CN105949226A - 铕铈共掺杂配合物荧光传感材料的制备方法及应用其检测有机小分子化合物 - Google Patents
铕铈共掺杂配合物荧光传感材料的制备方法及应用其检测有机小分子化合物 Download PDFInfo
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- CN105949226A CN105949226A CN201610464692.4A CN201610464692A CN105949226A CN 105949226 A CN105949226 A CN 105949226A CN 201610464692 A CN201610464692 A CN 201610464692A CN 105949226 A CN105949226 A CN 105949226A
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- europium
- cerium
- sensing material
- fluorescent sensing
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- 239000011540 sensing material Substances 0.000 title claims abstract description 40
- 229910052693 Europium Inorganic materials 0.000 title claims abstract description 24
- -1 small-molecule compounds Chemical class 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 title claims abstract description 20
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- IZCUOLNYELHOEC-UHFFFAOYSA-N [Eu].[Ce] Chemical compound [Eu].[Ce] IZCUOLNYELHOEC-UHFFFAOYSA-N 0.000 claims description 44
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 26
- 239000007864 aqueous solution Substances 0.000 claims description 19
- 229910052684 Cerium Inorganic materials 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical group OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims description 16
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 14
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 238000001291 vacuum drying Methods 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 229910002492 Ce(NO3)3·6H2O Inorganic materials 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- 229910002538 Eu(NO3)3·6H2O Inorganic materials 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 3
- 239000012046 mixed solvent Substances 0.000 claims description 3
- ZBGLGVFYHCSILI-UHFFFAOYSA-N acetic acid;europium Chemical compound [Eu].CC(O)=O ZBGLGVFYHCSILI-UHFFFAOYSA-N 0.000 claims description 2
- VGBWDOLBWVJTRZ-UHFFFAOYSA-K cerium(3+);triacetate Chemical compound [Ce+3].CC([O-])=O.CC([O-])=O.CC([O-])=O VGBWDOLBWVJTRZ-UHFFFAOYSA-K 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 5
- ZSDJVGXBJDDOCD-UHFFFAOYSA-N benzene dioctyl benzene-1,2-dicarboxylate Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1=CC=CC=C1 ZSDJVGXBJDDOCD-UHFFFAOYSA-N 0.000 claims 1
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- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000003446 ligand Substances 0.000 abstract description 2
- 239000011259 mixed solution Substances 0.000 abstract 2
- 150000003384 small molecules Chemical class 0.000 abstract 2
- 150000000703 Cerium Chemical class 0.000 abstract 1
- 150000000918 Europium Chemical class 0.000 abstract 1
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 12
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- 239000013110 organic ligand Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 235000013361 beverage Nutrition 0.000 description 3
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 1
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- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
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- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
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- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/182—Metal complexes of the rare earth metals, i.e. Sc, Y or lanthanide
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
Abstract
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CN201610464692.4A CN105949226B (zh) | 2016-06-23 | 2016-06-23 | 铕铈共掺杂配合物荧光传感材料的制备方法及应用其检测有机小分子化合物 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108962612A (zh) * | 2018-07-19 | 2018-12-07 | 黑龙江大学 | 一种均苯三甲酸配合物/二氧化钛复合光阳极的制备方法 |
CN109021247A (zh) * | 2018-09-19 | 2018-12-18 | 福州大学 | 一种层片状结构的稀土基金属有机框架化合物及其制备方法和应用 |
CN110256682A (zh) * | 2019-02-28 | 2019-09-20 | 江苏罗化新材料有限公司 | 有机发光材料及其制备方法 |
CN111909028A (zh) * | 2020-08-24 | 2020-11-10 | 北京石油化工学院 | 一种用于检测AFB1的Eu/Tb(BTC)的制备方法 |
CN111909029A (zh) * | 2020-08-24 | 2020-11-10 | 北京石油化工学院 | 一种用于检测肌酸酐的Eu/Tb(OH)(BDC)的制备方法 |
CN112457499A (zh) * | 2020-11-30 | 2021-03-09 | 华南理工大学 | 一种稀土基金属有机框架荧光纳米材料及其制备方法与应用 |
CN114516886A (zh) * | 2022-02-21 | 2022-05-20 | 温州大学 | 一种铕金属有机配合物及其制备方法和作为pH荧光探针的应用 |
-
2016
- 2016-06-23 CN CN201610464692.4A patent/CN105949226B/zh active Active
Non-Patent Citations (3)
Title |
---|
GUO H L. ET AL: ""Coordination Modulation Induced Synthesis of Nanoscale Eu1−xTbx−Metal-Organic Frameworks for Luminescent Thin Films"", 《ADV. MATER》 * |
王继业等: ""均苯三甲酸铕及铕镧配合物的合成及荧光性质"", 《发光学报》 * |
马瑞军等: ""均苯三甲酸铕掺杂配合物的合成及其荧光性能"", 《发光学报》 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108962612A (zh) * | 2018-07-19 | 2018-12-07 | 黑龙江大学 | 一种均苯三甲酸配合物/二氧化钛复合光阳极的制备方法 |
CN109021247A (zh) * | 2018-09-19 | 2018-12-18 | 福州大学 | 一种层片状结构的稀土基金属有机框架化合物及其制备方法和应用 |
CN109021247B (zh) * | 2018-09-19 | 2021-04-27 | 福州大学 | 一种层片状结构的稀土基金属有机框架化合物及其制备方法和应用 |
CN110256682A (zh) * | 2019-02-28 | 2019-09-20 | 江苏罗化新材料有限公司 | 有机发光材料及其制备方法 |
CN110256682B (zh) * | 2019-02-28 | 2021-09-21 | 江苏罗化新材料有限公司 | 有机发光材料及其制备方法 |
CN111909028A (zh) * | 2020-08-24 | 2020-11-10 | 北京石油化工学院 | 一种用于检测AFB1的Eu/Tb(BTC)的制备方法 |
CN111909029A (zh) * | 2020-08-24 | 2020-11-10 | 北京石油化工学院 | 一种用于检测肌酸酐的Eu/Tb(OH)(BDC)的制备方法 |
CN111909029B (zh) * | 2020-08-24 | 2022-09-06 | 北京石油化工学院 | 一种用于检测肌酸酐的Eu/Tb(OH)(BDC)的制备方法 |
CN111909028B (zh) * | 2020-08-24 | 2022-11-29 | 北京石油化工学院 | 一种用于检测AFB1的Eu/Tb(BTC)的制备方法 |
CN112457499A (zh) * | 2020-11-30 | 2021-03-09 | 华南理工大学 | 一种稀土基金属有机框架荧光纳米材料及其制备方法与应用 |
CN114516886A (zh) * | 2022-02-21 | 2022-05-20 | 温州大学 | 一种铕金属有机配合物及其制备方法和作为pH荧光探针的应用 |
CN114516886B (zh) * | 2022-02-21 | 2023-06-13 | 温州大学 | 一种铕金属有机配合物及其制备方法和作为pH荧光探针的应用 |
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CN105949226B (zh) | 2017-09-29 |
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