的方法 |
CN105949226A (zh) * | 2016-06-23 | 2016-09-21 | 哈尔滨工业大学 | 铕铈共掺杂配合物荧光传感材料的制备方法及应用其检测有机小分子化合物 |
CN106497547A (zh) * | 2016-10-21 | 2017-03-15 | 中国科学院长春光学精密机械与物理研究所 | 一种稀土发光材料及其制备方法、应用 |
CN106822926A (zh) * | 2017-02-20 | 2017-06-13 | 武汉科技大学 | 一种用于磁共振成像的纳米Gd‑MOFs的制备方法 |
Non-Patent Citations (2)
Title |
---|
刘雅娜: "基于稀土掺杂上转换发光材料的可控制备及其作为多功能药物载体的应用研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
王继业等: "均苯三甲酸铕及铕镧配合物的合成及荧光性质", 《发光学报》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112457499A (zh) * | 2020-11-30 | 2021-03-09 | 华南理工大学 | 一种稀土基金属有机框架荧光纳米材料及其制备方法与应用 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Organic light-emitting materials and their preparation methods Effective date of registration: 20221116 Granted publication date: 20210921 Pledgee: Jiangsu Nantong Rural Commercial Bank Co.,Ltd. Development Zone sub branch Pledgor: JIANGSU LUOHUA NEW MATERIAL Co.,Ltd. Registration number: Y2022320000715 |
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Date of cancellation: 20231109 Granted publication date: 20210921 Pledgee: Jiangsu Nantong Rural Commercial Bank Co.,Ltd. Development Zone sub branch Pledgor: JIANGSU LUOHUA NEW MATERIAL Co.,Ltd. Registration number: Y2022320000715 |
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Denomination of invention: Organic luminescent materials and their preparation methods Effective date of registration: 20231110 Granted publication date: 20210921 Pledgee: Jiangsu Nantong Rural Commercial Bank Co.,Ltd. Development Zone sub branch Pledgor: JIANGSU LUOHUA NEW MATERIAL Co.,Ltd. Registration number: Y2023980065177 |